1 00:00:00,050 --> 00:00:01,508 PRESENTER: The following content is 2 00:00:01,508 --> 00:00:03,800 provided under a Creative Commons license. 3 00:00:03,800 --> 00:00:06,530 Your support will help MIT OpenCourseWare continue 4 00:00:06,530 --> 00:00:10,110 to offer high quality educational resources for free. 5 00:00:10,110 --> 00:00:12,690 To make a donation or view additional materials 6 00:00:12,690 --> 00:00:16,590 from hundreds of MIT courses, visit MIT OpenCourseWare 7 00:00:16,590 --> 00:00:17,245 at ocw.mit.edu. 8 00:00:25,160 --> 00:00:29,900 PROFESSOR: Today we begin with the harmonic oscillator. 9 00:00:29,900 --> 00:00:33,010 And before we get into the harmonic oscillator, 10 00:00:33,010 --> 00:00:35,840 I want to touch on a few concepts that 11 00:00:35,840 --> 00:00:40,690 have been mentioned in class and just elaborate on them. 12 00:00:40,690 --> 00:00:45,550 It is the issue of nodes, and how solutions look at, 13 00:00:45,550 --> 00:00:48,920 and why solutions have more and more nodes, why 14 00:00:48,920 --> 00:00:52,360 the ground state has no nodes. 15 00:00:52,360 --> 00:00:55,220 This kind of stuff. 16 00:00:55,220 --> 00:01:02,600 So these are just a collection of remarks and an argument 17 00:01:02,600 --> 00:01:07,830 for you to understand a little more intuitively why 18 00:01:07,830 --> 00:01:11,620 these properties hold. 19 00:01:11,620 --> 00:01:15,430 So one first thing I want to mention 20 00:01:15,430 --> 00:01:20,010 is, if you have a Schrodinger equation for an energy 21 00:01:20,010 --> 00:01:21,020 eigenstate. 22 00:01:21,020 --> 00:01:28,040 Schrodinger equation for an energy eigenstate. 23 00:01:34,180 --> 00:01:43,060 You have an equation of the from minus h squared over 2m. 24 00:01:43,060 --> 00:01:53,230 d second dx squared psi of x plus v of x psi of x equal 25 00:01:53,230 --> 00:01:57,360 e times psi of x. 26 00:01:57,360 --> 00:02:00,030 Now the issue of this equation is 27 00:02:00,030 --> 00:02:05,820 that you're trying to solve for two things at the same time. 28 00:02:05,820 --> 00:02:09,550 If you're looking at what we call bound states, now 29 00:02:09,550 --> 00:02:11,570 what is a bound state? 30 00:02:11,570 --> 00:02:18,040 A bound state is something that is not extended all that much. 31 00:02:18,040 --> 00:02:22,270 So a bound state will be a wave function 32 00:02:22,270 --> 00:02:29,210 that goes to 0 as the absolute value of x goes to infinity. 33 00:02:29,210 --> 00:02:34,930 So it's a probability function that certainly doesn't 34 00:02:34,930 --> 00:02:36,980 extend all the way to infinity. 35 00:02:36,980 --> 00:02:39,090 It just collapses. 36 00:02:39,090 --> 00:02:41,000 It's normalizable. 37 00:02:41,000 --> 00:02:42,790 So these are bound states, and you're 38 00:02:42,790 --> 00:02:45,560 looking for bound states of this equation. 39 00:02:45,560 --> 00:02:49,680 And your difficulty is that you don't know psi, 40 00:02:49,680 --> 00:02:52,160 and you don't know E either. 41 00:02:52,160 --> 00:02:57,700 So you have to solve a problem in which, if you were thinking 42 00:02:57,700 --> 00:03:00,570 oh this is just a plain differential equation, 43 00:03:00,570 --> 00:03:03,530 give me the value of E. We know the potential, 44 00:03:03,530 --> 00:03:04,650 just calculate it. 45 00:03:04,650 --> 00:03:07,880 That's not the way it works in quantum mechanics, 46 00:03:07,880 --> 00:03:11,450 because you need to have normalizable solutions. 47 00:03:11,450 --> 00:03:15,380 So at the end of the day, as will be very clear today, 48 00:03:15,380 --> 00:03:19,210 this E gets fixed. 49 00:03:19,210 --> 00:03:22,740 You cannot get arbitrary values of E's. 50 00:03:22,740 --> 00:03:27,060 So I want to make a couple of remarks about this equation. 51 00:03:27,060 --> 00:03:29,635 Is that there's this thing that can't happen. 52 00:03:34,230 --> 00:03:48,300 Certainly, if v of x is a smooth potential, then if you observer 53 00:03:48,300 --> 00:03:52,602 that the wave function vanishes at some point, 54 00:03:52,602 --> 00:03:55,880 and the derivative of the wave function 55 00:03:55,880 --> 00:03:59,600 vanishes at that same point, these two things 56 00:03:59,600 --> 00:04:05,070 imply that psi of x is identically 0. 57 00:04:05,070 --> 00:04:08,000 And therefore it means that you really 58 00:04:08,000 --> 00:04:09,530 are not interested in that. 59 00:04:09,530 --> 00:04:12,430 That's not a solution of the Schrodinger equation. 60 00:04:12,430 --> 00:04:16,530 Psi equals 0 is obviously solves this, but it's not interesting. 61 00:04:16,530 --> 00:04:19,250 It doesn't represent the particle. 62 00:04:19,250 --> 00:04:23,740 So what I claim here is that, if it happens 63 00:04:23,740 --> 00:04:25,540 to be that you're solving the Schrodinger 64 00:04:25,540 --> 00:04:28,035 problem with some potential that is smooth, 65 00:04:28,035 --> 00:04:30,960 you can take derivatives of it. 66 00:04:30,960 --> 00:04:34,670 And then you encounter that the wave function vanishes 67 00:04:34,670 --> 00:04:38,830 at some point, and its slope vanishes at that same point. 68 00:04:38,830 --> 00:04:41,970 Then the wave function vanishes completely. 69 00:04:41,970 --> 00:04:45,120 So you cannot have a wave function, 70 00:04:45,120 --> 00:04:48,210 a psi of x that does the following. 71 00:04:48,210 --> 00:04:51,510 Comes down here. 72 00:04:51,510 --> 00:04:54,850 It becomes an inflection point and goes down. 73 00:04:54,850 --> 00:04:56,105 This is not allowed. 74 00:05:03,160 --> 00:05:07,610 If the wave function vanishes at some point, 75 00:05:07,610 --> 00:05:11,940 then the wave function is going to do this. 76 00:05:11,940 --> 00:05:16,450 It's going to hit at an angle, because you cannot have that 77 00:05:16,450 --> 00:05:20,640 the wave function is 0 and needs the derivative 0 at the same 78 00:05:20,640 --> 00:05:21,460 point. 79 00:05:21,460 --> 00:05:23,330 And the reason is simple. 80 00:05:23,330 --> 00:05:25,390 I'm not going to prove it now here. 81 00:05:25,390 --> 00:05:29,930 It is that you have a second order differential equation, 82 00:05:29,930 --> 00:05:32,200 and a second order differential equation 83 00:05:32,200 --> 00:05:35,680 is completely determined by knowing the function 84 00:05:35,680 --> 00:05:38,800 at the point and the the derivative at the point. 85 00:05:38,800 --> 00:05:42,570 And if both are 0s, like the most trivial kind 86 00:05:42,570 --> 00:05:46,610 of initial condition, the only solution consistent with this 87 00:05:46,610 --> 00:05:49,610 is psi equals 0 everywhere. 88 00:05:49,610 --> 00:05:51,600 So this can't happen. 89 00:05:51,600 --> 00:05:54,460 And it's something good for you to remember. 90 00:05:54,460 --> 00:05:57,040 If you have to do a plot of a wave function, 91 00:05:57,040 --> 00:05:59,240 you should never have this. 92 00:05:59,240 --> 00:06:04,855 So this is what we call the node in a wave function. 93 00:06:10,280 --> 00:06:13,780 It's a place where the wave function vanishes, 94 00:06:13,780 --> 00:06:15,800 and the derivative of the wave function 95 00:06:15,800 --> 00:06:17,360 better not vanish at that point. 96 00:06:21,720 --> 00:06:28,590 So this is one claim that it's not hard to prove, 97 00:06:28,590 --> 00:06:30,830 but we just don't try to do it. 98 00:06:30,830 --> 00:06:35,270 And there's another claim that I want you to be aware of. 99 00:06:35,270 --> 00:06:43,470 That for bound states in one dimension, 100 00:06:43,470 --> 00:06:50,650 in the kind of thing that we're doing now in one dimension, 101 00:06:50,650 --> 00:06:55,435 no degeneracy is possible. 102 00:07:01,410 --> 00:07:03,160 What do I mean by that? 103 00:07:03,160 --> 00:07:07,100 You will never find two bound states 104 00:07:07,100 --> 00:07:09,640 of a potential that are different that 105 00:07:09,640 --> 00:07:10,730 have the same energy. 106 00:07:10,730 --> 00:07:14,620 It's just absolutely impossible. 107 00:07:14,620 --> 00:07:19,076 It's a very wonderful result, but also I'm 108 00:07:19,076 --> 00:07:20,200 not going to prove it here. 109 00:07:20,200 --> 00:07:24,070 Maybe it will be given as an exercise later in the course. 110 00:07:24,070 --> 00:07:27,830 And it's discussed in 805 as well. 111 00:07:27,830 --> 00:07:31,540 But that's another statement that is very important. 112 00:07:31,540 --> 00:07:33,630 There's no degeneracy. 113 00:07:33,630 --> 00:07:38,610 Now you've looked at this simple potential, 114 00:07:38,610 --> 00:07:45,910 the square well infinite one. 115 00:07:45,910 --> 00:07:47,430 And how does it look? 116 00:07:47,430 --> 00:07:53,670 You have x going from 0 to a. 117 00:07:53,670 --> 00:07:56,220 And the potential is 0. 118 00:07:56,220 --> 00:07:58,660 From 0 to a is infinite otherwise. 119 00:07:58,660 --> 00:08:02,540 The particle is bound to stay inside the two 120 00:08:02,540 --> 00:08:04,920 walls of this potential. 121 00:08:04,920 --> 00:08:08,830 So in here we've plotted the potential as a function of x. 122 00:08:08,830 --> 00:08:11,270 Here is x. 123 00:08:11,270 --> 00:08:13,890 And the wave functions are things that you know already. 124 00:08:13,890 --> 00:08:14,649 Yes? 125 00:08:14,649 --> 00:08:17,190 AUDIENCE: Is it true if you have two wells next to each other 126 00:08:17,190 --> 00:08:20,299 that there's still no degeneracy if it's an infinite barrier? 127 00:08:20,299 --> 00:08:22,090 PROFESSOR: If there's two wells and there's 128 00:08:22,090 --> 00:08:24,370 an infinite barrier between them, 129 00:08:24,370 --> 00:08:26,600 it's like having two universes. 130 00:08:26,600 --> 00:08:31,250 So it's not really a one dimensional problem. 131 00:08:31,250 --> 00:08:33,870 If you have an infinite barrier like two worlds 132 00:08:33,870 --> 00:08:35,250 that can talk to each other. 133 00:08:35,250 --> 00:08:37,750 So yes, then you would have degeneracy. 134 00:08:37,750 --> 00:08:42,570 It's like saying you can have here one atom of hydrogen 135 00:08:42,570 --> 00:08:46,200 or something in one energy level, here another one. 136 00:08:46,200 --> 00:08:47,550 They don't talk to each other. 137 00:08:47,550 --> 00:08:49,520 They're degenerate states. 138 00:08:49,520 --> 00:08:53,375 But in general, we're talking about normal potentials 139 00:08:53,375 --> 00:08:55,770 that are preferably smooth. 140 00:08:55,770 --> 00:08:59,170 Most of these things are true even if they're not smooth. 141 00:08:59,170 --> 00:09:01,140 But it's a little more delicate. 142 00:09:01,140 --> 00:09:02,840 But certainly two potentials that 143 00:09:02,840 --> 00:09:05,030 are separated by an infinite barrier 144 00:09:05,030 --> 00:09:10,440 is not part of what we really want to consider. 145 00:09:10,440 --> 00:09:16,870 OK so these wave functions start with m equals 0, 1, 2, 146 00:09:16,870 --> 00:09:25,040 3, and psi ends of x are square root of 2 over a sin n 147 00:09:25,040 --> 00:09:28,340 plus 1 pi x over a. 148 00:09:28,340 --> 00:09:30,700 Things that you've seen already. 149 00:09:30,700 --> 00:09:36,030 And En, the energies are ever growing 150 00:09:36,030 --> 00:09:41,680 as a function of the integer n that characterizes them. 151 00:09:41,680 --> 00:09:44,650 2ma squared. 