1 00:00:01,000 --> 00:00:04,000 The following content is provided by MIT OpenCourseWare 2 00:00:04,000 --> 00:00:06,000 under a Creative Commons license. 3 00:00:06,000 --> 00:00:10,000 Additional information about our license and MIT 4 00:00:10,000 --> 00:00:15,000 OpenCourseWare in general is available at ocw.mit.edu. 5 00:00:15,000 --> 00:00:17,000 Great. Well, let's get going. 6 00:00:17,000 --> 00:00:22,000 Last time we ended up by discovering the electron. 7 00:00:22,000 --> 00:00:27,000 We discovered the fact that the atom was not the most basic 8 00:00:27,000 --> 00:00:33,000 constituent of matter. But in 1911 there was another 9 00:00:33,000 --> 00:00:38,000 discovery concerning the atom, and this is by Ernest 10 00:00:38,000 --> 00:00:43,000 Rutherford in England. And what Rutherford was 11 00:00:43,000 --> 00:00:49,000 interested in doing was studying the emission from the newly 12 00:00:49,000 --> 00:00:54,000 discovered radioactive elements such as radium. 13 00:00:54,000 --> 00:00:59,000 And so he borrowed, or he got, from Marie Curie, 14 00:00:59,000 --> 00:01:05,000 some radium bromide. And radium bromide was known to 15 00:01:05,000 --> 00:01:09,000 emit something called alpha particles. 16 00:01:09,000 --> 00:01:14,000 And they didn't really know what these alpha particles were. 17 00:01:14,000 --> 00:01:20,000 Now, they did know that the alpha particles were heavy, 18 00:01:20,000 --> 00:01:24,000 they were charged and that they were pretty energetic. 19 00:01:24,000 --> 00:01:30,000 That is what was known. Of course, today we know these 20 00:01:30,000 --> 00:01:34,000 alpha particles to be nothing other than helium with two 21 00:01:34,000 --> 00:01:38,000 electrons removed from the helium, helium double plus. 22 00:01:38,000 --> 00:01:42,000 Rutherford is in the lab and has this radium bromide, 23 00:01:42,000 --> 00:01:47,000 alpha particles being emitted and has some kind of detector 24 00:01:47,000 --> 00:01:50,000 out here to detect those alpha particles. 25 00:01:50,000 --> 00:01:55,000 And he measures a rate at which the alpha particles touch his 26 00:01:55,000 --> 00:02:00,000 detector. And it is about 132,000 alpha 27 00:02:00,000 --> 00:02:05,000 particles per minute. That's nice. 28 00:02:05,000 --> 00:02:12,000 Then what he does is takes a piece of gold foil and puts it 29 00:02:12,000 --> 00:02:19,000 in between the radium bromide emitter and the detector. 30 00:02:19,000 --> 00:02:26,000 And that gold foil is actually really very thin. 31 00:02:26,000 --> 00:02:32,000 It is 2x10^-5 inches. Two orders of magnitude thinner 32 00:02:32,000 --> 00:02:38,000 than the diameter of your hair. I often wonder how he handled 33 00:02:38,000 --> 00:02:42,000 that, but he did it. He put it in the middle here 34 00:02:42,000 --> 00:02:48,000 and then went to count the count rate as a result of putting this 35 00:02:48,000 --> 00:02:54,000 foil there, and the count rate is 132,000 alpha particles per 36 00:02:54,000 --> 00:02:57,000 minute. It didn't seem like that gold 37 00:02:57,000 --> 00:03:02,000 foil did anything. The alpha particles were just 38 00:03:02,000 --> 00:03:05,000 going right through to the detector. 39 00:03:05,000 --> 00:03:09,000 It didn't even seem to matter that there was that gold foil. 40 00:03:09,000 --> 00:03:13,000 The post-doc that was working on it, Geiger, 41 00:03:13,000 --> 00:03:16,000 of the Geiger Counter, was actually disappointed. 42 00:03:16,000 --> 00:03:19,000 Gee, that is a boring experiment. 43 00:03:19,000 --> 00:03:23,000 But Geiger was even a little bit more unhappy because he had 44 00:03:23,000 --> 00:03:27,000 this undergraduate hanging around the lab, 45 00:03:27,000 --> 00:03:31,000 this undergraduate named Marsden. 46 00:03:31,000 --> 00:03:34,000 And Marsden was really enthusiastic about doing 47 00:03:34,000 --> 00:03:37,000 something in the lab. He really wanted to do 48 00:03:37,000 --> 00:03:40,000 something. And Geiger, you know, 49 00:03:40,000 --> 00:03:42,000 what am I going to do with this kid? 50 00:03:42,000 --> 00:03:47,000 Geiger goes to Rutherford, look, this kid really wants to 51 00:03:47,000 --> 00:03:50,000 do something. What should I have him do? 52 00:03:50,000 --> 00:03:53,000 And Rutherford said, well, what you should have him 53 00:03:53,000 --> 00:03:58,000 do is take this detector and have him build it so that it can 54 00:03:58,000 --> 00:04:03,000 be swung around. So that it can be positioned 55 00:04:03,000 --> 00:04:05,000 here. So that we can check to see 56 00:04:05,000 --> 00:04:09,000 whether or not any of these alpha particles are 57 00:04:09,000 --> 00:04:12,000 backscattered, scattered back into the 58 00:04:12,000 --> 00:04:17,000 direction from which they came. And Geiger went away and 59 00:04:17,000 --> 00:04:20,000 thought, good, this is something to give the 60 00:04:20,000 --> 00:04:23,000 undergraduate. This is a ridiculous 61 00:04:23,000 --> 00:04:27,000 experiment. We know all the particles are 62 00:04:27,000 --> 00:04:31,000 going right through the detector. 