1 00:00:01,800 --> 00:00:06,120 PROFESSOR: Let me begin by introducing the subject. 2 00:00:06,120 --> 00:00:07,646 The subject is resonances. 3 00:00:15,410 --> 00:00:18,510 And we have seen, actually, a little bit 4 00:00:18,510 --> 00:00:22,800 of this in the resonant transmission 5 00:00:22,800 --> 00:00:26,040 of the Ramsauer-Townsend effect. 6 00:00:26,040 --> 00:00:28,440 Because of a resonance phenomenon 7 00:00:28,440 --> 00:00:34,080 within the square well obstacle, somehow, 8 00:00:34,080 --> 00:00:39,060 for some particular frequencies, for some particular energies, 9 00:00:39,060 --> 00:00:43,890 the particles were able to zoom by without experiencing 10 00:00:43,890 --> 00:00:46,620 any reflection, whatsoever. 11 00:00:46,620 --> 00:00:50,550 So let's begin the subject of resonances 12 00:00:50,550 --> 00:00:54,450 by asking a question. 13 00:00:54,450 --> 00:01:01,410 If you have the usual potential, the short range potential, 14 00:01:01,410 --> 00:01:06,850 which means, that for some distance, R, greater than 0, 15 00:01:06,850 --> 00:01:09,150 the potential is 0. 16 00:01:09,150 --> 00:01:12,920 Here we put a barrier, and over there 17 00:01:12,920 --> 00:01:18,100 could be anything, some potential. 18 00:01:18,100 --> 00:01:22,880 We've computed some-- this concept of time delay, 19 00:01:22,880 --> 00:01:25,130 there's a formula for the time delay. 20 00:01:25,130 --> 00:01:34,890 In fact, it was given by 2 h bar d delta dE, the time delay, 21 00:01:34,890 --> 00:01:40,640 2 h bar d delta dE. 22 00:01:44,140 --> 00:01:49,210 And we discussed that this time delay can be positive 23 00:01:49,210 --> 00:01:52,166 or it can be negative. 24 00:01:52,166 --> 00:01:55,560 If it's positive, it really means a time delay. 25 00:01:55,560 --> 00:01:57,140 You send in a wave packet. 26 00:01:57,140 --> 00:02:01,130 And it takes time to come back, more time than it 27 00:02:01,130 --> 00:02:05,150 would have taken if there had been no potential. 28 00:02:05,150 --> 00:02:08,025 You see, the time delay, you have a packet coming 29 00:02:08,025 --> 00:02:11,060 in from time minus infinity. 30 00:02:11,060 --> 00:02:14,130 And then it bounces back a time equal infinity. 31 00:02:14,130 --> 00:02:17,930 But nevertheless, you compare that with a situation 32 00:02:17,930 --> 00:02:19,320 in which there's no potential. 33 00:02:19,320 --> 00:02:22,050 And you see that there is some time delay. 34 00:02:22,050 --> 00:02:26,000 If you time the wave packet to reach at time equals 0, 35 00:02:26,000 --> 00:02:31,360 here, it will not reach back to where you were by time-- 36 00:02:31,360 --> 00:02:35,600 by whatever time-- suppose you have the wave packet here 37 00:02:35,600 --> 00:02:40,400 at t equal minus 10, then it goes here, and it delays, 38 00:02:40,400 --> 00:02:43,830 and at t equal 10, the packet has not reached, 39 00:02:43,830 --> 00:02:47,844 there is a time delay, a positive time delay. 40 00:02:47,844 --> 00:02:53,090 A negative time delay is the opposite. 41 00:02:53,090 --> 00:02:56,450 The packet arrives a little earlier. 42 00:02:56,450 --> 00:02:59,870 And the question I want to ask you, 43 00:02:59,870 --> 00:03:03,540 if you have a negative time delay, 44 00:03:03,540 --> 00:03:06,930 can it be arbitrarily large. 