1 00:00:01,030 --> 00:00:02,800 PROFESSOR: Delta function potential. 2 00:00:02,800 --> 00:00:06,120 So it's still a one-dimensional potential-- potential 3 00:00:06,120 --> 00:00:08,960 is a function of x. 4 00:00:08,960 --> 00:00:12,490 We'll write it this way-- minus alpha delta 5 00:00:12,490 --> 00:00:17,190 of x, where alpha is positive. 6 00:00:17,190 --> 00:00:22,030 So this is a delta function in a negative direction. 7 00:00:22,030 --> 00:00:23,910 So if you want to draw the potential-- 8 00:00:23,910 --> 00:00:27,350 there's no way to draw really nicely a delta function. 9 00:00:27,350 --> 00:00:32,970 So you just do a thick arrow with it pointing down. 10 00:00:32,970 --> 00:00:36,750 It's a representation of a potential that, somehow, 11 00:00:36,750 --> 00:00:42,070 is rather infinite at x equals zero-- 12 00:00:42,070 --> 00:00:45,010 but infinite and negative. 13 00:00:45,010 --> 00:00:49,990 It can be thought of as the limit of a square well that 14 00:00:49,990 --> 00:00:53,350 is becoming deeper and deeper. 15 00:00:53,350 --> 00:00:55,900 And, in fact, that could be a way 16 00:00:55,900 --> 00:00:59,200 to analytically calculate the energy 17 00:00:59,200 --> 00:01:03,010 levels-- by taking carefully the limit of a potential. 18 00:01:03,010 --> 00:01:07,180 It is becoming thinner and thinner, but deeper and deeper, 19 00:01:07,180 --> 00:01:11,290 which is the way you define or regulate the delta function. 20 00:01:11,290 --> 00:01:13,360 You can imagine the delta function 21 00:01:13,360 --> 00:01:16,450 as a sequence of functions, in which it's 22 00:01:16,450 --> 00:01:18,040 becoming more and more narrow-- 23 00:01:18,040 --> 00:01:19,850 but deeper at the same time. 24 00:01:19,850 --> 00:01:24,350 So that the area under the curve is still the same. 25 00:01:24,350 --> 00:01:27,970 So, at any rate, the delta function potential is 26 00:01:27,970 --> 00:01:31,690 a potential that should be understood as 0 everywhere , 27 00:01:31,690 --> 00:01:36,250 else except at the delta function where it becomes 28 00:01:36,250 --> 00:01:38,000 infinite. 29 00:01:38,000 --> 00:01:41,700 And there are all kinds of questions we can ask. 30 00:01:41,700 --> 00:01:42,500 OK. 31 00:01:42,500 --> 00:01:44,330 Are there bound states? 32 00:01:44,330 --> 00:01:46,430 What are bound states in this case? 33 00:01:46,430 --> 00:01:53,270 They are energy eigenstates with energy less than zero. 34 00:01:53,270 --> 00:02:02,160 So bound states, which means e less than zero. 35 00:02:02,160 --> 00:02:04,216 Do they exist? 36 00:02:04,216 --> 00:02:08,190 Does this potential have bound states? 37 00:02:08,190 --> 00:02:11,130 And, if it does, how many bound states? 38 00:02:11,130 --> 00:02:12,480 1, 2, 3? 39 00:02:12,480 --> 00:02:16,110 Does It depend on the intensity of the delta function? 40 00:02:16,110 --> 00:02:20,590 When you get more bound states, the deeper the potential is. 41 00:02:20,590 --> 00:02:23,580 Well, we'll try to figure out. 42 00:02:23,580 --> 00:02:26,550 In fact, there's a lot that can be figured out 43 00:02:26,550 --> 00:02:29,280 without calculating, too much. 44 00:02:29,280 --> 00:02:36,240 And it's a good habit to try to do those things before you-- 45 00:02:36,240 --> 00:02:39,010 not to be so impatient that you begin, 46 00:02:39,010 --> 00:02:41,100 and within a second start writing 47 00:02:41,100 --> 00:02:43,830 the differential equation trying to solve it. 48 00:02:43,830 --> 00:02:49,860 Get a little intuition about how any state could look like, 49 00:02:49,860 --> 00:02:54,210 and how could the answer for the energy eigenstates-- 50 00:02:54,210 --> 00:02:57,060 the energies-- what could they be? 51 00:02:57,060 --> 00:03:00,160 Could you just reason your way and conclude 52 00:03:00,160 --> 00:03:01,620 there's no bound states? 