63 00:04:31,000 --> 00:04:33,000 Okay. But Marsden was real happy. 64 00:04:33,000 --> 00:04:38,000 He gets to build this detector. He swings it around and gets 65 00:04:38,000 --> 00:04:41,000 Geiger there to do the first experiment. 66 00:04:41,000 --> 00:04:45,000 He puts the radium bromide and they listen and hear tick, 67 00:04:45,000 --> 00:04:48,000 tick, tick, tick, tick, tick. 68 00:04:48,000 --> 00:04:50,000 Geiger says, "Oh, it must just be 69 00:04:50,000 --> 00:04:53,000 background. Let me do a control experiment. 70 00:04:53,000 --> 00:04:58,000 Let me take the gold foil out of here so that all the 71 00:04:58,000 --> 00:05:03,000 particles have to be going in this direction." 72 00:05:03,000 --> 00:05:07,000 They take the gold foil out of there and listen, 73 00:05:07,000 --> 00:05:12,000 and they hear nothing. They put the gold foil back and 74 00:05:12,000 --> 00:05:14,000 they hear tick, tick, tick, tick, 75 00:05:14,000 --> 00:05:18,000 tick, tick. And they put a platinum foil in 76 00:05:18,000 --> 00:05:22,000 there and they hear tick, tick, tick, tick, 77 00:05:22,000 --> 00:05:25,000 tick, tick. Whatever metal they put in 78 00:05:25,000 --> 00:05:31,000 there, there were some particles coming off. 79 00:05:31,000 --> 00:05:35,000 And they got Rutherford down in the lab. 80 00:05:35,000 --> 00:05:39,000 Rutherford looks them over their shoulder. 81 00:05:39,000 --> 00:05:44,000 They do this again and again. Hey, it is real. 82 00:05:44,000 --> 00:05:47,000 It is real. And what is coming off? 83 00:05:47,000 --> 00:05:53,000 Well, the count rate is about 20 particles per minute. 84 00:05:53,000 --> 00:05:59,000 Not large but not zero. And the probability here of 85 00:05:59,000 --> 00:06:05,000 this backscattering is simply the number of particles 86 00:06:05,000 --> 00:06:08,000 backscattered, which is 20, 87 00:06:08,000 --> 00:06:14,000 over the total number of particles, or actually the count 88 00:06:14,000 --> 00:06:19,000 rate that the particles backscattered over the total 89 00:06:19,000 --> 00:06:23,000 incident count rate. That is 2x10^-4. 90 00:06:23,000 --> 00:06:26,000 That is not zero. Wow. 91 00:06:26,000 --> 00:06:32,000 Rutherford was excited. Rutherford later wrote, 92 00:06:32,000 --> 00:06:37,000 "It was quite the most incredible event that has ever 93 00:06:37,000 --> 00:06:42,000 happened to me in my life. It was almost as incredible as 94 00:06:42,000 --> 00:06:48,000 if you fired a 15 inch shell at a piece of tissue paper and it 95 00:06:48,000 --> 00:06:53,000 came back and hit you." What was the interpretation? 96 00:06:53,000 --> 00:06:59,000 The interpretation was the gold atoms that make up this foil, 97 00:06:59,000 --> 00:07:05,000 they must be mostly empty. Now, they knew that those atoms 98 00:07:05,000 --> 00:07:10,000 had some electrons in it because the electron had already been 99 00:07:10,000 --> 00:07:14,000 discovered. But these alpha particles seem 100 00:07:14,000 --> 00:07:19,000 to be going right through those gold atoms, for the most part. 101 00:07:19,000 --> 00:07:24,000 The atom, which he knew to be a diameter of about 10^-10 meters, 102 00:07:24,000 --> 00:07:30,000 most of that atom must be empty was the conclusion. 103 00:07:30,000 --> 00:07:35,000 But occasionally these helium double plus ions, 104 00:07:35,000 --> 00:07:40,000 these alpha particles, hit something massive. 105 00:07:40,000 --> 00:07:46,000 And that something massive then scatters those helium ions into 106 00:07:46,000 --> 00:07:49,000 the direction from which they came. 107 00:07:49,000 --> 00:07:55,000 And since that probability is small, well, the size of this 108 00:07:55,000 --> 00:08:01,000 massive part has to be really pretty small. 