152 00:09:44,650 --> 00:09:49,750 And the thing that you notice is that psi 0 153 00:09:49,750 --> 00:09:52,790 has technically no nodes. 154 00:09:52,790 --> 00:09:55,120 That is to say these wave functions have 155 00:09:55,120 --> 00:09:58,420 to varnish at the end, because the potential becomes infinite, 156 00:09:58,420 --> 00:10:01,340 which means a particle really can go through. 157 00:10:01,340 --> 00:10:03,370 The wave function has to be continuous. 158 00:10:03,370 --> 00:10:06,570 There cannot be any wave function to the left. 159 00:10:06,570 --> 00:10:08,730 So it has to vanish here. 160 00:10:08,730 --> 00:10:11,350 These things don't count as nodes. 161 00:10:11,350 --> 00:10:16,020 It is like a bound state has to vanish at infinity. 162 00:10:16,020 --> 00:10:18,470 And that's not what we count the node. 163 00:10:18,470 --> 00:10:20,910 A node is somewhere in the middle 164 00:10:20,910 --> 00:10:24,030 of the range of x where the wave function vanishes. 165 00:10:24,030 --> 00:10:25,640 So this is the ground state. 166 00:10:25,640 --> 00:10:30,750 This is psi zero has no nodes. 167 00:10:30,750 --> 00:10:35,500 Psi one would be something like that, has one node. 168 00:10:39,170 --> 00:10:42,900 And try the next ones. 169 00:10:42,900 --> 00:10:44,330 They have more and more nodes. 170 00:10:44,330 --> 00:10:47,015 So psi n has n nodes. 171 00:10:51,600 --> 00:10:58,480 And the interesting thing is that this result actually 172 00:10:58,480 --> 00:11:02,550 is true for extremely general potentials. 173 00:11:02,550 --> 00:11:05,200 You don't have to just do the square well 174 00:11:05,200 --> 00:11:08,240 to see that the ground state has no nodes. 175 00:11:08,240 --> 00:11:12,580 That first excited state was one node, and so on and so forth. 176 00:11:12,580 --> 00:11:16,580 It's true in general. 177 00:11:16,580 --> 00:11:18,710 This is actually a very nice result, 178 00:11:18,710 --> 00:11:21,590 but its difficult to prove. 179 00:11:21,590 --> 00:11:26,370 In fact, it's pretty hard to prove. 180 00:11:26,370 --> 00:11:28,590 So there is a nice argument. 181 00:11:28,590 --> 00:11:32,540 Not 100% rigorous, but thoroughly nice 182 00:11:32,540 --> 00:11:34,720 and really physical that I'm going 183 00:11:34,720 --> 00:11:37,890 to present to you why this result is true. 184 00:11:37,890 --> 00:11:40,030 So let's try to do that. 185 00:11:40,030 --> 00:11:41,430 So here is the general case. 186 00:11:41,430 --> 00:11:46,470 So I'm going to take a smooth v of x. 187 00:11:46,470 --> 00:11:48,160 That will be of this kind. 188 00:11:48,160 --> 00:11:55,310 The potential, here is x, and this potential 189 00:11:55,310 --> 00:12:01,210 is going to be like that. 190 00:12:01,210 --> 00:12:02,325 Smooth all over. 191 00:12:05,460 --> 00:12:09,440 And I will actually have it that it actually 192 00:12:09,440 --> 00:12:12,630 goes to infinity as x goes to infinity. 193 00:12:12,630 --> 00:12:15,290 Many of these things are really not necessary, 194 00:12:15,290 --> 00:12:19,610 but it simplifies our life. 195 00:12:24,290 --> 00:12:33,272 OK, so here is a result that it's known to be true. 196 00:12:33,272 --> 00:12:36,390 If this thing grows to infinity, the potential never 197 00:12:36,390 --> 00:12:41,210 stops growing, you get infinite number of bound states 198 00:12:41,210 --> 00:12:42,680 at fixed energies. 199 00:12:42,680 --> 00:12:45,380 One energy, two energy, three energy, 200 00:12:45,380 --> 00:12:47,330 infinite number of bound states. 201 00:12:50,710 --> 00:12:53,125 Number of bound states. 202 00:12:57,020 --> 00:12:58,550 That's a fact. 203 00:12:58,550 --> 00:13:01,810 I will not try to prove it. 204 00:13:01,810 --> 00:13:04,000 We'll do it for the harmonic oscillator. 205 00:13:04,000 --> 00:13:05,750 We'll see those infinite number of states, 206 00:13:05,750 --> 00:13:09,110 but here we can't prove it easily. 207 00:13:09,110 --> 00:13:11,120 Nevertheless, what I want to argue 208 00:13:11,120 --> 00:13:15,510 for you is that these states, as the first one, 209 00:13:15,510 --> 00:13:17,690 will have no nodes. 210 00:13:17,690 --> 00:13:20,490 The second state, the first excited state, 211 00:13:20,490 --> 00:13:21,710 will have one node. 212 00:13:21,710 --> 00:13:24,290 Next will have two nodes, three nodes, four nodes. 213 00:13:24,290 --> 00:13:29,050 We want to understand what is this issue of the nodes. 214 00:13:29,050 --> 00:13:31,270 OK. 215 00:13:31,270 --> 00:13:34,000 You're not trying to prove everything. 216 00:13:34,000 --> 00:13:36,360 But we're trying to prove or understand 217 00:13:36,360 --> 00:13:39,120 something that is very important. 218 00:13:39,120 --> 00:13:40,780 So how do we prove this? 219 00:13:40,780 --> 00:13:44,800 Or how do we understand that the nodes-- so there will 220 00:13:44,800 --> 00:13:46,880 be an infinite number of bound states, 221 00:13:46,880 --> 00:13:53,440 psi 0, psi 1, psi 2, up to psi n, and it goes on. 222 00:13:53,440 --> 00:13:57,485 And psi n has n nodes. 223 00:14:01,410 --> 00:14:02,090 All right. 224 00:14:06,290 --> 00:14:11,030 So what I'm going to do, in order to understand this, 225 00:14:11,030 --> 00:14:14,230 is I'm going to produce what we will call screened potentials. 226 00:14:16,930 --> 00:14:19,620 Screened potentials. 227 00:14:23,370 --> 00:14:28,390 I'm going to select the lowest point of the potential 228 00:14:28,390 --> 00:14:29,990 here for convenience. 229 00:14:29,990 --> 00:14:35,000 And I'm going to call it x equals 0 is the lowest point. 230 00:14:40,770 --> 00:14:46,860 And the screen potential will have a parameter a. 231 00:14:46,860 --> 00:14:52,280 It's a potential which is equal to v 232 00:14:52,280 --> 00:14:57,470 of x if the absolute value of x is less than a. 233 00:14:57,470 --> 00:15:04,580 And its infinity if the absolute value of x is greater than a. 234 00:15:04,580 --> 00:15:07,810 So I come here, and I want to see 235 00:15:07,810 --> 00:15:11,410 this is this potential, v of x, what 236 00:15:11,410 --> 00:15:14,651 is the screened potential for sum a? 237 00:15:14,651 --> 00:15:19,170 Well, I wanted colored chalk, but I don't have it. 238 00:15:19,170 --> 00:15:23,190 I go mark a here minus a. 239 00:15:23,190 --> 00:15:26,600 Here are the points between x and a. 240 00:15:26,600 --> 00:15:29,096 Absolute value of x less than a. 241 00:15:29,096 --> 00:15:32,290 Throughout this region the screened potential 242 00:15:32,290 --> 00:15:35,540 is the potential that you have. 243 00:15:35,540 --> 00:15:39,160 Nevertheless, for the rest, its infinite. 244 00:15:39,160 --> 00:15:42,820 So the screened potential is this thing. 245 00:15:42,820 --> 00:15:45,750 Is infinite there, and it's here this thing. 246 00:15:48,470 --> 00:15:52,410 So it's just some potential. 247 00:15:52,410 --> 00:15:55,150 You take it a screen and you just see 248 00:15:55,150 --> 00:15:58,422 one part of the potential, and let it go to infinity. 249 00:15:58,422 --> 00:15:59,630 So that's a screen potential. 250 00:16:02,190 --> 00:16:06,200 So now what I'm going to do is that I'm 251 00:16:06,200 --> 00:16:08,550 going to try to argue that you could 252 00:16:08,550 --> 00:16:13,590 try to find the bound state of the screen potential. 253 00:16:13,590 --> 00:16:17,950 Unless you remove the screen, you will find, 254 00:16:17,950 --> 00:16:20,830 as you let a go to infinity, you will 255 00:16:20,830 --> 00:16:25,560 find the bound states of the original potential. 256 00:16:25,560 --> 00:16:27,460 It's reasonable that that's true, 257 00:16:27,460 --> 00:16:29,240 because as you remove the screen, 258 00:16:29,240 --> 00:16:31,760 you're letting more of the potential be exposed, 259 00:16:31,760 --> 00:16:33,730 and more of the potential be exposed. 260 00:16:33,730 --> 00:16:37,440 And the wave functions eventually die, so as the time 261 00:16:37,440 --> 00:16:40,570 that you're very far away, you affect the wave functions 262 00:16:40,570 --> 00:16:41,425 less and less. 263 00:16:44,190 --> 00:16:45,680 So that's the argument. 264 00:16:45,680 --> 00:16:48,260 We're going to try to argue that we're 265 00:16:48,260 --> 00:16:50,150 going to look at the bound states 266 00:16:50,150 --> 00:16:54,550 of the screened potentials and see what happened, whether they 267 00:16:54,550 --> 00:16:58,490 tell us about the bound states the original potential. 268 00:16:58,490 --> 00:17:02,680 So for this, I'm going to begin with a screen 269 00:17:02,680 --> 00:17:08,210 potential in which a goes to 0 and say 270 00:17:08,210 --> 00:17:11,530 that a is equal to epsilon, very small. 271 00:17:11,530 --> 00:17:13,839 So what potential so do I have? 272 00:17:13,839 --> 00:17:21,390 A very tiny potential here from epsilon to minus epsilon. 273 00:17:21,390 --> 00:17:26,270 Now I chose the original point down here to be the minimum. 274 00:17:26,270 --> 00:17:31,300 So actually, the bottom part of the potential is really flat. 275 00:17:31,300 --> 00:17:35,240 And if you take epsilon going to 0, 276 00:17:35,240 --> 00:17:38,220 well, the potential might do this, 277 00:17:38,220 --> 00:17:42,390 but really at the bottom for sufficiently small epsilon, 278 00:17:42,390 --> 00:17:48,500 this is an infinite square well with psis to epsilon. 279 00:17:52,900 --> 00:17:57,520 I chose the minimum so that you don't get something like this. 280 00:17:57,520 --> 00:17:59,310 If it would be a point with a slope, 281 00:17:59,310 --> 00:18:00,710 this would be an ugly thing. 282 00:18:00,710 --> 00:18:02,460 So let's choose the minimum. 283 00:18:02,460 --> 00:18:05,770 And we have the screen potential here, and that's it. 284 00:18:05,770 --> 00:18:07,070 Now look what we do. 285 00:18:07,070 --> 00:18:11,065 We say all right, here there is a ground state. 286 00:18:13,680 --> 00:18:16,060 Very tiny. 287 00:18:16,060 --> 00:18:17,280 Goes like that. 288 00:18:17,280 --> 00:18:18,410 Vanishes here. 289 00:18:18,410 --> 00:18:21,090 Vanishes there. 290 00:18:21,090 --> 00:18:23,920 And has no nodes. 291 00:18:23,920 --> 00:18:24,720 Very tiny. 292 00:18:24,720 --> 00:18:28,190 You know the two 0s are very close to each other. 293 00:18:28,190 --> 00:18:30,550 And now I'm going to try to increase 294 00:18:30,550 --> 00:18:35,850 the value of the screen a. 295 00:18:35,850 --> 00:18:43,790 So suppose we've increased the screen, 296 00:18:43,790 --> 00:18:49,040 and now the potential is here. 297 00:18:49,040 --> 00:18:53,050 And now we have a finite screen. 298 00:18:53,050 --> 00:18:55,060 Here is the potential. 299 00:18:55,060 --> 00:18:57,090 And I look at the wave function. 300 00:18:57,090 --> 00:18:58,520 How it looks. 301 00:18:58,520 --> 00:19:00,910 Here is psi 0. 302 00:19:00,910 --> 00:19:03,480 This ground state psi 0. 303 00:19:06,030 --> 00:19:13,410 Well, since this thing in here, the potential becomes infinite, 304 00:19:13,410 --> 00:19:15,500 the wave function still must vanish here 305 00:19:15,500 --> 00:19:18,150 and still must vanish here. 306 00:19:18,150 --> 00:19:23,830 Now just for your imagination, think of this. 307 00:19:23,830 --> 00:19:28,900 At this stage, it still more or less looks like this. 308 00:19:28,900 --> 00:19:30,830 Maybe. 