1 00:00:00,050 --> 00:00:01,670 The following content is provided 2 00:00:01,670 --> 00:00:03,810 under a Creative Commons license. 3 00:00:03,810 --> 00:00:06,540 Your support will help MIT OpenCourseWare continue 4 00:00:06,540 --> 00:00:10,120 to offer high-quality educational resources for free. 5 00:00:10,120 --> 00:00:12,700 To make a donation or to view additional materials 6 00:00:12,700 --> 00:00:16,600 from hundreds of MIT courses, visit MIT OpenCourseWare 7 00:00:16,600 --> 00:00:17,282 at ocw.mit.edu. 8 00:00:21,282 --> 00:00:22,310 PROFESSOR: All right. 9 00:00:22,310 --> 00:00:30,750 So today, we'll continue our kind of review that included, 10 00:00:30,750 --> 00:00:34,130 of course, the last lecture, the variational principle that's 11 00:00:34,130 --> 00:00:38,560 supposed to be new stuff you didn't see in 804. 12 00:00:38,560 --> 00:00:42,690 And today, as we continue, we'll talk 13 00:00:42,690 --> 00:00:47,930 about position and momentum for about 30 minutes or 40 minutes, 14 00:00:47,930 --> 00:00:54,430 and then begin the study of spin. 15 00:00:54,430 --> 00:00:59,110 That will be spin-1/2 with a Stern-Gerlach experiment 16 00:00:59,110 --> 00:01:02,430 and the mathematics that comes out of it. 17 00:01:02,430 --> 00:01:05,310 Now, we will talk about the Stern-Gerlach experiment 18 00:01:05,310 --> 00:01:07,440 in quite some detail so that you can 19 00:01:07,440 --> 00:01:10,770 appreciate what was going on there. 20 00:01:10,770 --> 00:01:18,060 And then we will extract a few of the mathematical lessons 21 00:01:18,060 --> 00:01:23,410 that this experiment tells us about quantum mechanics. 22 00:01:23,410 --> 00:01:25,530 Immediately after that, which will 23 00:01:25,530 --> 00:01:30,030 be probably middle of next lecture, we will pivot. 24 00:01:30,030 --> 00:01:32,580 And as we learn this mathematics that 25 00:01:32,580 --> 00:01:37,790 the Stern-Gerlach experiment is telling us or asking us for, 26 00:01:37,790 --> 00:01:42,700 we will go in some detail on the necessary mathematics 27 00:01:42,700 --> 00:01:44,190 for quantum mechanics. 28 00:01:44,190 --> 00:01:48,790 We'll talk about vector spaces, linear operators, 29 00:01:48,790 --> 00:01:54,200 Hermitian operators, unitary operators, [INAUDIBLE], 30 00:01:54,200 --> 00:01:57,740 matrix representations, all kinds of things. 31 00:01:57,740 --> 00:02:02,120 That probably will be about two weeks, three lectures at least. 32 00:02:02,120 --> 00:02:05,940 So it will be a nice study. 33 00:02:05,940 --> 00:02:10,190 And in that way, people that don't 34 00:02:10,190 --> 00:02:12,370 have a background in linear algebra 35 00:02:12,370 --> 00:02:15,360 will feel more comfortable with what we're going to be doing. 36 00:02:15,360 --> 00:02:16,880 And I think even for the people that 37 00:02:16,880 --> 00:02:19,140 have a background in linear algebra, 38 00:02:19,140 --> 00:02:22,470 you will gain a new appreciation about the concepts 39 00:02:22,470 --> 00:02:23,950 that we meet here. 40 00:02:23,950 --> 00:02:28,790 So today, we begin, therefore, with position and momentum, 41 00:02:28,790 --> 00:02:31,640 and these are operators in quantum mechanics. 42 00:02:31,640 --> 00:02:36,260 And they have letters to denote them. x, 43 00:02:36,260 --> 00:02:39,900 we put a hat with it, that's a position operator. 44 00:02:39,900 --> 00:02:42,730 p, we put a hat on it. 45 00:02:42,730 --> 00:02:52,460 And the position and momentum operators don't commute. 46 00:02:52,460 --> 00:02:58,250 And the commutator is given by ih bar. 47 00:02:58,250 --> 00:03:02,990 Now, we have been dealing so far with wave functions. 48 00:03:02,990 --> 00:03:07,920 Our wave functions, where these functions of x and t, 49 00:03:07,920 --> 00:03:11,210 they represent the dynamics of your system, the dynamics 50 00:03:11,210 --> 00:03:13,410 of your particle as it moves in time. 51 00:03:13,410 --> 00:03:18,140 But time, as you are seeing in quantum mechanics, 52 00:03:18,140 --> 00:03:19,602 is a little bit of a spectator. 53 00:03:19,602 --> 00:03:21,980 It's an arena where things happen. 54 00:03:21,980 --> 00:03:25,670 But the operators, and most of the interesting things, 55 00:03:25,670 --> 00:03:30,570 are going on without reference to time. 56 00:03:30,570 --> 00:03:32,780 Time evolution, you have an expansion 57 00:03:32,780 --> 00:03:35,140 of a wave function in terms of energy, 58 00:03:35,140 --> 00:03:38,340 eigenstates, at a given time. 59 00:03:38,340 --> 00:03:40,650 And then you can evolve it easily 60 00:03:40,650 --> 00:03:43,700 with the way we've learned, adding e 61 00:03:43,700 --> 00:03:50,340 to the minus i et over h bar for each energy eigenstate. 62 00:03:50,340 --> 00:03:52,710 So time will play no role here. 63 00:03:52,710 --> 00:03:55,380 So when I talk about the wave function, at this moment 64 00:03:55,380 --> 00:03:57,630 you could put the time, but we will 65 00:03:57,630 --> 00:04:01,400 talk about the wave functions that have no time dependence. 66 00:04:01,400 --> 00:04:04,700 So, say, a psi of x wave function. 67 00:04:11,010 --> 00:04:16,970 So this psi of x may be the true wave function at time equals 0, 68 00:04:16,970 --> 00:04:23,510 or you could just simply think of it as the psi of x. 69 00:04:23,510 --> 00:04:26,770 Now, this wave function means that we're 70 00:04:26,770 --> 00:04:29,420 treating x in a particular way, and we 71 00:04:29,420 --> 00:04:33,310 say that we're working in the x representation, the position 72 00:04:33,310 --> 00:04:35,570 representation. 73 00:04:35,570 --> 00:04:39,870 Now, this means that we have an easy way 74 00:04:39,870 --> 00:04:43,800 to figure out what this operator does 75 00:04:43,800 --> 00:04:46,700 when it acts on this function. 76 00:04:46,700 --> 00:04:48,320 So what it acts on this function, 77 00:04:48,320 --> 00:04:50,840 it will give you another function, 78 00:04:50,840 --> 00:04:53,730 and the definition of this is that the position 79 00:04:53,730 --> 00:04:58,810 operator acting on the function psi of x 80 00:04:58,810 --> 00:05:03,070 is defined to be another function, 81 00:05:03,070 --> 00:05:06,845 which is the function x times psi of x. 82 00:05:16,390 --> 00:05:20,025 Well, we're talking about these wave functions and operators 83 00:05:20,025 --> 00:05:21,380 on wave functions. 84 00:05:21,380 --> 00:05:25,550 And a recurrent theme in quantum mechanics 85 00:05:25,550 --> 00:05:28,660 is that we will think of wave functions, 86 00:05:28,660 --> 00:05:31,160 sometimes we call them states. 87 00:05:31,160 --> 00:05:34,200 Sometimes we call them vectors. 88 00:05:34,200 --> 00:05:39,640 And we basically think of wave functions as vectors. 89 00:05:39,640 --> 00:05:42,550 And things that act on wave functions 90 00:05:42,550 --> 00:05:44,480 are the things that act on vectors. 91 00:05:44,480 --> 00:05:46,390 And the things that act on vectors, 92 00:05:46,390 --> 00:05:50,110 as you know in mathematics, is matrices. 93 00:05:50,110 --> 00:05:54,530 So we're compelled, even at this early stage, 94 00:05:54,530 --> 00:05:57,600 to get a picture of how that language would 95 00:05:57,600 --> 00:06:02,410 go if we're talking about these things. 96 00:06:02,410 --> 00:06:07,020 So how do we think of a wave function as a vector? 97 00:06:07,020 --> 00:06:12,000 And how do we think of x as a matrix? 98 00:06:12,000 --> 00:06:15,550 So there's a way to do that. 99 00:06:15,550 --> 00:06:21,580 It will not be totally precise, but it's clear enough. 100 00:06:21,580 --> 00:06:24,340 So suppose you have a wave function, 101 00:06:24,340 --> 00:06:28,545 and we're interested in its values from 0 up to a. 102 00:06:33,120 --> 00:06:38,230 This wave function is a function of x between 0 and a. 103 00:06:38,230 --> 00:06:45,250 So it's the psi of x for x between a and 0. 