45 00:03:06,930 --> 00:03:12,260 Well, if you send in a wave packet, 46 00:03:12,260 --> 00:03:16,530 it may find an infinite wall here, and then may bounce, 47 00:03:16,530 --> 00:03:19,460 and then yes, it comes back earlier 48 00:03:19,460 --> 00:03:22,180 than you expected, because the free packet would 49 00:03:22,180 --> 00:03:23,930 have gone here and back. 50 00:03:23,930 --> 00:03:27,620 But you wouldn't expect it to be able to come earlier 51 00:03:27,620 --> 00:03:30,740 than if there was an infinite wall here, 52 00:03:30,740 --> 00:03:32,580 because there is no infinite wall here, 53 00:03:32,580 --> 00:03:33,770 nor an infinite wall here. 54 00:03:33,770 --> 00:03:39,520 So it's just not going to bounce before it reaches here. 55 00:03:39,520 --> 00:03:42,110 The best it can do is bounce when it reaches here. 56 00:03:42,110 --> 00:03:45,950 So you should not expect, and this, sometimes, 57 00:03:45,950 --> 00:03:48,870 will [INAUDIBLE], there is nothing 58 00:03:48,870 --> 00:03:51,950 that can make it bounce until you reach here. 59 00:03:51,950 --> 00:03:57,370 So you cannot expect that the time advance is larger as if it 60 00:03:57,370 --> 00:04:01,396 would have bounced before reaching the obstacle, 61 00:04:01,396 --> 00:04:04,580 whatsoever. 62 00:04:04,580 --> 00:04:05,750 So this is important. 63 00:04:05,750 --> 00:04:10,610 We cannot have a negative time delay that this infinitely 64 00:04:10,610 --> 00:04:11,200 large. 65 00:04:11,200 --> 00:04:17,930 So, in fact, the time delay as, we're right in here, 66 00:04:17,930 --> 00:04:22,790 should be greater than the total travel distance 67 00:04:22,790 --> 00:04:23,710 that you may save. 68 00:04:23,710 --> 00:04:31,320 If you bounce here, you would save 2R over v. 69 00:04:31,320 --> 00:04:34,900 And you must be greater than that negative number, which 70 00:04:34,900 --> 00:04:37,800 is the total travel time that it would take 71 00:04:37,800 --> 00:04:40,440 to go back and forth, here. 72 00:04:40,440 --> 00:04:45,440 So we can do a little arithmetic, here. 73 00:04:45,440 --> 00:04:56,555 This is equal to 2 h bar d delta dk, and here, dE dk. 74 00:05:01,330 --> 00:05:06,380 This is still greater than or equal than minus 2R over v. 75 00:05:06,380 --> 00:05:10,635 And I want to put a sim, because our argument is not completely 76 00:05:10,635 --> 00:05:16,730 rigorous as to what's happening when it reaches here. 77 00:05:16,730 --> 00:05:19,210 It seems very plausible classically, 78 00:05:19,210 --> 00:05:21,830 but there's a bit of a correction 79 00:05:21,830 --> 00:05:24,860 if you do it exactly. 80 00:05:24,860 --> 00:05:29,400 So it's not an exact inequality we're deriving. 81 00:05:29,400 --> 00:05:36,650 And what is the E dk is h bar times the velocity. 82 00:05:42,620 --> 00:05:45,115 Remember, dE dk, you are differentiating 83 00:05:45,115 --> 00:05:48,640 h squared k squared over 2m. 84 00:05:48,640 --> 00:05:55,430 And you get h bar times hk over m. 85 00:05:55,430 --> 00:05:59,140 So therefore, this is h bar and the velocity. 86 00:05:59,140 --> 00:06:01,010 And the h bars cancel. 87 00:06:01,010 --> 00:06:02,475 The velocities cancel. 88 00:06:02,475 --> 00:06:05,860 Between these two sides, the 2s cancel. 89 00:06:05,860 --> 00:06:13,290 And you'll get that d delta dk must be greater than or equal, 90 00:06:13,290 --> 00:06:18,005 approximately, to R. 91 00:06:18,005 --> 00:06:21,020 And that's sometimes called Wigner's condition 92 00:06:21,020 --> 00:06:23,390 on scattering. 