109 00:08:01,000 --> 00:08:05,000 And from knowing the probabilities and knowing 110 00:08:05,000 --> 00:08:11,000 roughly what the diameter of the atoms were and how many layers 111 00:08:11,000 --> 00:08:15,000 of atoms he had, he was able to back out of 112 00:08:15,000 --> 00:08:20,000 those experiments a diameter for this massive part of 10^-14 113 00:08:20,000 --> 00:08:24,000 meters. And he called this massive part 114 00:08:24,000 --> 00:08:28,000 the nucleus. He called it the nucleus in 115 00:08:28,000 --> 00:08:33,000 analogy to the nucleus of a living cell. 116 00:08:33,000 --> 00:08:36,000 The heavy part, the dense part in a living 117 00:08:36,000 --> 00:08:41,000 cell-- that is where the name "nucleus" comes from. 118 00:08:41,000 --> 00:08:46,000 Now, Rutherford also realized that this nucleus here has to be 119 00:08:46,000 --> 00:08:50,000 positively charged. He knew about electrons and 120 00:08:50,000 --> 00:08:55,000 knew the atoms then were neutral, and so he reasoned this 121 00:08:55,000 --> 00:09:00,000 nucleus had to be positively charged. 122 00:09:00,000 --> 00:09:05,000 And then he did a bunch more experiments, more sophisticated 123 00:09:05,000 --> 00:09:10,000 experiments in which he actually measured here the angular 124 00:09:10,000 --> 00:09:15,000 distribution of the helium ion scattered from the nucleus. 125 00:09:15,000 --> 00:09:20,000 And from those very detailed measurements of the angular 126 00:09:20,000 --> 00:09:24,000 distribution, he was able to back out the 127 00:09:24,000 --> 00:09:28,000 fact that this nucleus, the charge on it was actually 128 00:09:28,000 --> 00:09:34,000 plus Z times e. Z is the atomic number. 129 00:09:34,000 --> 00:09:38,000 e is the unit charge. He did a bunch of different 130 00:09:38,000 --> 00:09:43,000 metals and was able to establish that the nucleus had a charge of 131 00:09:43,000 --> 00:09:48,000 plus Z times e. His model is that there is a 132 00:09:48,000 --> 00:09:50,000 very dense center, 10^-14 meters. 133 00:09:50,000 --> 00:09:55,000 This diameter of the nucleus is something that every MIT 134 00:09:55,000 --> 00:10:01,000 undergraduate should know. And he realized that then the 135 00:10:01,000 --> 00:10:05,000 electrons have to fill out the rest of this volume. 136 00:10:05,000 --> 00:10:09,000 That was his interpretation from these results. 137 00:10:09,000 --> 00:10:14,000 And think about Marsden, what a great UROP experiment. 138 00:10:14,000 --> 00:10:17,000 He discovered the nucleus. Isn't that great? 139 00:10:17,000 --> 00:10:22,000 Marsden had a long and successful career as a scientist 140 00:10:22,000 --> 00:10:26,000 also after that. Now, I should also tell you 141 00:10:26,000 --> 00:10:31,000 that this backscattering experiment is really the essence 142 00:10:31,000 --> 00:10:36,000 of how a quark was discovered. Quark are the fundamental 143 00:10:36,000 --> 00:10:40,000 elementary particles in protons and neutrons. 144 00:10:40,000 --> 00:10:42,000 Essentially, they took a high energy 145 00:10:42,000 --> 00:10:46,000 particle, scattered it through the proton or the neutron, 146 00:10:46,000 --> 00:10:49,000 and it backscatters. And, in that way, 147 00:10:49,000 --> 00:10:53,000 they discovered the quark and measured the diameter of the 148 00:10:53,000 --> 00:10:55,000 quark. And this was done by a couple 149 00:10:55,000 --> 00:11:00,000 of my colleagues in the Physics Department. 150 00:11:00,000 --> 00:11:05,000 Jerry Friedman and Henry Kendall, who has since passed 151 00:11:05,000 --> 00:11:09,000 away. Jerry Friedman is still around. 152 00:11:09,000 --> 00:11:13,000 He loves to talk to undergraduates, 153 00:11:13,000 --> 00:11:18,000 and many of you will get that opportunity. 154 00:11:18,000 --> 00:11:24,000 Now it is time for us to do our own Rutherford backscattering 155 00:11:24,000 --> 00:11:26,000 experiment. Yeah. 156 00:11:26,000 --> 00:11:31,000 [APPLAUSE] Here is our gold lattice. 157 00:11:31,000 --> 00:11:35,000 These Styrofoam balls are the gold nuclei. 158 00:11:35,000 --> 00:11:39,000 The space around them are the electrons. 159 00:11:39,000 --> 00:11:44,000 These things in the center here are just the posts on this 160 00:11:44,000 --> 00:11:48,000 frame. [LAUGHTER] This is a piece of 161 00:11:48,000 --> 00:11:52,000 equipment from my lab that I pressed into service, 162 00:11:52,000 --> 00:11:58,000 and so I couldn't cut these posts away because I would have 163 00:11:58,000 --> 00:12:04,000 trouble taking my manipulator out of my machine at a later 164 00:12:04,000 --> 00:12:08,000 time. So they are just there. 165 00:12:08,000 --> 00:12:11,000 But this is our one monolayer of gold nuclei. 