1 00:00:01,000 --> 00:00:04,000 The following content is provided by MIT OpenCourseWare 2 00:00:04,000 --> 00:00:06,000 under a Creative Commons license. 3 00:00:06,000 --> 00:00:10,000 Additional information about our license and MIT 4 00:00:10,000 --> 00:00:15,000 OpenCourseWare in general is available at ocw.mit.edu. 5 00:00:15,000 --> 00:00:17,000 Where were we, last time? 6 00:00:17,000 --> 00:00:22,000 Last time, we said we were setting aside the problem of the 7 00:00:22,000 --> 00:00:26,000 structure of the atom. We were setting it aside 8 00:00:26,000 --> 00:00:30,000 because we were stuck, and what we had to do was to 9 00:00:30,000 --> 00:00:34,000 look at another area of discussion. 10 00:00:34,000 --> 00:00:38,000 And that is this wave-particle duality of light and matter, 11 00:00:38,000 --> 00:00:43,000 because it is that discussion that is going to give us the 12 00:00:43,000 --> 00:00:48,000 clues about how to proceed. We are putting aside the 13 00:00:48,000 --> 00:00:53,000 discussion of the structure of the atom all the way until next 14 00:00:53,000 --> 00:00:57,000 Wednesday, because next Monday, I was reminded, 15 00:00:57,000 --> 00:01:10,000 is a student holiday. [APPLAUSE] 16 00:01:10,000 --> 00:01:14,000 And so we started. We talked about the wave-like 17 00:01:14,000 --> 00:01:19,000 properties of light. We said that the property of 18 00:01:19,000 --> 00:01:23,000 superposition, the fact that you can put waves 19 00:01:23,000 --> 00:01:29,000 at the same point in space and their amplitudes add. 20 00:01:29,000 --> 00:01:33,000 Since waves have both positive and negative amplitude, 21 00:01:33,000 --> 00:01:37,000 that means that you have constructive and destructive 22 00:01:37,000 --> 00:01:40,000 interference. And it is those interference 23 00:01:40,000 --> 00:01:43,000 phenomena, then, that are evidence for wave-like 24 00:01:43,000 --> 00:01:46,000 property. And we did the two-slit 25 00:01:46,000 --> 00:01:50,000 experiment to try to give you an example of interference 26 00:01:50,000 --> 00:01:53,000 phenomena. We were trying to understand 27 00:01:53,000 --> 00:01:57,000 those interference phenomena, and did so in terms of this 28 00:01:57,000 --> 00:02:02,000 diagram here. The interference phenomena that 29 00:02:02,000 --> 00:02:07,000 we saw was an array, actually a row of bright spots, 30 00:02:07,000 --> 00:02:10,000 dark spots, bright spots, dark spots. 31 00:02:10,000 --> 00:02:15,000 And we drew these semicircles here around each one of the 32 00:02:15,000 --> 00:02:18,000 slits. They represent a little bit of 33 00:02:18,000 --> 00:02:22,000 the wave that emanated through those slits. 34 00:02:22,000 --> 00:02:27,000 Because those slits are small, then, those waves emanated 35 00:02:27,000 --> 00:02:33,000 equally in all directions. That is why these semicircles 36 00:02:33,000 --> 00:02:37,000 represent the wave maxima. And what we discovered is that 37 00:02:37,000 --> 00:02:42,000 if we looked along this line here, this line which led to 38 00:02:42,000 --> 00:02:45,000 this bright spot, that all of the waves along 39 00:02:45,000 --> 00:02:48,000 this line were constructively interfering. 40 00:02:48,000 --> 00:02:53,000 That is, we had the maximum of the two waves at the same point 41 00:02:53,000 --> 00:02:58,000 in space, or the minimum of the two waves at the same point in 42 00:02:58,000 --> 00:03:02,000 space. And we noticed that everywhere 43 00:03:02,000 --> 00:03:05,000 along this line, where we had that constructive 44 00:03:05,000 --> 00:03:08,000 interference, the difference in the distance 45 00:03:08,000 --> 00:03:10,000 of the waves traveled was one lambda. 46 00:03:10,000 --> 00:03:13,000 We noticed, here, that everywhere along this line 47 00:03:13,000 --> 00:03:17,000 that led to a very bright spot, we had constructive 48 00:03:17,000 --> 00:03:20,000 interference. And the difference in distance 49 00:03:20,000 --> 00:03:23,000 traveled by those two waves was two lambda. 50 00:03:23,000 --> 00:03:25,000 And, likewise, up here, along this line, 51 00:03:25,000 --> 00:03:31,000 the difference in the distance traveled was zero lambda. 52 00:03:31,000 --> 00:03:34,000 And from just that, in a sense, qualitative 53 00:03:34,000 --> 00:03:37,000 observation, we drew a conclusion. 54 00:03:37,000 --> 00:03:41,000 And that conclusion was in order to get maximum 55 00:03:41,000 --> 00:03:46,000 constructive interference, a condition that had obtain, 56 00:03:46,000 --> 00:03:50,000 is that the difference in the distance traveled by the two 57 00:03:50,000 --> 00:03:55,000 waves has to be an integral multiple of the wavelength. 58 00:03:55,000 --> 00:03:59,000 N could be 0, 1, 2, 3, etc. 59 00:03:59,000 --> 00:04:03,000 And so, the very bright spot here that always bisects the two 60 00:04:03,000 --> 00:04:06,000 slits, since N is 0, we call that the zero-order 61 00:04:06,000 --> 00:04:10,000 interference feature, or the zero-order fraction 62 00:04:10,000 --> 00:04:13,000 feature. The bright spot that is either 63 00:04:13,000 --> 00:04:17,000 to the left or to the right or up or down of that center bright 64 00:04:17,000 --> 00:04:21,000 spot is the first-order diffraction feature or the 65 00:04:21,000 --> 00:04:23,000 first-order interference feature. 66 00:04:23,000 --> 00:04:28,000 And then the second bright spot up or down from the center is a 67 00:04:28,000 --> 00:04:32,000 second-order diffraction feature. 68 00:04:32,000 --> 00:04:35,000 And so on and so on. And in recitation section, 69 00:04:35,000 --> 00:04:40,000 what you also should have done, is you should have reasoned 70 00:04:40,000 --> 00:04:45,000 through what the condition was for destructive interference. 71 00:04:45,000 --> 00:04:50,000 That is in between these bright spots, you have dark spots as a 72 00:04:50,000 --> 00:04:53,000 result of destructive interference. 73 00:04:53,000 --> 00:04:58,000 And that results because, say, right here you get a dark 74 00:04:58,000 --> 00:05:02,000 spot -- Right here at that point you 75 00:05:02,000 --> 00:05:07,000 would see the maximum of one wave at the same point in space 76 00:05:07,000 --> 00:05:12,000 as the minimum of the other, and so they exactly cancel. 