309 00:19:30,830 --> 00:19:38,230 Now I'm going to ask, as I increase, can I produce a node? 310 00:19:38,230 --> 00:19:40,550 And look what's going to happen. 311 00:19:40,550 --> 00:19:44,110 So suppose it might happen that, as you increase, 312 00:19:44,110 --> 00:19:46,000 suddenly you produce a node. 313 00:19:46,000 --> 00:19:48,257 So here's what I'm saying here. 314 00:19:48,257 --> 00:19:49,340 I'm going to show it here. 315 00:19:49,340 --> 00:19:52,200 Suppose up to this point, there is no node. 316 00:19:52,200 --> 00:19:56,000 But then when I double it, when I increase it 317 00:19:56,000 --> 00:20:01,760 to twice the size, when I go to screen potential like that, 318 00:20:01,760 --> 00:20:05,970 suddenly there is a node in the middle. 319 00:20:05,970 --> 00:20:08,340 So if there is a node in the middle, 320 00:20:08,340 --> 00:20:12,660 one thing that could have happened is that you have this. 321 00:20:15,820 --> 00:20:19,920 And now look what must have happened then. 322 00:20:19,920 --> 00:20:26,560 As I stretch this, this slope must have been going down, 323 00:20:26,560 --> 00:20:31,080 and down, and down, until it flips to the other side 324 00:20:31,080 --> 00:20:33,250 to produce a node here. 325 00:20:33,250 --> 00:20:34,960 It could have happened on this side, 326 00:20:34,960 --> 00:20:36,810 but it's the same, so the argument is just 327 00:20:36,810 --> 00:20:38,220 done with this side. 328 00:20:38,220 --> 00:20:41,780 To produce a node you could have done somehow 329 00:20:41,780 --> 00:20:44,900 the slope here must have changed sine. 330 00:20:44,900 --> 00:20:49,230 But for that to happen continuously, at some point 331 00:20:49,230 --> 00:20:51,305 the this slope must have been 0. 332 00:20:54,660 --> 00:20:58,590 But you cannot have a 0 and 0 slope. 333 00:20:58,590 --> 00:21:04,010 So this thing can't flip, can't do this. 334 00:21:04,010 --> 00:21:05,810 Another thing that could have happened 335 00:21:05,810 --> 00:21:09,060 is that when we are here already, 336 00:21:09,060 --> 00:21:14,080 maybe the wave function looks like that. 337 00:21:14,080 --> 00:21:17,120 It doesn't flip at the edges, but produces something 338 00:21:17,120 --> 00:21:18,290 like that. 339 00:21:18,290 --> 00:21:21,590 But the only way this can happen continuously, 340 00:21:21,590 --> 00:21:25,390 and this potential is changing continuously, 341 00:21:25,390 --> 00:21:29,110 is for this thing at some intermediate stage, 342 00:21:29,110 --> 00:21:34,310 as you keep stretching the screen, this sort of starts 343 00:21:34,310 --> 00:21:37,560 to produce a depression here. 344 00:21:37,560 --> 00:21:42,000 And at some point, to get here it has to do this. 345 00:21:42,000 --> 00:21:43,530 But it can't do this either. 346 00:21:43,530 --> 00:21:46,940 It cannot vanish and have derivative like that. 347 00:21:46,940 --> 00:21:49,990 So actually, as you stretch the screen, 348 00:21:49,990 --> 00:21:54,320 there's no way to produce a node. 349 00:21:54,320 --> 00:21:57,360 That property forbids it. 350 00:21:57,360 --> 00:22:01,470 So by the time you go and take the screen to infinity, 351 00:22:01,470 --> 00:22:04,255 this wave function has no nodes. 352 00:22:07,620 --> 00:22:12,100 So that proves it that the ground state has no nodes. 353 00:22:12,100 --> 00:22:15,300 You could call this a physicist proof, 354 00:22:15,300 --> 00:22:19,880 which means-- not in the pejorative way. 355 00:22:19,880 --> 00:22:24,330 It means that it's reasonable, it's intuitive, 356 00:22:24,330 --> 00:22:28,460 and a mathematician working hard could make it rigorous. 357 00:22:32,300 --> 00:22:36,280 A bad physicist proof is one that is a little sloppy 358 00:22:36,280 --> 00:22:39,990 and no mathematician could fix it and make it work. 359 00:22:39,990 --> 00:22:44,370 So I think this is a good physics proof in that sense. 360 00:22:44,370 --> 00:22:46,460 Probably you can construct a real proof, 361 00:22:46,460 --> 00:22:50,410 or based on this, a very precise proof. 362 00:22:50,410 --> 00:22:53,970 Now look at excited states. 363 00:22:53,970 --> 00:23:00,090 Suppose you take now here this screen very little, 364 00:23:00,090 --> 00:23:05,375 and now consider the third excited state, psi three. 365 00:23:08,250 --> 00:23:10,840 I'm sorry, we'll call this psi 2 because it has two nodes. 366 00:23:13,880 --> 00:23:15,565 Well, maybe I should do psi 1. 367 00:23:18,610 --> 00:23:19,710 Psi 1. 368 00:23:19,710 --> 00:23:21,670 One node. 369 00:23:21,670 --> 00:23:23,200 Same thing. 370 00:23:23,200 --> 00:23:27,750 As you increase it, there's no way 371 00:23:27,750 --> 00:23:29,960 to create another node continuously. 372 00:23:29,960 --> 00:23:32,620 Because again, you have to flip at the edges, 373 00:23:32,620 --> 00:23:34,910 or you have to depress in the middle. 374 00:23:34,910 --> 00:23:38,640 So this one will evolve to a wave function that 375 00:23:38,640 --> 00:23:43,500 will have one node in the whole big potential. 376 00:23:43,500 --> 00:23:49,680 Now stayed does that state have more energy 377 00:23:49,680 --> 00:23:52,450 than the ground state? 378 00:23:52,450 --> 00:23:59,530 Well, it certainly begins with a small screen with more energy, 379 00:23:59,530 --> 00:24:03,730 because in the square well psi 1 has more energy. 380 00:24:03,730 --> 00:24:08,570 And that energy should be clear that it's not 381 00:24:08,570 --> 00:24:12,440 going to go below the energy of the ground state. 382 00:24:12,440 --> 00:24:13,640 Why? 383 00:24:13,640 --> 00:24:17,220 Because if it went below the energy of the ground state 384 00:24:17,220 --> 00:24:21,500 slowly, at some point for some value of the screen, 385 00:24:21,500 --> 00:24:25,160 it would have the same energy as the ground state. 386 00:24:25,160 --> 00:24:29,960 But no degeneracy is possible in one dimensional problems. 387 00:24:29,960 --> 00:24:31,750 So that can't happen. 388 00:24:31,750 --> 00:24:32,820 Cannot have that. 389 00:24:32,820 --> 00:24:35,980 So it will always stay a little higher. 390 00:24:35,980 --> 00:24:39,810 And therefore with one node you will be a little higher energy. 391 00:24:39,810 --> 00:24:43,390 With two nodes will be higher and higher. 392 00:24:43,390 --> 00:24:44,570 And that's it. 393 00:24:44,570 --> 00:24:45,940 That's the argument. 394 00:24:45,940 --> 00:24:51,260 Now, we've argued by this continuous deformation process 395 00:24:51,260 --> 00:24:54,760 that this potential not only has these bound states, 396 00:24:54,760 --> 00:25:05,100 but this is n nodes and En is greater than En prime for n 397 00:25:05,100 --> 00:25:08,890 greater than n prime. 398 00:25:08,890 --> 00:25:12,340 So the more nodes, the more energy. 399 00:25:12,340 --> 00:25:15,920 Pretty nice result, and that's really 400 00:25:15,920 --> 00:25:19,630 all I wanted to say about this problem. 401 00:25:19,630 --> 00:25:21,210 Are there any questions? 402 00:25:21,210 --> 00:25:21,710 Any? 403 00:25:29,582 --> 00:25:31,070 OK. 404 00:25:31,070 --> 00:25:34,440 So what we do now is the harmonic oscillator. 405 00:25:34,440 --> 00:25:39,570 That's going to keep us busy for the rest of today's lecture. 406 00:25:39,570 --> 00:25:43,170 It's a very interesting problem. 407 00:25:43,170 --> 00:25:49,450 And it's a most famous quantum mechanics problem in a sense, 408 00:25:49,450 --> 00:25:55,310 because it happens to be useful in many, many applications. 409 00:25:55,310 --> 00:25:58,070 If you have any potential-- so what 410 00:25:58,070 --> 00:26:02,010 is the characteristic of the harmonic oscillator? 411 00:26:02,010 --> 00:26:03,245 Harmonic oscillator. 412 00:26:05,850 --> 00:26:08,720 Oscillator. 413 00:26:08,720 --> 00:26:15,580 Well, the energy operator is p squared over 2m plus, we write, 414 00:26:15,580 --> 00:26:19,910 one half m omega squared x squared 415 00:26:19,910 --> 00:26:23,180 where omega is this omega that you always 416 00:26:23,180 --> 00:26:27,230 think of angular velocity, or angular frequency. 417 00:26:27,230 --> 00:26:28,870 It's more like angular frequency. 418 00:26:28,870 --> 00:26:32,670 Omega has units of 1 over time. 419 00:26:32,670 --> 00:26:36,880 It's actually put 2pi over the period of an oscillation. 420 00:26:36,880 --> 00:26:40,090 And this you know from classical mechanics. 421 00:26:40,090 --> 00:26:43,730 If you have a harmonic oscillator of this form, yeah, 422 00:26:43,730 --> 00:26:47,620 it actually oscillates with this frequency. 423 00:26:47,620 --> 00:26:49,680 And E is the energy operator, and this 424 00:26:49,680 --> 00:26:53,020 is the energy of the oscillator. 425 00:26:53,020 --> 00:26:55,640 So what defines an oscillator? 426 00:26:55,640 --> 00:27:00,170 It's something in which the potential energy, this term 427 00:27:00,170 --> 00:27:01,950 is v of x. 428 00:27:01,950 --> 00:27:04,880 v of x is quadratic in x. 429 00:27:04,880 --> 00:27:07,870 That is a harmonic oscillator. 430 00:27:07,870 --> 00:27:10,910 Then you arrange the constants to make sense. 431 00:27:10,910 --> 00:27:13,260 This has units of energy, because this 432 00:27:13,260 --> 00:27:16,700 has units of length squared. 433 00:27:16,700 --> 00:27:18,820 1 over time squared. 434 00:27:18,820 --> 00:27:21,210 Length over time is velocity squared 435 00:27:21,210 --> 00:27:23,140 times mass is kinetic energy. 436 00:27:23,140 --> 00:27:26,680 So this term has the units of energy. 437 00:27:26,680 --> 00:27:29,440 And you good with that. 438 00:27:29,440 --> 00:27:30,930 And why is this useful? 439 00:27:30,930 --> 00:27:39,190 Because actually in any sort of arbitrary potential, rather 440 00:27:39,190 --> 00:27:42,030 general potential at least, whenever 441 00:27:42,030 --> 00:27:47,190 you have a minimum where the derivative vanishes, 442 00:27:47,190 --> 00:27:50,060 then the second derivative need not vanish. 443 00:27:50,060 --> 00:27:53,790 Then it's a good approximation to think 444 00:27:53,790 --> 00:27:57,810 of the potential at the minimum as a quadratic potential. 445 00:27:57,810 --> 00:28:02,840 It fits the potential nicely over a good region. 446 00:28:02,840 --> 00:28:06,190 And therefore when you have two molecules with a bound 447 00:28:06,190 --> 00:28:09,250 or something oscillating, there is a potential. 448 00:28:09,250 --> 00:28:11,780 It has a minimum at the equilibrium position. 449 00:28:11,780 --> 00:28:15,060 And the oscillations are governed 450 00:28:15,060 --> 00:28:18,110 by some harmonic oscillator. 451 00:28:18,110 --> 00:28:21,460 When you have photons in space time traveling, 452 00:28:21,460 --> 00:28:23,810 there is a set of harmonic oscillators 453 00:28:23,810 --> 00:28:27,420 that correspond to photons. 454 00:28:27,420 --> 00:28:28,830 Many, many applications. 455 00:28:28,830 --> 00:28:32,450 Endless amount of applications for the harmonic oscillator. 456 00:28:32,450 --> 00:28:36,080 So we really want to understand this system quantum 457 00:28:36,080 --> 00:28:37,570 mechanically. 