1 00:00:00,886 --> 00:00:04,971 PROFESSOR: How about the expectation value 2 00:00:04,971 --> 00:00:09,329 of the Hamiltonian in a stationary state? 3 00:00:09,329 --> 00:00:11,370 You would imagine, somehow it has 4 00:00:11,370 --> 00:00:14,520 to do with energy ion states and energy. 5 00:00:14,520 --> 00:00:17,370 So let's see what happens. 6 00:00:17,370 --> 00:00:20,100 The expectation value of the Hamiltonian 7 00:00:20,100 --> 00:00:23,610 on this stationary state. 8 00:00:23,610 --> 00:00:31,056 That would be integral dx stationary state 9 00:00:31,056 --> 00:00:35,980 Hamiltonian stationary state. 10 00:00:39,452 --> 00:00:42,630 And we're going to see this statement that we made 11 00:00:42,630 --> 00:00:45,146 a few minutes ago become clear. 12 00:00:45,146 --> 00:00:50,505 Well what do we get here? dx psi star 13 00:00:50,505 --> 00:01:00,415 of x e to the i Et over h bar H e to the minus i 14 00:01:00,415 --> 00:01:06,394 Et over h bar psi of x. 15 00:01:06,394 --> 00:01:13,290 And H hat couldn't care less about the time dependence, 16 00:01:13,290 --> 00:01:16,820 that exponential is irrelevant to H hat. 17 00:01:16,820 --> 00:01:21,630 That exponential of time can be moved across and cancelled with 18 00:01:21,630 --> 00:01:22,150 this one. 19 00:01:24,720 --> 00:01:27,555 And therefore you get that this is 20 00:01:27,555 --> 00:01:37,898 equal to dx psi star of x H hat psi of x, which is a nice thing 21 00:01:37,898 --> 00:01:39,722 to notice. 22 00:01:39,722 --> 00:01:44,800 The expectation value of H on the full stationary state 23 00:01:44,800 --> 00:01:48,050 is equal to the expectation value of H 24 00:01:48,050 --> 00:01:52,816 on the spatial part of the stationary state. 25 00:01:52,816 --> 00:01:54,760 That's neat. 26 00:01:54,760 --> 00:01:56,802 I think it should be noted. 27 00:01:56,802 --> 00:02:03,350 So it's equal to the H of little psi of x. 28 00:02:03,350 --> 00:02:06,970 But this one, we can evaluate, because if we 29 00:02:06,970 --> 00:02:13,884 are in a stationary state, H hat psi of x is E times psi of x. 30 00:02:13,884 --> 00:02:17,250 So we get an E integral the x psi 31 00:02:17,250 --> 00:02:21,340 star of psi, which we already show 32 00:02:21,340 --> 00:02:25,950 that integral is equal to one, so we get the energy. 33 00:02:32,950 --> 00:02:35,280 So two interesting things. 34 00:02:35,280 --> 00:02:37,950 The expectation value of this quantity 35 00:02:37,950 --> 00:02:40,590 of H in the stationary state is the same 36 00:02:40,590 --> 00:02:44,110 as it's quotation value of H in the spatial part, 37 00:02:44,110 --> 00:02:47,724 and it's manually equal to the energy. 38 00:02:50,390 --> 00:02:59,700 By the way, you know, these states are energy eigenstates, 39 00:02:59,700 --> 00:03:06,090 these psi of x's, so you would expect zero uncertainty 40 00:03:06,090 --> 00:03:09,120 because they are energy eigenstates. 41 00:03:09,120 --> 00:03:14,815 So the zero uncertainty of the energy operator in an energy 42 00:03:14,815 --> 00:03:15,757 eigenstate. 43 00:03:15,757 --> 00:03:20,460 There's zero uncertainty even in the whole stationary state. 44 00:03:20,460 --> 00:03:28,705 If you have an H squared here, it would give you an E squared, 45 00:03:28,705 --> 00:03:32,860 and the expectation value of H is equal to E, 46 00:03:32,860 --> 00:03:36,610 so the expectation value of H squared minus the expectation 47 00:03:36,610 --> 00:03:40,480 value of H squared would be zero. 48 00:03:40,480 --> 00:03:43,595 Each one would be equal to E squared. 49 00:03:43,595 --> 00:03:47,780 Nothing would happen, no uncertainties whatsoever. 50 00:03:47,780 --> 00:03:55,820 So let me say once more, in general, being 51 00:03:55,820 --> 00:04:02,298 so important here is the comment that the expectation 52 00:04:02,298 --> 00:04:18,270 value of any time independent operator, so comments 1, 53 00:04:18,270 --> 00:04:30,965 the expectation value of any time-independent operator 54 00:04:30,965 --> 00:04:44,000 Q in a stationary state is time-independent. 55 00:04:47,840 --> 00:04:49,646 So how does that go? 56 00:04:49,646 --> 00:04:51,062 It's the same thing. 