77 00:05:12,000 --> 00:05:17,000 And so by just analyzing what waves were destructively 78 00:05:17,000 --> 00:05:21,000 interfering, you should have come up with a general 79 00:05:21,000 --> 00:05:24,000 expression for destructive interference, 80 00:05:24,000 --> 00:05:27,000 of N plus one-half, that quanity, 81 00:05:27,000 --> 00:05:32,000 times lambda. That is your general condition 82 00:05:32,000 --> 00:05:37,000 for destructive interference, the difference in the distance 83 00:05:37,000 --> 00:05:41,000 traveled by the two waves. This kind of diagram here we 84 00:05:41,000 --> 00:05:45,000 are also going to see on Friday, because this interference 85 00:05:45,000 --> 00:05:49,000 phenomenon is the property associated with waves. 86 00:05:49,000 --> 00:05:54,000 And what we are going to do is see this diagram again when we 87 00:05:54,000 --> 00:06:00,000 scatter electrons for particles. We are going to see that 88 00:06:00,000 --> 00:06:04,000 particles, also, will destructively and 89 00:06:04,000 --> 00:06:09,000 constructively interfere. They also have wave-like 90 00:06:09,000 --> 00:06:13,000 properties. That is what we will do on 91 00:06:13,000 --> 00:06:15,000 Friday. We have established, 92 00:06:15,000 --> 00:06:20,000 now, the wave-like properties of radiation, 93 00:06:20,000 --> 00:06:26,000 so I would like to move on and talk about the evidence for the 94 00:06:26,000 --> 00:06:31,000 particle-like nature of radiation. 95 00:06:36,000 --> 00:06:41,000 The evidence for the particle-like nature of 96 00:06:41,000 --> 00:06:48,000 radiation comes from an effect called the photoelectric effect. 97 00:06:48,000 --> 00:06:53,000 Shortly after Thompson discovered the electron, 98 00:06:53,000 --> 00:07:00,000 scientists were noticing that if you took a metal and shined 99 00:07:00,000 --> 00:07:06,000 radiation on that metal, that indeed electrons were 100 00:07:06,000 --> 00:07:10,000 emitted. Electrons came off. 101 00:07:10,000 --> 00:07:14,000 These were called photoelectrons. 102 00:07:14,000 --> 00:07:20,000 However, the radiation that you shined on the metal had to have 103 00:07:20,000 --> 00:07:26,000 a frequency nu that was greater than or equal to some threshold 104 00:07:26,000 --> 00:07:32,000 frequency, nu nought. That is, if you took radiation 105 00:07:32,000 --> 00:07:38,000 of some frequency here, nu, that was less than this 106 00:07:38,000 --> 00:07:43,000 threshold frequency, well, you did not get any 107 00:07:43,000 --> 00:07:48,000 electrons off. Well, another way to kind of 108 00:07:48,000 --> 00:07:54,000 understand that data or that effect is to just plot the 109 00:07:54,000 --> 00:08:01,000 number of the electrons that come off as a function of the 110 00:08:01,000 --> 00:08:08,000 frequency of the radiation. And so at low frequency, 111 00:08:08,000 --> 00:08:12,000 there are no electrons, but all of a sudden you get to 112 00:08:12,000 --> 00:08:16,000 nu nought, and then electrons start coming off. 113 00:08:16,000 --> 00:08:21,000 And no matter how high you increase the frequency here, 114 00:08:21,000 --> 00:08:25,000 the number of electrons that come off remains the same, 115 00:08:25,000 --> 00:08:30,000 remains constant. And it turned out that for the 116 00:08:30,000 --> 00:08:34,000 metals that were looked at, at that time, 117 00:08:34,000 --> 00:08:38,000 the threshold frequency, here, was in the UV range of 118 00:08:38,000 --> 00:08:43,000 the electromagnetic spectrum. Well, in addition to just 119 00:08:43,000 --> 00:08:47,000 measuring the number of electrons and generally 120 00:08:47,000 --> 00:08:52,000 observing this effect, scientists did not understand 121 00:08:52,000 --> 00:08:56,000 what was going on. So they just started measuring 122 00:08:56,000 --> 00:09:02,000 everything they could think about measuring. 123 00:09:02,000 --> 00:09:06,000 And one quantity that they measured was the kinetic energy 124 00:09:06,000 --> 00:09:10,000 of these electrons that were being emitted. 125 00:09:10,000 --> 00:09:15,000 And so you take kinetic energy here, KE, as a function of the 126 00:09:15,000 --> 00:09:18,000 frequency. They found that at low 127 00:09:18,000 --> 00:09:22,000 frequency, again, there is no kinetic energy, 128 00:09:22,000 --> 00:09:27,000 because there are no electrons. And then at some frequency, 129 00:09:27,000 --> 00:09:32,000 all of a sudden electrons started coming off. 130 00:09:32,000 --> 00:09:38,000 And the kinetic energy of those electrons seemed to increase 131 00:09:38,000 --> 00:09:43,000 with the frequency once past that threshold frequency, 132 00:09:43,000 --> 00:09:47,000 nu nought. Well, this was really another 133 00:09:47,000 --> 00:09:51,000 one of these conundrums, here, at that time, 134 00:09:51,000 --> 00:09:57,000 because classical physics, classical electromagnetism, 135 00:09:57,000 --> 00:10:04,000 classical physics had no way of explaining these data. 136 00:10:04,000 --> 00:10:06,000 And, in fact, what classical physics 137 00:10:06,000 --> 00:10:10,000 predicted is that the kinetic energy of these electrons, 138 00:10:10,000 --> 00:10:14,000 that that kinetic energy should have nothing to do with the 139 00:10:14,000 --> 00:10:18,000 frequency of the light. That is, the kinetic energy was 140 00:10:18,000 --> 00:10:21,000 constant. As you increased the frequency 141 00:10:21,000 --> 00:10:24,000 of the light, classical physics would tell 142 00:10:24,000 --> 00:10:28,000 you that the kinetic energy should not be affected by the 143 00:10:28,000 --> 00:10:33,000 frequency of the light. There was nothing in the 144 00:10:33,000 --> 00:10:38,000 classical way of thinking, classical electromagnetism that 145 00:10:38,000 --> 00:10:43,000 connected the frequency of the light to the kind of energy, 146 00:10:43,000 --> 00:10:48,000 to the kinetic energy. There was no way for blue light 147 00:10:48,000 --> 00:10:52,000 to make the electrons have a larger kinetic energy, 148 00:10:52,000 --> 00:10:57,000 and for blue light to have an effect on the kinetic energy, 149 00:10:57,000 --> 00:11:04,000 and red light to not have an effect on the kinetic energy. 