104 00:06:45,250 --> 00:06:47,420 That's all the information. 105 00:06:47,420 --> 00:06:50,410 What we're going to do is we're going 106 00:06:50,410 --> 00:06:55,540 to divide this thing, this line, this segment, 107 00:06:55,540 --> 00:06:56,940 into a lot of pieces. 108 00:06:56,940 --> 00:06:58,610 And we're going to say, look, instead 109 00:06:58,610 --> 00:07:03,040 of writing a function like sine of x or cosine of x, 110 00:07:03,040 --> 00:07:05,910 let's just give the values and organize them 111 00:07:05,910 --> 00:07:09,780 as if this will be a vector of many components. 112 00:07:09,780 --> 00:07:15,800 So let's divide this in sizes epsilon, 113 00:07:15,800 --> 00:07:20,510 such that N times epsilon is equal to a. 114 00:07:20,510 --> 00:07:23,700 So there are N of these intervals. 115 00:07:23,700 --> 00:07:29,696 So we think of psi as a vector whose first component 116 00:07:29,696 --> 00:07:31,390 is psi at 0. 117 00:07:31,390 --> 00:07:34,190 The second is psi at epsilon. 118 00:07:34,190 --> 00:07:38,500 The third is psi at 2 epsilon. 119 00:07:38,500 --> 00:07:43,560 And the last one is psi at N epsilon. 120 00:07:43,560 --> 00:07:47,370 And depending on how much accuracy you want to work with, 121 00:07:47,370 --> 00:07:54,390 you take epsilon smaller and larger, keeping a constant. 122 00:07:54,390 --> 00:07:59,110 And this would be like summarizing all the information 123 00:07:59,110 --> 00:08:00,705 of a function in a vector. 124 00:08:03,870 --> 00:08:08,800 Now, that's intuitively a nice way to think of it. 125 00:08:08,800 --> 00:08:13,960 May look, with your background in classical physics, 126 00:08:13,960 --> 00:08:18,910 a little strange that we sort of put the value at 0 127 00:08:18,910 --> 00:08:22,740 along the x-axis, first component, the value at epsilon 128 00:08:22,740 --> 00:08:26,260 along the y, the value of 2 epsilon along the z. 129 00:08:26,260 --> 00:08:27,630 But we need more axes. 130 00:08:27,630 --> 00:08:30,270 So you need many axes here. 131 00:08:30,270 --> 00:08:39,299 In this case, this is a N plus 1 column vector. 132 00:08:39,299 --> 00:08:43,480 It has N plus 1 entries, because 0 up 133 00:08:43,480 --> 00:08:45,740 to N, that's N plus 1 entries. 134 00:08:49,060 --> 00:08:53,900 But that's a fine way of thinking of it. 135 00:08:53,900 --> 00:08:56,700 Not exact because we have an epsilon. 136 00:08:56,700 --> 00:09:00,020 In this way of thinking about the wave function, 137 00:09:00,020 --> 00:09:08,110 we can then ask, what does the matrix x hat look like? 138 00:09:08,110 --> 00:09:13,110 So x hat is an operator, and it acts this way. 139 00:09:13,110 --> 00:09:15,650 So here is how it looks like. 140 00:09:15,650 --> 00:09:25,180 We would think of x hat as an N plus 1 times N plus 1 matrix. 141 00:09:30,110 --> 00:09:33,150 And its entries are 0 everywhere, 142 00:09:33,150 --> 00:09:35,190 except in the diagonal, where they 143 00:09:35,190 --> 00:09:41,980 are 0 epsilon, 2 epsilon, up to N epsilon. 144 00:09:44,685 --> 00:09:47,265 And here is a big 0 and a big 0. 145 00:09:49,980 --> 00:09:55,700 This, I claim, is the way you should think of the x operator 146 00:09:55,700 --> 00:10:01,640 if you thought of the wave function the way we wrote it. 147 00:10:01,640 --> 00:10:03,380 And how do we check that? 148 00:10:03,380 --> 00:10:09,500 Well, x operator acting on psi should be this acting on that. 149 00:10:09,500 --> 00:10:13,200 And then, indeed, we see that if x hat 150 00:10:13,200 --> 00:10:18,560 is acting on psi of x, what do we get? 151 00:10:18,560 --> 00:10:25,350 Well, it's easy to multiply a diagonal matrix times a vector. 152 00:10:25,350 --> 00:10:31,190 Here you get 0 times psi of 0. 153 00:10:31,190 --> 00:10:36,390 You get a vector, so let me make this thinner. 154 00:10:36,390 --> 00:10:45,180 Then I get epsilon times psi of epsilon, 2 epsilon times 155 00:10:45,180 --> 00:10:53,090 psi of 2 epsilon, up to N epsilon times psi of N epsilon. 156 00:10:53,090 --> 00:10:58,490 And indeed, that matrix looks like the matrix associated 157 00:10:58,490 --> 00:11:02,890 with this wave function because here 158 00:11:02,890 --> 00:11:05,950 is the value at 0 of this wave function. 159 00:11:05,950 --> 00:11:11,040 Here is the value at epsilon of this wave function, and so on. 160 00:11:11,040 --> 00:11:15,410 So this has worked out all right. 161 00:11:15,410 --> 00:11:20,560 We can think of the wave function as a column vector, 162 00:11:20,560 --> 00:11:24,540 and then the position operator as this vector as well. 163 00:11:27,270 --> 00:11:32,670 Now, given that we know how the x operator is defined, 164 00:11:32,670 --> 00:11:37,250 we can also think easily about what 165 00:11:37,250 --> 00:11:40,810 is the expectation value of x on a wave function. 166 00:11:40,810 --> 00:11:43,800 Something that you really know, but now 167 00:11:43,800 --> 00:11:46,370 maybe becomes a little clearer. 168 00:11:46,370 --> 00:11:49,850 Here you're supposed to do psi star 169 00:11:49,850 --> 00:11:56,590 of x times the x operator acting on psi of x. 170 00:11:56,590 --> 00:11:59,220 But we have the definition of this, 171 00:11:59,220 --> 00:12:05,040 so this is, as you imagine, dx-- and I should put primes maybe, 172 00:12:05,040 --> 00:12:09,430 well, I don't have to put primes-- dx psi 173 00:12:09,430 --> 00:12:14,910 star of x x psi of x, which is what 174 00:12:14,910 --> 00:12:16,575 you would have done anyway. 175 00:12:20,960 --> 00:12:26,200 Well, given that we've started with this, we can ask also, 176 00:12:26,200 --> 00:12:29,960 is there eigenstates of the x operator? 177 00:12:39,360 --> 00:12:40,970 Yes, there are. 178 00:12:40,970 --> 00:12:44,790 but then fortunately, are a bit singular. 179 00:12:44,790 --> 00:12:48,150 So what should be an eigenstate of x? 180 00:12:48,150 --> 00:12:51,860 It's some sort of state. 181 00:12:51,860 --> 00:12:55,480 Intuitively, it has a definite value of the position. 182 00:12:55,480 --> 00:12:57,970 So it just exists for some value of x. 183 00:12:57,970 --> 00:13:01,390 So it's naturally thought as a delta function. 184 00:13:01,390 --> 00:13:09,370 So let me define a function, psi sub x0 of x. 185 00:13:09,370 --> 00:13:13,530 So it's a function of x labeled by x0, 186 00:13:13,530 --> 00:13:17,320 and define it to be delta of x minus x0. 187 00:13:21,050 --> 00:13:24,790 So I claim that is an eigenstate of x hat. 188 00:13:24,790 --> 00:13:31,750 x hat on psi x0 of x is equal, by definition, 189 00:13:31,750 --> 00:13:42,990 to x times psi x0 of x, which is x times delta of x minus x0. 190 00:13:42,990 --> 00:13:45,220 And when you multiply a function of x 191 00:13:45,220 --> 00:13:48,250 times a delta function in x, it is 192 00:13:48,250 --> 00:13:50,660 possible to evaluate the function that 193 00:13:50,660 --> 00:13:53,550 is being multiplied by the delta function 194 00:13:53,550 --> 00:13:57,350 at the place where the delta function fires. 195 00:13:57,350 --> 00:14:00,880 It has the same effect on integrals or anything 196 00:14:00,880 --> 00:14:01,730 that you would do. 197 00:14:01,730 --> 00:14:08,230 So here, this is equal to x0 times delta x minus x0. 198 00:14:08,230 --> 00:14:11,950 You evaluate the x at x0. 199 00:14:11,950 --> 00:14:18,550 And finally, this is x0 times that function psi x0 of x. 200 00:14:18,550 --> 00:14:23,490 And therefore, you've shown that this operator acting 201 00:14:23,490 --> 00:14:27,510 on this function reproduces the function-- that's 202 00:14:27,510 --> 00:14:30,880 the definition of eigenstate as an operator-- 203 00:14:30,880 --> 00:14:36,170 and the eigenvalue is the number that appears here, and it's x0. 204 00:14:36,170 --> 00:14:44,150 So this function is an eigenstate 205 00:14:44,150 --> 00:14:51,950 of x hat with eigenvalue, e.v., x0. 