57 00:04:51,062 --> 00:04:56,600 Q hat on the psi of x and t is general, 58 00:04:56,600 --> 00:05:07,069 now it's integral dx capital Psi of x and t Q hat psi of x and t 59 00:05:07,069 --> 00:05:12,162 equals integral dx-- you have to start breaking the things now. 60 00:05:12,162 --> 00:05:18,206 Little psi star of x E to the i et over H bar. 61 00:05:18,206 --> 00:05:20,540 And I'll put the whole thing here. 62 00:05:20,540 --> 00:05:27,910 Q hat Psi of x E to the minus i et over H. 63 00:05:27,910 --> 00:05:32,330 So it's the same thing. 64 00:05:32,330 --> 00:05:40,700 Q doesn't care about time So this factor just moves across 65 00:05:40,700 --> 00:05:44,904 and cancels this factor. 66 00:05:44,904 --> 00:05:47,700 The time dependence completely disappears. 67 00:05:47,700 --> 00:05:51,843 And in this case, we just get-- this 68 00:05:51,843 --> 00:05:59,702 is equal to integral dx psi star Q psi, which is the expectation 69 00:05:59,702 --> 00:06:07,270 value of Q on little psi of x, which is clearly 70 00:06:07,270 --> 00:06:11,730 time-independent, because the state has no time anymore 71 00:06:11,730 --> 00:06:14,900 and the operator has no time. 72 00:06:14,900 --> 00:06:22,180 So everybody loves their time and we're in good shape. 73 00:06:22,180 --> 00:06:24,792 The second problem is kind of a peculiarity, 74 00:06:24,792 --> 00:06:30,506 but it's important to emphasize superposition. 75 00:06:30,506 --> 00:06:33,910 It's always true, but the superposition 76 00:06:33,910 --> 00:06:40,940 of two stationary states is or is not a stationary state? 77 00:06:40,940 --> 00:06:41,844 STUDENT: No. 78 00:06:41,844 --> 00:06:43,080 PROFESSOR: No, good. 79 00:06:43,080 --> 00:06:46,720 It's not a stationary state in general 80 00:06:46,720 --> 00:06:49,110 because it's not factorizing. 81 00:06:49,110 --> 00:06:54,010 You have two stationary states with different energies, 82 00:06:54,010 --> 00:06:58,408 each one has its own exponential, 83 00:06:58,408 --> 00:07:02,510 and therefore, the whole state is not factorized 84 00:07:02,510 --> 00:07:05,050 between space and time. 85 00:07:05,050 --> 00:07:08,328 One time-dependence has one space-dependence plus another 86 00:07:08,328 --> 00:07:10,202 time-dependence and another space-dependence, 87 00:07:10,202 --> 00:07:13,000 you cannot factor it. 88 00:07:13,000 --> 00:07:16,740 So it's not just a plain fact. 89 00:07:16,740 --> 00:07:29,446 So the superposition of two stationary states 90 00:07:29,446 --> 00:07:39,924 of different energy is not stationary. 91 00:07:46,307 --> 00:07:51,310 And it's more than just saying, OK, it's not stationary. 92 00:07:51,310 --> 00:07:54,310 What it means is that if you take the expectation 93 00:07:54,310 --> 00:08:00,690 value of a time-independent operator, 94 00:08:00,690 --> 00:08:04,740 it may have time-dependence, because you are not anymore 95 00:08:04,740 --> 00:08:07,222 guaranteed by the stationary state 96 00:08:07,222 --> 00:08:10,630 that the expectation value has no time-dependence. 97 00:08:10,630 --> 00:08:16,850 That's how, eventually, these things have time-dependence, 98 00:08:16,850 --> 00:08:19,620 because these things are not [INAUDIBLE] 99 00:08:19,620 --> 00:08:21,250 on stationary states. 100 00:08:21,250 --> 00:08:23,302 On stationary states, these things 101 00:08:23,302 --> 00:08:27,694 would have no time-dependence. 102 00:08:27,694 --> 00:08:31,500 And that's important, because it would 103 00:08:31,500 --> 00:08:33,740 be very boring, quantum mechanics, 104 00:08:33,740 --> 00:08:36,429 if expectation values of operators 105 00:08:36,429 --> 00:08:38,419 were always time-independent. 106 00:08:38,419 --> 00:08:39,515 So what's happening? 107 00:08:39,515 --> 00:08:42,616 Whatever you measure never changes, nothing moves, 108 00:08:42,616 --> 00:08:44,590 nothing changes. 109 00:08:44,590 --> 00:08:47,500 And the way it's solved is because you 110 00:08:47,500 --> 00:08:50,100 do have those stationary states that will give you 111 00:08:50,100 --> 00:08:51,674 lots of solutions. 112 00:08:51,674 --> 00:08:53,790 And then we combine them. 113 00:08:53,790 --> 00:08:56,640 And as we combine them, we can get time-dependence 114 00:08:56,640 --> 00:09:00,290 and we can get the most [INAUDIBLE] equation.