166 00:12:11,000 --> 00:12:17,000 And so what are we going to do? Well, what we are going to do 167 00:12:17,000 --> 00:12:22,000 is try to measure the diameter of these Styrofoam balls in the 168 00:12:22,000 --> 00:12:27,000 same way that Rutherford did. And so we are going to need 169 00:12:27,000 --> 00:12:34,000 some alpha particles. What are we going to use for an 170 00:12:34,000 --> 00:12:39,000 alpha particle? Well, we have some ping-pong 171 00:12:39,000 --> 00:12:44,000 balls for alpha particles. Let's do that. 172 00:12:44,000 --> 00:12:51,000 We have 287 alpha particles, or ping-pong balls, 173 00:12:51,000 --> 00:13:00,000 and we are going to measure the probability of backscattering. 174 00:13:00,000 --> 00:13:04,000 The probability of backscattering will be the 175 00:13:04,000 --> 00:13:10,000 number that actually backscatter divided by the number that we 176 00:13:10,000 --> 00:13:16,000 throw, or the total number. That is what we are going to 177 00:13:16,000 --> 00:13:19,000 measure. But now I have to take this 178 00:13:19,000 --> 00:13:25,000 probability and I have to relate it to the diameter of these 179 00:13:25,000 --> 00:13:30,000 nuclei. How am I going to do that? 180 00:13:30,000 --> 00:13:36,000 Well, that probability is going to be equal to the total surface 181 00:13:36,000 --> 00:13:42,000 area of the crystal here. I have already measured the 182 00:13:42,000 --> 00:13:47,000 total area. I know that the total area is 183 00:13:47,000 --> 00:13:52,000 2,148 square inches. That is in the denominator, 184 00:13:52,000 --> 00:14:00,000 but now the numerator is simply the total area of the nuclei. 185 00:14:00,000 --> 00:14:05,000 The total area of the nuclei is the area of one nucleus, 186 00:14:05,000 --> 00:14:09,000 A sub i, summed over the total number of 187 00:14:09,000 --> 00:14:13,000 nuclei, which I have already counted as 119. 188 00:14:13,000 --> 00:14:19,000 And so the total area is times the cross-sectional area 189 00:14:19,000 --> 00:14:25,000 here of any one of these nuclei. And that is pi d squared over 4. 190 00:14:25,000 --> 00:14:30,000 I can solve that equation, 191 00:14:30,000 --> 00:14:34,000 for the diameter, in terms of the probability. 192 00:14:34,000 --> 00:14:40,000 And when I solve that equation, d is equal to 4.79 times the 193 00:14:40,000 --> 00:14:45,000 probability to the one-half power. 194 00:14:45,000 --> 00:14:50,000 What we are going to do is measure this probability by 195 00:14:50,000 --> 00:14:55,000 throwing the ping-pong balls and calculating and determining how 196 00:14:55,000 --> 00:15:00,000 many backscatter. And then we are going to use 197 00:15:00,000 --> 00:15:05,000 that to get this diameter of the nuclei. 198 00:15:05,000 --> 00:15:09,000 The same experiment that was done to actually measure the 199 00:15:09,000 --> 00:15:14,000 diameter of the nucleus. Now you are going to do this 200 00:15:14,000 --> 00:15:18,000 experiment. Every one of you are going to 201 00:15:18,000 --> 00:15:21,000 get a ping-pong ball from the TAs. 202 00:15:21,000 --> 00:15:25,000 TAs, why don't you give out the ping-pong balls, 203 00:15:25,000 --> 00:15:30,000 and then I will give you some instructions. 204 00:15:30,000 --> 00:15:34,000 All right. The pi d squared over 4 205 00:15:34,000 --> 00:15:40,000 is the cross-sectional area in terms of the diameter of 206 00:15:40,000 --> 00:15:45,000 these balls. I just wrote it in terms of d 207 00:15:45,000 --> 00:15:48,000 instead of r. Yes? 208 00:16:00,000 --> 00:16:02,000 That is correct. Good point. 209 00:16:02,000 --> 00:16:06,000 That balls that we are throwing actually have size compared to 210 00:16:06,000 --> 00:16:11,000 in the case of the Rutherford backscattering experiment where 211 00:16:11,000 --> 00:16:15,000 the projectile was almost a point compared to the size of 212 00:16:15,000 --> 00:16:17,000 the nucleus. In our experiment, 213 00:16:17,000 --> 00:16:20,000 you are quite right, our balls are about the 214 00:16:20,000 --> 00:16:24,000 diameter there. And so, if we were doing a more 215 00:16:24,000 --> 00:16:27,000 exact experiment, we would do a little different 216 00:16:27,000 --> 00:16:31,000 calculation. We would take into 217 00:16:31,000 --> 00:16:37,000 consideration the size of the actual ball that we were 218 00:16:37,000 --> 00:16:40,000 throwing. But we are not going to do 219 00:16:40,000 --> 00:16:43,000 that. Because we are not throwing 220 00:16:43,000 --> 00:16:47,000 that many balls, we don't really have the 221 00:16:47,000 --> 00:16:53,000 statistics to do a more exacting kind of calculation. 222 00:16:53,000 --> 00:16:57,000 But you are quite right. Yes? 223 00:17:05,000 --> 00:17:08,000 Well, he didn't know. Although, he knew the fact that 224 00:17:08,000 --> 00:17:11,000 it was backscattering, that it had to be much, 225 00:17:11,000 --> 00:17:13,000 much less massive than the nucleus. 