206 00:14:59,010 --> 00:15:03,260 The only complication with this eigenfunction 207 00:15:03,260 --> 00:15:05,780 is that it's not normalizable. 208 00:15:05,780 --> 00:15:09,060 So it doesn't represent the particle. 209 00:15:09,060 --> 00:15:13,690 It can be used to represent the particle, 210 00:15:13,690 --> 00:15:16,490 but it's a useful function. 211 00:15:16,490 --> 00:15:19,000 You can think of it as something that 212 00:15:19,000 --> 00:15:22,360 can help you do physics, and don't insist 213 00:15:22,360 --> 00:15:26,000 that it represents a particle. 214 00:15:26,000 --> 00:15:28,640 So this is the story for position. 215 00:15:28,640 --> 00:15:32,680 And the position gets actually more interesting as soon 216 00:15:32,680 --> 00:15:37,380 as you introduce the dual quantity, momentum. 217 00:15:37,380 --> 00:15:40,660 So what is momentum here? 218 00:15:40,660 --> 00:15:55,020 So momentum is an operator, and this operator must be defined. 219 00:15:55,020 --> 00:15:59,890 Now, you had a shorthand for it in 804, 220 00:15:59,890 --> 00:16:04,790 which is p hat equal h bar over i d dx. 221 00:16:08,070 --> 00:16:10,910 And this shorthand means actually 222 00:16:10,910 --> 00:16:17,220 that, in what we call the position representation where 223 00:16:17,220 --> 00:16:22,420 we're using wave functions that depend on x, well, 224 00:16:22,420 --> 00:16:25,190 the momentum is given by this operator. 225 00:16:25,190 --> 00:16:27,880 And the story of why this was the case 226 00:16:27,880 --> 00:16:30,150 was sort of something that was elaborated 227 00:16:30,150 --> 00:16:33,870 on in 804, the work of de Broglie, that 228 00:16:33,870 --> 00:16:38,430 saw that the wavelength of the wave 229 00:16:38,430 --> 00:16:40,620 has to do with the momentum of a wave. 230 00:16:40,620 --> 00:16:42,850 And finally, people understood that this 231 00:16:42,850 --> 00:16:46,080 would measure the momentum of the wave. 232 00:16:46,080 --> 00:16:47,800 So this is the operator. 233 00:16:47,800 --> 00:16:51,570 And therefore, in the representation that 234 00:16:51,570 --> 00:16:56,750 we're working-- representation is a word that has a lot 235 00:16:56,750 --> 00:17:00,250 of precise meaning, but now I'm just using it in the sense 236 00:17:00,250 --> 00:17:03,430 that, well, we're working either with x's or with p's. 237 00:17:03,430 --> 00:17:05,140 And we're working with x's. 238 00:17:05,140 --> 00:17:09,440 That's why p looks like something to do with x. 239 00:17:09,440 --> 00:17:13,369 So what is p hat on a wave function? 240 00:17:13,369 --> 00:17:17,739 Well, that's what this means. 241 00:17:17,739 --> 00:17:20,119 It's another wave function obtained 242 00:17:20,119 --> 00:17:23,990 by taking the x derivative. 243 00:17:23,990 --> 00:17:28,620 So that's the definition of it acting on a wave function. 244 00:17:28,620 --> 00:17:33,310 The one thing that must be verified, of course, 245 00:17:33,310 --> 00:17:38,340 is that this definition is consistent or implies 246 00:17:38,340 --> 00:17:39,780 this commutation relation. 247 00:17:43,330 --> 00:17:46,840 So you've defined it as an operator. 248 00:17:46,840 --> 00:17:49,770 x, we've defined it as an operator. 249 00:17:49,770 --> 00:17:51,330 But most of us think that it doesn't 250 00:17:51,330 --> 00:17:53,850 look like an operator is multiplying. 251 00:17:53,850 --> 00:17:56,580 But it is an operator. 252 00:17:56,580 --> 00:17:59,230 So this one does look like an operator. 253 00:17:59,230 --> 00:18:02,000 It's a differential operator. 254 00:18:02,000 --> 00:18:08,250 And you can try to see if this equation is true. 255 00:18:08,250 --> 00:18:10,900 And the way to test these commutators 256 00:18:10,900 --> 00:18:13,110 is something that, again, I don't think 257 00:18:13,110 --> 00:18:17,630 is unfamiliar to you, but let's go through it, 258 00:18:17,630 --> 00:18:24,070 is that you try to evaluate this product of operators 259 00:18:24,070 --> 00:18:27,510 acting on a wave function. 260 00:18:27,510 --> 00:18:32,400 And if things work out well, we'll 261 00:18:32,400 --> 00:18:40,174 see you should get ih bar times that wave function. 262 00:18:40,174 --> 00:18:43,090 If that is the case, you say, OK, I've 263 00:18:43,090 --> 00:18:47,670 proven that equation, because it's an operator equation. 264 00:18:47,670 --> 00:18:50,440 The left-hand side of that equation 265 00:18:50,440 --> 00:18:53,510 is the product in different orders of two operators, 266 00:18:53,510 --> 00:18:55,290 therefore it's an operator. 267 00:18:55,290 --> 00:18:57,710 The right-hand side is another operator. 268 00:18:57,710 --> 00:19:02,270 It's the operator multiplied by ih, anything that you'll get. 269 00:19:02,270 --> 00:19:07,530 Well, if this is an operator identity, 270 00:19:07,530 --> 00:19:10,250 the operator on the left must be equal to the operator 271 00:19:10,250 --> 00:19:14,440 on the right, which just means that, acting on anything, 272 00:19:14,440 --> 00:19:16,080 they must give the same answer. 273 00:19:16,080 --> 00:19:20,000 So if I managed to prove that this is equal to this, 274 00:19:20,000 --> 00:19:24,550 I've proven that for anything that is the answer. 275 00:19:24,550 --> 00:19:28,330 And therefore, I can write the top one. 276 00:19:28,330 --> 00:19:31,890 And let me just do it, even though this 277 00:19:31,890 --> 00:19:37,240 may be kind of familiar to many of you. 278 00:19:37,240 --> 00:19:42,510 It's good to do this slowly once in your life. 279 00:19:42,510 --> 00:19:44,800 So let's go through this. 280 00:19:44,800 --> 00:19:50,360 So this says x operator p operator on psi 281 00:19:50,360 --> 00:19:54,840 minus p operator of x operator on psi. 282 00:19:54,840 --> 00:20:01,460 When you have several operators, like ABC acting on psi, 283 00:20:01,460 --> 00:20:04,990 this really means let C act on psi, 284 00:20:04,990 --> 00:20:11,960 and then let B act on C psi, and then let A act on that. 285 00:20:11,960 --> 00:20:13,970 The operators act one by one. 286 00:20:13,970 --> 00:20:16,360 The closest one acts first. 287 00:20:16,360 --> 00:20:21,540 So here I'm supposed to let B act on psi, 288 00:20:21,540 --> 00:20:23,160 but that means that thing. 289 00:20:23,160 --> 00:20:30,180 So now x is acting on h over i d psi dx. 290 00:20:32,750 --> 00:20:40,090 On this one, I have p acting on x psi, 291 00:20:40,090 --> 00:20:43,900 because that's what x hat psi is. 292 00:20:43,900 --> 00:20:47,770 Here, this is multiplication by x of a function of x. 293 00:20:47,770 --> 00:20:52,120 So this is just h over i x d psi dx. 294 00:20:55,310 --> 00:21:01,920 And here, I have h over i d dx of this whole thing x psi. 295 00:21:04,950 --> 00:21:07,750 And you can see that when you act here, 296 00:21:07,750 --> 00:21:12,080 you act first on the x, and you get something. 297 00:21:12,080 --> 00:21:16,580 And then you act on the psi, and you get this same term. 298 00:21:16,580 --> 00:21:24,130 So the only contribution here is equal to minus h over 299 00:21:24,130 --> 00:21:28,330 i, the d dx on x times psi, which 300 00:21:28,330 --> 00:21:32,530 is ih bar psi, which is what I wanted to show. 301 00:21:36,050 --> 00:21:41,170 So this is true. 302 00:21:41,170 --> 00:21:44,880 And therefore, you could say that this definition is 303 00:21:44,880 --> 00:21:47,800 consistent with your definition of x, 304 00:21:47,800 --> 00:21:51,710 and they represent this operator. 305 00:21:51,710 --> 00:21:57,010 One more thing you could try to do, and it's fun to do it, 306 00:21:57,010 --> 00:22:02,930 is we had a matrix representation for x. 307 00:22:02,930 --> 00:22:05,353 Can I think of p as a matrix? 308 00:22:07,980 --> 00:22:09,180 How would you do it? 309 00:22:09,180 --> 00:22:11,880 What kind of matrix would p look like? 310 00:22:15,680 --> 00:22:17,386 Well, yes? 311 00:22:17,386 --> 00:22:20,410 AUDIENCE: You just generate a finite difference equation. 