1 00:00:00,500 --> 00:00:13,360 PROFESSOR: Time evolution of a free particle wave packet. 2 00:00:18,030 --> 00:00:24,930 So, suppose you know psi of x and 0. 3 00:00:24,930 --> 00:00:34,300 Suppose you know psi of x and 0. 4 00:00:34,300 --> 00:00:37,520 So what do you do next, if you want 5 00:00:37,520 --> 00:00:40,320 to calculate psi of x and t? 6 00:00:44,870 --> 00:00:57,660 Well, the first step, step one, is calculate phi of k. 7 00:00:57,660 --> 00:01:04,870 So you have phi of k is equal 1 over square root of 2 pi 8 00:01:04,870 --> 00:01:11,240 integral dx psi of x, 0 e to the minus ikx. 9 00:01:15,720 --> 00:01:18,000 So you must do this integral. 10 00:01:21,870 --> 00:01:28,440 Step two-- step two-- 11 00:01:28,440 --> 00:01:39,910 with this, now rewrite and say that psi of x, 0 12 00:01:39,910 --> 00:01:46,380 is 1 over square root of 2 pi dk e to the-- 13 00:01:46,380 --> 00:01:51,210 no, I'm sorry-- phi of k, e to the ikx. 14 00:01:55,400 --> 00:02:02,840 So that has achieved our rewriting of psi of x and 0, 15 00:02:02,840 --> 00:02:06,970 which was an arbitrary function as a superposition of plane 16 00:02:06,970 --> 00:02:07,470 waves. 17 00:02:10,460 --> 00:02:17,266 Step three is the most fun step of all. 18 00:02:17,266 --> 00:02:22,500 Step three-- you look at this, and then you say, 19 00:02:22,500 --> 00:02:27,200 well, I know now what psi of x and t is. 20 00:02:27,200 --> 00:02:31,700 Evolving this is as easy as doing nothing. 21 00:02:31,700 --> 00:02:37,110 What I must do here is 1 over square root of 2 pi-- 22 00:02:37,110 --> 00:02:46,570 just copy this-- dk, phi of k, e to the ikx. 23 00:02:46,570 --> 00:02:50,510 And I put here minus omega of k, t. 24 00:02:53,630 --> 00:02:59,840 And I remind you that h bar omega of k is the energy, 25 00:02:59,840 --> 00:03:07,160 and it's equal to h squared k squared over 2m. 26 00:03:07,160 --> 00:03:10,340 This is our free particle. 27 00:03:10,340 --> 00:03:15,410 And I claim that, just by writing this, 28 00:03:15,410 --> 00:03:17,900 I've solved the Schrodinger equation 29 00:03:17,900 --> 00:03:21,670 and I've time-evolved everything. 30 00:03:21,670 --> 00:03:22,840 The answer is there-- 31 00:03:22,840 --> 00:03:27,100 I didn't have to solve the differential equation, or-- 32 00:03:27,100 --> 00:03:28,330 that's it. 33 00:03:28,330 --> 00:03:30,760 That's the answer. 34 00:03:30,760 --> 00:03:32,400 Claim this is the answer. 35 00:03:38,550 --> 00:03:41,380 And the reason is important. 36 00:03:43,940 --> 00:03:49,340 If you come equipped with a Schrodinger equation, what 37 00:03:49,340 --> 00:03:58,580 should you check, that ih bar d psi dt is equal to h psi-- 38 00:03:58,580 --> 00:04:05,360 which is minus h-- squared over 2m, d second, dx squared psi. 39 00:04:05,360 --> 00:04:10,100 Well, you can add with ih d dt on this thing. 40 00:04:10,100 --> 00:04:12,590 And you remember all that happens 41 00:04:12,590 --> 00:04:17,740 is that they all concentrate on this thing. 42 00:04:17,740 --> 00:04:21,339 And it solves this, because it's a plane wave. 43 00:04:21,339 --> 00:04:26,350 So this thing, this psi of x and t, 44 00:04:26,350 --> 00:04:30,300 solves the Schrodinger equation. 45 00:04:30,300 --> 00:04:34,260 It's a superposition of plane waves, each of which 46 00:04:34,260 --> 00:04:37,960 solves the free Schrodinger equation. 47 00:04:37,960 --> 00:04:44,090 So, we also mention that since the Schrodinger equation is 48 00:04:44,090 --> 00:04:48,110 first ordered in time, if you know the wave function at one 49 00:04:48,110 --> 00:04:52,350 time, and you solve it, you get the wave function at any time. 50 00:04:52,350 --> 00:04:57,580 So here is a solution that is a solution of the Schrodinger 51 00:04:57,580 --> 00:04:58,640 equation. 52 00:04:58,640 --> 00:05:02,040 But at time equals 0-- 53 00:05:02,040 --> 00:05:09,400 this is 0-- and we reduce this to psi of x and 0. 54 00:05:09,400 --> 00:05:12,130 So it has the right condition. 55 00:05:12,130 --> 00:05:14,520 Not only solve the Schrodinger equation, 56 00:05:14,520 --> 00:05:18,010 but it reduces to the right thing. 57 00:05:18,010 --> 00:05:20,580 So it is the answer. 