1 00:00:06,990 --> 00:00:10,130 [MUSIC PLAYING] 2 00:00:16,597 --> 00:00:18,180 PROFESSOR: Hello everyone, today we're 3 00:00:18,180 --> 00:00:20,600 going to learn how a Solar Cell is able to turn light 4 00:00:20,600 --> 00:00:23,790 generated mobile charges into electricity. 5 00:00:23,790 --> 00:00:25,420 Today's lesson will use everything 6 00:00:25,420 --> 00:00:28,460 we've learned in the past videos to understand this effect. 7 00:00:28,460 --> 00:00:30,440 So, make sure you understand the material 8 00:00:30,440 --> 00:00:32,990 from the previous videos before watching. 9 00:00:32,990 --> 00:00:36,510 First, let's go over the structure of a Solar Cell. 10 00:00:36,510 --> 00:00:38,342 Here's a cell that I made. 11 00:00:38,342 --> 00:00:40,300 And we can see that a metal ribbon is connected 12 00:00:40,300 --> 00:00:43,970 to the top metal contacts, which form a grid. 13 00:00:43,970 --> 00:00:45,480 The spaces between the grid lines 14 00:00:45,480 --> 00:00:48,460 allow light to enter the cell. 15 00:00:48,460 --> 00:00:51,360 If we flip over the cell we see the entire back surface 16 00:00:51,360 --> 00:00:53,230 is coated with metal, which allows 17 00:00:53,230 --> 00:00:55,610 easy extraction of charge from the back surface. 18 00:00:55,610 --> 00:00:57,590 Additionally, we have another metal ribbon 19 00:00:57,590 --> 00:01:00,276 that's connected to the backside. 20 00:01:00,276 --> 00:01:01,650 Now, let's hook up our Solar Cell 21 00:01:01,650 --> 00:01:03,860 to an ammeter to measure the current. 22 00:01:03,860 --> 00:01:06,670 So, here we have an ammeter connected to our Solar Cell 23 00:01:06,670 --> 00:01:09,430 and our light source which will simulate the sun. 24 00:01:09,430 --> 00:01:12,826 And we can see that if we turn on our light source 25 00:01:12,826 --> 00:01:15,200 we start to read a current flowing out of our Solar Cell. 26 00:01:15,200 --> 00:01:20,070 In this case about 0.12 amps or 120 milliamps. 27 00:01:20,070 --> 00:01:23,980 Now, if we turn off the light the output of the cell 28 00:01:23,980 --> 00:01:27,670 drops to zero and we no longer read any current. 29 00:01:27,670 --> 00:01:29,230 We know from our last demo the light 30 00:01:29,230 --> 00:01:31,500 generates mobile charges and silicon. 31 00:01:31,500 --> 00:01:34,170 But how do these mobile charges become a electric current 32 00:01:34,170 --> 00:01:36,110 coming out of our Solar Cell? 33 00:01:36,110 --> 00:01:39,640 The secret has to do with doping. 34 00:01:39,640 --> 00:01:42,660 The top layer is doped with phosphorus, shown in blue. 35 00:01:42,660 --> 00:01:46,310 Well the bottom layer is doped in boron, shown in red. 36 00:01:46,310 --> 00:01:48,380 The different dopants interact in a way, 37 00:01:48,380 --> 00:01:50,870 which we'll describe shortly, to create an electric field 38 00:01:50,870 --> 00:01:52,630 in our device where the Boron-doped and 39 00:01:52,630 --> 00:01:54,315 Phosphorous-doped regions meet. 40 00:01:54,315 --> 00:01:57,580 It is this electric field that acts as a one way valve 41 00:01:57,580 --> 00:01:59,940 in our Solar Cell for electrons and holes. 42 00:01:59,940 --> 00:02:01,480 An electric field is created when 43 00:02:01,480 --> 00:02:04,240 positive and negative charges are separated. 44 00:02:04,240 --> 00:02:08,919 As you know, opposite charges attract and like charges repel. 45 00:02:08,919 --> 00:02:11,020 We'll exploit this property by creating 46 00:02:11,020 --> 00:02:13,920 a sheet of positive charges on the left and negative charges 47 00:02:13,920 --> 00:02:16,900 on the right, thus producing an electric field, which 48 00:02:16,900 --> 00:02:18,990 we denote with the Greek letter z. 49 00:02:18,990 --> 00:02:21,460 If you were to insert a negatively charged particle, 50 00:02:21,460 --> 00:02:23,710 such as an electron, into this field 51 00:02:23,710 --> 00:02:26,310 it would move toward the positive charges. 52 00:02:26,310 --> 00:02:29,710 Alternatively, if you put a positively charged particle 53 00:02:29,710 --> 00:02:33,330 it would move toward the negative charges. 54 00:02:33,330 --> 00:02:36,040 We're able to create an electric field inside our Solar Cell 55 00:02:36,040 --> 00:02:39,320 by using different dopants on either side of the device. 56 00:02:39,320 --> 00:02:42,820 Here we have our silicon lattice, which is un-doped. 57 00:02:42,820 --> 00:02:44,990 We'll start by replacing some of the silicon atoms 58 00:02:44,990 --> 00:02:47,180 with phosphorus atoms on one side. 59 00:02:47,180 --> 00:02:51,200 On the opposite side we'll put in boron atoms. 60 00:02:51,200 --> 00:02:54,070 To focus on our dopant atoms and the mobile 61 00:02:54,070 --> 00:02:57,800 charges they introduce we'll fade out the silicon lattice. 