458 00:28:37,570 --> 00:28:39,870 And what does that mean? 459 00:28:39,870 --> 00:28:43,790 Is that we really want to calculate and solve 460 00:28:43,790 --> 00:28:45,790 the Schrodinger equation. 461 00:28:45,790 --> 00:28:49,570 This is our first step in understanding the system. 462 00:28:49,570 --> 00:28:51,060 There's going to be a lot of work 463 00:28:51,060 --> 00:28:54,320 to be done even once we have the solutions of the Schrodinger 464 00:28:54,320 --> 00:28:54,940 equation. 465 00:28:54,940 --> 00:28:57,520 But the first thing is to figure out 466 00:28:57,520 --> 00:29:01,530 what are the energy eigenstates or the solutions 467 00:29:01,530 --> 00:29:04,500 of the Schrodinger equation for this problem. 468 00:29:04,500 --> 00:29:08,750 So notice that here in this problem 469 00:29:08,750 --> 00:29:12,910 there's an energy quantity. 470 00:29:16,160 --> 00:29:18,520 Remember, when you have a harmontonian like that, 471 00:29:18,520 --> 00:29:22,000 and people say so what is the ground state energy? 472 00:29:22,000 --> 00:29:25,390 Well, have to find the ground state wave function. 473 00:29:25,390 --> 00:29:26,810 Have to do things. 474 00:29:26,810 --> 00:29:28,910 Give me an hour, I'll find it. 475 00:29:28,910 --> 00:29:29,900 And all that. 476 00:29:29,900 --> 00:29:33,170 But if you want an approximate value, 477 00:29:33,170 --> 00:29:37,590 dimensional analysis will do it, roughly what is it going to be. 478 00:29:37,590 --> 00:29:41,640 Well, with this constant how do you produce an energy? 479 00:29:41,640 --> 00:29:44,730 Well, you remember what Einstein did, 480 00:29:44,730 --> 00:29:51,020 and you know that h bar omega has units of energy. 481 00:29:51,020 --> 00:29:55,320 So that's an energy associated with Lagrangian energy 482 00:29:55,320 --> 00:29:57,150 like quantity. 483 00:29:57,150 --> 00:30:00,340 And we expect that that energy is 484 00:30:00,340 --> 00:30:02,030 going to be the relevant energy. 485 00:30:02,030 --> 00:30:04,070 And in fact, we'll find that the ground state 486 00:30:04,070 --> 00:30:06,010 energy is just one half of that. 487 00:30:08,870 --> 00:30:11,520 There's another quantity that may be interesting. 488 00:30:11,520 --> 00:30:13,640 How about the length? 489 00:30:13,640 --> 00:30:16,205 How do you construct a length from these quantities? 490 00:30:20,620 --> 00:30:26,070 Well, you can start doing m omega h bar 491 00:30:26,070 --> 00:30:28,210 and put powers and struggle. 492 00:30:28,210 --> 00:30:31,100 I hate doing that. 493 00:30:31,100 --> 00:30:34,770 I always try to find some way of doing it and avoiding 494 00:30:34,770 --> 00:30:35,780 that thing. 495 00:30:35,780 --> 00:30:42,030 So I know that energies go like h 496 00:30:42,030 --> 00:30:47,240 over h squared over m length squared. 497 00:30:47,240 --> 00:30:51,550 So I'm going to call the length a quantity a. 498 00:30:51,550 --> 00:30:54,210 So ma squared. 499 00:30:54,210 --> 00:30:55,615 That has units of energy. 500 00:30:59,740 --> 00:31:01,917 And you should remember that because energy 501 00:31:01,917 --> 00:31:07,790 is b squared over 2m, and b by De Broglie 502 00:31:07,790 --> 00:31:10,910 is h bar over sub lamda. 503 00:31:10,910 --> 00:31:15,360 So h bar squared, lambda squared, and m here, 504 00:31:15,360 --> 00:31:16,780 that's units of energy. 505 00:31:16,780 --> 00:31:18,570 So that's a length. 506 00:31:18,570 --> 00:31:20,970 On the other hand, we have another way 507 00:31:20,970 --> 00:31:24,620 to construct an energy is with this thing, 508 00:31:24,620 --> 00:31:27,190 m omega squared length squared. 509 00:31:27,190 --> 00:31:32,840 So that's also m omega squared a squared. 510 00:31:32,840 --> 00:31:34,880 That's another energy. 511 00:31:34,880 --> 00:31:40,680 So from this equation I find that a to the fourth 512 00:31:40,680 --> 00:31:46,160 is h squared over m squared omega squared. 513 00:31:46,160 --> 00:31:49,390 And it's a little complicated, so a squared 514 00:31:49,390 --> 00:31:52,495 is h bar over m omega. 515 00:31:55,360 --> 00:31:58,640 So that's a length. 516 00:31:58,640 --> 00:31:59,690 Length squared. 517 00:31:59,690 --> 00:32:01,480 I don't want to take the square root. 518 00:32:01,480 --> 00:32:04,130 We can leave it for a moment there. 519 00:32:04,130 --> 00:32:08,680 But that's important because of that's a length scale. 520 00:32:08,680 --> 00:32:11,780 And if somebody would ask you in the ground state, 521 00:32:11,780 --> 00:32:14,760 how far is this particle oscillating, 522 00:32:14,760 --> 00:32:19,940 you would say probably about a square root of this. 523 00:32:19,940 --> 00:32:27,710 Would be a natural answer and probably about right. 524 00:32:27,710 --> 00:32:33,310 So OK, energy and units is very important 525 00:32:33,310 --> 00:32:35,290 to begin your analysis. 526 00:32:35,290 --> 00:32:38,440 So what is the Schrodinger equation? 527 00:32:38,440 --> 00:32:41,030 The Schrodinger equation for this thing 528 00:32:41,030 --> 00:32:48,590 is going to be minus h squared over 2m, d second psi, 529 00:32:48,590 --> 00:32:54,580 dx squared plus the potential, one half m omega squared 530 00:32:54,580 --> 00:33:00,640 x squared psi is equal E psi. 531 00:33:00,640 --> 00:33:08,150 And the big problem is I don't know psi and I don't know E. 532 00:33:08,150 --> 00:33:11,550 Now there's so many elegant ways of solving the harmonic 533 00:33:11,550 --> 00:33:12,050 oscillator. 534 00:33:15,020 --> 00:33:18,222 You will see those next lecture. 535 00:33:18,222 --> 00:33:20,300 Allan Adams will be back here. 536 00:33:20,300 --> 00:33:25,850 But we all have to go through once in your life 537 00:33:25,850 --> 00:33:30,670 through the direct, uninspired method of solving it. 538 00:33:33,680 --> 00:33:38,390 Because most of the times when you have a new problem, 539 00:33:38,390 --> 00:33:42,130 you will not come up with a beautiful, elegant method 540 00:33:42,130 --> 00:33:44,830 to avoid solving the differential equation. 541 00:33:44,830 --> 00:33:47,430 You will have to struggle with the differential equation. 542 00:33:47,430 --> 00:33:51,220 So today we struggle with the differential equation. 543 00:33:51,220 --> 00:33:53,080 We're going to just do it. 544 00:33:53,080 --> 00:33:56,600 And I'm going to do it slow enough and in detail enough 545 00:33:56,600 --> 00:33:59,380 that I hope you follow everything. 546 00:33:59,380 --> 00:34:01,280 I'll just keep a couple of things, 547 00:34:01,280 --> 00:34:06,210 but it will be one line computations that I will skip. 548 00:34:06,210 --> 00:34:10,949 So this equation is some sort of fairly difficult thing. 549 00:34:10,949 --> 00:34:15,750 And it's complicated and made fairly unpleasant 550 00:34:15,750 --> 00:34:18,960 by the presence of all these constants. 551 00:34:18,960 --> 00:34:23,159 What kind of equation is that with all these constants? 552 00:34:23,159 --> 00:34:26,719 They shouldn't be there, all this constants, in fact. 553 00:34:26,719 --> 00:34:31,159 So this is the first step, cleaning up the equation. 554 00:34:31,159 --> 00:34:32,510 We have to clean it up. 555 00:34:32,510 --> 00:34:33,010 Why? 556 00:34:33,010 --> 00:34:37,130 Because the nice functions in life like y 557 00:34:37,130 --> 00:34:41,850 double prime is equal to minus y have no units. 558 00:34:41,850 --> 00:34:44,909 The derivatives create no units. 559 00:34:44,909 --> 00:34:49,639 y has the same units of that, and the solution is sine of x, 560 00:34:49,639 --> 00:34:52,400 where x must have no units, because you cannot find 561 00:34:52,400 --> 00:34:55,960 the sine of one centimeter. 562 00:34:55,960 --> 00:34:59,400 So this thing, we should have the same thing here. 563 00:34:59,400 --> 00:35:00,720 No units anywhere. 564 00:35:04,100 --> 00:35:05,830 So how can we do that? 565 00:35:05,830 --> 00:35:08,600 This is an absolutely necessary first step. 566 00:35:08,600 --> 00:35:11,120 If you're going to be carrying all these constants, 567 00:35:11,120 --> 00:35:13,610 you'll get nowhere. 568 00:35:13,610 --> 00:35:16,590 So we have to clean it up. 569 00:35:16,590 --> 00:35:18,520 So what I'm going to try to see is 570 00:35:18,520 --> 00:35:22,260 that look, here is psi, psi, and psi. 571 00:35:22,260 --> 00:35:26,750 So suppose I do the following thing, 572 00:35:26,750 --> 00:35:30,050 that I will clean up the right hand 573 00:35:30,050 --> 00:35:37,960 side by dividing by something with units of energy. 574 00:35:37,960 --> 00:35:42,340 So I'm going to do the following way. 575 00:35:42,340 --> 00:35:52,610 I'm going to divide all by 1 over h bar omega. 576 00:35:52,610 --> 00:35:56,190 And this 2 I'm going to multiply by 2. 577 00:35:56,190 --> 00:36:07,760 So multiply by 2 over h bar omega. 578 00:36:07,760 --> 00:36:11,190 So what do I achieve with that first step? 579 00:36:11,190 --> 00:36:14,550 I achieve that these 2s disappear. 580 00:36:14,550 --> 00:36:16,540 Well, that's not too bad. 581 00:36:16,540 --> 00:36:19,270 Not that great either, I think. 582 00:36:19,270 --> 00:36:23,050 But in the right hand side, this has units of energy. 583 00:36:23,050 --> 00:36:26,490 And the right hand side will not have units of energy. 584 00:36:26,490 --> 00:36:27,940 So what do we get here? 585 00:36:27,940 --> 00:36:29,510 So we get minus. 586 00:36:29,510 --> 00:36:39,280 The h becomes an h alone over-- the m disappears-- so m omega. 587 00:36:39,280 --> 00:36:44,000 The second psi the x squared. 588 00:36:44,000 --> 00:36:49,860 The 1/2 disappeared, so m omega over h 589 00:36:49,860 --> 00:37:01,900 bar x squared psi equals 2 E over h bar omega psi. 590 00:37:01,900 --> 00:37:05,760 It looks actually quite better already. 591 00:37:05,760 --> 00:37:07,070 Should agree with that. 592 00:37:07,070 --> 00:37:14,040 It looks a lot nicer Now I can use a name for this. 593 00:37:14,040 --> 00:37:18,650 I want to call this the dimensionless value 594 00:37:18,650 --> 00:37:19,750 of the energy. 595 00:37:19,750 --> 00:37:23,120 So a calligraphic e. 596 00:37:23,120 --> 00:37:25,510 It has no units. 597 00:37:25,510 --> 00:37:29,850 It's telling me if I find some energy, that that energy really 598 00:37:29,850 --> 00:37:34,970 is this number, this pure number is how many times bigger 599 00:37:34,970 --> 00:37:39,650 is e with respect to h omega over 2. 600 00:37:39,650 --> 00:37:43,350 So I'll write this now as e psi. 601 00:37:43,350 --> 00:37:44,540 And look what I have. 602 00:37:44,540 --> 00:37:48,160 I have no units here. 603 00:37:48,160 --> 00:37:50,480 And I have a psi. 604 00:37:50,480 --> 00:37:52,140 And I have a psi. 605 00:37:52,140 --> 00:37:56,020 But things have worked out already. 606 00:37:56,020 --> 00:38:00,000 Look, the same factor here, h over m omega 607 00:38:00,000 --> 00:38:02,530 is upside down here. 608 00:38:02,530 --> 00:38:06,670 And this factor has units of length squared. 609 00:38:06,670 --> 00:38:12,000 Length squared times d d length squared has no units. 610 00:38:12,000 --> 00:38:14,320 And here's 1 over length squared. 611 00:38:17,880 --> 00:38:20,620 1 over length squared times length squared. 