150 00:11:04,000 --> 00:11:07,000 In addition, what classical physics 151 00:11:07,000 --> 00:11:13,000 predicted is that the kinetic energy of the electrons should 152 00:11:13,000 --> 00:11:17,000 be dependent on the intensity of the light. 153 00:11:17,000 --> 00:11:22,000 That is, the more and more intense the radiation on the 154 00:11:22,000 --> 00:11:28,000 metal, the more and more kinetic energy those electrons should 155 00:11:28,000 --> 00:11:31,000 have. Because, after all, 156 00:11:31,000 --> 00:11:36,000 if you increase the intensity of the light going into the 157 00:11:36,000 --> 00:11:41,000 metal, you are putting more and more energy into it. 158 00:11:41,000 --> 00:11:45,000 That should be reflected in just how energetic those 159 00:11:45,000 --> 00:11:49,000 electrons were picked out. The more energy in, 160 00:11:49,000 --> 00:11:54,000 the electrons ought to come out with larger and larger kinetic 161 00:11:54,000 --> 00:11:58,000 energy. Of course, the observation was 162 00:11:58,000 --> 00:12:03,000 that the kinetic energy of the electrons had nothing to do with 163 00:12:03,000 --> 00:12:09,000 the intensity of light. The kinetic energy of the 164 00:12:09,000 --> 00:12:14,000 electrons did not increase as you made the light brighter and 165 00:12:14,000 --> 00:12:18,000 brighter. As you put more and more energy 166 00:12:18,000 --> 00:12:21,000 in, the kinetic energy remained the same. 167 00:12:21,000 --> 00:12:26,000 It didn't have an effect. This was a real conundrum here. 168 00:12:26,000 --> 00:12:31,000 The known classical physics was making predictions really just 169 00:12:31,000 --> 00:12:36,000 contrary to what was being observed. 170 00:12:36,000 --> 00:12:41,000 These data, here, of the kinetic energy versus 171 00:12:41,000 --> 00:12:45,000 the frequency, were around for a few years 172 00:12:45,000 --> 00:12:50,000 before Einstein took a look at them in 1905, 173 00:12:50,000 --> 00:12:56,000 a hundred years ago. And he looked at these data for 174 00:12:56,000 --> 00:13:03,000 many different metals. Here is some data for metal A, 175 00:13:03,000 --> 00:13:07,000 for example, and here is some data for metal 176 00:13:07,000 --> 00:13:09,000 B. And, in both cases, 177 00:13:09,000 --> 00:13:15,000 it certainly looked like the kinetic energy was linearly 178 00:13:15,000 --> 00:13:19,000 dependent on the frequency of the radiation. 179 00:13:19,000 --> 00:13:25,000 But what was different for the two different metals was the 180 00:13:25,000 --> 00:13:30,000 threshold frequency here, nu nought. 181 00:13:30,000 --> 00:13:36,000 What Einstein did was, he went and fitted a straight 182 00:13:36,000 --> 00:13:43,000 line to these data, y equals mx plus b. 183 00:13:43,000 --> 00:13:46,000 And when he did that, 184 00:13:46,000 --> 00:13:51,000 and he went to calculate the slope here, m, 185 00:13:51,000 --> 00:13:59,000 of these lines, he thought "very interesting." 186 00:13:59,000 --> 00:14:05,000 Because the slope of those lines was 6.626x10^-34 joule 187 00:14:05,000 --> 00:14:09,000 seconds. The slope of those lines was 188 00:14:09,000 --> 00:14:14,000 something called Planck's constant, h. 189 00:14:14,000 --> 00:14:19,000 You say so what? Well, the reason he was so 190 00:14:19,000 --> 00:14:25,000 interested in this is because just a few years earlier, 191 00:14:25,000 --> 00:14:31,000 there was a scientist by the name of Max Planck who was 192 00:14:31,000 --> 00:14:38,000 interested in understanding what was called the black-body 193 00:14:38,000 --> 00:14:44,000 radiation data. What is a black-body? 194 00:14:44,000 --> 00:14:47,000 Well, let's just, for simplicity purposes, 195 00:14:47,000 --> 00:14:53,000 think of the black-body as the burner on an electric stove. 196 00:14:53,000 --> 00:14:58,000 What you know is that if you turn up the voltage on that 197 00:14:58,000 --> 00:15:04,000 burner, the burner gets hot. It increased in temperature. 198 00:15:04,000 --> 00:15:07,000 And you increase the temperature, and sooner or 199 00:15:07,000 --> 00:15:10,000 later, that burner is glowing bright red. 200 00:15:10,000 --> 00:15:13,000 And you increase the temperature some more, 201 00:15:13,000 --> 00:15:16,000 and the burner is glowing a brighter red. 202 00:15:16,000 --> 00:15:19,000 And you increase it some more, and it is glowing orange. 203 00:15:19,000 --> 00:15:23,000 And you increase it some more, which you shouldn't do, 204 00:15:23,000 --> 00:15:27,000 and it's glowing yellow. And then if you could increase 205 00:15:27,000 --> 00:15:31,000 it some more, it's glowing white. 206 00:15:31,000 --> 00:15:34,000 What is happening, as you increase the 207 00:15:34,000 --> 00:15:39,000 temperature, is that the radiation from that black-body, 208 00:15:39,000 --> 00:15:44,000 this is the black-body radiation, is increasing in 209 00:15:44,000 --> 00:15:47,000 intensity. But, more importantly, 210 00:15:47,000 --> 00:15:51,000 the frequency is getting larger and larger. 211 00:15:51,000 --> 00:15:54,000 Dark red, bright red, orange, yellow, 212 00:15:54,000 --> 00:15:57,000 white, those are all frequencies. 213 00:15:57,000 --> 00:16:04,000 The frequency is shifting to higher and higher values. 214 00:16:04,000 --> 00:16:10,000 And what was actually done at that time is that the intensity 215 00:16:10,000 --> 00:16:16,000 of that black-body radiation, oh, and this material is not in 216 00:16:16,000 --> 00:16:21,000 your notes, because you are not responsible for it. 217 00:16:21,000 --> 00:16:27,000 I am just trying to make this surprise that Einstein noticed 218 00:16:27,000 --> 00:16:32,000 about the slope. I am just trying to put it in 219 00:16:32,000 --> 00:16:35,000 some context, why he was so surprised and 220 00:16:35,000 --> 00:16:39,000 amazed at it. This black-body intensity here, 221 00:16:39,000 --> 00:16:43,000 people had dispersed that radiation and looked at the 222 00:16:43,000 --> 00:16:46,000 frequencies that were coming off. 223 00:16:46,000 --> 00:16:49,000 This is intensity versus frequency. 