312 00:22:20,410 --> 00:22:22,620 PROFESSOR: You could do it, exactly, 313 00:22:22,620 --> 00:22:25,920 with taking finite differences. 314 00:22:25,920 --> 00:22:28,590 So for example, if you think that you 315 00:22:28,590 --> 00:22:35,555 want to produce the wave function psi prime at 0, 316 00:22:35,555 --> 00:22:39,200 psi prime at epsilon, psi prime, that's 317 00:22:39,200 --> 00:22:41,240 what the derivative gives you, you'll 318 00:22:41,240 --> 00:22:47,970 write this as 1 over epsilon, say, psi at epsilon 319 00:22:47,970 --> 00:22:50,040 minus psi at 0. 320 00:22:50,040 --> 00:22:53,950 That's the derivative at 0 roughly. 321 00:22:53,950 --> 00:23:00,720 It would be psi at 2 epsilon minus psi at 0 over 2. 322 00:23:00,720 --> 00:23:03,759 And you could build it. 323 00:23:03,759 --> 00:23:04,550 You could build it. 324 00:23:04,550 --> 00:23:05,600 I'm not going to do it. 325 00:23:05,600 --> 00:23:08,920 You may want to do it and try and see 326 00:23:08,920 --> 00:23:13,550 how the derivative operator looks as a matrix. 327 00:23:13,550 --> 00:23:18,100 And then if you really want to spend some time thinking 328 00:23:18,100 --> 00:23:21,770 about it, you could try to see if this matrix 329 00:23:21,770 --> 00:23:27,000 and this matrix commute to give the right answer. 330 00:23:27,000 --> 00:23:28,800 And as you try it, you will figure out 331 00:23:28,800 --> 00:23:32,430 all kinds of funny things that we 332 00:23:32,430 --> 00:23:34,580 will talk about later in the course. 333 00:23:34,580 --> 00:23:39,010 So you can represent the momentum operator as a matrix 334 00:23:39,010 --> 00:23:41,580 indeed, and there are interesting things 335 00:23:41,580 --> 00:23:47,960 to say about it, and it's a good subject. 336 00:23:47,960 --> 00:23:52,090 So let's continue with the momentum 337 00:23:52,090 --> 00:23:55,380 and ask for eigenstates of the momentum. 338 00:23:55,380 --> 00:24:06,796 So eigenstates of p, you know them. 339 00:24:06,796 --> 00:24:09,250 They're e to the ipx things. 340 00:24:09,250 --> 00:24:13,650 So let's write them with some convenient normalization. 341 00:24:16,180 --> 00:24:18,780 This is an [INAUDIBLE] wave function 342 00:24:18,780 --> 00:24:21,880 that depends on x with momentum p. 343 00:24:21,880 --> 00:24:24,250 And we'll write it, as a definition, 344 00:24:24,250 --> 00:24:32,000 as e to the ipx over h bar, and I'll put it a 2 pi h bar here. 345 00:24:34,540 --> 00:24:38,440 It's kind of a useful normalization. 346 00:24:38,440 --> 00:24:46,530 Then p hat on psi p of x, well, p hat is supposed 347 00:24:46,530 --> 00:24:56,615 to take h over i d dx, and take h over i d dx of psi p. 348 00:24:59,290 --> 00:25:03,330 And h over i cancels the i over h. 349 00:25:03,330 --> 00:25:05,680 When you take the d dx, you get p out, 350 00:25:05,680 --> 00:25:07,520 and you get the same wave function. 351 00:25:07,520 --> 00:25:12,590 So indeed, you get p times psi p of x. 352 00:25:12,590 --> 00:25:19,010 So indeed, this is the eigenstate of the momentum 353 00:25:19,010 --> 00:25:21,655 operator, and it has momentum p. 354 00:25:24,980 --> 00:25:28,150 Well, what is the use of this? 355 00:25:28,150 --> 00:25:33,370 Well, say you have a representation, what 356 00:25:33,370 --> 00:25:36,180 we call the position representation, 357 00:25:36,180 --> 00:25:38,880 of the wave function and operators. 358 00:25:38,880 --> 00:25:42,450 Let us think now of the momentum representation. 359 00:25:42,450 --> 00:25:45,200 So what does all that mean? 360 00:25:45,200 --> 00:25:49,760 Well, there is the Fourier transform operation 361 00:25:49,760 --> 00:25:54,780 in which we have psi of p. 362 00:25:54,780 --> 00:26:00,780 Well, let me write it this way, actually. 363 00:26:00,780 --> 00:26:05,930 I'll write any psi of x physically 364 00:26:05,930 --> 00:26:11,340 can be represented as a sum of momentum eigenstates. 365 00:26:11,340 --> 00:26:15,040 Therefore, that's Fourier's theorem, 366 00:26:15,040 --> 00:26:23,600 minus infinity to infinity dp e to the ipx over h bar 367 00:26:23,600 --> 00:26:29,060 square root of 2 pi h psi tilde of p. 368 00:26:31,880 --> 00:26:38,870 That's Fourier transformation, defines psi tilde of p. 369 00:26:38,870 --> 00:26:44,450 And Fourier's theorem is the fact that not only you 370 00:26:44,450 --> 00:26:49,020 can do that, but you can invert it so that psi tilde of p 371 00:26:49,020 --> 00:26:52,935 can also be written as an integral, this time over x 372 00:26:52,935 --> 00:27:00,620 from minus infinity to infinity e to the minus ipx over h 373 00:27:00,620 --> 00:27:09,190 bar, also 2 pi h bar psi of x. 374 00:27:09,190 --> 00:27:12,690 So let's ponder this equation for a couple of minutes. 375 00:27:15,640 --> 00:27:21,820 Well, as a physicist, you think of this, well, 376 00:27:21,820 --> 00:27:25,910 this is telling me that any wave function could 377 00:27:25,910 --> 00:27:30,380 be written as a superposition of momentum eigenstates. 378 00:27:30,380 --> 00:27:33,050 Here are the momentum eigenstates. 379 00:27:33,050 --> 00:27:35,140 And for each value of momentum, you 380 00:27:35,140 --> 00:27:39,040 have some coefficient here that tells me how much of that 381 00:27:39,040 --> 00:27:40,640 momentum eigenstate I have. 382 00:27:44,340 --> 00:27:46,600 Now, here is the opposite one. 383 00:27:46,600 --> 00:27:52,050 Psi tilde of p and psi of x are related in this way. 384 00:27:52,050 --> 00:27:55,340 So these coefficients, if you want to calculate them, 385 00:27:55,340 --> 00:27:57,900 you calculate them this way. 386 00:27:57,900 --> 00:28:03,100 But now let's think of it as a change of representation. 387 00:28:06,810 --> 00:28:10,210 The physics is contained in psi of x. 388 00:28:10,210 --> 00:28:15,060 All what you wish to know about this physical system in quantum 389 00:28:15,060 --> 00:28:18,040 mechanics is there in psi of x. 390 00:28:18,040 --> 00:28:21,600 But it's also there in psi of p, because they 391 00:28:21,600 --> 00:28:24,270 contain the same information. 392 00:28:24,270 --> 00:28:28,370 So there are different ways of encoding the same information. 393 00:28:31,540 --> 00:28:36,150 What is the relation between them? 394 00:28:36,150 --> 00:28:39,240 This, we thought of it as a vector, 395 00:28:39,240 --> 00:28:44,210 vector in position space, an infinite dimensional space 396 00:28:44,210 --> 00:28:46,880 that is talking about positions. 397 00:28:46,880 --> 00:28:51,580 This is another vector in momentum space. 398 00:28:51,580 --> 00:28:53,720 Think of it now the infinite line. 399 00:28:53,720 --> 00:28:58,390 So this is an infinite vector with all those points little 400 00:28:58,390 --> 00:29:02,030 by little, from minus infinity to plus infinity, all of them 401 00:29:02,030 --> 00:29:05,300 there, gigantic vector. 402 00:29:05,300 --> 00:29:08,410 And here is another gigantic vector with p 403 00:29:08,410 --> 00:29:11,250 from minus infinity to infinity. 404 00:29:11,250 --> 00:29:13,420 And in between, there's an integral. 405 00:29:13,420 --> 00:29:17,530 But now, with your picture of quantum mechanics, 406 00:29:17,530 --> 00:29:21,740 you see an integral, but you also see a matrix. 407 00:29:21,740 --> 00:29:23,580 And what is this matrix? 408 00:29:23,580 --> 00:29:28,650 Think of this as some sort of psi sub p. 409 00:29:31,180 --> 00:29:38,590 And this as some sort of matrix, px 410 00:29:38,590 --> 00:29:47,020 psi x, in which if you have a product-- you'll remember when 411 00:29:47,020 --> 00:29:51,230 you multiply matrices, a matrix on a vector, 412 00:29:51,230 --> 00:29:54,520 you sum over the second index. 413 00:29:54,520 --> 00:29:56,360 That's the product for matrix. 