53 00:03:01,620 --> 00:03:02,820 Or one bound state? 54 00:03:02,820 --> 00:03:03,960 Or two? 55 00:03:03,960 --> 00:03:05,840 All these things are pretty useful. 56 00:03:05,840 --> 00:03:10,355 So one way, as you can imagine, is to think of units. 57 00:03:15,800 --> 00:03:20,710 And what are the constants in this problem? 58 00:03:20,710 --> 00:03:23,340 In this problem we'll have three constants. 59 00:03:23,340 --> 00:03:29,730 Alpha, the mass of the particle, and h-bar. 60 00:03:29,730 --> 00:03:32,340 So with alpha, the mass and the particle, 61 00:03:32,340 --> 00:03:36,450 and h-bar you can ask, how do I construct the quantity 62 00:03:36,450 --> 00:03:38,910 with units of energy? 63 00:03:38,910 --> 00:03:42,100 If there there's only one way to construct the quantity 64 00:03:42,100 --> 00:03:46,510 with units of energy, then the energy of a bound state 65 00:03:46,510 --> 00:03:48,880 will be proportional to that quantity-- 66 00:03:48,880 --> 00:03:52,840 because that's the only quantity that can carry the units. 67 00:03:52,840 --> 00:03:55,150 And here, indeed, there's only one way 68 00:03:55,150 --> 00:03:58,000 to construct that quantity with units of energy-- 69 00:03:58,000 --> 00:04:00,730 from these three. 70 00:04:00,730 --> 00:04:02,020 That's to be expected. 71 00:04:02,020 --> 00:04:08,290 With three constants that are not linearly dependent-- 72 00:04:08,290 --> 00:04:11,830 whatever that is supposed to mean-- 73 00:04:11,830 --> 00:04:17,019 you can build anything that has units of length, mass, or time. 74 00:04:17,019 --> 00:04:18,700 And from that you can build something 75 00:04:18,700 --> 00:04:20,000 that has units of energy. 76 00:04:20,000 --> 00:04:25,030 So you can now decide, well, what are the units of alpha? 77 00:04:25,030 --> 00:04:32,350 The units of alpha have give you energy, 78 00:04:32,350 --> 00:04:36,070 but the delta function has units of one over length. 79 00:04:36,070 --> 00:04:38,522 This has one over length. 80 00:04:38,522 --> 00:04:42,940 , Remember if you integrate over x the delta function gives you 81 00:04:42,940 --> 00:04:43,440 1. 82 00:04:43,440 --> 00:04:45,960 So this has units of 1 over length. 83 00:04:45,960 --> 00:04:48,150 And, therefore, alpha has to have 84 00:04:48,150 --> 00:04:52,140 units of energy times length. 85 00:04:54,690 --> 00:04:59,120 So this is not quite enough to solve the problem, 86 00:04:59,120 --> 00:05:03,010 because I want to write e-- 87 00:05:03,010 --> 00:05:06,810 think of finding how do you get units of energy 88 00:05:06,810 --> 00:05:08,040 from these quantities? 89 00:05:08,040 --> 00:05:11,610 But l-- we still don't have a length scale either. 90 00:05:11,610 --> 00:05:13,900 So we have to do a little more work. 91 00:05:13,900 --> 00:05:21,550 So from here we say that units of energy is alpha over l. 92 00:05:21,550 --> 00:05:23,340 There should be a way to say that this 93 00:05:23,340 --> 00:05:25,800 is an equality between units. 94 00:05:25,800 --> 00:05:31,300 I could put units or leave it just like that. 95 00:05:34,540 --> 00:05:37,660 So in terms of units, it's this. 96 00:05:37,660 --> 00:05:40,120 But in terms of units, energy-- 97 00:05:40,120 --> 00:05:42,490 you should always remember-- 98 00:05:42,490 --> 00:05:44,340 is p squared over m. 99 00:05:44,340 --> 00:05:48,800 And p is h-bar over a length. 100 00:05:48,800 --> 00:05:53,200 So that's p squared and that's m. 101 00:05:53,200 --> 00:05:56,170 So that's also units of energy 102 00:05:56,170 --> 00:06:05,100 From these two you can get what has units of length. 