226 00:17:13,000 --> 00:17:18,000 I think that he also measured the energy of the backscattered 227 00:17:18,000 --> 00:17:19,000 particle. And from that, 228 00:17:19,000 --> 00:17:23,000 you can back out the fact that it is much less massive than the 229 00:17:23,000 --> 00:17:26,000 nucleus. There are a few other details, 230 00:17:26,000 --> 00:17:29,000 you are quite right, that I have left out in this 231 00:17:29,000 --> 00:17:35,000 discussion that he had to know in order to get this number. 232 00:17:35,000 --> 00:17:39,000 Here is the thing. You have to aim your alpha 233 00:17:39,000 --> 00:17:46,000 particles at this lattice. And then you have to watch your 234 00:17:46,000 --> 00:17:50,000 ball. [LAUGHTER] You have to watch to 235 00:17:50,000 --> 00:17:56,000 see if it scatters back at you, because at the end I am going 236 00:17:56,000 --> 00:18:02,000 to ask you if your ball backscattered. 237 00:18:02,000 --> 00:18:07,000 And we need an accurate count. Now, if you hit one of these 238 00:18:07,000 --> 00:18:11,000 things and it backscatters, that doesn't count. 239 00:18:11,000 --> 00:18:16,000 Only if it hits the Styrofoam ball does it count. 240 00:18:16,000 --> 00:18:20,000 If it hits the Styrofoam ball and goes through, 241 00:18:20,000 --> 00:18:25,000 that doesn't count. It literally has to backscatter 242 00:18:25,000 --> 00:18:30,000 at you. Was there a question over here? 243 00:18:30,000 --> 00:18:32,000 If you miss you miss. [LAUGHTER] Now, 244 00:18:32,000 --> 00:18:37,000 I do invite you to come a little closer so that you can at 245 00:18:37,000 --> 00:18:40,000 least hit the crystal. Yes? 246 00:18:47,000 --> 00:18:50,000 That is correct. Well, you have got a defect. 247 00:18:50,000 --> 00:18:55,000 These are a little bit lighter. Oh, you have some more here. 248 00:18:55,000 --> 00:18:57,000 Oh, okay. You can have a regular one. 249 00:18:57,000 --> 00:19:01,000 Anybody need one yet? I have a couple. 250 00:19:01,000 --> 00:19:03,000 Oh, all right. You need one? 251 00:19:03,000 --> 00:19:08,000 Because I need them all thrown. Did you have a question? 252 00:19:13,000 --> 00:19:15,000 What is the mean free path? 253 00:19:20,000 --> 00:19:25,000 That I am going to have to give you an expression for at some 254 00:19:25,000 --> 00:19:30,000 other time, but there is certainly a decay pathway. 255 00:19:30,000 --> 00:19:35,000 I have another ball here. Now, are you ready? 256 00:19:35,000 --> 00:19:43,000 You can come down closer, but now I have one piece of 257 00:19:43,000 --> 00:19:48,000 advice for you. That is, only fools aim for 258 00:19:48,000 --> 00:19:56,000 their chemistry professor. [LAUGHTER] Go to it. 259 00:20:53,000 --> 00:21:00,000 Did you throw your balls? You missed the crystal. 260 00:21:00,000 --> 00:21:05,000 All right. Has our supply of alpha 261 00:21:05,000 --> 00:21:11,000 particles been exhausted? All done? 262 00:21:11,000 --> 00:21:18,000 All right. [APPLAUSE] Now comes the big 263 00:21:18,000 --> 00:21:23,000 test. How many of you had an alpha 264 00:21:23,000 --> 00:21:33,000 particle that backscattered? Let's keep your hand high 265 00:21:33,000 --> 00:21:37,000 because I have to count accurately. 266 00:21:37,000 --> 00:21:42,000 In this section I see one. Two? 267 00:21:42,000 --> 00:21:43,000 Cheater. No. 268 00:21:43,000 --> 00:21:48,000 Two, three, four, five, six, seven, 269 00:21:48,000 --> 00:21:51,000 eight, nine, ten, eleven, 270 00:21:51,000 --> 00:21:58,000 twelve, thirteen. Did I get everybody? 271 00:22:03,000 --> 00:22:04,000 I got everybody? 13? 272 00:22:04,000 --> 00:22:09,000 Right, not deflection. If it hit and went through, 273 00:22:09,000 --> 00:22:15,000 that does not count. It has to come back at you. 274 00:22:20,000 --> 00:22:23,000 Yes. [LAUGHTER] That is right. 275 00:22:23,000 --> 00:22:27,000 All right. Does anybody want to change 276 00:22:27,000 --> 00:22:30,000 their count? 13 balls? 277 00:22:30,000 --> 00:22:34,000 I am sorry? If it just hit it and moved but 278 00:22:34,000 --> 00:22:38,000 did not backscatter, it does not count. 279 00:22:38,000 --> 00:22:43,000 The nuclei will move. They will move, 280 00:22:43,000 --> 00:22:48,000 certainly, because there is a momentum transfer. 281 00:22:48,000 --> 00:22:51,000 Well, not quite like that. No. 282 00:22:51,000 --> 00:22:55,000 We have 13 balls that backscattered? 283 00:22:55,000 --> 00:23:00,000 Okay. Let's see what we got. 284 00:23:05,000 --> 00:23:13,000 The probability, here, then, is 13 over 287. 