224 00:16:49,000 --> 00:16:54,000 Here is a general shape of that intensity versus frequency. 225 00:16:54,000 --> 00:17:00,000 That was observed for some temperature T one. 226 00:17:00,000 --> 00:17:05,000 That was a low temperature. And then, when the temperature 227 00:17:05,000 --> 00:17:10,000 was increased and the intensity versus frequency was observed, 228 00:17:10,000 --> 00:17:14,000 well, the frequencies generally got higher. 229 00:17:14,000 --> 00:17:18,000 This is higher temperature. Intensity goes up. 230 00:17:18,000 --> 00:17:22,000 And you increase the temperature some more, 231 00:17:22,000 --> 00:17:25,000 and you get even higher frequency. 232 00:17:25,000 --> 00:17:30,000 T three is the highest temperature. 233 00:17:30,000 --> 00:17:36,000 And that is what the data were. What Planck was trying to do 234 00:17:36,000 --> 00:17:43,000 was to understand the origin of that black-body radiation. 235 00:17:43,000 --> 00:17:48,000 What he said was that in these black-bodies, 236 00:17:48,000 --> 00:17:52,000 in these materials, what there must be are 237 00:17:52,000 --> 00:17:59,000 oscillators that are giving off this radiation. 238 00:17:59,000 --> 00:18:04,000 But he had another little kick to these oscillators. 239 00:18:04,000 --> 00:18:10,000 These oscillators were giving off radiation or energy in 240 00:18:10,000 --> 00:18:13,000 chunks, in quanta, in particles. 241 00:18:13,000 --> 00:18:18,000 And using that idea, plus some statistical 242 00:18:18,000 --> 00:18:23,000 mechanics, he was able to calculate the shapes of these 243 00:18:23,000 --> 00:18:26,000 curves. That is, he indeed got, 244 00:18:26,000 --> 00:18:32,000 for the lowest temperature here, a curve that looked like 245 00:18:32,000 --> 00:18:36,000 this. And for T two, 246 00:18:36,000 --> 00:18:39,000 he got a curve that looked like this. 247 00:18:39,000 --> 00:18:44,000 And for T three, he got a curve that looked like 248 00:18:44,000 --> 00:18:47,000 this. He got the shape right, 249 00:18:47,000 --> 00:18:50,000 but he wanted to get the intensity right, 250 00:18:50,000 --> 00:18:53,000 too. What he realized he had to do 251 00:18:53,000 --> 00:18:57,000 was he essentially needed to have a scaling factor, 252 00:18:57,000 --> 00:19:04,000 actually, in front of his frequencies of his oscillators. 253 00:19:04,000 --> 00:19:07,000 He wanted a constant. And so he said, 254 00:19:07,000 --> 00:19:13,000 what constant do I have to have in order to make all of these 255 00:19:13,000 --> 00:19:18,000 data fit the observation? That constant is Planck's 256 00:19:18,000 --> 00:19:22,000 constant, his own 6.626x10^-34 joule seconds. 257 00:19:22,000 --> 00:19:26,000 There it is. That is Planck's constant. 258 00:19:26,000 --> 00:19:31,000 That is it. There is nothing deeper here. 259 00:19:31,000 --> 00:19:36,000 It is a natural constant. It comes from our observations 260 00:19:36,000 --> 00:19:39,000 of the world, of nature. 261 00:19:39,000 --> 00:19:42,000 That is it. It is a fitting constant. 262 00:19:42,000 --> 00:19:47,000 And so that is why Einstein was so amazed, here, 263 00:19:47,000 --> 00:19:54,000 when he realized this number is the same as what comes out of 264 00:19:54,000 --> 00:19:57,000 here. There must be something very 265 00:19:57,000 --> 00:20:04,000 fundamental about this h, this Planck's constant. 266 00:20:04,000 --> 00:20:09,000 That is the story. Isn't that amazing? 267 00:20:09,000 --> 00:20:16,000 What Einstein then proceeded to do, of course, 268 00:20:16,000 --> 00:20:24,000 is to write down the equation of the straight line that he 269 00:20:24,000 --> 00:20:33,000 just put through these data. And so that equation is the 270 00:20:33,000 --> 00:20:38,000 kinetic energy equal to nu, which is our x, 271 00:20:38,000 --> 00:20:44,000 h, which is the slope. And then what he found was that 272 00:20:44,000 --> 00:20:50,000 the intercept here, of course, is minus h times nu 273 00:20:50,000 --> 00:20:56,000 nought. This is plus minus h times nu 274 00:20:56,000 --> 00:21:02,000 nought. And that is the equation of a 275 00:21:02,000 --> 00:21:05,000 straight line. Of course, he realized, 276 00:21:05,000 --> 00:21:11,000 if this is energy on this side, boy, there better be energy on 277 00:21:11,000 --> 00:21:14,000 this side. And so this h times nu 278 00:21:14,000 --> 00:21:18,000 better be an energy. And since this nu was the 279 00:21:18,000 --> 00:21:22,000 frequency of the incident radiation, therefore, 280 00:21:22,000 --> 00:21:27,000 h times nu better be the energy of the incident radiation, 281 00:21:27,000 --> 00:21:32,000 E sub i. That is where this expression, 282 00:21:32,000 --> 00:21:36,000 energy equals h times nu comes from. 283 00:21:36,000 --> 00:21:40,000 Nothing more. That is where it comes from, 284 00:21:40,000 --> 00:21:45,000 the photoelectric effect. This was the first time that 285 00:21:45,000 --> 00:21:50,000 there was any relationship between the frequency of the 286 00:21:50,000 --> 00:21:53,000 radiation and the energy of the radiation. 287 00:21:53,000 --> 00:21:58,000 In classical electromagnetism, there is no relationship 288 00:21:58,000 --> 00:22:03,000 between the frequency and the energy. 289 00:22:03,000 --> 00:22:08,000 This was the first time in which that relationship was 290 00:22:08,000 --> 00:22:12,000 observed. And what this is saying is the 291 00:22:12,000 --> 00:22:16,000 following. This is saying that you can 292 00:22:16,000 --> 00:22:23,000 have any frequency of radiation you want, but the corresponding 293 00:22:23,000 --> 00:22:30,000 energy comes in these chunks of h times nu. 294 00:22:30,000 --> 00:22:35,000 h is a quantization constant. Radiation, nu, 295 00:22:35,000 --> 00:22:41,000 is continuous, but the energy that corresponds 296 00:22:41,000 --> 00:22:48,000 to any given frequency of radiation is h times nu. 297 00:22:48,000 --> 00:22:56,000 This E equals h times nu, here, is thought of as a 298 00:22:56,000 --> 00:23:02,000 quantum of energy. A particle of energy. 