1 00:00:00,500 --> 00:00:05,610 PROFESSOR: If you have potential transmission 2 00:00:05,610 --> 00:00:08,230 coefficient for a potential where 3 00:00:08,230 --> 00:00:13,620 z0 is equal to 13 pi over 4. 4 00:00:13,620 --> 00:00:18,930 That's a square well of certain depth, 5 00:00:18,930 --> 00:00:22,830 and we represent it in this way. 6 00:00:22,830 --> 00:00:32,130 Remember n must be greater than or equal than 2z0 over pi. 7 00:00:32,130 --> 00:00:33,930 So this will be 13/2. 8 00:00:36,760 --> 00:00:44,190 And 13/2 means that we can start with n equals 7, 8, 9, and all 9 00:00:44,190 --> 00:00:45,550 those. 10 00:00:45,550 --> 00:00:51,880 Remember, this n counts which bound state 11 00:00:51,880 --> 00:00:54,290 of the infinite square well you're talking about. 12 00:00:54,290 --> 00:00:59,830 And the energy that you must use are your integers, 13 00:00:59,830 --> 00:01:01,490 are positive energy. 14 00:01:01,490 --> 00:01:07,650 So positive energies mean that you have sufficiently large n, 15 00:01:07,650 --> 00:01:14,040 and the n that this sufficiently large is 7 in this case. 16 00:01:14,040 --> 00:01:22,640 So you can then determine from this formula what 17 00:01:22,640 --> 00:01:26,920 is the value of e n over v0. 18 00:01:26,920 --> 00:01:39,283 So for example E7 over v0 turns out to be 0.15976. 19 00:01:39,283 --> 00:01:47,120 E8 over v0 turns out to be 0.514793. 20 00:01:47,120 --> 00:01:53,060 And E9 over v0 is 0.91716. 21 00:01:53,060 --> 00:02:04,730 So if you plot it, you have here E, or capital energy, over v0. 22 00:02:04,730 --> 00:02:10,460 And you want to plug the transmission probability. 23 00:02:10,460 --> 00:02:12,410 And it begins with 0. 24 00:02:12,410 --> 00:02:15,650 That was the question a second ago. 25 00:02:15,650 --> 00:02:18,860 And then it may reach 1. 26 00:02:18,860 --> 00:02:22,230 And it will reach 1 at each one of those values. 27 00:02:22,230 --> 00:02:27,710 So if, here is 1, 0.15. 28 00:02:27,710 --> 00:02:40,690 There will be 0.15, 0.51, and 0.92. 29 00:02:40,690 --> 00:02:43,900 So you get this, and here another one, and here 30 00:02:43,900 --> 00:02:44,680 another one. 31 00:02:51,244 --> 00:02:52,160 Probability like that. 32 00:02:57,760 --> 00:03:03,360 So that's a typical graph for the transmission probability. 33 00:03:03,360 --> 00:03:11,460 It oscillates, and it reaches 1 at several points 34 00:03:11,460 --> 00:03:12,310 forever and ever. 35 00:03:12,310 --> 00:03:14,230 And the amplitude become smaller, 36 00:03:14,230 --> 00:03:17,370 so it's really overall tending to 1. 37 00:03:20,880 --> 00:03:23,520 So these two people we're talking about, 38 00:03:23,520 --> 00:03:26,520 Ramsauer and Townsend. 39 00:03:26,520 --> 00:03:34,710 They lived from 1860s to 1940s and '50s. 40 00:03:34,710 --> 00:03:41,500 And they did their famous experiment in 1921. 41 00:03:41,500 --> 00:03:47,250 So their experiment was elastic scattering 42 00:03:47,250 --> 00:03:53,610 of low energy electrons off of rare gas atoms. 43 00:03:53,610 --> 00:03:59,910 So Ramsauer and Townsend, in 1921, 44 00:03:59,910 --> 00:04:04,980 they scattered elastically. 45 00:04:09,360 --> 00:04:13,720 That means the particles didn't change their identities. 46 00:04:13,720 --> 00:04:15,640 They didn't create more particles. 47 00:04:15,640 --> 00:04:19,089 It was just electrons came in and electrons went out. 48 00:04:19,089 --> 00:04:22,500 Electrons. 49 00:04:22,500 --> 00:04:31,010 And these are low energy electrons, 50 00:04:31,010 --> 00:04:38,550 off of rare gas atoms. 51 00:04:42,340 --> 00:04:44,860 So these are noble gases. 52 00:04:44,860 --> 00:04:48,880 Their shells are completely filled. 53 00:04:48,880 --> 00:04:54,190 And they're rather inert, very unreactive, high ionization 54 00:04:54,190 --> 00:04:57,400 energies, no low energy states you 55 00:04:57,400 --> 00:05:00,100 can scatter these atoms into. 56 00:05:00,100 --> 00:05:03,670 So basically very unreactive atom. 57 00:05:03,670 --> 00:05:10,720 And you can imagine it as a very beautiful spherical cloud. 58 00:05:10,720 --> 00:05:12,190 We can draw some electrons, there's 59 00:05:12,190 --> 00:05:17,060 some protons, a nucleus here, and an electron cloud. 60 00:05:17,060 --> 00:05:20,050 So how does this look to an electron? 61 00:05:20,050 --> 00:05:23,730 Well, you know from electrostatics 62 00:05:23,730 --> 00:05:26,800 that if you have total charge 0 and it's totally spherically 63 00:05:26,800 --> 00:05:29,560 symmetric, no electric field outside. 64 00:05:29,560 --> 00:05:34,570 So the electron comes in, feels nothing. 