285 00:23:13,000 --> 00:23:16,000 That probability is equal to 286 00:23:19,000 --> 00:23:29,000 If I now that this probability and plug it into here, 287 00:23:29,000 --> 00:23:40,000 what we are going to get is a diameter of 1.0 inches. 288 00:23:40,000 --> 00:23:48,000 And the diameter on the average of those particles is about 0.85 289 00:23:48,000 --> 00:23:52,000 inches. You did a really pretty good 290 00:23:52,000 --> 00:23:56,000 job. You got the diameter of the 291 00:23:56,000 --> 00:24:00,000 nucleus. [APPLAUSE] 292 00:24:00,000 --> 00:24:04,000 That is great. And that is the way the nuclear 293 00:24:04,000 --> 00:24:07,000 diameter was, in fact, measured and 294 00:24:07,000 --> 00:24:11,000 discovered. But now we have the problem 295 00:24:11,000 --> 00:24:16,000 that the scientists had in 1912, and that is what is the 296 00:24:16,000 --> 00:24:21,000 structure of the atom? We now know it has a nucleus. 297 00:24:21,000 --> 00:24:25,000 It has an electron. How do they hang together? 298 00:24:25,000 --> 00:24:31,000 Where are they in the atom? We are going to talk about the 299 00:24:31,000 --> 00:24:35,000 classical description here of the atom. 300 00:24:35,000 --> 00:24:39,000 And the first question that we have to ask is, 301 00:24:39,000 --> 00:24:45,000 what is the force that keeps the electron and the nucleus 302 00:24:45,000 --> 00:24:49,000 together? What are the four fundamental 303 00:24:49,000 --> 00:24:51,000 forces? Gravity is one. 304 00:24:51,000 --> 00:24:55,000 And that is the strongest or the weakest? 305 00:24:55,000 --> 00:24:56,000 Weakest. Gravity. 306 00:24:56,000 --> 00:25:01,000 Next stronger force? Electromagnetic. 307 00:25:01,000 --> 00:25:05,000 I will just abbreviate it EM. Next stronger force? 308 00:25:05,000 --> 00:25:06,000 Weak force. And the next? 309 00:25:06,000 --> 00:25:08,000 Strong. Weak and strong are 310 00:25:08,000 --> 00:25:12,000 intranuclear forces. They are operable between the 311 00:25:12,000 --> 00:25:17,000 protons, the neutrons and the other elementary particles that 312 00:25:17,000 --> 00:25:20,000 make up the nucleus. It does not have a lot of 313 00:25:20,000 --> 00:25:24,000 effect, the weak and the strong force, on chemistry, 314 00:25:24,000 --> 00:25:30,000 except for beta emission for the radioactive elements. 315 00:25:30,000 --> 00:25:36,000 Gravity actually does have no known chemical significance to 316 00:25:36,000 --> 00:25:40,000 chemistry. And so all of chemistry is tied 317 00:25:40,000 --> 00:25:45,000 up here in the electromagnetic force, which I am, 318 00:25:45,000 --> 00:25:50,000 at the moment, going to simplify and just call 319 00:25:50,000 --> 00:25:55,000 the Coulomb force. Now, we know how to describe 320 00:25:55,000 --> 00:26:01,000 the Coulomb force between charged particles. 321 00:26:01,000 --> 00:26:03,000 We know what expression to write down. 322 00:26:03,000 --> 00:26:06,000 Let's do that. If we have the nucleus, 323 00:26:06,000 --> 00:26:09,000 which is positively charged, and the electron here, 324 00:26:09,000 --> 00:26:13,000 which is negatively charged, and they are at some distance r 325 00:26:13,000 --> 00:26:16,000 between each other, the expression that describes 326 00:26:16,000 --> 00:26:20,000 how that force of interaction changes with distance, 327 00:26:20,000 --> 00:26:24,000 this Coulomb's force law, it is just the magnitude of the 328 00:26:24,000 --> 00:26:28,000 charge of the electron times the magnitude of the charge on the 329 00:26:28,000 --> 00:26:31,000 nucleus over 4 pi epsilon nought times r squared. 330 00:26:36,000 --> 00:26:40,000 I am going to just treat the force as a scalar, 331 00:26:40,000 --> 00:26:43,000 just for simplicity purposes here. 332 00:26:43,000 --> 00:26:47,000 Epsilon nought is the permittivity of vacuum. 333 00:26:47,000 --> 00:26:51,000 It is a factor in there for unit conversation. 334 00:26:51,000 --> 00:26:56,000 r, then, is the distance between the electron and the 335 00:26:56,000 --> 00:27:00,000 nucleus. What does this say? 336 00:27:00,000 --> 00:27:03,000 Well, this says that when r goes to infinity, 337 00:27:03,000 --> 00:27:06,000 what is the force? Zero. 338 00:27:06,000 --> 00:27:09,000 The particles are infinitely far apart. 339 00:27:09,000 --> 00:27:13,000 There is no force between them. In this case, 340 00:27:13,000 --> 00:27:16,000 an attractive force between them. 341 00:27:16,000 --> 00:27:20,000 When r is equal to zero, what is the force? 