58 00:05:20,580 --> 00:05:22,660 And we could say-- 59 00:05:28,800 --> 00:05:33,330 we could say that there is a step four, which is-- 60 00:05:40,400 --> 00:05:48,390 step four would be do the k integral. 61 00:05:52,620 --> 00:05:54,990 And sometimes it's possible. 62 00:05:54,990 --> 00:06:01,710 You see, in here, once you have this phi of k, 63 00:06:01,710 --> 00:06:04,350 maybe you can just look at it and say, oh, 64 00:06:04,350 --> 00:06:09,630 yeah, I can do this k integral and get psi of x and 0, 65 00:06:09,630 --> 00:06:12,150 recover what I know. 66 00:06:12,150 --> 00:06:17,470 I know how to do-- this integral is a little harder, 67 00:06:17,470 --> 00:06:20,070 because k appears a little more complicated. 68 00:06:20,070 --> 00:06:26,230 But it has the whole answer to the problem. 69 00:06:26,230 --> 00:06:30,000 I think one should definitely focus on this 70 00:06:30,000 --> 00:06:37,320 and appreciate that, with zero effort and Fourier's theorem, 71 00:06:37,320 --> 00:06:43,050 you're managing to solve the propagation of any initial wave 72 00:06:43,050 --> 00:06:45,400 function for all times. 73 00:06:45,400 --> 00:06:51,330 So there will be an exercise in the homework, which is called 74 00:06:51,330 --> 00:06:58,900 evolving the free Gaussian-- 75 00:06:58,900 --> 00:07:01,080 Gaussian. 76 00:07:01,080 --> 00:07:05,400 So you take a psi a of x and time 77 00:07:05,400 --> 00:07:11,970 equals 0 to be e to the minus x squared over 4a 78 00:07:11,970 --> 00:07:17,010 squared over 2 pi to the 1/4-- 79 00:07:17,010 --> 00:07:21,660 that's for normalization-- square root of a. 80 00:07:21,660 --> 00:07:23,280 And so what is this? 81 00:07:23,280 --> 00:07:25,920 This is a psi-- 82 00:07:25,920 --> 00:07:30,870 this is a Gaussian-- and the uncertainty's roughly a-- 83 00:07:30,870 --> 00:07:32,190 is that right? 84 00:07:32,190 --> 00:07:37,560 Delta x is about a, because that controls 85 00:07:37,560 --> 00:07:39,410 the width of the Gaussian. 86 00:07:45,050 --> 00:07:50,760 And now, you have a Gaussian that you have to evolve. 87 00:07:50,760 --> 00:07:53,450 And what's going to happen with it? 88 00:07:53,450 --> 00:07:58,940 This Gaussian, as written, doesn't 89 00:07:58,940 --> 00:08:02,930 represent a moving Gaussian. 90 00:08:02,930 --> 00:08:05,450 To be a moving Gaussian, you would 91 00:08:05,450 --> 00:08:07,940 like to see maybe things of [? the ?] from e 92 00:08:07,940 --> 00:08:13,970 to the ipx that represent waves with momentum. 93 00:08:13,970 --> 00:08:18,390 So I don't see anything like that in this wave function. 94 00:08:18,390 --> 00:08:23,000 So this must be a Gaussian that is just sitting here. 95 00:08:23,000 --> 00:08:26,910 And what is it going to do in time? 96 00:08:26,910 --> 00:08:30,460 Well, it's presumably going to spread out. 97 00:08:30,460 --> 00:08:33,610 So the width is going to change in time. 98 00:08:33,610 --> 00:08:38,760 There's going to be a time in which the shape changes. 99 00:08:38,760 --> 00:08:41,940 Will it be similar to what you have here? 100 00:08:41,940 --> 00:08:43,679 Yes. 101 00:08:43,679 --> 00:08:45,550 The time will be related. 102 00:08:45,550 --> 00:08:49,360 So time for changes. 103 00:08:49,360 --> 00:08:52,140 So there will be some relevant time 104 00:08:52,140 --> 00:08:57,570 in this problem for which the width starts to change. 105 00:08:57,570 --> 00:09:05,980 And it will be related to ma squared over h bar. 106 00:09:05,980 --> 00:09:09,550 In fact, you will find that with a 2, 107 00:09:09,550 --> 00:09:13,210 the formulas look very, very neat. 108 00:09:13,210 --> 00:09:16,990 And that's the relevant time for the formation of the Gaussian. 109 00:09:16,990 --> 00:09:19,560 So you will do those four steps. 110 00:09:19,560 --> 00:09:22,600 They're all doable for Gaussians. 111 00:09:22,600 --> 00:09:26,290 And you'll find the Fourier transform, 112 00:09:26,290 --> 00:09:28,330 which is another Gaussian. 113 00:09:28,330 --> 00:09:30,730 Then you will put the right things 114 00:09:30,730 --> 00:09:33,850 and then try to do the integral back. 115 00:09:33,850 --> 00:09:38,500 The answer is a bit messy for psi, 116 00:09:38,500 --> 00:09:43,330 but not messy for psi squared, which is what we typically 117 00:09:43,330 --> 00:09:45,250 ask you to find.