65 00:05:34,570 --> 00:05:39,190 And as soon as you penetrate this, at any point here, 66 00:05:39,190 --> 00:05:41,940 the electric field points in. 67 00:05:41,940 --> 00:05:44,620 Or, well, it actually points out, 68 00:05:44,620 --> 00:05:48,850 but the electron will feel a force in. 69 00:05:48,850 --> 00:05:52,840 Because the charge in the outside 70 00:05:52,840 --> 00:05:56,100 shell doesn't produce any field. 71 00:05:56,100 --> 00:05:59,650 But now, the protons in the nucleus 72 00:05:59,650 --> 00:06:01,810 beat the effect of the electrons. 73 00:06:01,810 --> 00:06:08,700 So there's a force in, a force in, that goes in. 74 00:06:08,700 --> 00:06:15,990 So basically this is like a deep square well, or spherical well, 75 00:06:15,990 --> 00:06:17,390 representing the atom. 76 00:06:17,390 --> 00:06:20,670 The atom can be some sort of spherical well 77 00:06:20,670 --> 00:06:25,680 that attracts the electrons. 78 00:06:25,680 --> 00:06:31,430 So what these people did were throwing these electrons. 79 00:06:31,430 --> 00:06:34,670 And they considered that this electron scattered 80 00:06:34,670 --> 00:06:38,840 a lot when they bounced back. 81 00:06:38,840 --> 00:06:41,220 On the other hand, if they continued, 82 00:06:41,220 --> 00:06:49,190 if the electrons pass by, they said nothing has happened. 83 00:06:49,190 --> 00:06:54,410 So the reflection coefficient for them, the reflection 84 00:06:54,410 --> 00:06:55,160 coefficient. 85 00:06:58,550 --> 00:07:08,810 Reflection coefficient is a proxy, 86 00:07:08,810 --> 00:07:18,820 a good representation for the scattering cross-section. 87 00:07:24,400 --> 00:07:32,260 So the reflection coefficient, what they found experimentally 88 00:07:32,260 --> 00:07:37,780 was a reflection coefficient, R, that as a function of energy 89 00:07:37,780 --> 00:07:40,690 was very high. 90 00:07:40,690 --> 00:07:43,510 And people thought at this moment, OK, 91 00:07:43,510 --> 00:07:47,050 these are like particles colliding with particles. 92 00:07:47,050 --> 00:07:49,930 Their energies shouldn't make much difference, you know. 93 00:07:49,930 --> 00:07:53,950 You either collide or you don't collide, and you bounce back 94 00:07:53,950 --> 00:07:56,650 or you don't bounce back. 95 00:07:56,650 --> 00:08:00,870 So they thought that this would be flat. 96 00:08:00,870 --> 00:08:06,070 But nevertheless, it actually went down enormously, 97 00:08:06,070 --> 00:08:08,980 and then it went up again. 98 00:08:08,980 --> 00:08:14,980 So they found that for electrons with about 1 Ev, 99 00:08:14,980 --> 00:08:18,850 that's very low energy electrons, 100 00:08:18,850 --> 00:08:21,060 but they were going pretty fast. 101 00:08:21,060 --> 00:08:25,480 And E1, Ev electron is going like at 600 kilometers 102 00:08:25,480 --> 00:08:26,080 per second. 103 00:08:29,090 --> 00:08:33,770 So the reflection was going like this. 104 00:08:33,770 --> 00:08:38,350 And they had no explanation why it was so sensitive 105 00:08:38,350 --> 00:08:43,390 with energy, and why there would be a funny effect going on, 106 00:08:43,390 --> 00:08:46,930 that the reflection would suddenly go down, 107 00:08:46,930 --> 00:08:50,800 and just basically the particles would get transmitted. 108 00:08:50,800 --> 00:08:55,570 But if you think of reflection here as a continuous line 109 00:08:55,570 --> 00:08:58,550 and transmission as a dotted line, 110 00:08:58,550 --> 00:09:02,740 the transmission that must alter the reflection to be 1 111 00:09:02,740 --> 00:09:12,150 would be going up here and would have reached near 1 112 00:09:12,150 --> 00:09:14,990 at this value of the energy. 113 00:09:14,990 --> 00:09:19,450 So the explanation eventually was this effect, 114 00:09:19,450 --> 00:09:22,050 that you should do well and there 115 00:09:22,050 --> 00:09:26,860 is a resonant effect in the well, and for some energies 116 00:09:26,860 --> 00:09:30,700 the resonance is such that it allows the particles to just go 117 00:09:30,700 --> 00:09:33,190 through and not scatter. 118 00:09:33,190 --> 00:09:37,300 So this had to wait some time, because the experiment was done 119 00:09:37,300 --> 00:09:42,100 in 1921, and Schrodinger and everybody started 120 00:09:42,100 --> 00:09:48,320 doing good work in 1925, and of wave mechanics took a while. 121 00:09:48,320 --> 00:09:53,230 But eventually it was recognized that basically it's 122 00:09:53,230 --> 00:09:57,310 resonant transmission, what is happening there. 123 00:09:57,310 --> 00:10:00,130 Well, if you want to get the numbers right, 124 00:10:00,130 --> 00:10:03,010 if you want to get that Ev better, you 125 00:10:03,010 --> 00:10:08,830 have to do a spherical model of the square, finite square well, 126 00:10:08,830 --> 00:10:12,310 you have this spherical well, and do it a little more 127 00:10:12,310 --> 00:10:12,960 precisely. 128 00:10:12,960 --> 00:10:16,200 But then the agreement is pretty reasonable.