93 00:06:23,390 --> 00:06:26,480 And it basically is the idea that the time delay, 94 00:06:26,480 --> 00:06:29,240 the time advance cannot be too large. 95 00:06:29,240 --> 00:06:32,940 OK, so now we can ask the second question. 96 00:06:32,940 --> 00:06:38,405 How about the time delay, a true time delay, 97 00:06:38,405 --> 00:06:40,350 can it be very large? 98 00:06:40,350 --> 00:06:42,810 Can it be arbitrarily large? 99 00:06:42,810 --> 00:06:46,493 Suppose we have a barrier of this form. 100 00:06:46,493 --> 00:06:50,520 And now you send a particle with a little bit higher energy 101 00:06:50,520 --> 00:06:51,650 here. 102 00:06:51,650 --> 00:06:53,950 Now, this particle is going to have 103 00:06:53,950 --> 00:06:55,130 very little kinetic energy. 104 00:06:55,130 --> 00:07:01,250 So it's going to travel quite slowly here, and go back. 105 00:07:01,250 --> 00:07:07,130 And this time, it's going to delay quite a bit, probably. 106 00:07:07,130 --> 00:07:09,740 But the problem is, if you create-- there's nothing 107 00:07:09,740 --> 00:07:12,950 very peculiar about this, if you go a little lower, 108 00:07:12,950 --> 00:07:16,870 than you're advanced, and then suddenly, it gets delayed. 109 00:07:16,870 --> 00:07:21,560 It's not that evident, but the phenomenon of resonance 110 00:07:21,560 --> 00:07:28,230 is precisely what we get when we, sort of, trap the particle. 111 00:07:28,230 --> 00:07:34,060 And then we make it be, as far as it seems, arbitrarily large, 112 00:07:34,060 --> 00:07:37,200 if you design a well properly. 113 00:07:37,200 --> 00:07:39,710 But the thing that we have to design, 114 00:07:39,710 --> 00:07:42,410 the example of what we're going to design, 115 00:07:42,410 --> 00:07:46,840 is different from all the things I've drawn so far. 116 00:07:46,840 --> 00:07:50,860 It's the following way, this is just an example. 117 00:07:53,810 --> 00:07:57,875 I have this zero line of the energy. 118 00:07:57,875 --> 00:08:00,910 This is v of x. 119 00:08:00,910 --> 00:08:02,706 This is x. 120 00:08:02,706 --> 00:08:06,440 And then I put an attractive potential here. 121 00:08:11,770 --> 00:08:14,120 And here is minus v0. 122 00:08:16,910 --> 00:08:22,278 And then I put a barrier here with a v1. 123 00:08:25,710 --> 00:08:29,280 So what I'm going to aim at is, you see, 124 00:08:29,280 --> 00:08:34,720 if v1 will be extremely large, there will be-- 125 00:08:34,720 --> 00:08:37,700 well, if v0 is extremely large, then 126 00:08:37,700 --> 00:08:39,750 begin there would be bound states here, 127 00:08:39,750 --> 00:08:42,830 but these are not scattering states. 128 00:08:42,830 --> 00:08:46,440 On the other hand, if v1 will also be infinite, 129 00:08:46,440 --> 00:08:48,340 you would have bound states here, 130 00:08:48,340 --> 00:08:50,290 but they could not escape. 131 00:08:50,290 --> 00:08:53,610 So certainly, if I combine these two, 132 00:08:53,610 --> 00:08:58,940 I put a v0 and maybe a larger v1, 133 00:08:58,940 --> 00:09:01,720 I can almost create bound states here. 134 00:09:01,720 --> 00:09:03,960 But they're not really bound states, 135 00:09:03,960 --> 00:09:09,120 because they can leak out and produce scattering states. 136 00:09:09,120 --> 00:09:12,900 But these are going to be resonances. 