612 00:38:20,620 --> 00:38:22,660 So things have worked out. 613 00:38:22,660 --> 00:38:28,490 And we can now simply say x is going 614 00:38:28,490 --> 00:38:32,560 to be equal to au, a new variable. 615 00:38:32,560 --> 00:38:35,450 This is going to be your new variable for your differential 616 00:38:35,450 --> 00:38:41,480 equation in which is this thing. 617 00:38:41,480 --> 00:38:49,570 And then this differential equation 618 00:38:49,570 --> 00:38:53,025 really has cleaned up perfectly well. 619 00:38:57,020 --> 00:38:59,450 So how does it look now? 620 00:38:59,450 --> 00:39:05,220 Well, it's all gone actually, because if you 621 00:39:05,220 --> 00:39:14,050 have x equals au, d dx by chain rule is 1 over a d du. 622 00:39:17,500 --> 00:39:19,440 And to derivatives this with respect 623 00:39:19,440 --> 00:39:29,790 to x it's 1 over a squared times the d second du squared. 624 00:39:29,790 --> 00:39:32,590 And this thing is a squared. 625 00:39:32,590 --> 00:39:36,470 So actually you cancel this factor. 626 00:39:36,470 --> 00:39:39,360 And when I write x equals to au, you 627 00:39:39,360 --> 00:39:41,205 get an a squared times this. 628 00:39:41,205 --> 00:39:43,950 And a squared times this is 1. 629 00:39:43,950 --> 00:39:46,190 So your differential equations has 630 00:39:46,190 --> 00:39:53,230 become minus the second psi du squared, 631 00:39:53,230 --> 00:39:56,740 where u is a dimensionless quantity, because this has 632 00:39:56,740 --> 00:39:58,820 units of length, this has units of length. 633 00:39:58,820 --> 00:40:01,640 No units here. 634 00:40:01,640 --> 00:40:02,720 You have no units. 635 00:40:02,720 --> 00:40:07,580 So minus d second du squared plus u 636 00:40:07,580 --> 00:40:12,805 squared psi is equal to e psi. 637 00:40:18,320 --> 00:40:21,890 Much nicer. 638 00:40:21,890 --> 00:40:24,770 This is an equation we can think about 639 00:40:24,770 --> 00:40:27,830 without being distracted by this endless amount 640 00:40:27,830 --> 00:40:29,656 of little trivialities. 641 00:40:33,690 --> 00:40:38,760 But still we haven't solved it, and how are we 642 00:40:38,760 --> 00:40:42,290 going to solve this equation? 643 00:40:42,290 --> 00:40:46,860 So let's again think of what should happen. 644 00:40:46,860 --> 00:40:51,780 Somehow it should happen that these e's get fixed. 645 00:40:51,780 --> 00:40:55,750 And there is some solution just for some values of e's. 646 00:40:55,750 --> 00:41:00,090 It's not obvious at this stage how that is going to happen. 647 00:41:00,090 --> 00:41:00,940 Yes? 648 00:41:00,940 --> 00:41:01,856 AUDIENCE: [INAUDIBLE]. 649 00:41:06,290 --> 00:41:12,220 PROFESSOR: Here for example, let me do this term. 650 00:41:12,220 --> 00:41:18,200 h bar over m omega is minus, from that equation, a squared. 651 00:41:18,200 --> 00:41:26,640 But dx squared is 1 over a squared d du squared. 652 00:41:26,640 --> 00:41:29,820 So a squared cancels. 653 00:41:29,820 --> 00:41:33,380 And here the x is equal a squared times u, 654 00:41:33,380 --> 00:41:35,585 so again cancels. 655 00:41:39,060 --> 00:41:44,640 OK so what is the problem here? 656 00:41:44,640 --> 00:41:48,150 The problem is that most likely what is going to go wrong 657 00:41:48,150 --> 00:41:51,760 is that this solution for arbitrary values of e's is 658 00:41:51,760 --> 00:41:55,500 going to diverge at infinity, and you're never 659 00:41:55,500 --> 00:41:57,810 going to be able to normalize it. 660 00:41:57,810 --> 00:42:02,050 So let's try to understand how the solution looks 661 00:42:02,050 --> 00:42:04,010 as we go to infinity. 662 00:42:04,010 --> 00:42:05,710 So this is the first thing you should 663 00:42:05,710 --> 00:42:07,520 do with an equation like that. 664 00:42:07,520 --> 00:42:13,880 How does this solution look as u goes to infinity? 665 00:42:13,880 --> 00:42:18,400 Now we may not be able to solve it exactly in that case either, 666 00:42:18,400 --> 00:42:22,930 but we're going to gain insight into what's happening. 667 00:42:22,930 --> 00:42:25,940 So here it is. 668 00:42:25,940 --> 00:42:30,950 When u goes to infinity, this term, whatever psi is, 669 00:42:30,950 --> 00:42:33,190 this term is much bigger than that, 670 00:42:33,190 --> 00:42:37,060 because we're presumably working with some fixed energy 671 00:42:37,060 --> 00:42:38,810 that we still don't know what it is, 672 00:42:38,810 --> 00:42:42,500 but it's a fixed number and, for you, sufficiently large. 673 00:42:42,500 --> 00:42:44,430 This is going to dominate. 674 00:42:44,430 --> 00:42:46,620 So the equation that we're trying 675 00:42:46,620 --> 00:42:53,840 to solve as u goes to infinity, the equation sort of becomes 676 00:42:53,840 --> 00:42:58,240 psi double prime-- prime is for two derivatives-- 677 00:42:58,240 --> 00:43:02,330 is equal to u squared psi. 678 00:43:08,860 --> 00:43:13,270 OK, so how do we get an idea what solves 679 00:43:13,270 --> 00:43:16,020 this is not all that obvious. 680 00:43:16,020 --> 00:43:19,720 It's certainly not a power of u, because when you differentiate 681 00:43:19,720 --> 00:43:22,640 the power of u, you lower the degree 682 00:43:22,640 --> 00:43:25,650 rather than increase the degree. 683 00:43:25,650 --> 00:43:29,200 So what function increases degree as you differentiate? 684 00:43:29,200 --> 00:43:32,350 It's not the trivial function. 685 00:43:32,350 --> 00:43:34,420 Cannot be a polynomial. 686 00:43:34,420 --> 00:43:36,150 If it could be even a polynomial, 687 00:43:36,150 --> 00:43:39,230 if you take two derivatives, it kind cannot be equal to x 688 00:43:39,230 --> 00:43:40,440 squared times a polynomial. 689 00:43:40,440 --> 00:43:43,320 It's sort of upside down. 690 00:43:43,320 --> 00:43:46,390 So if you think about it for a little while, 691 00:43:46,390 --> 00:43:48,180 you don't have an exact solution, 692 00:43:48,180 --> 00:43:51,650 but you would imagine that something like this 693 00:43:51,650 --> 00:43:55,780 would do it, an e to the u squared. 694 00:43:55,780 --> 00:43:58,280 Because an e to the u squared, when 695 00:43:58,280 --> 00:44:04,390 you differentiate with respect to us, you produce a u down. 696 00:44:04,390 --> 00:44:05,830 When you one derivative. 697 00:44:05,830 --> 00:44:07,420 When you take another derivative, 698 00:44:07,420 --> 00:44:09,650 well, it's more complicated, but one term you 699 00:44:09,650 --> 00:44:11,980 will produce another u down. 700 00:44:11,980 --> 00:44:16,670 So that probably is quite good. 701 00:44:16,670 --> 00:44:18,290 So let's try that. 702 00:44:18,290 --> 00:44:21,310 Let's try to see if we have something like that. 703 00:44:21,310 --> 00:44:22,890 So I will try something. 704 00:44:26,900 --> 00:44:33,290 I'll try psi equals 2. 705 00:44:37,420 --> 00:44:41,480 I'm going to try the following thing. 706 00:44:41,480 --> 00:44:49,250 e to the alpha u squared over 2 where alpha is a number. 707 00:44:49,250 --> 00:44:50,590 I don't know how much it is. 708 00:44:50,590 --> 00:44:53,740 Alpha is some number. 709 00:44:53,740 --> 00:44:56,950 Now could try this alone, but I actually 710 00:44:56,950 --> 00:45:01,860 want to emphasize to you that if this 711 00:45:01,860 --> 00:45:05,090 is the behavior near infinity, it 712 00:45:05,090 --> 00:45:07,430 won't make any difference if you put here, 713 00:45:07,430 --> 00:45:12,800 for example, something like u to the power k. 714 00:45:12,800 --> 00:45:17,250 It will also be roughly a solution. 715 00:45:17,250 --> 00:45:20,660 So let's see that. 716 00:45:20,660 --> 00:45:22,475 So for that I have to differentiate. 717 00:45:27,290 --> 00:45:31,460 And let's see what we get. 718 00:45:31,460 --> 00:45:37,850 So we're trying to see how the function behaves far, far away. 719 00:45:37,850 --> 00:45:39,880 You might say well look, probably 720 00:45:39,880 --> 00:45:41,850 that alpha should be negative. 721 00:45:41,850 --> 00:45:43,940 But let's see what the equation tells us 722 00:45:43,940 --> 00:45:46,760 before we put anything in there. 723 00:45:46,760 --> 00:45:53,270 So if I do psi prime, you would get what? 724 00:45:53,270 --> 00:45:54,900 You would get one term that would 725 00:45:54,900 --> 00:46:02,170 be alpha u times this u to the k into the alpha u squared 726 00:46:02,170 --> 00:46:02,760 over 2. 727 00:46:02,760 --> 00:46:06,580 I differentiated the exponential. 728 00:46:06,580 --> 00:46:08,850 I differentiated the exponential. 729 00:46:08,850 --> 00:46:10,640 And then you would get a term where 730 00:46:10,640 --> 00:46:12,260 you differentiate the power. 731 00:46:12,260 --> 00:46:17,120 So you get ku to the k minus 1 into the alpha u 732 00:46:17,120 --> 00:46:19,470 squared over 2. 733 00:46:19,470 --> 00:46:23,120 If you take a second derivative, well, I 734 00:46:23,120 --> 00:46:25,620 can differentiate the exponential again, 735 00:46:25,620 --> 00:46:28,840 so I will get alpha u now squared, 736 00:46:28,840 --> 00:46:31,690 because each derivative of this exponent 737 00:46:31,690 --> 00:46:35,120 produces a factor of alpha u. 738 00:46:35,120 --> 00:46:40,396 u to the k into the alpha u squared over 2. 739 00:46:40,396 --> 00:46:50,240 And a couple more terms that they all have less powers of u, 740 00:46:50,240 --> 00:46:56,020 because this term has u to the k plus-- 741 00:46:56,020 --> 00:46:58,270 already has u to the k plus 1. 742 00:46:58,270 --> 00:47:00,390 And this has u to the k minus 1. 743 00:47:00,390 --> 00:47:03,010 They differ by two powers of u. 744 00:47:03,010 --> 00:47:08,930 So for illustration, please, if you want, do it. 745 00:47:08,930 --> 00:47:12,840 Three lines, you should skip three lines in your notebook 746 00:47:12,840 --> 00:47:17,510 if you're taking notes and get the following. 747 00:47:17,510 --> 00:47:21,080 No point in me doing this algebra here. 748 00:47:21,080 --> 00:47:23,810 Alpha u squared over 2. 749 00:47:23,810 --> 00:47:28,550 Because actually it's not all that important. 750 00:47:28,550 --> 00:47:37,840 Over alpha 1 over u squared plus k minus 1 over alpha 751 00:47:37,840 --> 00:47:41,680 squared 1 over u to the fourth. 752 00:47:41,680 --> 00:47:42,840 That's all you get. 753 00:47:49,510 --> 00:47:56,510 Look, this is alpha squared u squared 754 00:47:56,510 --> 00:48:01,260 times psi times these things. 755 00:48:01,260 --> 00:48:07,910 1 plus 2 k plus 1 over alpha 1 over u squared. 756 00:48:07,910 --> 00:48:12,620 So when u goes to infinity, your solution 757 00:48:12,620 --> 00:48:18,200 works, because these thing's are negligible. 758 00:48:18,200 --> 00:48:21,400 So you get a number times u squared. 759 00:48:21,400 --> 00:48:23,985 That is the equation you are trying to solve up there. 760 00:48:27,020 --> 00:48:30,650 And therefore, you get that the equation if alpha 761 00:48:30,650 --> 00:48:34,240 squared is equal to 1. 762 00:48:34,240 --> 00:48:40,050 And that means and really that alpha can be plus minus 1. 763 00:48:40,050 --> 00:48:45,270 And roughly this solution near infinity, 764 00:48:45,270 --> 00:48:48,990 probably there's two solutions. 765 00:48:51,820 --> 00:48:54,390 This is a second order differential equation, 766 00:48:54,390 --> 00:48:57,910 so even near infinity there should be two solutions. 