414 00:29:56,360 --> 00:29:59,400 And then the first index is the index here. 415 00:29:59,400 --> 00:30:04,330 So here is what it, more or less, is like. 416 00:30:04,330 --> 00:30:07,040 Psi tilde of p [? subtend ?] by this, 417 00:30:07,040 --> 00:30:11,750 and this matrix depends on two labels, p and x, and it's that. 418 00:30:11,750 --> 00:30:16,340 So it's a matrix full of phases. 419 00:30:16,340 --> 00:30:20,020 So how do you pass from the coordinate representation 420 00:30:20,020 --> 00:30:23,490 of the information, a vector of all values of the wave 421 00:30:23,490 --> 00:30:25,340 function in all positions? 422 00:30:25,340 --> 00:30:31,140 By multiplying with this matrix of phases that is here, 423 00:30:31,140 --> 00:30:33,070 and it gives you this representation. 424 00:30:33,070 --> 00:30:38,670 So different representations means using different vectors 425 00:30:38,670 --> 00:30:42,140 to represent the physics. 426 00:30:42,140 --> 00:30:45,610 And this vector is a very nice one. 427 00:30:45,610 --> 00:30:49,070 And because of these properties of the momentum operator 428 00:30:49,070 --> 00:30:52,940 and all these things, this vector is also a very nice one. 429 00:30:52,940 --> 00:30:55,690 And there's an integral transform 430 00:30:55,690 --> 00:30:59,480 or some sort of infinite matrix product that relates them. 431 00:31:02,450 --> 00:31:05,700 And we shouldn't be uncomfortable about it. 432 00:31:05,700 --> 00:31:07,260 That's all fine. 433 00:31:07,260 --> 00:31:12,190 So we say that we have, for example, 434 00:31:12,190 --> 00:31:22,260 psi of x as one representation of the state and psi tilde of p 435 00:31:22,260 --> 00:31:25,635 as another representation of the same physics. 436 00:31:30,950 --> 00:31:38,780 We can do one more thing here, If I continue. 437 00:31:38,780 --> 00:31:46,160 We can take that boxed equation on the blackboard up there 438 00:31:46,160 --> 00:31:54,430 and act with h bar over i d dx on psi of x. 439 00:31:57,120 --> 00:32:02,160 So that is equal to h i d dx, and I'll 440 00:32:02,160 --> 00:32:08,070 write what psi of x is, is minus infinity to infinity dp e 441 00:32:08,070 --> 00:32:12,680 to the ipx over h bar square root 442 00:32:12,680 --> 00:32:17,950 of 2 pi h bar psi tilde of p. 443 00:32:22,580 --> 00:32:28,190 Now, when we act on this, as you know, h bar over i d dx 444 00:32:28,190 --> 00:32:32,020 just acts on this and produces the factor of p. 445 00:32:32,020 --> 00:32:38,410 So this is equal to minus infinity to infinity dp e 446 00:32:38,410 --> 00:32:45,890 to the ipx over h bar over square root of 2 pi h bar p 447 00:32:45,890 --> 00:32:48,140 times psi tilde of p. 448 00:32:54,720 --> 00:32:59,240 So look at this equation again. 449 00:32:59,240 --> 00:33:02,940 This double arrow is to mean that there 450 00:33:02,940 --> 00:33:05,080 are equivalent physics in them. 451 00:33:05,080 --> 00:33:06,790 They have the same information. 452 00:33:06,790 --> 00:33:10,300 It's the same data encoded in a different way. 453 00:33:10,300 --> 00:33:13,329 And that different way, this arrow 454 00:33:13,329 --> 00:33:14,412 is Fourier transformation. 455 00:33:17,420 --> 00:33:20,750 And this Fourier transformation is explained here. 456 00:33:20,750 --> 00:33:26,920 So now you have Fourier transformation the same way. 457 00:33:26,920 --> 00:33:30,270 So here we have-- what we've learned 458 00:33:30,270 --> 00:33:41,120 is that h over i d dx of psi is represented in momentum space 459 00:33:41,120 --> 00:33:47,060 by p psi tilde of p. 460 00:33:47,060 --> 00:33:52,620 And this was p hat acting on psi of x. 461 00:33:55,520 --> 00:34:00,900 So the corresponding thing in momentum space of p hat 462 00:34:00,900 --> 00:34:08,530 acting on psi of x is p multiplying psi tilde of p, 463 00:34:08,530 --> 00:34:15,590 which is to say that we can think of the abstract operator 464 00:34:15,590 --> 00:34:25,620 p hat acting on psi tilde of p as just p psi tilde of p. 465 00:34:33,040 --> 00:34:39,639 So in momentum space, the operator p hat 466 00:34:39,639 --> 00:34:41,260 acts in a very easy way. 467 00:34:44,280 --> 00:34:48,300 In coordinate space, it takes derivatives. 468 00:34:48,300 --> 00:34:51,940 In momentum space, it's multiplicative. 469 00:34:51,940 --> 00:34:58,620 So in position space, x is multiplicative. 470 00:34:58,620 --> 00:35:05,380 But in momentum space, x would not be multiplicative. 471 00:35:05,380 --> 00:35:07,780 x would also be a derivative. 472 00:35:07,780 --> 00:35:11,870 So I leave it for you as an exercise 473 00:35:11,870 --> 00:35:19,540 to show that or convince yourself in several ways, 474 00:35:19,540 --> 00:35:34,270 that x hat is really i h bar d dp in p space, in i h bar d dp. 475 00:35:36,960 --> 00:35:37,760 All right. 476 00:35:37,760 --> 00:35:43,590 So that's really all I wanted to say about position and momentum 477 00:35:43,590 --> 00:35:45,850 operators at this moment. 478 00:35:45,850 --> 00:35:49,960 They will come back when we'll introduce bra-ket notation 479 00:35:49,960 --> 00:35:50,460 in detail. 480 00:35:50,460 --> 00:35:52,550 We'll revisit this a little. 481 00:35:52,550 --> 00:35:56,690 But the main concepts have been illustrated. 482 00:35:56,690 --> 00:35:57,980 Are there questions? 483 00:35:57,980 --> 00:36:01,330 We're about to leave this, so if you 484 00:36:01,330 --> 00:36:02,750 have any questions at this moment. 485 00:36:02,750 --> 00:36:03,310 Yes? 486 00:36:03,310 --> 00:36:04,795 AUDIENCE: Could you explain again 487 00:36:04,795 --> 00:36:10,240 how you used this [INAUDIBLE] h bar over i d dx 488 00:36:10,240 --> 00:36:12,730 assign to [INAUDIBLE]? 489 00:36:12,730 --> 00:36:13,920 PROFESSOR: Right. 490 00:36:13,920 --> 00:36:18,760 So the question was, why did I associate these things? 491 00:36:18,760 --> 00:36:24,340 So it really goes back here to what the meaning of this arrow 492 00:36:24,340 --> 00:36:25,420 is. 493 00:36:25,420 --> 00:36:28,510 The meaning of this arrow is Fourier transformation. 494 00:36:28,510 --> 00:36:34,420 So this psi tilde and psi of x are related in this way. 495 00:36:34,420 --> 00:36:36,540 That's Fourier transformation, and that's 496 00:36:36,540 --> 00:36:38,850 what we mean by this arrow. 497 00:36:38,850 --> 00:36:43,950 It also means that whatever physics you have here, 498 00:36:43,950 --> 00:36:45,760 you have it there. 499 00:36:45,760 --> 00:36:52,570 So really, when you have something acting on a state, 500 00:36:52,570 --> 00:36:56,050 for example, if you have some operator acting in here, well, 501 00:36:56,050 --> 00:36:58,270 you get a new wave function. 502 00:36:58,270 --> 00:37:00,410 And there should be one on the right that 503 00:37:00,410 --> 00:37:03,810 corresponds to it, that has the same information as the one 504 00:37:03,810 --> 00:37:06,030 in which you've acted with something. 505 00:37:06,030 --> 00:37:10,330 So what we claim here is that, also in the sense of Fourier 506 00:37:10,330 --> 00:37:15,420 transformation or having the same information, h bar over i, 507 00:37:15,420 --> 00:37:20,130 the derivative of psi, is encoded by this. 508 00:37:20,130 --> 00:37:24,660 So we say, thinking abstractly, what is this? 509 00:37:24,660 --> 00:37:28,970 This is the momentum operator. 510 00:37:28,970 --> 00:37:35,350 Therefore, I'm going to say that the momentum operator really 511 00:37:35,350 --> 00:37:39,000 is the same momentum operator, whether it acts 512 00:37:39,000 --> 00:37:42,810 on wave functions that you show them to mean this way or wave 513 00:37:42,810 --> 00:37:45,680 functions that, because you're in another mood, 514 00:37:45,680 --> 00:37:48,660 you decide to give them to me in momentum space. 515 00:37:48,660 --> 00:37:53,690 So as you change your mood, the operator takes different forms 516 00:37:53,690 --> 00:37:56,380 but is doing the same thing. 517 00:37:56,380 --> 00:37:58,030 It's totally reversible. 