137 00:09:12,900 --> 00:09:16,410 This part and this, this being a attractive, 138 00:09:16,410 --> 00:09:20,220 trying to keep the particle in, and this being a barrier, 139 00:09:20,220 --> 00:09:26,210 can combine to produce a state that gets trapped here, 140 00:09:26,210 --> 00:09:30,020 and stays a very long, time, will have a very long time 141 00:09:30,020 --> 00:09:31,430 delay. 142 00:09:31,430 --> 00:09:34,290 And that's the phenomenon of resonances. 143 00:09:34,290 --> 00:09:37,500 We need to trap that particle, somehow. 144 00:09:37,500 --> 00:09:42,460 And we're going to see now the details of how this works, 145 00:09:42,460 --> 00:09:44,220 and what the properties are. 146 00:09:44,220 --> 00:09:49,060 Now, it's very interesting that actually, these resonances 147 00:09:49,060 --> 00:09:53,286 occur at some particular energies. 148 00:09:53,286 --> 00:09:55,660 And they have different properties. 149 00:09:55,660 --> 00:09:58,895 But we can identify energies of resonances. 150 00:09:58,895 --> 00:10:01,800 And these are not bound states. 151 00:10:01,800 --> 00:10:03,270 They're just resonances. 152 00:10:03,270 --> 00:10:05,790 They eventually escape. 153 00:10:05,790 --> 00:10:10,560 And they're not normalizable, really, but in some ways 154 00:10:10,560 --> 00:10:14,440 they behave as bound states for awhile. 155 00:10:14,440 --> 00:10:20,590 They stay there for a while and do nice things. 156 00:10:20,590 --> 00:10:24,810 So let's set this off. 157 00:10:27,360 --> 00:10:30,750 Now we're going to spare you a little bit 158 00:10:30,750 --> 00:10:34,550 of these calculations, because the important thing is 159 00:10:34,550 --> 00:10:38,810 that you know how to set it up, and if you get an answer, 160 00:10:38,810 --> 00:10:42,434 you know how to plot it, how to get the units out, 161 00:10:42,434 --> 00:10:44,290 how to try to understand it. 162 00:10:44,290 --> 00:10:46,360 So that's what we're going to do. 163 00:10:46,360 --> 00:10:51,842 I'm going to put an energy here, an energy, E. 164 00:10:51,842 --> 00:10:55,470 And I'm going to receive E to be less than v1 165 00:10:55,470 --> 00:10:57,850 and greater than 0. 166 00:10:57,850 --> 00:11:05,020 I don't expect true resonances beyond, 167 00:11:05,020 --> 00:11:07,540 because the particle just bounces out. 168 00:11:07,540 --> 00:11:09,192 It doesn't get trapped. 169 00:11:09,192 --> 00:11:13,940 The phenomenon of resonance is a little more intricate than just 170 00:11:13,940 --> 00:11:16,140 having a long time delay. 171 00:11:16,140 --> 00:11:17,988 There's more that has to happen. 172 00:11:21,060 --> 00:11:22,855 Another thing that will happen, is 173 00:11:22,855 --> 00:11:26,130 if the particle spends a lot of time here, 174 00:11:26,130 --> 00:11:31,158 you would find, in this spirit of resonance, 175 00:11:31,158 --> 00:11:34,450 that the amplitude of the wave function 176 00:11:34,450 --> 00:11:39,040 here is going to be very big. 177 00:11:39,040 --> 00:11:41,420 So you will scan the energy and the amplitude. 178 00:11:41,420 --> 00:11:43,590 It will be normal, normal, normal. 179 00:11:43,590 --> 00:11:47,854 And suddenly for some energy it becomes very big. 180 00:11:47,854 --> 00:11:50,870 And we're going to do that. 181 00:11:50,870 --> 00:11:53,650 The way I'm going to develop that, we're going to calculate 182 00:11:53,650 --> 00:11:55,592 this, plot these things. 