299 00:23:02,000 --> 00:23:08,000 A chunk of energy. Later on, it became the photon, 300 00:23:08,000 --> 00:23:15,000 the energy of a photon. If this h times nu here 301 00:23:15,000 --> 00:23:20,000 was an energy, well, this h times nu nought 302 00:23:20,000 --> 00:23:25,000 also better be an energy. 303 00:23:25,000 --> 00:23:32,000 It is the threshold energy. Let's draw an energy level 304 00:23:32,000 --> 00:23:36,000 diagram to try to understand that. 305 00:23:36,000 --> 00:23:40,000 I am going to plot an energy here. 306 00:23:40,000 --> 00:23:44,000 Let's draw an energy level for an electron. 307 00:23:44,000 --> 00:23:49,000 This is an electron, here, bound to the metal. 308 00:23:49,000 --> 00:23:56,000 And we know that it takes some energy to rip this electron off 309 00:23:56,000 --> 00:24:01,000 of the metal. Up here, at higher energy, 310 00:24:01,000 --> 00:24:03,000 is going to be our free electron. 311 00:24:03,000 --> 00:24:06,000 I will just call it electron-free, 312 00:24:06,000 --> 00:24:11,000 not bound to the metal anymore. And the energy that is required 313 00:24:11,000 --> 00:24:15,000 to pull the electron off, from the bound state to its 314 00:24:15,000 --> 00:24:20,000 free state, is this threshold energy, h times nu nought. 315 00:24:20,000 --> 00:24:23,000 This threshold energy is like 316 00:24:23,000 --> 00:24:27,000 an ionization potential. You know what the ionization 317 00:24:27,000 --> 00:24:32,000 potential is. Just the energy required to 318 00:24:32,000 --> 00:24:35,000 pull an electron off an atom or a molecule. 319 00:24:35,000 --> 00:24:40,000 However, when we are pulling an electron off a chunk of a metal, 320 00:24:40,000 --> 00:24:43,000 we actually have another name for it. 321 00:24:43,000 --> 00:24:47,000 It is called the work function. That is just historical, 322 00:24:47,000 --> 00:24:51,000 but it is the same thing as an ionization potential. 323 00:24:51,000 --> 00:24:54,000 And we often give it the symbol phi. 324 00:24:54,000 --> 00:24:58,000 That threshold energy, ionization energy for a metal, 325 00:24:58,000 --> 00:25:01,000 is the work function, here, h times nu, 326 00:25:01,000 --> 00:25:06,000 phi. The important point here is 327 00:25:06,000 --> 00:25:11,000 this. In order to get an electron off 328 00:25:11,000 --> 00:25:17,000 of the metal, what you have to have is 329 00:25:17,000 --> 00:25:24,000 energy, E sub i. That energy E sub i has to be 330 00:25:24,000 --> 00:25:32,000 equal to at least the threshold energy, h times nu nought. 331 00:25:32,000 --> 00:25:37,000 If you come in with energy of 332 00:25:37,000 --> 00:25:41,000 this radiation, of this wavelength and that 333 00:25:41,000 --> 00:25:45,000 frequency, you pulled the electron off, 334 00:25:45,000 --> 00:25:50,000 and then the electron is off the metal and it just kind of 335 00:25:50,000 --> 00:25:53,000 stays there. It doesn't move away. 336 00:25:53,000 --> 00:25:57,000 But you can also come in with energy here, E sub i, 337 00:25:57,000 --> 00:26:03,000 that is greater than this work function, than the threshold 338 00:26:03,000 --> 00:26:07,000 energy. And you can pull the electron 339 00:26:07,000 --> 00:26:09,000 off. But then, the electron is 340 00:26:09,000 --> 00:26:14,000 actually going to move away from the metal, and the energy with 341 00:26:14,000 --> 00:26:18,000 which it moves away from the metal, its kinetic energy, 342 00:26:18,000 --> 00:26:23,000 is just the incident energy minus this threshold energy. 343 00:26:23,000 --> 00:26:27,000 It is the excess energy here. And I am going to write it as 344 00:26:27,000 --> 00:26:33,000 the kinetic energy. From that energy level diagram, 345 00:26:33,000 --> 00:26:37,000 this energy, the incident energy, 346 00:26:37,000 --> 00:26:43,000 has to be equal to the work function, h nu nought, 347 00:26:43,000 --> 00:26:48,000 plus the kinetic energy. 348 00:26:48,000 --> 00:26:54,000 Or, if I turned this around, the kinetic energy is equal to 349 00:26:54,000 --> 00:27:02,000 the incident energy minus h nu nought. 350 00:27:02,000 --> 00:27:06,000 The actual expression for the energy that Einstein found, 351 00:27:06,000 --> 00:27:08,000 I just turned that equation around. 352 00:27:08,000 --> 00:27:11,000 This is an equation that you have to know. 353 00:27:11,000 --> 00:27:14,000 I will not give this to you on an exam. 354 00:27:14,000 --> 00:27:17,000 Now, you don't have to memorize it. 355 00:27:17,000 --> 00:27:21,000 You just have to reason it. Draw yourself an energy 356 00:27:21,000 --> 00:27:23,000 diagram. You know conservation of 357 00:27:23,000 --> 00:27:26,000 energy. The sum of these two energies 358 00:27:26,000 --> 00:27:30,000 has to equal the incident energy. 359 00:27:30,000 --> 00:27:37,000 Then you will be all set. Now, what is very important 360 00:27:37,000 --> 00:27:44,000 here is the following. If I come in with radiation 361 00:27:44,000 --> 00:27:50,000 that is, say, a half of the threshold energy. 362 00:27:50,000 --> 00:27:58,000 Suppose I come in with two photons, where each photon is 363 00:27:58,000 --> 00:28:03,000 one half h nu -- 364 00:28:08,000 --> 00:28:12,000 The bottom line is that you are not going to get an electron 365 00:28:12,000 --> 00:28:15,000 off. Even though you are coming in 366 00:28:15,000 --> 00:28:19,000 with two photons, which together are going to 367 00:28:19,000 --> 00:28:23,000 give you the threshold energy, you won't get a photon off. 368 00:28:23,000 --> 00:28:28,000 You have to come in with at least the energy of the work 369 00:28:28,000 --> 00:28:33,000 function. A photon has to have at least 370 00:28:33,000 --> 00:28:37,000 this energy to get an electron off. 371 00:28:37,000 --> 00:28:42,000 That is the particle-like nature of radiation. 