518 00:37:58,030 --> 00:38:02,460 It's acting on that-- you see, the operator is always 519 00:38:02,460 --> 00:38:06,370 the same, but you give me the data in two different ways, 520 00:38:06,370 --> 00:38:10,170 then the operator has to do the thing in a different way. 521 00:38:10,170 --> 00:38:12,770 So that's what it means that the operator has 522 00:38:12,770 --> 00:38:15,030 different representations. 523 00:38:15,030 --> 00:38:16,770 In the [INAUDIBLE] representation, 524 00:38:16,770 --> 00:38:18,790 it looks like a derivative. 525 00:38:18,790 --> 00:38:21,915 In the momentum representation, it looks like multiplying. 526 00:38:25,130 --> 00:38:27,828 Other questions? 527 00:38:27,828 --> 00:38:28,806 Yes? 528 00:38:28,806 --> 00:38:31,904 AUDIENCE: So by saying that they sort of represent 529 00:38:31,904 --> 00:38:33,320 [INAUDIBLE] to the same positions, 530 00:38:33,320 --> 00:38:36,605 does that mean that h bar over i p e to the xi and p psi p 531 00:38:36,605 --> 00:38:38,620 are like the same [INAUDIBLE]? 532 00:38:38,620 --> 00:38:43,690 PROFESSOR: That h bar over d dx psi and p-- yeah. 533 00:38:43,690 --> 00:38:47,400 They are the same data, the same state 534 00:38:47,400 --> 00:38:49,345 represented in different ways. 535 00:38:49,345 --> 00:38:49,845 Yeah. 536 00:38:54,800 --> 00:38:55,470 All right. 537 00:38:55,470 --> 00:38:58,470 So time for a change. 538 00:38:58,470 --> 00:39:03,460 We're going to talk about Stern-Gerlach and spin. 539 00:39:03,460 --> 00:39:09,580 Now, spin will keep us busy the biggest chunk of this semester. 540 00:39:09,580 --> 00:39:14,310 So it will be spin-1/2, and we're really going to go 541 00:39:14,310 --> 00:39:17,200 into enormous detail on it. 542 00:39:17,200 --> 00:39:20,830 So this is just the beginning of the story that 543 00:39:20,830 --> 00:39:25,030 will be elaborated at various stages. 544 00:39:25,030 --> 00:39:30,420 So at this moment, I will talk about this experiment 545 00:39:30,420 --> 00:39:33,090 that led to the discovery of spin, 546 00:39:33,090 --> 00:39:37,200 and if you try to invent the theory that describes 547 00:39:37,200 --> 00:39:42,050 this experiment, what you would possibly begin doing. 548 00:39:42,050 --> 00:39:44,340 And then we go through the mathematics, 549 00:39:44,340 --> 00:39:48,720 as I mentioned to you, for maybe a week and a half or two weeks, 550 00:39:48,720 --> 00:39:52,260 and then return to the spin with more tools 551 00:39:52,260 --> 00:39:55,960 to understand it well. 552 00:39:55,960 --> 00:40:00,420 So the subject is the Stern-Gerlach experiment, 553 00:40:00,420 --> 00:40:06,050 Stern-Gerlach experiment. 554 00:40:12,650 --> 00:40:21,080 So the Stern-Gerlach experiment was done in Frankfurt, 1922. 555 00:40:21,080 --> 00:40:23,930 It was an experiment that, in fact, people 556 00:40:23,930 --> 00:40:25,672 were extraordinarily confused. 557 00:40:25,672 --> 00:40:29,080 It was not clear why they were doing it. 558 00:40:29,080 --> 00:40:33,590 And for quite a while, people didn't 559 00:40:33,590 --> 00:40:37,170 understand what they were getting, 560 00:40:37,170 --> 00:40:39,400 what was happening with it. 561 00:40:39,400 --> 00:40:46,760 In fact, Pauli had thought that the electron has 562 00:40:46,760 --> 00:40:48,890 like two degrees of freedom and didn't 563 00:40:48,890 --> 00:40:53,410 know what it was, those two degrees of freedom. 564 00:40:53,410 --> 00:40:57,605 Kronig suggested that it had to do somehow 565 00:40:57,605 --> 00:41:01,350 with the rotation of the electron. 566 00:41:01,350 --> 00:41:05,620 Now, Pauli said that's nonsense. 567 00:41:05,620 --> 00:41:09,950 How can an electron rotate and have angular momentum 568 00:41:09,950 --> 00:41:11,770 because it has a rotation? 569 00:41:11,770 --> 00:41:15,450 It would have to rotate so fast, even faster 570 00:41:15,450 --> 00:41:18,200 than the speed of light to have the angular momentum, 571 00:41:18,200 --> 00:41:21,510 and then this little ball that would be the electron 572 00:41:21,510 --> 00:41:22,790 would disintegrate. 573 00:41:22,790 --> 00:41:27,060 And it made no sense to him that there would be such a thing. 574 00:41:27,060 --> 00:41:30,890 So Kronig didn't publish this. 575 00:41:30,890 --> 00:41:35,986 Then there were another two people, Uhlenbeck and Goudsmit, 576 00:41:35,986 --> 00:41:40,190 at the same time, around 1925, had 577 00:41:40,190 --> 00:41:44,870 the same idea, angular momentum of this particle. 578 00:41:44,870 --> 00:41:48,860 And their advisor was Ehrenfest, and said 579 00:41:48,860 --> 00:41:52,285 it doesn't make too much sense, but you should publish it. 580 00:41:52,285 --> 00:41:54,390 [LAUGHTER] 581 00:41:54,390 --> 00:41:57,080 And thanks to their publishing, they 582 00:41:57,080 --> 00:42:00,430 are given credit for discovering the spin of the electron. 583 00:42:00,430 --> 00:42:03,390 And Pauli, a couple of years later, 584 00:42:03,390 --> 00:42:05,260 decided, after all, I was wrong. 585 00:42:05,260 --> 00:42:08,380 Yes, it is spin, and it's all working out. 586 00:42:08,380 --> 00:42:14,160 And 1927, five years after the experiment basically, 587 00:42:14,160 --> 00:42:17,110 people understood what was going on. 588 00:42:17,110 --> 00:42:20,040 So what were these people trying to do? 589 00:42:20,040 --> 00:42:23,400 First, Stern and Gerlach were atomic physicists, 590 00:42:23,400 --> 00:42:26,550 and they were just interested in measuring 591 00:42:26,550 --> 00:42:34,220 speeds of thermal motion of ions. 592 00:42:34,220 --> 00:42:37,460 So they would send beams of these ions 593 00:42:37,460 --> 00:42:41,530 and put magnetic fields and deflect them and measure 594 00:42:41,530 --> 00:42:43,550 their velocities. 595 00:42:43,550 --> 00:42:46,170 And eventually, they were experts 596 00:42:46,170 --> 00:42:47,580 doing this kind of thing. 597 00:42:47,580 --> 00:42:51,630 And they heard of Bohr, that said that the electron has 598 00:42:51,630 --> 00:42:56,440 angular momentum and is going around the proton in circles, 599 00:42:56,440 --> 00:42:58,280 so it might have angular momentum. 600 00:42:58,280 --> 00:43:01,120 They said, oh, if it has angular momentum because it's 601 00:43:01,120 --> 00:43:05,330 going around the proton, maybe we can detect it. 602 00:43:05,330 --> 00:43:09,080 And when they did the experiment, they got something. 603 00:43:09,080 --> 00:43:11,510 And they said, well, we're seeing it. 604 00:43:11,510 --> 00:43:14,520 But it was not that. 605 00:43:14,520 --> 00:43:17,700 They were not seeing the orbital angular momentum 606 00:43:17,700 --> 00:43:24,650 of the electron because that electron in these silver atoms 607 00:43:24,650 --> 00:43:27,310 actually has no angular momentum, 608 00:43:27,310 --> 00:43:30,340 as we will see, no orbital angular momentum. 609 00:43:30,340 --> 00:43:31,370 It only has spin. 610 00:43:31,370 --> 00:43:34,220 So they were actually seeing the spin. 611 00:43:34,220 --> 00:43:36,090 So it was a big confusion. 612 00:43:36,090 --> 00:43:37,650 It took some time. 613 00:43:37,650 --> 00:43:41,660 Basically, they took the beam, and they split it 614 00:43:41,660 --> 00:43:45,770 with a magnetic field, and the clean split 615 00:43:45,770 --> 00:43:47,510 was something nobody understood. 616 00:43:47,510 --> 00:43:51,440 So they called it space quantization, 617 00:43:51,440 --> 00:43:54,500 as of it's separated in space. 618 00:43:54,500 --> 00:43:56,710 Space is quantized. 619 00:43:56,710 --> 00:43:59,570 A pretty awful name, of course. 