342 00:27:20,000 --> 00:27:23,000 Infinite. And anywhere in between, 343 00:27:23,000 --> 00:27:28,000 that force is described by this one over r squared 344 00:27:28,000 --> 00:27:33,000 dependence. You can see that as the 345 00:27:33,000 --> 00:27:39,000 particles come closer and closer together, the force between them 346 00:27:39,000 --> 00:27:42,000 gets larger and larger. The closer they get, 347 00:27:42,000 --> 00:27:47,000 the larger the force, the more they want to be 348 00:27:47,000 --> 00:27:50,000 together. This expression is just telling 349 00:27:50,000 --> 00:27:56,000 me, if I held one particle and the other particle in my hand, 350 00:27:56,000 --> 00:28:02,000 and I held them at some distance from each other -- 351 00:28:02,000 --> 00:28:06,000 That expression is just telling me the force with which I have 352 00:28:06,000 --> 00:28:09,000 to kind of exert to keep them apart. 353 00:28:09,000 --> 00:28:14,000 But now, if I let them go, you know what is going to 354 00:28:14,000 --> 00:28:16,000 happen. They are going to come 355 00:28:16,000 --> 00:28:19,000 together. They are going to want to come 356 00:28:19,000 --> 00:28:23,000 together because of that force. And what is not in this 357 00:28:23,000 --> 00:28:27,000 expression? What is not in that expression 358 00:28:27,000 --> 00:28:31,000 is any information about how those particles move under 359 00:28:31,000 --> 00:28:37,000 influence of that force. Nowhere in this expression is 360 00:28:37,000 --> 00:28:42,000 there an r of t, how that distance changes with 361 00:28:42,000 --> 00:28:45,000 time. And so what we need to describe 362 00:28:45,000 --> 00:28:48,000 that is a force law. And in 1911, 363 00:28:48,000 --> 00:28:52,000 the force law that seemed to describe the motion of all 364 00:28:52,000 --> 00:28:56,000 bodies, including astronomical ones, of course, 365 00:28:56,000 --> 00:29:01,000 the equation of motion that described how bodies move are 366 00:29:01,000 --> 00:29:06,000 Newton's equations of motion. And, in particular, 367 00:29:06,000 --> 00:29:09,000 F equals ma. And, of course, 368 00:29:09,000 --> 00:29:13,000 I can write that acceleration as a time derivative of the 369 00:29:13,000 --> 00:29:16,000 velocity, dv over dt. 370 00:29:16,000 --> 00:29:19,000 And that velocity, of course, itself is a change 371 00:29:19,000 --> 00:29:22,000 in the position with respect to time. 372 00:29:22,000 --> 00:29:26,000 This is m, the second derivative of r with respect to 373 00:29:26,000 --> 00:29:30,000 time. 374 00:29:30,000 --> 00:29:34,000 If I know the force that is operation, which is this, 375 00:29:34,000 --> 00:29:39,000 I can take this and plug it in here, and I am going to have a 376 00:29:39,000 --> 00:29:44,000 differential equation. And that differential equation 377 00:29:44,000 --> 00:29:49,000 is going to allow me to solve for what r is as a function of 378 00:29:49,000 --> 00:29:53,000 time, the distance between the two particles. 379 00:29:53,000 --> 00:29:58,000 And it is going to allow me to solve for that distance in a way 380 00:29:58,000 --> 00:30:03,000 that we call deterministic, exactly. 381 00:30:03,000 --> 00:30:06,000 In other words, if I know where the particles 382 00:30:06,000 --> 00:30:11,000 are to start with, using this equation of motion, 383 00:30:11,000 --> 00:30:14,000 this force law, I can tell you where those 384 00:30:14,000 --> 00:30:19,000 particles are going to be for all future time exactly. 385 00:30:19,000 --> 00:30:23,000 It is deterministic, the classical mechanical 386 00:30:23,000 --> 00:30:26,000 approach. Now, in order to solve this 387 00:30:26,000 --> 00:30:31,000 differential equation, I am going to have to develop a 388 00:30:31,000 --> 00:30:36,000 model for the atom. All differential equations, 389 00:30:36,000 --> 00:30:40,000 for the most part, describing physical processes 390 00:30:40,000 --> 00:30:44,000 are going to need a model. They are going to need some 391 00:30:44,000 --> 00:30:48,000 boundary conditions or initial conditions. 392 00:30:48,000 --> 00:30:52,000 And the model, of course, that came to mind 393 00:30:52,000 --> 00:30:55,000 for the atom, is one in which the nucleus is 394 00:30:55,000 --> 00:31:00,000 in the center. And the electron moves around 395 00:31:00,000 --> 00:31:06,000 that nucleus with uniform circular motion and with a fixed 396 00:31:06,000 --> 00:31:09,000 radius. We are going to call that fixed 397 00:31:09,000 --> 00:31:14,000 radius r star. It is a planetary model. 398 00:31:14,000 --> 00:31:19,000 That seems like a good guess for the structure of the atom. 399 00:31:19,000 --> 00:31:25,000 Now, if you have a particle undergoing uniform circular 400 00:31:25,000 --> 00:31:30,000 motion at some well-defined radius here. 401 00:31:30,000 --> 00:31:34,000 That particle is being constantly accelerated. 