767 00:48:57,910 --> 00:49:03,440 So we expect as u goes to infinity psi of u 768 00:49:03,440 --> 00:49:09,290 will be some constant A times u to the k times 769 00:49:09,290 --> 00:49:13,670 e to the minus u squared over 2. 770 00:49:13,670 --> 00:49:16,400 That's where alpha equal minus 1. 771 00:49:16,400 --> 00:49:24,080 Plus Bu to the k into the plus u squared over 2. 772 00:49:24,080 --> 00:49:26,340 And what is k? 773 00:49:26,340 --> 00:49:28,180 Well, we don't know what is k. 774 00:49:28,180 --> 00:49:30,700 It seems to work for all k. 775 00:49:30,700 --> 00:49:36,000 That may seem a little confusing now, but don't worry. 776 00:49:36,000 --> 00:49:42,280 We'll see other things happening here very soon. 777 00:49:42,280 --> 00:49:45,030 So look at what has happened. 778 00:49:45,030 --> 00:49:48,300 We've identified that most likely your wave function 779 00:49:48,300 --> 00:49:50,920 is going to look like this at infinity. 780 00:49:50,920 --> 00:49:54,540 So we're going to want to this part not to be present. 781 00:49:54,540 --> 00:49:57,210 So presumably we're going to want a solution that 782 00:49:57,210 --> 00:50:00,590 just has this, because this is normalizable. 783 00:50:00,590 --> 00:50:05,930 The integral of any power times a Gaussian is convergence. 784 00:50:05,930 --> 00:50:07,440 So this can be normalized. 785 00:50:07,440 --> 00:50:11,830 The Gaussian falls so fast that any power can 786 00:50:11,830 --> 00:50:14,490 be integrated against a Gaussian. 787 00:50:14,490 --> 00:50:17,660 Any power however big doesn't grow big enough 788 00:50:17,660 --> 00:50:19,770 to compensate a Gaussian. 789 00:50:19,770 --> 00:50:21,655 It's impossible to compensate a Gaussian. 790 00:50:25,210 --> 00:50:26,525 So we hope for this. 791 00:50:31,690 --> 00:50:34,700 But we want to translate what we've 792 00:50:34,700 --> 00:50:38,630 learned into some technical advantage 793 00:50:38,630 --> 00:50:40,430 in solving the differential equation, 794 00:50:40,430 --> 00:50:44,960 because, after all, we wanted be insight how it looks far way, 795 00:50:44,960 --> 00:50:48,100 but we wanted to solve the differential equation. 796 00:50:48,100 --> 00:50:50,790 So how can we use this insight we now 797 00:50:50,790 --> 00:50:57,560 have to simplify the solution of the differential equation? 798 00:50:57,560 --> 00:51:03,000 The idea is to change variables a little bit. 799 00:51:03,000 --> 00:51:14,660 So write psi of u to be equal to h of u times e 800 00:51:14,660 --> 00:51:17,450 to the minus u squared over 2. 801 00:51:21,670 --> 00:51:23,780 Now you're going to say wait, what are you doing? 802 00:51:23,780 --> 00:51:26,190 Are you making an approximation now 803 00:51:26,190 --> 00:51:28,990 that this is what is going to look far away? 804 00:51:28,990 --> 00:51:32,710 Or what are you putting there? 805 00:51:32,710 --> 00:51:35,050 I'm not making any approximation. 806 00:51:35,050 --> 00:51:40,340 I'm just saying whatever pis is, it can always 807 00:51:40,340 --> 00:51:42,100 be written in this way. 808 00:51:42,100 --> 00:51:42,600 Why? 809 00:51:42,600 --> 00:51:45,440 Because if you have a psi of u, you 810 00:51:45,440 --> 00:51:51,840 can write it as psi of u over e to the minus u squared 811 00:51:51,840 --> 00:51:55,940 over 2 times e minus u squared over 2. 812 00:51:55,940 --> 00:51:59,210 Very trivially this can always be done. 813 00:51:59,210 --> 00:52:02,640 As long as we say that h is arbitrary, 814 00:52:02,640 --> 00:52:07,650 there's nothing, no constraint here. 815 00:52:07,650 --> 00:52:10,040 I have not assume anything, nothing. 816 00:52:10,040 --> 00:52:16,360 I'm just hoping that I have a differential equation for psi. 817 00:52:16,360 --> 00:52:20,850 That because this is a very clever factor, the differential 818 00:52:20,850 --> 00:52:24,500 equation for h will be simpler. 819 00:52:24,500 --> 00:52:30,010 Because part of the dependence has been taken over. 820 00:52:30,010 --> 00:52:34,700 So maybe h, for example, could be now a polynomial solution, 821 00:52:34,700 --> 00:52:38,520 because this product has been taken care. 822 00:52:38,520 --> 00:52:43,580 So the hope is that by writing this equation 823 00:52:43,580 --> 00:52:46,290 it will become an equation for h of u, 824 00:52:46,290 --> 00:52:49,800 and that equation will be simpler. 825 00:52:49,800 --> 00:52:52,070 So will it be simpler? 826 00:52:52,070 --> 00:52:56,340 Well, here again this is not difficult. 827 00:52:56,340 --> 00:53:00,060 You're supposed to plug into equation one-- 828 00:53:00,060 --> 00:53:03,220 this is the equation one-- plug into one. 829 00:53:11,900 --> 00:53:12,870 I won't do it. 830 00:53:12,870 --> 00:53:16,270 It's three lines of algebra to plug into one 831 00:53:16,270 --> 00:53:18,580 and calculate the equation for h of u. 832 00:53:18,580 --> 00:53:20,070 You should do it. 833 00:53:20,070 --> 00:53:24,185 It's the kind of thing that one should do at least once. 834 00:53:26,830 --> 00:53:28,260 So please do it. 835 00:53:28,260 --> 00:53:30,890 It's three, four lines. 836 00:53:30,890 --> 00:53:32,520 It's not long. 837 00:53:32,520 --> 00:53:34,170 But I'll just write the answer. 838 00:53:37,710 --> 00:53:39,790 So by the time you substitute, of course, 839 00:53:39,790 --> 00:53:41,980 the e to the minus u squared over 2 840 00:53:41,980 --> 00:53:44,940 is going to cancel from everywhere. 841 00:53:44,940 --> 00:53:46,210 It's very here. 842 00:53:46,210 --> 00:53:48,190 You just need to take two derivatives, 843 00:53:48,190 --> 00:53:51,350 so it becomes a second order differential equation. 844 00:53:51,350 --> 00:53:54,760 And indeed, it becomes a tractable differential 845 00:53:54,760 --> 00:53:56,080 equation. 846 00:53:56,080 --> 00:54:08,070 The second h, du squared minus 2u dh du plus e minus 1 h 847 00:54:08,070 --> 00:54:08,880 equals 0. 848 00:54:15,740 --> 00:54:19,470 OK, that is our equation now. 849 00:54:19,470 --> 00:54:25,530 So now we face the problem finally solving this equation. 850 00:54:25,530 --> 00:54:27,640 So before we start, maybe there's 851 00:54:27,640 --> 00:54:31,441 some questions of what we've done so far. 852 00:54:31,441 --> 00:54:31,940 Let's see. 853 00:54:31,940 --> 00:54:34,980 Any questions? 854 00:54:38,080 --> 00:54:38,970 Yes? 855 00:54:38,970 --> 00:54:42,130 AUDIENCE: Do you have right there in the middle 856 00:54:42,130 --> 00:54:45,632 would be-- this equation is linear, so can we just 857 00:54:45,632 --> 00:54:51,065 [INAUDIBLE] minus u squared over 2 and you stuck it to that u 858 00:54:51,065 --> 00:54:51,911 to the k. 859 00:54:51,911 --> 00:54:52,890 PROFESSOR: It's here? 860 00:54:52,890 --> 00:54:53,495 This thing? 861 00:54:53,495 --> 00:54:54,120 AUDIENCE: Yeah. 862 00:54:54,120 --> 00:54:57,900 Could you then just power series what's going on at 0 with those 863 00:54:57,900 --> 00:55:01,120 u to the k terms [INAUDIBLE]? 864 00:55:01,120 --> 00:55:02,320 PROFESSOR: No. 865 00:55:02,320 --> 00:55:08,350 This is the behavior as u goes to infinity. 866 00:55:08,350 --> 00:55:12,640 So I actually don't know that the function near 0 867 00:55:12,640 --> 00:55:15,450 is going to behave like u to the k. 868 00:55:15,450 --> 00:55:17,100 We really don't know. 869 00:55:17,100 --> 00:55:20,920 It suggest to you that maybe the solution 870 00:55:20,920 --> 00:55:25,050 is going to be near 0 u to the k times some polynomial 871 00:55:25,050 --> 00:55:26,060 or something like that. 872 00:55:26,060 --> 00:55:29,120 But it's not that, because this analysis was just 873 00:55:29,120 --> 00:55:30,290 done at infinity. 874 00:55:30,290 --> 00:55:36,494 So we really have no information still what's going on near 0. 875 00:55:36,494 --> 00:55:37,160 Other questions? 876 00:55:39,860 --> 00:55:40,958 Yes? 877 00:55:40,958 --> 00:55:45,369 AUDIENCE: So is k some arbitrary number or is it an integer? 878 00:55:45,369 --> 00:55:47,660 PROFESSOR: At this moment, actually, it doesn't matter. 879 00:55:47,660 --> 00:55:50,260 Is that right? 880 00:55:50,260 --> 00:55:51,320 Doesn't matter. 881 00:55:51,320 --> 00:55:56,420 The analysis that we did here suggests it could be anything. 882 00:55:56,420 --> 00:56:00,640 That's why I just didn't put it into h or u. 883 00:56:00,640 --> 00:56:03,520 I didn't put it because would be strange to put here 884 00:56:03,520 --> 00:56:05,590 a u to the k. 885 00:56:05,590 --> 00:56:07,530 I wouldn't know what to make of it. 886 00:56:07,530 --> 00:56:10,430 So at this moment, the best thing to say 887 00:56:10,430 --> 00:56:14,050 is we don't know what it is, and maybe we'll understand it. 888 00:56:14,050 --> 00:56:14,830 And we will. 889 00:56:14,830 --> 00:56:18,010 In a few seconds, we'll sort of see what's going on. 890 00:56:20,570 --> 00:56:24,195 OK, so how does one solve this equation? 891 00:56:27,900 --> 00:56:31,610 Well, it's not a trivial equation, again. 892 00:56:31,610 --> 00:56:35,500 But it can be solved by polynomials, 893 00:56:35,500 --> 00:56:36,670 and we'll see that. 894 00:56:36,670 --> 00:56:39,080 But the way we solve this equation 895 00:56:39,080 --> 00:56:42,940 is by a power series expansion. 896 00:56:42,940 --> 00:56:45,670 Now you could do it by hand first, 897 00:56:45,670 --> 00:56:48,370 and I did it when I was preparing 898 00:56:48,370 --> 00:56:50,470 the lecture yesterday. 899 00:56:50,470 --> 00:56:57,060 I said I'm going to just write h of u 900 00:56:57,060 --> 00:57:03,880 equal a constant a0 plus a1u plus a2u squared 901 00:57:03,880 --> 00:57:07,360 plus a3u cubed. 902 00:57:07,360 --> 00:57:11,030 And I plugged it in here. 903 00:57:11,030 --> 00:57:13,220 And I just did the first few terms 904 00:57:13,220 --> 00:57:15,490 and start to see what happened. 905 00:57:15,490 --> 00:57:17,850 And I found after a little thinking 906 00:57:17,850 --> 00:57:24,410 that a2 is determined by a0, and a3 907 00:57:24,410 --> 00:57:30,100 is determined by a1 once you substitute. 908 00:57:30,100 --> 00:57:34,090 It's not the obvious when you look at this, but that happens. 909 00:57:34,090 --> 00:57:37,820 So when you face a problem like that, 910 00:57:37,820 --> 00:57:41,060 don't go high power to begin with. 911 00:57:41,060 --> 00:57:43,910 Just try a simple series and see what happens. 912 00:57:43,910 --> 00:57:45,530 And you see a little pattern. 913 00:57:45,530 --> 00:57:48,670 And then you can do a more sophisticated analysis. 914 00:57:48,670 --> 00:57:51,610 So what would be a more sophisticated analysis? 915 00:57:51,610 --> 00:57:55,030 To write h of u equal the sum from j 916 00:57:55,030 --> 00:58:00,262 equals 0 to infinity aju to the j. 917 00:58:03,496 --> 00:58:06,370 Then if you take a derivative, because we're 918 00:58:06,370 --> 00:58:11,780 going to need the derivative, dh du 919 00:58:11,780 --> 00:58:18,860 would be the sum from j equals 0 to infinity. 920 00:58:18,860 --> 00:58:24,500 j times aju to the j minus 1. 921 00:58:24,500 --> 00:58:27,360 You would say that doesn't look very good 922 00:58:27,360 --> 00:58:31,000 because for j equals 0 you have 1 over u. 923 00:58:31,000 --> 00:58:31,990 That's crazy. 