372 00:28:42,000 --> 00:28:47,000 Energy comes in chunks, in particles of energy, 373 00:28:47,000 --> 00:28:53,000 in quanta of energy. Likewise, if I came in here 374 00:28:53,000 --> 00:29:00,000 with a photon that had twice the energy of the work function or 375 00:29:00,000 --> 00:29:05,000 the threshold energy, I would still only get one 376 00:29:05,000 --> 00:29:11,000 electron off. I would not get two electrons 377 00:29:11,000 --> 00:29:15,000 off, even though energetically you would be able, 378 00:29:15,000 --> 00:29:19,000 in principle, to get two electrons off. 379 00:29:19,000 --> 00:29:23,000 But you won't. You will only get one electron 380 00:29:23,000 --> 00:29:26,000 off. Whenever you send a photon in, 381 00:29:26,000 --> 00:29:31,000 if it has enough energy, that is if its energy is equal 382 00:29:31,000 --> 00:29:35,000 to or greater than the work function, you will get an 383 00:29:35,000 --> 00:29:40,000 electron off. There is one electron for every 384 00:29:40,000 --> 00:29:44,000 photon. You never get two electrons for 385 00:29:44,000 --> 00:29:48,000 every photon, or you can never get one 386 00:29:48,000 --> 00:29:52,000 electron for two photons that are lower energy. 387 00:29:52,000 --> 00:29:56,000 That is the particle quantum nature of radiation. 388 00:29:56,000 --> 00:30:00,000 That is important. Yes? 389 00:30:08,000 --> 00:30:18,000 What is the form of the photon? What do you mean by form? 390 00:30:18,000 --> 00:30:25,000 Oh, you want a picture of the photon. 391 00:30:25,000 --> 00:30:33,000 You're looking at them. You cannot draw a picture of a 392 00:30:33,000 --> 00:30:39,000 photon because you want to relate it to something that is 393 00:30:39,000 --> 00:30:42,000 within your classical experience. 394 00:30:42,000 --> 00:30:48,000 And you cannot do that. It isn't a classical particle. 395 00:30:48,000 --> 00:30:53,000 That is what you're working with right here. 396 00:30:53,000 --> 00:30:59,000 You are trying to use your experiences, that are everyday 397 00:30:59,000 --> 00:31:05,000 experiences, to explain something that isn't within your 398 00:31:05,000 --> 00:31:13,000 everyday experiences. You don't have a frame or a 399 00:31:13,000 --> 00:31:18,000 format to do that. Yeah? 400 00:31:30,000 --> 00:31:33,000 Yes. If you have a constant flux of 401 00:31:33,000 --> 00:31:39,000 photons onto the surface, you will have a constant flux 402 00:31:39,000 --> 00:31:44,000 of electrons. Now, there is a probability. 403 00:31:44,000 --> 00:31:50,000 It is not necessarily the case that every photon gets in, 404 00:31:50,000 --> 00:31:56,000 will eject electrons, because there are other kinds 405 00:31:56,000 --> 00:32:02,000 of competing processes. Whatever the rate with which 406 00:32:02,000 --> 00:32:07,000 the photons come in. It depends on the flux of the 407 00:32:07,000 --> 00:32:11,000 photons. And we will have some problems 408 00:32:11,000 --> 00:32:17,000 like that, where we are going to assume that the probability of 409 00:32:17,000 --> 00:32:23,000 the electron coming off is going to be one, so one electron for 410 00:32:23,000 --> 00:32:26,000 every photon. But, in reality, 411 00:32:26,000 --> 00:32:32,000 there are competing processes. Are all electrons being 412 00:32:32,000 --> 00:32:35,000 ejected? Actually, some electrons. 413 00:32:35,000 --> 00:32:39,000 Again, this goes to the probability. 414 00:32:39,000 --> 00:32:47,000 Some are actually kind of going in, too, into deeper the metal. 415 00:32:53,000 --> 00:32:55,000 Not the probability, right. 416 00:32:55,000 --> 00:33:01,000 The rate at which the electrons come out with is dependent on 417 00:33:01,000 --> 00:33:06,000 the intensity. The more photons you send in, 418 00:33:06,000 --> 00:33:12,000 the larger the number of photons per second coming in, 419 00:33:12,000 --> 00:33:18,000 the larger the number of electrons per second coming out. 420 00:33:18,000 --> 00:33:23,000 This is a plot, here, of the energy of the 421 00:33:23,000 --> 00:33:26,000 electrons. That's all right. 422 00:33:26,000 --> 00:33:30,000 Other questions? Yeah? 423 00:33:35,000 --> 00:33:36,000 Eventually. Yes. 424 00:33:36,000 --> 00:33:39,000 Absolutely. There are other problems that 425 00:33:39,000 --> 00:33:43,000 will come in. Usually, your light source 426 00:33:43,000 --> 00:33:48,000 isn't so energetic that you could possibly do that. 427 00:33:48,000 --> 00:33:53,000 Now, also usually what happens is that you've got your metal 428 00:33:53,000 --> 00:33:58,000 grounded, so that as you lose electrons, new electrons come in 429 00:33:58,000 --> 00:34:03,000 and fill it up to the fermi level. 430 00:34:03,000 --> 00:34:06,000 And so you don't charge up your sample. 431 00:34:06,000 --> 00:34:10,000 In an experiment, if you had your metal just not 432 00:34:10,000 --> 00:34:15,000 grounded and you did shine some radiation, what would happen is 433 00:34:15,000 --> 00:34:18,000 the metal would start to charge up. 434 00:34:18,000 --> 00:34:23,000 Then, that would make it difficult to get electrons off. 435 00:34:23,000 --> 00:34:25,000 Yes? 436 00:34:35,000 --> 00:34:37,000 Yes. How strongly those electrons 437 00:34:37,000 --> 00:34:42,000 are bound to the metal depends on the electronic structure of 438 00:34:42,000 --> 00:34:44,000 the metal. And we are going to talk a 439 00:34:44,000 --> 00:34:49,000 little bit about what determines the strength of the interaction 440 00:34:49,000 --> 00:34:53,000 for electrons on atoms and molecules, but it is similar to 441 00:34:53,000 --> 00:34:57,000 what it is for metals. That is coming in a few days. 442 00:34:57,000 --> 00:34:59,000 Yes? 443 00:35:04,000 --> 00:35:05,000 Yes, there is. Right. 444 00:35:05,000 --> 00:35:08,000 You don't actually have to have a metal. 445 00:35:08,000 --> 00:35:11,000 You could do it. There are usually higher 446 00:35:11,000 --> 00:35:14,000 frequencies on insulators and semiconductors, 447 00:35:14,000 --> 00:35:17,000 right. It is harder to see the effect, 448 00:35:17,000 --> 00:35:19,000 but it can be done and has been done. 449 00:35:19,000 --> 00:35:24,000 Well, what I want to do right now is to show you an experiment 450 00:35:24,000 --> 00:35:27,000 we are going to do. We are going to do a 451 00:35:27,000 --> 00:35:30,000 photoelectron experiment. 452 00:35:45,000 --> 00:35:53,000 And the experiment is this. We have a device up here. 453 00:35:53,000 --> 00:36:00,000 What we have is an aluminum plate. 