620 00:43:59,570 --> 00:44:03,200 There's nothing quantized about space here. 621 00:44:03,200 --> 00:44:07,600 But it reflects that when you don't know what's really 622 00:44:07,600 --> 00:44:12,500 happening, your names don't come out too well. 623 00:44:12,500 --> 00:44:17,460 So what we have to understand here, 624 00:44:17,460 --> 00:44:20,540 our goal today is to just see what's 625 00:44:20,540 --> 00:44:27,310 happening in that experiment, quantify a bit the results, 626 00:44:27,310 --> 00:44:33,050 and then extract the quantum mechanical lessons from it. 627 00:44:33,050 --> 00:44:35,900 So let us begin with the important thing. 628 00:44:35,900 --> 00:44:39,380 You don't see the spin directly. 629 00:44:39,380 --> 00:44:43,930 What you see is magnetic moments. 630 00:44:43,930 --> 00:44:45,600 So what's that? 631 00:44:45,600 --> 00:44:47,680 So what are magnetic moments? 632 00:44:47,680 --> 00:45:00,340 Magnetic moments, mu, is the analog, the magnetic analog 633 00:45:00,340 --> 00:45:01,780 of an electric dipole. 634 00:45:01,780 --> 00:45:03,740 A mu is called a magnetic dipole. 635 00:45:03,740 --> 00:45:05,740 You say it has a magnetic moment. 636 00:45:08,680 --> 00:45:14,160 And the magnetic moment is given by I times the area. 637 00:45:14,160 --> 00:45:15,490 What does that mean? 638 00:45:15,490 --> 00:45:20,360 Well, a precise discussion would take some time. 639 00:45:20,360 --> 00:45:24,110 But roughly, you can simplify when 640 00:45:24,110 --> 00:45:28,150 you think of a loop that is in a plane, in which case 641 00:45:28,150 --> 00:45:31,270 there's an area associated to it. 642 00:45:31,270 --> 00:45:33,570 And if the loop is this one, the area 643 00:45:33,570 --> 00:45:38,280 is defined as the normal vector to the oriented loop. 644 00:45:38,280 --> 00:45:42,140 So an oriented loop has an area vector. 645 00:45:42,140 --> 00:45:43,960 And the orientation could be focused 646 00:45:43,960 --> 00:45:45,500 the direction of the current. 647 00:45:45,500 --> 00:45:46,450 There is some area. 648 00:45:46,450 --> 00:45:49,970 And the magnetic moment is given by this thing. 649 00:45:49,970 --> 00:45:52,520 It points up in the circumstances 650 00:45:52,520 --> 00:45:55,580 when this current goes like that. 651 00:45:55,580 --> 00:45:58,630 So that's a magnetic moment. 652 00:45:58,630 --> 00:46:01,930 A little bit of units. 653 00:46:01,930 --> 00:46:06,020 The way units work out is that mu B-- magnetic moments 654 00:46:06,020 --> 00:46:11,190 and magnetic fields have units of energy. 655 00:46:14,680 --> 00:46:19,140 So magnetic moments you could define 656 00:46:19,140 --> 00:46:26,450 as energy, which is joules, divided by tesla, 657 00:46:26,450 --> 00:46:32,520 or ergs divided by gauss, because mu B has 658 00:46:32,520 --> 00:46:35,490 units of energy. 659 00:46:35,490 --> 00:46:39,300 So how do magnetic moments originate 660 00:46:39,300 --> 00:46:43,340 in a charge configuration? 661 00:46:43,340 --> 00:46:46,230 Well, you can simply have a little current like that. 662 00:46:46,230 --> 00:46:49,630 But let's consider a different situation 663 00:46:49,630 --> 00:46:58,040 in which you have a ring of charge, 664 00:46:58,040 --> 00:47:08,945 a ring of charge of some radius R. It has a total charge Q, 665 00:47:08,945 --> 00:47:12,350 and it has a linear charge density lambda. 666 00:47:12,350 --> 00:47:17,980 It's uniform, and it's rotating with some velocity 667 00:47:17,980 --> 00:47:24,220 v. If you wish, it also has a mass M. There are all 668 00:47:24,220 --> 00:47:25,720 kinds of [? parameters. ?] How many? 669 00:47:25,720 --> 00:47:29,490 Mass, charge, radius, and velocity. 670 00:47:29,490 --> 00:47:30,100 Here we go. 671 00:47:30,100 --> 00:47:35,250 We have our solid ring of charge rotating, 672 00:47:35,250 --> 00:47:39,030 and we want to figure out something quite fundamental, 673 00:47:39,030 --> 00:47:41,470 which is the origin of this principle. 674 00:47:41,470 --> 00:47:46,300 We said, you really never see spins directly. 675 00:47:46,300 --> 00:47:49,960 You never see this intrinsic angular momentum directly. 676 00:47:49,960 --> 00:47:53,280 You see magnetic moments. 677 00:47:53,280 --> 00:47:55,800 But then actually what happens is 678 00:47:55,800 --> 00:47:58,310 that there's a universal relation 679 00:47:58,310 --> 00:48:00,615 between magnetic moments and angular momentum. 680 00:48:00,615 --> 00:48:04,370 This is a key concept in physics. 681 00:48:04,370 --> 00:48:05,890 Maybe you've seen it before. 682 00:48:05,890 --> 00:48:07,080 Maybe you haven't. 683 00:48:07,080 --> 00:48:11,540 Probably you might have seen that in 802. 684 00:48:11,540 --> 00:48:13,040 So how does that go? 685 00:48:13,040 --> 00:48:16,020 Let's calculate the magnetic moment. 686 00:48:16,020 --> 00:48:22,830 So the current is the linear charge density 687 00:48:22,830 --> 00:48:23,650 times the velocity. 688 00:48:28,440 --> 00:48:32,760 The linear charge density is the total charge 689 00:48:32,760 --> 00:48:35,705 divided by 2 pi R times the velocity. 690 00:48:38,360 --> 00:48:41,060 Now the area, to give the magnetic moment, 691 00:48:41,060 --> 00:48:44,120 we'll have mu is equal to I times the area. 692 00:48:44,120 --> 00:48:49,300 So it would be this Q times 2 pi R v 693 00:48:49,300 --> 00:48:54,700 times the area, which would be pi R squared. 694 00:48:54,700 --> 00:49:00,605 So the pi's cancel, and we get 1/2 QvR. 695 00:49:08,520 --> 00:49:10,550 OK. 696 00:49:10,550 --> 00:49:14,510 1/2 QvR, and that's fine and interesting. 697 00:49:14,510 --> 00:49:20,230 But OK, depends on the radius, depends on the velocity. 698 00:49:20,230 --> 00:49:26,200 So here is the magnetic moment is supposed to be going up. 699 00:49:26,200 --> 00:49:27,730 But what else is going up? 700 00:49:27,730 --> 00:49:31,020 The angular momentum of this thing is also going up. 701 00:49:31,020 --> 00:49:35,026 So what is the magnitude of the angular momentum L? 702 00:49:35,026 --> 00:49:36,476 L is angular momentum. 703 00:49:39,700 --> 00:49:43,690 Well, it's the mass times the momentum-- 704 00:49:43,690 --> 00:49:47,970 it's the mass momentum cross R, so MvR. 705 00:49:53,790 --> 00:49:58,270 The momentum of R cross p for each piece, 706 00:49:58,270 --> 00:50:02,910 contributes the same, so you just take the total momentum. 707 00:50:02,910 --> 00:50:06,260 This really is 0, but add them up little by little, 708 00:50:06,260 --> 00:50:08,270 and you've got your MvR. 709 00:50:11,050 --> 00:50:22,780 So here you have vR, so here you put 1/2 Q over M MvR. 710 00:50:25,330 --> 00:50:38,600 And you discover that mu is equal to 1/2 Q over M L. 711 00:50:38,600 --> 00:50:49,430 So maybe write it better-- Q over 2M L. I'm sorry, 712 00:50:49,430 --> 00:50:50,835 this is the normal. 713 00:50:50,835 --> 00:50:54,710 The M shouldn't change, M. 714 00:50:54,710 --> 00:50:59,680 And I box this relation because an interesting thing 715 00:50:59,680 --> 00:51:00,440 has happened. 716 00:51:00,440 --> 00:51:04,510 All kinds of incidentals have dropped out. 717 00:51:04,510 --> 00:51:08,090 Like the velocity has dropped out. 718 00:51:08,090 --> 00:51:11,140 The radius has dropped out as well. 719 00:51:11,140 --> 00:51:14,140 So if I have one ring with this radius 720 00:51:14,140 --> 00:51:16,390 and another ring with a bigger radius, 721 00:51:16,390 --> 00:51:19,740 the relation between mu and L is the same, 722 00:51:19,740 --> 00:51:23,090 as long as it's rotating with the same speed. 723 00:51:23,090 --> 00:51:26,900 So this is actually a universal relation. 724 00:51:26,900 --> 00:51:29,330 It is not just true for a little ring. 725 00:51:29,330 --> 00:51:33,790 It's true for a solid sphere or any solid object axially 726 00:51:33,790 --> 00:51:35,880 symmetric. 727 00:51:35,880 --> 00:51:36,830 It would be true. 728 00:51:36,830 --> 00:51:43,030 You could consider any object that is axially symmetric, 729 00:51:43,030 --> 00:51:45,870 and then you start considering all the little rings that 730 00:51:45,870 --> 00:51:46,710 can be built. 731 00:51:46,710 --> 00:51:49,340 And for every ring, mu over L is the same, 732 00:51:49,340 --> 00:51:51,880 and they all point in the same direction. 