103 00:06:05,100 --> 00:06:06,860 Length. 104 00:06:06,860 --> 00:06:09,830 You pass the l to this side-- the l 105 00:06:09,830 --> 00:06:11,871 squared to this left-hand side. 106 00:06:11,871 --> 00:06:12,370 Divide. 107 00:06:12,370 --> 00:06:20,950 So you get l is h squared over m alpha. 108 00:06:20,950 --> 00:06:25,970 And if I substitute back into this l here, 109 00:06:25,970 --> 00:06:33,660 e would be alpha over l, which is h squared, alpha squared, m. 110 00:06:33,660 --> 00:06:38,500 So that's the quantity that has units of energy. 111 00:06:38,500 --> 00:06:44,730 M alpha squared over h squared has units of energy. 112 00:06:44,730 --> 00:06:46,830 If this has units of energy-- 113 00:06:46,830 --> 00:06:50,080 the bound state energy. 114 00:06:50,080 --> 00:06:53,460 Now, if you have a bounce state here, 115 00:06:53,460 --> 00:06:57,810 it has to decay in order to be normalizable. 116 00:06:57,810 --> 00:07:00,930 In order to be normalizable it has to decay, 117 00:07:00,930 --> 00:07:06,090 so it has to be in the forbidden region throughout x. 118 00:07:06,090 --> 00:07:10,790 So the energy as we said is negative, 119 00:07:10,790 --> 00:07:14,410 energy of a bound state-- if it exists. 120 00:07:14,410 --> 00:07:16,910 And this bound state energy would 121 00:07:16,910 --> 00:07:25,970 have to be negative some number m alpha squared over h squared. 122 00:07:25,970 --> 00:07:28,850 And that's very useful information. 123 00:07:28,850 --> 00:07:30,950 The whole problem has been reduced 124 00:07:30,950 --> 00:07:33,540 to calculating a number. 125 00:07:33,540 --> 00:07:37,670 It better be and the answer cannot be any other way. 126 00:07:37,670 --> 00:07:40,290 There's no other way to get the units of energy. 127 00:07:40,290 --> 00:07:43,880 So if a bound state exists it has to be that. 128 00:07:43,880 --> 00:07:47,830 And that number could be pi, it could be 1/3, 1/4, 129 00:07:47,830 --> 00:07:49,820 it could be anything. 130 00:07:53,150 --> 00:07:56,690 There's a naturalness to that problem 131 00:07:56,690 --> 00:08:01,610 in that you don't expect that number to be a trillion. 132 00:08:01,610 --> 00:08:05,900 Nor do you expect that number to be 10 to the minus 6. 133 00:08:05,900 --> 00:08:08,810 Because there's no way-- where would those numbers appear? 134 00:08:08,810 --> 00:08:12,110 So this number should be a number of order one, 135 00:08:12,110 --> 00:08:16,370 and we're going to wait and see what it is. 136 00:08:16,370 --> 00:08:21,660 So that's one thing we know already about this problem. 137 00:08:21,660 --> 00:08:26,270 The other thing we can do is to think of the regulated delta 138 00:08:26,270 --> 00:08:27,530 function. 139 00:08:27,530 --> 00:08:33,870 So we think of this as a potential that has this form. 140 00:08:33,870 --> 00:08:37,220 So here is v of x, and here is x. 141 00:08:40,630 --> 00:08:44,490 And for this potential-- 142 00:08:44,490 --> 00:08:45,630 if you have a bound state-- 143 00:08:48,420 --> 00:08:52,260 how would the wave function look? 144 00:08:52,260 --> 00:08:54,480 Well, it would have to-- 145 00:08:54,480 --> 00:08:57,820 suppose you have a ground state-- 146 00:08:57,820 --> 00:09:01,378 it's an even potential. 147 00:09:01,378 --> 00:09:03,700 The delta function is even, too. 148 00:09:03,700 --> 00:09:04,590 It's in the middle. 149 00:09:04,590 --> 00:09:05,610 It's symmetric. 150 00:09:05,610 --> 00:09:09,610 There's nothing asymmetric about the delta function. 151 00:09:09,610 --> 00:09:12,890 So if it's an even potential the ground states 152 00:09:12,890 --> 00:09:16,110 should be even, because the ground state 153 00:09:16,110 --> 00:09:18,930 is supposed to have no nodes. 