454 00:36:00,000 --> 00:36:05,000 And that aluminum plate is mounted on this blue metal rod. 455 00:36:05,000 --> 00:36:10,000 And in the middle of this rod is a needle on a pivot. 456 00:36:10,000 --> 00:36:14,000 And this is a fairly frictionless pivot. 457 00:36:14,000 --> 00:36:17,000 This black ring, here, is just a support 458 00:36:17,000 --> 00:36:22,000 structure, an insulating support structure. 459 00:36:22,000 --> 00:36:27,000 What we are going to do is put some excess charge on this 460 00:36:27,000 --> 00:36:32,000 aluminum plate. And that excess charge is going 461 00:36:32,000 --> 00:36:35,000 to run down this metal rod and then onto this needle. 462 00:36:35,000 --> 00:36:40,000 And because that excess charge, the electrons on the needle and 463 00:36:40,000 --> 00:36:43,000 the electrons on the metal rod are repulsive, 464 00:36:43,000 --> 00:36:45,000 since this is rather frictionless, 465 00:36:45,000 --> 00:36:49,000 that needle is going to move because of the repulsive 466 00:36:49,000 --> 00:36:52,000 interactions between these electrons. 467 00:36:52,000 --> 00:36:56,000 What we're then going to do is try to do the photoelectron 468 00:36:56,000 --> 00:37:00,000 experiment. We are going to take some UV 469 00:37:00,000 --> 00:37:07,000 radiation and shine it on this metal and drive the electrons 470 00:37:07,000 --> 00:37:09,000 off. And we should see, 471 00:37:09,000 --> 00:37:14,000 then, the needle swing back to its original position. 472 00:37:14,000 --> 00:37:20,000 I need a couple of volunteers in order to do this experiment 473 00:37:20,000 --> 00:37:22,000 here. Come on up. 474 00:37:22,000 --> 00:37:24,000 All right. Fantastic. 475 00:37:24,000 --> 00:37:27,000 I think that is all right. Good. 476 00:37:27,000 --> 00:37:32,000 Okay. One of you needs to be the 477 00:37:32,000 --> 00:37:35,000 charger, and the other needs to be the discharger. 478 00:37:35,000 --> 00:37:38,000 Which one? You want to discharge? 479 00:37:38,000 --> 00:37:41,000 Discharge, okay. You come over here. 480 00:37:41,000 --> 00:37:45,000 And what you are going to do is discharge the aluminum plate 481 00:37:45,000 --> 00:37:48,000 after we get some excess charge on it. 482 00:37:48,000 --> 00:37:52,000 You are going to do it just by holding it up to here. 483 00:37:52,000 --> 00:37:57,000 You have to get it kind of close because it is not a very 484 00:37:57,000 --> 00:38:03,000 intense UV source. Could you get the video cam on 485 00:38:03,000 --> 00:38:09,000 the side or on the center to get where we are putting it? 486 00:38:09,000 --> 00:38:13,000 I guess we are putting it on the side, right? 487 00:38:13,000 --> 00:38:15,000 Okay. There we go. 488 00:38:15,000 --> 00:38:19,000 There is the device. You are the charger. 489 00:38:19,000 --> 00:38:24,000 What we are going to do, to get the excess charge, 490 00:38:24,000 --> 00:38:30,000 we are taking a piece of natural fur. 491 00:38:30,000 --> 00:38:33,000 We are going to rub it on this Lucite rod. 492 00:38:33,000 --> 00:38:37,000 You have to keep your fingers on the yellow tape here. 493 00:38:37,000 --> 00:38:41,000 And we are going to transfer some of the natural oils here 494 00:38:41,000 --> 00:38:44,000 onto this rod. And there are plenty of 495 00:38:44,000 --> 00:38:47,000 negative ions around here and free electrons. 496 00:38:47,000 --> 00:38:52,000 That oil likes those negative charges, and so there are going 497 00:38:52,000 --> 00:38:57,000 to be excess negative charges on this Lucite rod. 498 00:38:57,000 --> 00:39:03,000 And then you are going to come over here and just touch the 499 00:39:03,000 --> 00:39:08,000 edge of this and let the electrons flow onto there. 500 00:39:08,000 --> 00:39:13,000 Are you right-handed? You have to rub that really, 501 00:39:13,000 --> 00:39:16,000 really hard. [LAUGHTER] Great. 502 00:39:16,000 --> 00:39:19,000 Go over there. Touch the end. 503 00:39:19,000 --> 00:39:23,000 Cool. Why don't you give it another 504 00:39:23,000 --> 00:39:30,000 jolt here and we will really move that needle over. 505 00:39:30,000 --> 00:39:31,000 Okay. Discharger. 506 00:39:31,000 --> 00:39:33,000 We have to give it another jolt. 507 00:39:33,000 --> 00:39:36,000 That is okay. You may have touched it with 508 00:39:36,000 --> 00:39:40,000 something else and discharged it a little bit. 509 00:39:40,000 --> 00:39:43,000 No, that's okay. You have to get the hang of 510 00:39:43,000 --> 00:39:46,000 this, here. You are doing fantastic. 511 00:39:46,000 --> 00:39:49,000 Take it off. That's what it is. 512 00:39:49,000 --> 00:39:53,000 You are holding it on too long. Okay, that is pretty good. 513 00:39:53,000 --> 00:39:57,000 Put it in front there. Get it a little bit closer. 514 00:39:57,000 --> 00:40:02,000 Here comes the UV radiation. We did it. 515 00:40:02,000 --> 00:40:06,000 Try it again really hard. Just touch it. 516 00:40:06,000 --> 00:40:09,000 Take it off. Do it again. 517 00:40:09,000 --> 00:40:14,000 You need to do it again. You've got to get it right 518 00:40:14,000 --> 00:40:16,000 here. Not too much, 519 00:40:16,000 --> 00:40:18,000 not too little. Okay. 520 00:40:18,000 --> 00:40:22,000 It is doing it. Discharge in front. 521 00:40:22,000 --> 00:40:27,000 Electrons off. Now we have to do a control 522 00:40:27,000 --> 00:40:33,000 experiment. That is, you have got to charge 523 00:40:33,000 --> 00:40:38,000 it up again, but now, when you put the light there, 524 00:40:38,000 --> 00:40:44,000 what I am going to do is hold up a Pyrex plate in between the 525 00:40:44,000 --> 00:40:49,000 light and the metal. It is going to block the 526 00:40:49,000 --> 00:40:53,000 radiation, and it should not discharge. 527 00:40:53,000 --> 00:40:57,000 You need to get on there. Fantastic. 528 00:40:57,000 --> 00:41:02,000 There it goes. Here is the plate. 529 00:41:02,000 --> 00:41:07,000 Get it to a little bit lower. Do a good discharge. 530 00:41:07,000 --> 00:41:12,000 [APPLAUSE] Fantastic. Thank you very much. 531 00:41:12,000 --> 00:41:15,000 Thank you for being a good sport. 