183 00:11:55,592 --> 00:11:57,990 And then we are going to ask whether there 184 00:11:57,990 --> 00:12:03,830 is a mathematical condition that picks resonances. 185 00:12:03,830 --> 00:12:08,230 Well, how do I, if I want to explain to somebody in 30 186 00:12:08,230 --> 00:12:11,200 seconds where are the resonances, 187 00:12:11,200 --> 00:12:16,680 how do you calculate them, you cannot tell that somebody, OK, 188 00:12:16,680 --> 00:12:20,590 calculate it for all energies, do all the plots, 189 00:12:20,590 --> 00:12:24,985 and see some peak in some thing, and this is a resonance. 190 00:12:24,985 --> 00:12:26,860 This is what we're going to do to begin with, 191 00:12:26,860 --> 00:12:30,130 but then we'll get more sophisticated. 192 00:12:30,130 --> 00:12:32,145 So let's put k in. 193 00:12:32,145 --> 00:12:39,330 So let's call this k prime, the wave number in this area. 194 00:12:39,330 --> 00:12:44,050 Kappa here, because it's a forbidden region, and k 195 00:12:44,050 --> 00:12:46,980 over here, as usual. 196 00:12:46,980 --> 00:12:54,310 So k squared is 2mE over h bar squared. 197 00:12:54,310 --> 00:13:00,950 K prime squared is equal to 2m, the total kinetic energy 198 00:13:00,950 --> 00:13:07,300 is E plus v0, over h squared. 199 00:13:07,300 --> 00:13:13,705 And kappa squared is again, similar formula, but this time 200 00:13:13,705 --> 00:13:18,130 is the energy differential between v1 and E, 201 00:13:18,130 --> 00:13:24,460 so 2m v1 minus E over h squared. 202 00:13:24,460 --> 00:13:26,830 All of these three numbers are positive. 203 00:13:26,830 --> 00:13:29,560 And they are the relevant constants 204 00:13:29,560 --> 00:13:31,386 to write wave functions. 205 00:13:34,860 --> 00:13:37,095 So we have to write a wave function. 206 00:13:37,095 --> 00:13:38,920 And I'm going to write a wave function 207 00:13:38,920 --> 00:13:41,950 because it takes a little tinkering 208 00:13:41,950 --> 00:13:44,270 to do it in an efficient way. 209 00:13:47,974 --> 00:13:50,300 There is one that you don't have to think, 210 00:13:50,300 --> 00:13:52,500 you just have to remember. 211 00:13:52,500 --> 00:13:53,970 It's the one outside. 212 00:13:53,970 --> 00:13:58,920 It's the universal formula, e to the i delta 213 00:13:58,920 --> 00:14:13,570 sine kx plus delta is valid for for x greater than R. 214 00:14:13,570 --> 00:14:17,000 This one we derived at the beginning of our analysis 215 00:14:17,000 --> 00:14:20,470 of scattering. 216 00:14:20,470 --> 00:14:22,060 How about the other region. 217 00:14:22,060 --> 00:14:23,920 Oops, I should have put letters here. 218 00:14:23,920 --> 00:14:30,120 These are a and 2a they are positions. 219 00:14:30,120 --> 00:14:34,670 And therefore, it's not R in here. 220 00:14:34,670 --> 00:14:38,610 Well, it's R, it's the range of the potential, but here is 2a. 221 00:14:44,110 --> 00:14:45,826 How about the other one? 222 00:14:45,826 --> 00:14:49,050 In this region, it's kind of simple again. 223 00:14:49,050 --> 00:14:51,790 The wave function has to vanish here, has to be 224 00:14:51,790 --> 00:14:54,520 sines or cosines of k prime. 225 00:14:54,520 --> 00:14:57,970 So it has to be a sine function of k prime. 226 00:14:57,970 --> 00:15:02,470 And since we don't put an extra constant in here, 227 00:15:02,470 --> 00:15:04,550 we kind of put an extra constant in here, 228 00:15:04,550 --> 00:15:10,573 there must be a constant here, A sine of k prime x. 229 00:15:10,573 --> 00:15:15,850 And that must be for x between 0 and a. 230 00:15:15,850 --> 00:15:18,450 We used k prime, the wave from over there. 