154 00:09:18,930 --> 00:09:23,100 And it's supposed to be even if the potential is even. 155 00:09:23,100 --> 00:09:24,540 So how will it look? 156 00:09:24,540 --> 00:09:28,440 Well, it shouldn't be decaying in this region. 157 00:09:28,440 --> 00:09:32,610 So, presumably, it decays here. 158 00:09:32,610 --> 00:09:36,530 It decays there-- symmetrically. 159 00:09:36,530 --> 00:09:42,580 And in the middle it curves in the other direction. 160 00:09:42,580 --> 00:09:44,520 It is in an allowed region-- 161 00:09:44,520 --> 00:09:47,730 and you remember that's kind of allowed this way. 162 00:09:47,730 --> 00:09:51,290 So that's probably the way it looks. 163 00:09:51,290 --> 00:09:56,240 Now, if that bound state exists, somehow, 164 00:09:56,240 --> 00:10:00,490 as I narrow this and go down-- 165 00:10:00,490 --> 00:10:06,170 as it becomes even more narrow, very narrow now, but very deep. 166 00:10:06,170 --> 00:10:09,510 This region becomes smaller. 167 00:10:09,510 --> 00:10:13,020 And I would pretty much expect the wave function 168 00:10:13,020 --> 00:10:15,810 to have a discontinuity. 169 00:10:15,810 --> 00:10:18,390 You basically don't have enough power 170 00:10:18,390 --> 00:10:21,630 to see the curving that is happening here. 171 00:10:21,630 --> 00:10:24,940 Especially because the curving is going down. 172 00:10:24,940 --> 00:10:27,120 The distance is going down. 173 00:10:27,120 --> 00:10:33,490 So if this bound state exists, as you approach 174 00:10:33,490 --> 00:10:36,220 the limit in which this becomes a delta function 175 00:10:36,220 --> 00:10:42,240 the energy moves a little, but stays finite at some number. 176 00:10:42,240 --> 00:10:46,550 And the curvature that is created by the delta function 177 00:10:46,550 --> 00:10:50,150 is not visible, and the thing looks just discontinuous 178 00:10:50,150 --> 00:10:53,350 in its derivative. 179 00:10:53,350 --> 00:10:55,890 So this is an intuitive way to understand 180 00:10:55,890 --> 00:10:57,480 that the wave function we're looking 181 00:10:57,480 --> 00:11:02,330 for is going to be discontinuous on its derivative. 182 00:11:02,330 --> 00:11:05,050 Let's write the differential equation, 183 00:11:05,050 --> 00:11:07,550 even though we're still not going to solve it. 184 00:11:07,550 --> 00:11:09,430 So what is the differential equation? 185 00:11:09,430 --> 00:11:16,270 Minus h squared over m, psi double prime, 186 00:11:16,270 --> 00:11:20,420 is equal to E psi. 187 00:11:20,420 --> 00:11:24,170 And, therefore-- and I write this, and you say, 188 00:11:24,170 --> 00:11:25,730 oh, what are you writing? 189 00:11:25,730 --> 00:11:28,220 I'm writing the differential equation 190 00:11:28,220 --> 00:11:31,500 when x is different from 0. 191 00:11:35,610 --> 00:11:38,380 No potential when x is different from 0. 192 00:11:38,380 --> 00:11:41,710 So this applies for positive x and negative x. 193 00:11:41,710 --> 00:11:44,140 It doesn't apply at x equals 0. 194 00:11:44,140 --> 00:11:46,280 We'll have to deal with that later. 195 00:11:46,280 --> 00:11:50,050 So then, no potential for x different from 0. 196 00:11:50,050 --> 00:11:51,960 And this differential equation becomes 197 00:11:51,960 --> 00:11:59,980 psi double prime equals minus 2m e over h squared psi. 198 00:11:59,980 --> 00:12:03,040 And this is equal to kappa squared 199 00:12:03,040 --> 00:12:09,880 psi, where kappa squared is minus 2me over h squared. 200 00:12:09,880 --> 00:12:13,350 And it's positive. 201 00:12:13,350 --> 00:12:16,000 Let's make that positive. 202 00:12:16,000 --> 00:12:19,180 It's positive because the energy is negative 203 00:12:19,180 --> 00:12:22,450 and we're looking for bound states. 