532 00:41:15,000 --> 00:41:19,000 That is the photoelectron experiment. 533 00:41:19,000 --> 00:41:24,000 Hey, it works. Well, what I want to do now is 534 00:41:24,000 --> 00:41:32,000 just spend a few minutes working on a few problems. 535 00:41:32,000 --> 00:41:36,000 I think these are pretty straightforward, 536 00:41:36,000 --> 00:41:42,000 but I just want to make sure that everybody is on the same 537 00:41:42,000 --> 00:41:47,000 page here in terms of being able to do the homework. 538 00:41:47,000 --> 00:41:53,000 Here is the first problem. The first problem says, 539 00:41:53,000 --> 00:41:57,000 how many photons? And remember what we said a 540 00:41:57,000 --> 00:42:02,000 photon was? E equals h nu. 541 00:42:02,000 --> 00:42:07,000 This is the number of joules. Implied is the number of joules 542 00:42:07,000 --> 00:42:11,000 per photon, although we don't usually write this, 543 00:42:11,000 --> 00:42:15,000 but that is what that is, joules per photon. 544 00:42:15,000 --> 00:42:20,000 You may want to write it as you do these problems. 545 00:42:20,000 --> 00:42:28,000 How many photons associated with radiation of a wavelength 546 00:42:28,000 --> 00:42:35,000 lambda equals one picometer, which is 1.0x10^-12 meters, 547 00:42:35,000 --> 00:42:42,000 how many of these do you need in order to create, 548 00:42:42,000 --> 00:42:49,000 say, a laser pulse of energy that is one joule? 549 00:42:49,000 --> 00:42:55,000 Lasers are pulsed, so I am talking about a pulse 550 00:42:55,000 --> 00:43:02,000 of energy, one joule. You want to draw yourself a 551 00:43:02,000 --> 00:43:06,000 picture, here. We are drawing a picture of one 552 00:43:06,000 --> 00:43:08,000 pulse of energy, one joule. 553 00:43:08,000 --> 00:43:13,000 Now, we have not been given the frequency, here, 554 00:43:13,000 --> 00:43:17,000 of this radiation, but we know the wavelength, 555 00:43:17,000 --> 00:43:21,000 and we know the relationship between frequency and 556 00:43:21,000 --> 00:43:25,000 wavelength. It is just c over lambda. 557 00:43:25,000 --> 00:43:30,000 I know what lambda is. I can calculate nu. 558 00:43:30,000 --> 00:43:34,000 And, when I do that, I find that the energy of the 559 00:43:34,000 --> 00:43:40,000 photon, hc over lambda, that energy of the 560 00:43:40,000 --> 00:43:44,000 photon is 1.99x10^-13 joules per photon. 561 00:43:44,000 --> 00:43:50,000 And I am using one more figure than is significant since this 562 00:43:50,000 --> 00:43:55,000 an intermediate step in the calculation. 563 00:43:55,000 --> 00:44:02,000 If I want a pulse of one joule of energy and I am asked how 564 00:44:02,000 --> 00:44:10,000 many photons do I need to get that, and each photon is 565 00:44:10,000 --> 00:44:16,000 1.99x10^-13 joules, well, that means that I am 566 00:44:16,000 --> 00:44:24,000 going to need 5.0x10^12 photons. There was a question here? 567 00:44:24,000 --> 00:44:30,000 All right. Let's work another one. 568 00:44:30,000 --> 00:44:34,000 Here, we want to define what we mean by power. 569 00:44:34,000 --> 00:44:40,000 This says the power of radiation from the continuous 570 00:44:40,000 --> 00:44:44,000 laser is three milliwatts. 571 00:44:44,000 --> 00:44:50,000 We have some laser, and the power of that radiation 572 00:44:50,000 --> 00:44:55,000 coming out is three milliwatts. Well, what is power? 573 00:44:55,000 --> 00:45:02,000 Power is energy per unit time. It is the energy delivered or 574 00:45:02,000 --> 00:45:06,000 the energy expended per unit time. 575 00:45:06,000 --> 00:45:11,000 The unit of power that we are going to use is a watt. 576 00:45:11,000 --> 00:45:16,000 A watt is a joule per second. We are told that we have 577 00:45:16,000 --> 00:45:22,000 radiation of three milliwatts. That is 3.0x10^-3 joules per 578 00:45:22,000 --> 00:45:25,000 second. And the question asks, 579 00:45:25,000 --> 00:45:30,000 how long will it take for a total energy of one joule to be 580 00:45:30,000 --> 00:45:36,000 supplied? Well, one joule. 581 00:45:36,000 --> 00:45:47,000 And we have the rate of energy supply as 3x10^-3 joules per 582 00:45:47,000 --> 00:45:54,000 second. That gives us 330 seconds. 583 00:45:54,000 --> 00:46:04,000 That is straightforward. Finally, we have one more. 584 00:46:04,000 --> 00:46:11,000 It says, how many photons per second of, again, 585 00:46:11,000 --> 00:46:17,000 the same radiation, of the wavelength of one 586 00:46:17,000 --> 00:46:22,000 picometer. That means, again, 587 00:46:22,000 --> 00:46:29,000 we are dealing with photons that have an energy of 588 00:46:29,000 --> 00:46:39,000 1.99x10^-13 joules per photon. How many photons per second, 589 00:46:39,000 --> 00:46:45,000 the rate of photons at the wavelength do you have to have, 590 00:46:45,000 --> 00:46:49,000 or do you have, if the power of the radiation 591 00:46:49,000 --> 00:46:54,000 is three milliwatts? Well, the power of the 592 00:46:54,000 --> 00:47:00,000 radiation is 3.0x10^-3 joules per second, -- 593 00:47:00,000 --> 00:47:06,000 -- and we have 1.99x10^-13 joules per photon. 594 00:47:11,000 --> 00:47:18,000 In order to have this kind of power, what we have to have 595 00:47:18,000 --> 00:47:25,000 being emitted is 1.5x10^10 photons per second. 596 00:47:34,000 --> 00:47:38,000 All right. The photoelectric effect is one 597 00:47:38,000 --> 00:47:43,000 of the experiments that demonstrated the particle-like 598 00:47:43,000 --> 00:47:46,000 nature of light, of radiation. 599 00:47:46,000 --> 00:47:52,000 Particle-like nature because you have to have these chunks of 600 00:47:52,000 --> 00:47:57,000 energy to make some process occur. 601 00:47:57,000 --> 00:48:03,000 Next time, we are going to look at and will just talk briefly 602 00:48:03,000 --> 00:48:09,000 about the other experiments that demonstrated the particle-like 603 00:48:09,000 --> 00:48:14,000 nature of radiation. And that other experiment is 604 00:48:14,000 --> 00:48:18,000 the demonstration that a photon has momentum, 605 00:48:18,000 --> 00:48:22,000 even though it doesn't have any mass. 606 00:48:22,562 --> 00:48:25,000 See you Wednesday. See you Friday.