402 00:31:34,000 --> 00:31:40,000 And I can write that acceleration a as the linear 403 00:31:40,000 --> 00:31:45,000 velocity squared over that radius of its orbit. 404 00:31:45,000 --> 00:31:51,000 It is being accelerated because the velocity 405 00:31:51,000 --> 00:31:55,000 vector. The direction is changing, 406 00:31:55,000 --> 00:32:00,000 so there is a constant acceleration. 407 00:32:00,000 --> 00:32:02,000 Now, this expression, for many of you, 408 00:32:02,000 --> 00:32:06,000 I pulled out of the air. Some of you have seen it 409 00:32:06,000 --> 00:32:08,000 before. It is an 8.01 topic. 410 00:32:08,000 --> 00:32:13,000 You are going to see it this semester, but later on and in 411 00:00:08,010 --> 00:32:15,000 You are not responsible for 412 00:32:15,000 --> 00:32:19,000 this right now here, but you will recall later on 413 00:32:19,000 --> 00:32:23,000 this semester that you have seen it here in 5.112. 414 00:32:23,000 --> 00:32:26,000 But, if this is the acceleration, 415 00:32:26,000 --> 00:32:30,000 I can take this expression for the acceleration and plug it 416 00:32:30,000 --> 00:32:36,000 into here. Plug in my operating force law. 417 00:32:36,000 --> 00:32:42,000 And, in so doing, I am going to get -- 418 00:32:50,000 --> 00:32:56,000 -- e squared over 4 pi epsilon nought r star squared. 419 00:33:00,000 --> 00:33:04,000 That is the F. Mass times the acceleration, 420 00:33:04,000 --> 00:33:09,000 m times v squared over r star. That is my equation of motion 421 00:33:09,000 --> 00:33:14,000 particular to this problem of a planetary model. 422 00:33:14,000 --> 00:33:20,000 And now I can solve that for v squared, the linear velocity of 423 00:33:20,000 --> 00:33:23,000 that electron going around the nucleus. 424 00:33:23,000 --> 00:33:29,000 That comes out to be e squared over 4 pi epsilon nought m r 425 00:33:29,000 --> 00:33:34,000 star. 426 00:33:34,000 --> 00:33:39,000 Now, the reason I wanted to calculate the velocity squared 427 00:33:39,000 --> 00:33:44,000 here is because I want to calculate kinetic energy. 428 00:33:44,000 --> 00:33:47,000 And that is easy to do. Kinetic energy, 429 00:33:47,000 --> 00:33:51,000 I will call K, is one-half m times v squared. 430 00:33:51,000 --> 00:33:57,000 If I plug in the v squared right in there, 431 00:33:57,000 --> 00:34:03,000 I get one-half e squared over 4 pi epsilon nought r star. 432 00:34:03,000 --> 00:34:10,000 So far, everything looks okay. 433 00:34:10,000 --> 00:34:15,000 We have a planetary model. Coulomb's law is operable. 434 00:34:15,000 --> 00:34:21,000 We know the acceleration. We just calculated the kinetic 435 00:34:21,000 --> 00:34:26,000 energy of this electron going around the nucleus. 436 00:34:26,000 --> 00:34:33,000 What I want to do now is I want to know the total energy of the 437 00:34:33,000 --> 00:34:37,000 system. I just calculated the kinetic 438 00:34:37,000 --> 00:34:42,000 energy of the system, but I want to know the total 439 00:34:42,000 --> 00:34:47,000 energy of the system. And the total energy of the 440 00:34:47,000 --> 00:34:52,000 system, I am going to call this capital E, total energy, 441 00:34:52,000 --> 00:34:58,000 is the kinetic energy plus the potential energy. 442 00:34:58,000 --> 00:35:02,000 And I want the total energy of the system for two reasons. 443 00:35:02,000 --> 00:35:06,000 One is I want to show you that the system is bound, 444 00:35:06,000 --> 00:35:10,000 that the total energy is going to be negative, 445 00:35:10,000 --> 00:35:15,000 that it is lower than the total energy when the electron and the 446 00:35:15,000 --> 00:35:19,000 nucleus are separated. I want to show you that within 447 00:35:19,000 --> 00:35:23,000 this classical model, the electron and the nucleus do 448 00:35:23,000 --> 00:35:26,000 look bound. To do that, I need to show you 449 00:35:26,000 --> 00:35:32,000 the total energy is negative. To do that, I need to calculate 450 00:35:32,000 --> 00:35:36,000 the potential energy. That is what I want to do. 451 00:35:36,000 --> 00:35:41,000 Secondly, I want to get an expression for the total energy. 452 00:35:41,000 --> 00:35:47,000 Because, using that expression, I am going to show you how this 453 00:35:47,000 --> 00:35:51,000 classical mechanics fails. How Newton's equations of 454 00:35:51,000 --> 00:35:55,000 motion won't work to describe this problem. 455 00:35:55,000 --> 00:36:01,000 Now, I have run out of time. I will do that on Monday, 456 00:36:01,000 --> 00:36:04,000 but that is where we are going. All right. 457 00:36:04,892 --> 00:36:07,000 See you on Monday.