204 00:12:22,450 --> 00:12:26,690 So we're looking for bound states only. 205 00:12:26,690 --> 00:12:28,560 Kappa squared is positive. 206 00:12:28,560 --> 00:12:32,470 And this differential equation is just this. 207 00:12:32,470 --> 00:12:35,690 I'll copy it again here. 208 00:12:35,690 --> 00:12:38,990 Kappa squared psi. 209 00:12:38,990 --> 00:12:42,920 And the solutions of this equation are-- solutions-- 210 00:12:46,130 --> 00:12:52,640 are e to the minus kappa x and e to the kappa x. 211 00:12:52,640 --> 00:12:59,840 Or, if you wish, cosh kappa x and sinh kappa x-- 212 00:12:59,840 --> 00:13:00,830 whichever you prefer. 213 00:13:13,920 --> 00:13:16,560 This is something we now have to use in order 214 00:13:16,560 --> 00:13:17,550 to produce a solution. 215 00:13:20,200 --> 00:13:24,900 But now, let's see if I can figure out 216 00:13:24,900 --> 00:13:26,940 how many bound states there are. 217 00:13:33,240 --> 00:13:37,840 If there is one bound state, it's going to be even. 218 00:13:37,840 --> 00:13:39,180 It's the ground state. 219 00:13:39,180 --> 00:13:40,975 It has no nodes. 220 00:13:40,975 --> 00:13:45,800 It has to be even, because the potential is even. 221 00:13:45,800 --> 00:13:50,990 If I have the first excited state after the ground state, 222 00:13:50,990 --> 00:13:53,330 it will have to be odd. 223 00:13:53,330 --> 00:13:59,320 It would have to vanish at x equals 0, because it's odd. 224 00:13:59,320 --> 00:14:01,010 There is it's node-- 225 00:14:01,010 --> 00:14:02,390 it has to have one node. 226 00:14:04,910 --> 00:14:10,800 For an odd bound state-- 227 00:14:14,200 --> 00:14:17,310 or first excited state-- 228 00:14:21,250 --> 00:14:26,590 you'd have to have psi equals 0 at x equals 0. 229 00:14:32,670 --> 00:14:37,920 And the way to do that would be to have a sinh, because this 230 00:14:37,920 --> 00:14:39,530 doesn't vanish at zero. 231 00:14:39,530 --> 00:14:40,870 This doesn't vanish at zero. 232 00:14:40,870 --> 00:14:43,050 And cosh doesn't vanish at zero. 233 00:14:43,050 --> 00:14:51,210 So you would need psi of x equals sinh of kappa x. 234 00:14:56,730 --> 00:14:59,230 But that's not good. 235 00:14:59,230 --> 00:15:06,420 sinh of kappa x is like this and blows up. 236 00:15:06,420 --> 00:15:08,030 Blows down. 237 00:15:08,030 --> 00:15:10,590 It has to go like this. 238 00:15:10,590 --> 00:15:13,230 It is in a forbidden region, so it has 239 00:15:13,230 --> 00:15:17,230 to be convex towards the axis. 240 00:15:17,230 --> 00:15:18,300 And convex here. 241 00:15:18,300 --> 00:15:19,930 But it blows up. 242 00:15:19,930 --> 00:15:23,370 So there's no such solution. 243 00:15:23,370 --> 00:15:24,240 No such solution. 244 00:15:26,750 --> 00:15:29,630 You cannot have an odd bound state. 245 00:15:29,630 --> 00:15:33,870 So since the bound states alternate-- even, odd, even, 246 00:15:33,870 --> 00:15:36,270 odd, even, odd-- 247 00:15:36,270 --> 00:15:37,560 you're stuck. 248 00:15:37,560 --> 00:15:41,720 You only will have a ground state-- if we're lucky-- 249 00:15:41,720 --> 00:15:47,970 but no excited state that is bound, while a finite square 250 00:15:47,970 --> 00:15:48,470 will. 251 00:15:48,470 --> 00:15:51,590 You remember this quantity z0 that 252 00:15:51,590 --> 00:15:56,420 tells you how many bound states you can have. 253 00:15:56,420 --> 00:16:00,080 Probably you're anticipating that in the case 254 00:16:00,080 --> 00:16:02,630 of the delta function potential, you can only 255 00:16:02,630 --> 00:16:05,630 have one bound state, if any. 256 00:16:05,630 --> 00:16:07,960 The first excited state would not exist. 257 00:16:07,960 --> 00:16:11,630 So, enough preliminaries. 258 00:16:11,630 --> 00:16:14,410 Let's just solve that now.