924 00:58:31,990 --> 00:58:35,650 But indeed for j equals 0, the j here multiplies it 925 00:58:35,650 --> 00:58:37,090 and makes it 0. 926 00:58:37,090 --> 00:58:40,110 So this is OK. 927 00:58:40,110 --> 00:58:44,630 Now the term that we actually need is minus 2u dh du. 928 00:58:44,630 --> 00:58:53,750 So here minus 2u dh du would be equal to the sum from j 929 00:58:53,750 --> 00:59:02,745 equals 0 to infinity, and I will have minus 2jaju to the j. 930 00:59:02,745 --> 00:59:07,990 The u makes this j minus 1 j, and the constant went there. 931 00:59:07,990 --> 00:59:11,990 So here is so far h. 932 00:59:11,990 --> 00:59:14,250 Here is this other term that we're 933 00:59:14,250 --> 00:59:18,582 going to need for the differential equation. 934 00:59:18,582 --> 00:59:20,290 And then there's the last term that we're 935 00:59:20,290 --> 00:59:22,125 going to need for the differential equation, 936 00:59:22,125 --> 00:59:23,465 so I'm going to go here. 937 00:59:29,570 --> 00:59:32,110 So what do we get for this last term. 938 00:59:32,110 --> 00:59:33,800 We'll have to take a second derivative. 939 00:59:37,200 --> 00:59:40,290 So we'll take-- h prime was there, 940 00:59:40,290 --> 00:59:46,790 so d second h du squared will be the sum from j 941 00:59:46,790 --> 00:59:58,075 equals 0 of j times j minus 1 aju to the j minus 2. 942 01:00:03,980 --> 01:00:09,580 Now you have to rewrite this in order to make it tractable. 943 01:00:09,580 --> 01:00:14,060 You want everything to have u to the j's. 944 01:00:14,060 --> 01:00:17,960 You don't want actually to have u to the j minus 2. 945 01:00:17,960 --> 01:00:20,130 So the first thing that you notice 946 01:00:20,130 --> 01:00:28,690 is that this sum actually begins with 2, because for 0 and 1 947 01:00:28,690 --> 01:00:29,370 it vanishes. 948 01:00:29,370 --> 01:00:37,600 So I can write j times j minus 1 aj u to j minus 2. 949 01:00:37,600 --> 01:00:39,470 Like that. 950 01:00:39,470 --> 01:00:47,520 And then I can say let j be equal to j prime plus 2. 951 01:00:52,270 --> 01:00:55,150 Look, j begins with 2 in this sum. 952 01:00:55,150 --> 01:01:00,620 So if j is j prime plus 2, j prime will begin with 0. 953 01:01:00,620 --> 01:01:06,490 So we've shifted the sum so it's j prime equals 0 to infinity. 954 01:01:06,490 --> 01:01:09,850 And whenever I have a j I must put j prime plus 2. 955 01:01:09,850 --> 01:01:13,210 So j prime plus 2. 956 01:01:13,210 --> 01:01:24,350 j prime plus 1 aj prime plus 2 u to the j prime. 957 01:01:24,350 --> 01:01:28,670 Wherever I had j, I put j prime plus 2. 958 01:01:28,670 --> 01:01:33,110 And finally you say j or j prime is the same name, 959 01:01:33,110 --> 01:01:34,800 so let's call it j. 960 01:01:34,800 --> 01:01:36,830 j equals 0. 961 01:01:36,830 --> 01:01:38,610 j plus 2. 962 01:01:38,610 --> 01:01:41,480 j plus 1. 963 01:01:41,480 --> 01:01:43,997 aj plus 2 uj. 964 01:01:49,320 --> 01:01:52,730 So we got the series expansion of everything, 965 01:01:52,730 --> 01:01:56,285 so we just plug into the differential equation. 966 01:01:59,260 --> 01:02:01,170 So where is the differential equation? 967 01:02:01,170 --> 01:02:03,150 It's here. 968 01:02:03,150 --> 01:02:04,990 So I'll plug it in. 969 01:02:04,990 --> 01:02:05,990 Let's see what we get. 970 01:02:08,590 --> 01:02:13,420 We'll get some from j equals 0 to infinity. 971 01:02:13,420 --> 01:02:15,880 Let's see the second derivative is here. 972 01:02:18,680 --> 01:02:35,510 j plus 2 times j plus 1 aj plus 2 uj, so I'll put it here. 973 01:02:39,500 --> 01:02:41,830 So that's this second derivative term. 974 01:02:41,830 --> 01:02:44,150 Now this one. 975 01:02:44,150 --> 01:02:44,870 It's easy. 976 01:02:44,870 --> 01:02:48,100 Minus 2j aj and the uj is there. 977 01:02:48,100 --> 01:02:49,390 So minus 2jaj. 978 01:02:55,050 --> 01:03:02,400 Last term is just e minus 1, because it's 979 01:03:02,400 --> 01:03:05,880 the function this times aj as well. 980 01:03:08,610 --> 01:03:10,890 That's h. 981 01:03:10,890 --> 01:03:13,870 And look, this whole thing must be 0. 982 01:03:13,870 --> 01:03:16,970 So what you learn is that this coefficient must 983 01:03:16,970 --> 01:03:19,920 be 0 for every value of j. 984 01:03:19,920 --> 01:03:23,710 Now it's possible to-- here is aj and aj, 985 01:03:23,710 --> 01:03:26,030 so it's actually one single thing. 986 01:03:26,030 --> 01:03:27,720 Let me write it here. 987 01:03:27,720 --> 01:03:38,850 j plus 2 times j plus 1 aj plus 2 minus 2j 988 01:03:38,850 --> 01:03:46,870 plus 1 minus e aj uj. 989 01:03:46,870 --> 01:03:49,840 I think I got it right. 990 01:03:49,840 --> 01:03:51,130 Yes. 991 01:03:51,130 --> 01:03:52,300 And this is the same sum. 992 01:03:55,830 --> 01:04:01,370 And now, OK, it's a lot of work, but we're getting there. 993 01:04:01,370 --> 01:04:03,330 This must be 0. 994 01:04:03,330 --> 01:04:08,230 So actually that solves for aj plus 2 in terms of aj. 995 01:04:08,230 --> 01:04:11,760 What I had told you that you can notice in two minutes 996 01:04:11,760 --> 01:04:12,880 if you try it a little. 997 01:04:12,880 --> 01:04:15,710 That a2 seems to be determined by a0. 998 01:04:15,710 --> 01:04:18,740 And a3 seems to be determined by a2. 999 01:04:18,740 --> 01:04:24,600 So this is saying that aj plus 2 is 1000 01:04:24,600 --> 01:04:36,380 given by 2j plus 1 minus e over j plus 2 j plus 1 aj. 1001 01:04:44,790 --> 01:04:47,460 A very nice recursive relation. 1002 01:04:47,460 --> 01:04:51,780 So indeed, if you put the value of a0, 1003 01:04:51,780 --> 01:04:57,320 it will determine for you a2, a4, a6, a8, all the even ones. 1004 01:04:57,320 --> 01:05:04,070 If you put the value of a1, it will determine for you a3, a5. 1005 01:05:04,070 --> 01:05:10,070 So a solution is determined by you telling me how much is a0, 1006 01:05:10,070 --> 01:05:12,600 and telling me how much is a1. 1007 01:05:12,600 --> 01:05:15,130 Two constants, two numbers. 1008 01:05:15,130 --> 01:05:17,830 That's what you expect from a second order differential 1009 01:05:17,830 --> 01:05:18,660 equation. 1010 01:05:18,660 --> 01:05:20,370 The value of the function at the point, 1011 01:05:20,370 --> 01:05:22,190 the derivative at a point. 1012 01:05:22,190 --> 01:05:27,240 In fact, you are looking at a0 and a1 1013 01:05:27,240 --> 01:05:31,110 as the two constants that will determine a solution. 1014 01:05:31,110 --> 01:05:34,300 And this is the value of h at 0. 1015 01:05:34,300 --> 01:05:37,590 This is the derivative of h at 0. 1016 01:05:37,590 --> 01:05:51,830 So we can now write the following facts 1017 01:05:51,830 --> 01:05:53,790 about the solution that we have found. 1018 01:05:57,720 --> 01:05:59,090 So what do we know? 1019 01:05:59,090 --> 01:06:13,170 That solutions fixed by giving a0 and a1. 1020 01:06:15,680 --> 01:06:19,245 That correspond to the value of the function at 0 1021 01:06:19,245 --> 01:06:23,120 and the derivative of the function at 0. 1022 01:06:23,120 --> 01:06:25,350 And this gives one solution. 1023 01:06:25,350 --> 01:06:29,780 Once you fix a0, you get a2, a4. 1024 01:06:29,780 --> 01:06:33,330 And this is an even solution, because it 1025 01:06:33,330 --> 01:06:36,940 has only even powers. 1026 01:06:36,940 --> 01:06:43,360 And then from a1, you fixed a3, a5, all the other ones 1027 01:06:43,360 --> 01:06:44,470 with an odd solution. 1028 01:06:50,055 --> 01:06:50,555 OK. 1029 01:06:53,680 --> 01:06:55,810 Well, we solve the differential equation, 1030 01:06:55,810 --> 01:06:58,690 which is really, in a sense, bad, 1031 01:06:58,690 --> 01:07:01,880 because we were expecting that we can only solve it 1032 01:07:01,880 --> 01:07:03,185 for some values of the energy. 1033 01:07:05,690 --> 01:07:13,460 Moreover, you have a0, you get a2, a4, a6, a8. 1034 01:07:13,460 --> 01:07:18,220 This will go on forever and not terminate. 1035 01:07:18,220 --> 01:07:20,910 And then it will be an infinite polynomial that 1036 01:07:20,910 --> 01:07:24,160 grows up and doesn't ever decline, 1037 01:07:24,160 --> 01:07:28,070 which is sort of contradictory with the idea 1038 01:07:28,070 --> 01:07:31,710 that we had before that near infinity 1039 01:07:31,710 --> 01:07:37,160 the function was going to be some power, some fixed power, 1040 01:07:37,160 --> 01:07:39,410 times this exponential. 1041 01:07:39,410 --> 01:07:44,950 So this is what we're looking for, this h function now. 1042 01:07:44,950 --> 01:07:47,000 It doesn't look like a fixed power. 1043 01:07:47,000 --> 01:07:50,240 It looks like it goes forever. 1044 01:07:50,240 --> 01:07:53,790 So let's see what happens eventually 1045 01:07:53,790 --> 01:07:58,190 when the coefficient, the value of the j index is large. 1046 01:07:58,190 --> 01:08:02,460 For large j. 1047 01:08:06,960 --> 01:08:13,500 aj plus 2 is roughly equal to, for large a, whatever 1048 01:08:13,500 --> 01:08:17,580 the energy is, sufficiently large, the most important here 1049 01:08:17,580 --> 01:08:20,565 is the 2j here, the j and the j. 1050 01:08:20,565 --> 01:08:23,600 So you get 2 over j aj. 1051 01:08:29,810 --> 01:08:37,649 So roughly for large j, it behaves like that. 1052 01:08:37,649 --> 01:08:41,300 And now you have to ask yourself the question, 1053 01:08:41,300 --> 01:08:45,140 if you have a power series expansion whose coefficients 1054 01:08:45,140 --> 01:08:51,020 behave like that, how badly is it at infinity? 1055 01:08:51,020 --> 01:08:52,130 How about is it? 1056 01:08:55,380 --> 01:08:57,800 You know it's the power series expansion 1057 01:08:57,800 --> 01:09:01,770 because your h was all these coefficients. 1058 01:09:01,770 --> 01:09:03,670 And suppose they behave like that. 1059 01:09:03,670 --> 01:09:06,910 They grow in that way or decay in this way, 1060 01:09:06,910 --> 01:09:09,470 because they're decaying. 1061 01:09:09,470 --> 01:09:11,770 Is this a solution that's going to blow up? 1062 01:09:11,770 --> 01:09:15,050 Or is it not going to blow up? 1063 01:09:15,050 --> 01:09:19,569 And here comes an important thing. 1064 01:09:19,569 --> 01:09:22,380 This is pretty bad behavior, actually. 1065 01:09:22,380 --> 01:09:24,979 It's pretty awful behavior. 1066 01:09:24,979 --> 01:09:28,439 So let's see that. 1067 01:09:28,439 --> 01:09:29,290 That's pretty bad. 1068 01:09:34,810 --> 01:09:35,950 How do we see that? 1069 01:09:35,950 --> 01:09:39,210 Well you could do it in different ways, 1070 01:09:39,210 --> 01:09:41,189 depending on whether you want to derive 1071 01:09:41,189 --> 01:09:45,560 that this is a bad behavior or guess it. 1072 01:09:45,560 --> 01:09:48,580 I'm going to guess something. 1073 01:09:48,580 --> 01:09:53,910 I'm going to look at how does e to the u squared 1074 01:09:53,910 --> 01:09:56,430 behave as a power series. 1075 01:09:56,430 --> 01:09:59,030 Well, you know as a power series exponential 1076 01:09:59,030 --> 01:10:04,750 is 1 over n u squared to the n. 1077 01:10:04,750 --> 01:10:06,080 Here's n factorial. 1078 01:10:06,080 --> 01:10:07,715 n equals 0 to infinity. 1079 01:10:10,950 --> 01:10:18,810 Now these two n's, u to the 2n, these are all even powers. 