62 00:02:57,800 --> 00:02:59,800 Recall that phosphorus atoms introduce 63 00:02:59,800 --> 00:03:03,010 static positive charges in mobile negative charges. 64 00:03:03,010 --> 00:03:05,620 While boron atoms introduce static negative charges 65 00:03:05,620 --> 00:03:08,040 in mobile positive charges. 66 00:03:08,040 --> 00:03:10,890 All the mobile charges are free to move around at random. 67 00:03:10,890 --> 00:03:13,250 A process known as diffusion. 68 00:03:13,250 --> 00:03:15,610 Here we see a single electron moving around 69 00:03:15,610 --> 00:03:16,880 on its random walk. 70 00:03:16,880 --> 00:03:20,110 During this random motion if an electron and hole encounter 71 00:03:20,110 --> 00:03:23,380 each other they neutralize and effectively vanish. 72 00:03:23,380 --> 00:03:25,490 As this process of holes and electrons 73 00:03:25,490 --> 00:03:27,035 randomly defusing and neutralizing 74 00:03:27,035 --> 00:03:29,750 as the interface continues, the total number 75 00:03:29,750 --> 00:03:32,490 of mobile charges in the device decreases. 76 00:03:32,490 --> 00:03:34,240 This leaves a region at the interface 77 00:03:34,240 --> 00:03:36,620 of immobile static charges where the net charge 78 00:03:36,620 --> 00:03:40,170 is negative on one side and positive on the other. 79 00:03:40,170 --> 00:03:43,050 These opposing sheets of charge create an electric field 80 00:03:43,050 --> 00:03:46,550 of the interface, which at this point is very weak. 81 00:03:46,550 --> 00:03:48,870 As charges continue to diffuse, they're 82 00:03:48,870 --> 00:03:51,610 still able to move across this weak electric field 83 00:03:51,610 --> 00:03:54,110 and neutralize. 84 00:03:54,110 --> 00:03:56,380 As this happens, the sheets of net positive 85 00:03:56,380 --> 00:03:58,940 and net negative static charges widen 86 00:03:58,940 --> 00:04:02,370 and the electric field grows in strength. 87 00:04:02,370 --> 00:04:04,470 Now that the electric field is stronger, 88 00:04:04,470 --> 00:04:06,860 as other mobile charges continue to move and diffuse 89 00:04:06,860 --> 00:04:08,750 around the lattice, they're now repelled 90 00:04:08,750 --> 00:04:11,630 by the field and electrons to the left and holes stay 91 00:04:11,630 --> 00:04:13,994 to the right. 92 00:04:13,994 --> 00:04:15,660 It is this electric field that separates 93 00:04:15,660 --> 00:04:18,320 light generated mobile charges and pushes them 94 00:04:18,320 --> 00:04:21,440 to the extreme ends of the device. 95 00:04:21,440 --> 00:04:24,440 The image we see now is our Solar Cell in the dark. 96 00:04:24,440 --> 00:04:28,310 However, recall that our silicon atoms are still present. 97 00:04:28,310 --> 00:04:30,210 And if light strikes our silicon atom, 98 00:04:30,210 --> 00:04:33,720 a mobile hole and electron is generated. 99 00:04:33,720 --> 00:04:36,044 As these mobile charges move around randomly 100 00:04:36,044 --> 00:04:37,710 there's a chance that they will randomly 101 00:04:37,710 --> 00:04:39,420 encounter the electric field. 102 00:04:39,420 --> 00:04:42,780 The mobile electron will get repelled by the electric field. 103 00:04:42,780 --> 00:04:45,384 However, the mobile hole will get swept to the other side 104 00:04:45,384 --> 00:04:46,300 by the electric field. 105 00:04:50,910 --> 00:04:52,320 Now, let's zoom out. 106 00:04:52,320 --> 00:04:54,560 We can see that after the electric field has pushed 107 00:04:54,560 --> 00:04:56,860 our light excited electron and hole to the left 108 00:04:56,860 --> 00:04:59,760 and right respectively, we now have an extra negative charge 109 00:04:59,760 --> 00:05:02,310 on the left and extra positive charge on the right. 110 00:05:04,980 --> 00:05:07,470 If we connect a wire to short the two opposite sides 111 00:05:07,470 --> 00:05:09,750 together the excess electrons are 112 00:05:09,750 --> 00:05:12,790 attracted to the excess holes on the opposite side. 113 00:05:12,790 --> 00:05:16,960 This attraction is what drives electricity through our wire. 114 00:05:16,960 --> 00:05:19,470 As light continually shines on the Solar Cell 115 00:05:19,470 --> 00:05:22,120 charges are constantly being pushed out of the device 116 00:05:22,120 --> 00:05:23,510 and driving the electric current. 117 00:05:27,632 --> 00:05:29,750 Now hopefully you understand the basics 118 00:05:29,750 --> 00:05:33,060 of how these amazing, but rather simple, devices work. 119 00:05:33,060 --> 00:05:35,900 We hope that this knowledge will provide the basic foundation 120 00:05:35,900 --> 00:05:38,900 while tackling more difficult and abstract concepts while you 121 00:05:38,900 --> 00:05:40,610 learn the material in this course. 122 00:05:40,610 --> 00:05:43,750 I'm Joe Sullivan, thanks for watching.