231 00:15:18,450 --> 00:15:23,080 And there is A. And what we were saying about resonances, 232 00:15:23,080 --> 00:15:27,940 is that, well, A may depend on k. 233 00:15:27,940 --> 00:15:30,145 And when you have a resonance, A is 234 00:15:30,145 --> 00:15:34,380 going to [INAUDIBLE], presumably because the particle spends 235 00:15:34,380 --> 00:15:39,350 a long time inside the well. 236 00:15:39,350 --> 00:15:43,600 And now I have to write this one in here. 237 00:15:43,600 --> 00:15:45,873 And this is the one that, you can 238 00:15:45,873 --> 00:15:49,860 do it, do a little bit more work, or do it kind of, 239 00:15:49,860 --> 00:15:52,196 efficiently. 240 00:15:52,196 --> 00:15:54,765 In that region we have exponentials, 241 00:15:54,765 --> 00:15:59,444 like we have e to the kappa x and e to the minus kappa x. 242 00:16:02,440 --> 00:16:08,926 Or I may want to have sinh of kappa x and cosh of kappa 243 00:16:08,926 --> 00:16:11,295 x to write my solutions. 244 00:16:11,295 --> 00:16:13,930 But I actually don't want either of them 245 00:16:13,930 --> 00:16:16,920 too much, because I would like to write 246 00:16:16,920 --> 00:16:23,070 an answer that almost imposes continuity in a nice way. 247 00:16:23,070 --> 00:16:37,190 So I could use sinh of kappa x minus a and cosh of kappa x 248 00:16:37,190 --> 00:16:38,095 minus a. 249 00:16:38,095 --> 00:16:40,610 These are all solutions. 250 00:16:40,610 --> 00:16:43,130 You can choose whichever pair you want. 251 00:16:46,490 --> 00:16:51,500 So for example, if I want to implement continuity 252 00:16:51,500 --> 00:16:54,770 with this thing, this wave function, 253 00:16:54,770 --> 00:16:56,615 I want to write something that I don't 254 00:16:56,615 --> 00:16:59,290 have to write another equation for continuity. 255 00:16:59,290 --> 00:17:08,210 So I will write A sine of k prime a-- 256 00:17:08,210 --> 00:17:11,839 so far, this wave function, if x equal a, 257 00:17:11,839 --> 00:17:13,910 coincides with this one. 258 00:17:13,910 --> 00:17:17,369 But this is no wave function yet, not with an x dependence, 259 00:17:17,369 --> 00:17:19,349 so I have to put more. 260 00:17:19,349 --> 00:17:24,589 But then, I know that cosh is 1 for x equals zero. 261 00:17:24,589 --> 00:17:32,830 So I put here a cosh kappa x minus a. 262 00:17:32,830 --> 00:17:39,470 And now this is a solution that matches that one at x equals a. 263 00:17:39,470 --> 00:17:44,050 At x equal a, the cosh becomes 1 and matches. 264 00:17:44,050 --> 00:17:46,400 But this kind of need a complete solution. 265 00:17:46,400 --> 00:17:47,600 It's not general enough. 266 00:17:47,600 --> 00:17:56,280 So you have to put a B sinh of kappa x minus a. 267 00:17:56,280 --> 00:17:59,690 And this won't ruin the matching, because at x equal a, 268 00:17:59,690 --> 00:18:01,670 that second term vanishes. 269 00:18:01,670 --> 00:18:05,780 So we're still matching well there. 270 00:18:05,780 --> 00:18:09,060 And Well matching here is non-trivial 271 00:18:09,060 --> 00:18:11,810 when I impose some conditions. 272 00:18:11,810 --> 00:18:16,010 So you still have to match derivatives and do a little bit 273 00:18:16,010 --> 00:18:19,060 of work but not too much work.