1080 01:10:18,810 --> 01:10:21,720 So I'm going to change letters here, 1081 01:10:21,720 --> 01:10:28,400 and I'm going to work with j from 0, 2, 4, over the evens. 1082 01:10:28,400 --> 01:10:32,980 So I will write u to the j here. 1083 01:10:32,980 --> 01:10:36,360 And that this correct, because you produce u to the 0, 1084 01:10:36,360 --> 01:10:39,510 u to the 2, u to the fourth, these things. 1085 01:10:39,510 --> 01:10:43,362 And j is really 2n, so here you will 1086 01:10:43,362 --> 01:10:48,560 have one over j over 2 factorial. 1087 01:10:48,560 --> 01:10:51,730 Now you might say, j over 2, isn't that a fraction? 1088 01:10:51,730 --> 01:10:54,170 No, it's not a fraction, because j is even. 1089 01:10:54,170 --> 01:10:55,690 So this is a nice factorial. 1090 01:10:58,600 --> 01:11:06,056 Now this is the coefficient, cj u to the j. 1091 01:11:06,056 --> 01:11:09,170 And let's see how this coefficients vary. 1092 01:11:09,170 --> 01:11:14,490 So this cj is 1 over j over 2 factorial. 1093 01:11:14,490 --> 01:11:20,800 What is cj plus 2 over cj? 1094 01:11:20,800 --> 01:11:23,560 Which is the analogue of this thing. 1095 01:11:23,560 --> 01:11:30,940 Well, this would be 1 over j plus 2 over 2 factorial. 1096 01:11:30,940 --> 01:11:36,340 And here is up there, so j over 2 factorial. 1097 01:11:36,340 --> 01:11:40,310 Well, this has one more factor in the denominator 1098 01:11:40,310 --> 01:11:41,970 than the numerator. 1099 01:11:41,970 --> 01:11:49,270 So this is roughly one over j over 2 1100 01:11:49,270 --> 01:11:52,105 plus 1, the last value of this. 1101 01:11:52,105 --> 01:11:55,690 This integer is just one bigger than that. 1102 01:11:55,690 --> 01:11:58,800 Now if j is large, this is roughly 1 1103 01:11:58,800 --> 01:12:02,730 over j over 2, which is 2 over j. 1104 01:12:02,730 --> 01:12:06,470 Oh, exactly that stuff. 1105 01:12:06,470 --> 01:12:09,145 So it's pretty bad. 1106 01:12:09,145 --> 01:12:13,380 If this series goes on forever, it 1107 01:12:13,380 --> 01:12:18,080 will diverge like e to the u squared. 1108 01:12:18,080 --> 01:12:24,160 And your h will be like e to the u squared with e to the minus 1109 01:12:24,160 --> 01:12:27,780 u squared over 2 is going to be like e to the plus. 1110 01:12:27,780 --> 01:12:32,160 u squared over 2 is going to go and behave this one. 1111 01:12:32,160 --> 01:12:37,350 So it's going to do exactly the wrong thing. 1112 01:12:37,350 --> 01:12:43,280 If this series doesn't terminate, 1113 01:12:43,280 --> 01:12:46,290 we have not succeeded. 1114 01:12:46,290 --> 01:12:51,200 But happily, the series may terminate, 1115 01:12:51,200 --> 01:12:54,420 because the j's are integers. 1116 01:12:54,420 --> 01:12:58,670 So maybe for some energies that are integers, 1117 01:12:58,670 --> 01:13:01,720 it terminates, and that's a solution. 1118 01:13:01,720 --> 01:13:05,090 The only way to get a solution is if the series terminates. 1119 01:13:05,090 --> 01:13:08,360 The only way it can terminate is that the e 1120 01:13:08,360 --> 01:13:14,020 is some odd number over here. 1121 01:13:14,020 --> 01:13:16,030 And that will solve the thing. 1122 01:13:16,030 --> 01:13:19,200 So we actually need to do this. 1123 01:13:19,200 --> 01:13:21,230 This shows the energy. 1124 01:13:21,230 --> 01:13:24,500 You found why it's quantized. 1125 01:13:24,500 --> 01:13:28,150 So let's do it then. 1126 01:13:28,150 --> 01:13:31,550 We're really done with this in a sense. 1127 01:13:31,550 --> 01:13:36,460 This is the most important point of the lecture, 1128 01:13:36,460 --> 01:13:39,480 is that the series must terminate, 1129 01:13:39,480 --> 01:13:42,530 otherwise it will blow up horrendously. 1130 01:13:42,530 --> 01:13:44,550 If it terminates as a polynomial, 1131 01:13:44,550 --> 01:13:46,640 then everything is good. 1132 01:13:46,640 --> 01:13:58,900 So to terminate you can choose 2j plus 1 minus e to be 0. 1133 01:13:58,900 --> 01:14:05,010 This will make aj plus 2 equal to 0. 1134 01:14:07,970 --> 01:14:13,930 And your solution, your h of u, will begin. 1135 01:14:13,930 --> 01:14:17,800 aj will be the last one that is non-zero, 1136 01:14:17,800 --> 01:14:25,020 so it will be aj times u to the j, 1137 01:14:25,020 --> 01:14:33,500 and it will go down like aj minus 2 u to the j minus 2. 1138 01:14:33,500 --> 01:14:37,380 It will go down in steps of 2, because this recursion 1139 01:14:37,380 --> 01:14:40,100 is always by steps of two. 1140 01:14:40,100 --> 01:14:41,232 So that's it. 1141 01:14:41,232 --> 01:14:44,350 That's going to be the solution where these coefficients are 1142 01:14:44,350 --> 01:14:47,160 going to be fixed by the recursive relation, 1143 01:14:47,160 --> 01:14:49,720 and we have this. 1144 01:14:49,720 --> 01:14:56,180 Now most people here call j equal n. 1145 01:14:56,180 --> 01:14:58,080 So let's call it n. 1146 01:14:58,080 --> 01:15:04,420 And then we have 2n plus 1 minus e equals 0. 1147 01:15:04,420 --> 01:15:12,580 And h of u would be an u to the n plus all these things. 1148 01:15:12,580 --> 01:15:14,120 That's the h. 1149 01:15:14,120 --> 01:15:18,810 The full solution is h times e to the minus u 1150 01:15:18,810 --> 01:15:21,290 squared over 2 as we will see. 1151 01:15:21,290 --> 01:15:25,250 But recall what e was. 1152 01:15:25,250 --> 01:15:28,480 e here is 2n plus 1. 1153 01:15:28,480 --> 01:15:36,620 But he was the true energy divided by h omega over two. 1154 01:15:36,620 --> 01:15:37,935 That was long ago. 1155 01:15:41,310 --> 01:15:42,790 It's gone. 1156 01:15:42,790 --> 01:15:46,150 Long gone. 1157 01:15:46,150 --> 01:15:50,160 So what have you found therefore? 1158 01:15:50,160 --> 01:15:59,258 That the energy, that' we'll call en, 1159 01:15:59,258 --> 01:16:02,680 the energy of the nth solution is 1160 01:16:02,680 --> 01:16:07,770 going to be h omega over 2 2n plus 1. 1161 01:16:07,770 --> 01:16:13,890 So it's actually h omega, and people write it n plus 1/2. 1162 01:16:13,890 --> 01:16:15,570 Very famous result. 1163 01:16:15,570 --> 01:16:20,440 The nth level of the harmonic oscillator has this energy. 1164 01:16:20,440 --> 01:16:25,060 And moreover, these objects, people 1165 01:16:25,060 --> 01:16:27,220 choose these-- you see the constants are 1166 01:16:27,220 --> 01:16:28,720 related by steps of two. 1167 01:16:28,720 --> 01:16:32,770 So just like you could start with a0, or a1 and go up, 1168 01:16:32,770 --> 01:16:34,640 you can go down. 1169 01:16:34,640 --> 01:16:38,990 People call these functions Hermite functions. 1170 01:16:38,990 --> 01:16:44,230 And they fix the notation so that this an is 2 to the n. 1171 01:16:44,230 --> 01:16:45,160 They like it. 1172 01:16:45,160 --> 01:16:46,880 It's a nice normalization. 1173 01:16:46,880 --> 01:16:52,410 So actually h of n is what we call 1174 01:16:52,410 --> 01:16:56,880 the Hermite function of u sub n. 1175 01:16:56,880 --> 01:17:02,960 And it goes like 2 to the n u to the n plus order u 1176 01:17:02,960 --> 01:17:06,170 to the n minus 2 plus n minus 4, and it 1177 01:17:06,170 --> 01:17:07,855 goes on and on like that. 1178 01:17:13,180 --> 01:17:18,300 OK, a couple things and we're done. 1179 01:17:18,300 --> 01:17:23,780 Just for reference, the Hermite polynomial, 1180 01:17:23,780 --> 01:17:25,950 if you're interested in it, is the one 1181 01:17:25,950 --> 01:17:28,230 that solves this equation. 1182 01:17:28,230 --> 01:17:30,470 And the Hermite sub n corresponds 1183 01:17:30,470 --> 01:17:36,570 to e sub n, which is 2n plus 1. 1184 01:17:36,570 --> 01:17:39,330 So the Hermite solution from that the equation 1185 01:17:39,330 --> 01:17:47,378 is that the Hermite polynomial satisfies this minus 2u 1186 01:17:47,378 --> 01:17:52,480 d Hn du plus 2n. 1187 01:17:52,480 --> 01:17:55,050 Because en is 2n plus 1. 1188 01:17:55,050 --> 01:17:59,240 So it's 2n Hn equals 0. 1189 01:17:59,240 --> 01:18:02,130 That's the equation for the Hermite polynomial, 1190 01:18:02,130 --> 01:18:05,530 and interesting thing to know. 1191 01:18:05,530 --> 01:18:08,100 Actually, if you want to generate the efficiently 1192 01:18:08,100 --> 01:18:11,490 the Hermite polynomials, there's something called the generating 1193 01:18:11,490 --> 01:18:13,450 function. 1194 01:18:13,450 --> 01:18:17,730 e to the minus z squared plus 2zu. 1195 01:18:17,730 --> 01:18:23,440 If you expand it in a power series of z, 1196 01:18:23,440 --> 01:18:27,660 it actually gives you n equals 0 to infinity. 1197 01:18:27,660 --> 01:18:32,780 If it's a power series of z, it will be some z to the n's. 1198 01:18:32,780 --> 01:18:37,605 You can put a factor here n, and here is Hn of u. 1199 01:18:40,620 --> 01:18:43,740 So you can use your mathematic program 1200 01:18:43,740 --> 01:18:46,590 and expand this in powers of z. 1201 01:18:46,590 --> 01:18:51,370 Collect the various powers of u that appear with z to the n, 1202 01:18:51,370 --> 01:18:56,260 and that's Hn It's the most efficient way of generating Hn 1203 01:18:56,260 --> 01:18:59,480 And moreover, if you want to play in mathematics, 1204 01:18:59,480 --> 01:19:03,840 you can show that such definition of Hn 1205 01:19:03,840 --> 01:19:05,950 satisfies this equation. 1206 01:19:05,950 --> 01:19:08,380 So it produces the solution. 1207 01:19:08,380 --> 01:19:10,810 So what have we found? 1208 01:19:10,810 --> 01:19:13,910 Our end result is the following. 1209 01:19:13,910 --> 01:19:17,080 Let me finish with that here. 1210 01:19:17,080 --> 01:19:25,070 We had this potential, and the first energy level is called E0 1211 01:19:25,070 --> 01:19:27,620 and has energy h omega over 2. 1212 01:19:27,620 --> 01:19:29,940 The next energy is E1. 1213 01:19:29,940 --> 01:19:33,810 It has 3/2 h omega. 1214 01:19:33,810 --> 01:19:39,830 Next one is E2 5/2 h omega. 1215 01:19:39,830 --> 01:19:42,940 This polynomial is nth degree polynomial. 1216 01:19:42,940 --> 01:19:46,860 So it has n zeros, therefore n nodes. 1217 01:19:46,860 --> 01:19:50,470 So these wave functions will have the right number of nodes. 1218 01:19:50,470 --> 01:19:54,030 E0, the psi 0, will have no nodes. 1219 01:19:54,030 --> 01:19:59,300 When you have psi 0, the Hn becomes a number for n 1220 01:19:59,300 --> 01:20:00,510 equals zero. 1221 01:20:00,510 --> 01:20:02,830 And the whole solution is the exponential 1222 01:20:02,830 --> 01:20:05,610 of u squared over 2. 1223 01:20:05,610 --> 01:20:08,960 The whole solution, in fact, is, as we wrote, 1224 01:20:08,960 --> 01:20:15,150 psi n Hn of u e to the minus u squared over 2. 1225 01:20:15,150 --> 01:20:18,630 In plain English, if you use an x, 1226 01:20:18,630 --> 01:20:24,890 it will be Hn u with x over that constant a we had. 1227 01:20:24,890 --> 01:20:30,470 And you have minus x squared over 2a squared. 1228 01:20:30,470 --> 01:20:32,810 Those are your eigenfunctions. 1229 01:20:32,810 --> 01:20:34,750 These are the solutions. 1230 01:20:34,750 --> 01:20:39,020 Discrete spectrum, evenly spaced, the nicest spectrum 1231 01:20:39,020 --> 01:20:40,530 possible. 1232 01:20:40,530 --> 01:20:42,730 All the nodes are there. 1233 01:20:42,730 --> 01:20:46,620 You will solve this in a more clever way next time. 1234 01:20:46,620 --> 01:20:48,170 [APPLAUSE]