733 00:51:51,880 --> 00:51:56,220 Therefore, it's true under very general grounds. 734 00:51:56,220 --> 00:51:59,790 And that is a very famous relation. 735 00:51:59,790 --> 00:52:03,770 So now you could speculate that, indeed, 736 00:52:03,770 --> 00:52:12,390 the reason that a particle may have a magnetic moment if it's 737 00:52:12,390 --> 00:52:15,610 made by a little ball of charge that is rotating. 738 00:52:15,610 --> 00:52:18,900 But that was exactly what Pauli didn't like, of course. 739 00:52:21,928 --> 00:52:24,600 And you would like to see what's really 740 00:52:24,600 --> 00:52:25,980 happening with particles. 741 00:52:25,980 --> 00:52:31,770 So when you think of a true quantum mechanical particle, 742 00:52:31,770 --> 00:52:37,550 let's think of a particle in general, a solid particle 743 00:52:37,550 --> 00:52:38,110 rotating. 744 00:52:38,110 --> 00:52:43,160 We'll change the name to S for spin angular momentum. 745 00:52:43,160 --> 00:52:46,480 Because that little part, this is just one particle. 746 00:52:46,480 --> 00:52:48,920 We're not thinking of that little particle 747 00:52:48,920 --> 00:52:51,700 going around a nucleus. 748 00:52:51,700 --> 00:52:55,310 We're thinking of that little particle rotating. 749 00:52:55,310 --> 00:52:57,620 So this is a little piece of that little particle 750 00:52:57,620 --> 00:52:59,270 that is rotating. 751 00:52:59,270 --> 00:53:08,640 So you could ask, if, for the electron, 752 00:53:08,640 --> 00:53:12,150 for example, is it true that mu is 753 00:53:12,150 --> 00:53:17,595 equal to e over 2 mass of the electron times its spin? 754 00:53:22,030 --> 00:53:28,040 So this would be a vindication of this classical analysis. 755 00:53:28,040 --> 00:53:34,770 It might be that it's related in this way. 756 00:53:34,770 --> 00:53:48,910 So actually, it's not quite true, 757 00:53:48,910 --> 00:53:53,080 but let's still improve this a little bit. 758 00:53:53,080 --> 00:54:00,590 In terms of units, we like to put an h bar here and a 2Me. 759 00:54:00,590 --> 00:54:05,700 And put spin here, angular momentum, divided by h. 760 00:54:05,700 --> 00:54:11,960 Because this has no units, h bar has the units 761 00:54:11,960 --> 00:54:17,000 of angular momentum, x times p. 762 00:54:17,000 --> 00:54:19,390 It's the same units, so units of angular momentum. 763 00:54:19,390 --> 00:54:24,430 So h bar would be convenient. 764 00:54:24,430 --> 00:54:33,270 So that over here, you would have units of a dipole moment, 765 00:54:33,270 --> 00:54:38,300 or magnetic moment, magnetic moment units. 766 00:54:43,300 --> 00:54:47,810 So what does happen for the electron? 767 00:54:47,810 --> 00:54:52,810 Well, it's almost true, but not quite. 768 00:54:52,810 --> 00:54:57,680 In fact, what you get is that you need a fudge factor. 769 00:54:57,680 --> 00:55:00,700 The fudge factor is that, actually, 770 00:55:00,700 --> 00:55:02,800 for elementary particles, you have 771 00:55:02,800 --> 00:55:06,980 a g, which is a constant, which is the fudge factor, 772 00:55:06,980 --> 00:55:15,850 e h bar 2 over M of the particle S over h bar. 773 00:55:15,850 --> 00:55:19,410 Sometimes called the Lande factor. 774 00:55:19,410 --> 00:55:22,410 You must put a number there. 775 00:55:22,410 --> 00:55:28,140 Now, the good thing is that the number sometimes 776 00:55:28,140 --> 00:55:31,030 can be calculated and predicted. 777 00:55:31,030 --> 00:55:34,100 So when people did this, they figured out 778 00:55:34,100 --> 00:55:38,950 that for the electron the number is actually a 2. 779 00:55:38,950 --> 00:55:46,210 So for the electron, g of the electron is equal to 2. 780 00:55:46,210 --> 00:55:49,770 Now that, you would say, cannot be an accident. 781 00:55:49,770 --> 00:55:54,720 It's twice what you would predict sort of classically. 782 00:55:54,720 --> 00:55:59,250 And the Dirac equation, the relativistic equation 783 00:55:59,250 --> 00:56:02,010 of the electron that you have not studied yet 784 00:56:02,010 --> 00:56:07,200 but you will study soon, predicts this g equal to 2. 785 00:56:07,200 --> 00:56:08,880 It was considered a great success 786 00:56:08,880 --> 00:56:12,670 that that equation gave the right answer, that people 787 00:56:12,670 --> 00:56:16,400 understood that this number was going to be 2. 788 00:56:16,400 --> 00:56:19,670 So for the electron, this is 2. 789 00:56:19,670 --> 00:56:25,210 So this quantity is called-- it's a magnetic dipole 790 00:56:25,210 --> 00:56:32,210 moment-- is called mu B for Bohr magneton. 791 00:56:39,900 --> 00:56:44,330 So how big is a mu B? 792 00:56:44,330 --> 00:56:51,880 It's about 9.3 times 10 to the minus 24 joules per tesla. 793 00:56:55,454 --> 00:56:56,380 AUDIENCE: Professor. 794 00:56:56,380 --> 00:56:57,520 PROFESSOR: Yes? 795 00:56:57,520 --> 00:56:58,966 AUDIENCE: [INAUDIBLE]. 796 00:56:58,966 --> 00:57:01,376 So where exactly does the fudge factor come in? 797 00:57:01,376 --> 00:57:05,112 Is it just merely because [INAUDIBLE]? 798 00:57:05,112 --> 00:57:05,820 PROFESSOR: Right. 799 00:57:05,820 --> 00:57:11,590 So the classical analysis is not valid. 800 00:57:11,590 --> 00:57:14,800 So it's pretty invalid, in fact. 801 00:57:14,800 --> 00:57:19,530 You see, the picture of an electron, 802 00:57:19,530 --> 00:57:22,480 as of today, is that it's a point particle. 803 00:57:22,480 --> 00:57:27,200 And a point particle literally means no size. 804 00:57:27,200 --> 00:57:30,880 The electron is not a little ball of charge. 805 00:57:30,880 --> 00:57:32,740 Otherwise, it would have parts. 806 00:57:32,740 --> 00:57:34,970 So an electron is a point particle. 807 00:57:34,970 --> 00:57:38,250 Therefore, a point particle cannot be rotating and have 808 00:57:38,250 --> 00:57:39,020 a spin. 809 00:57:39,020 --> 00:57:43,670 So how does the electron manage to have spin? 810 00:57:43,670 --> 00:57:45,720 That you can't answer in physics. 811 00:57:45,720 --> 00:57:47,590 It just has it. 812 00:57:47,590 --> 00:57:51,640 Just like a point particle that has no size can have mass. 813 00:57:51,640 --> 00:57:54,670 How do you have mass if you have no size? 814 00:57:54,670 --> 00:57:56,130 You get accustomed to the idea. 815 00:57:56,130 --> 00:57:58,550 The mathematics says it's possible. 816 00:57:58,550 --> 00:58:00,420 You don't run into trouble. 817 00:58:00,420 --> 00:58:06,510 So this particle has no size, but it has an angular spin, 818 00:58:06,510 --> 00:58:09,070 angular momentum, as if it would be rotating. 819 00:58:09,070 --> 00:58:12,520 But it's definitely not the case that it's rotating. 820 00:58:12,520 --> 00:58:17,420 And therefore, this 2 confirms that it was a pointless idea 821 00:58:17,420 --> 00:58:19,260 to believe that it would be true. 822 00:58:19,260 --> 00:58:22,720 Nevertheless, kind of unit analyses 823 00:58:22,720 --> 00:58:26,770 or maybe some truth to the fact that quantum mechanics 824 00:58:26,770 --> 00:58:29,290 changes classical mechanics. 825 00:58:29,290 --> 00:58:32,580 Turns out that it's closely related. 826 00:58:32,580 --> 00:58:36,910 For the proton, for example, the magnetic moment of the proton 827 00:58:36,910 --> 00:58:40,510 is quite complicated as well because the proton is made out 828 00:58:40,510 --> 00:58:43,110 of quarks that are rotating inside. 829 00:58:43,110 --> 00:58:47,070 And how do you get the spin of the proton 830 00:58:47,070 --> 00:58:48,790 and the magnetic moment of the proton? 831 00:58:48,790 --> 00:58:50,000 It's complicated. 832 00:58:50,000 --> 00:58:54,560 The neutron, that has no charge, has a magnetic moment, 833 00:58:54,560 --> 00:58:58,450 because somehow the quarks inside arrange in a way 834 00:58:58,450 --> 00:59:01,900 that their angular momentum doesn't quite cancel. 835 00:59:05,580 --> 00:59:08,690 So for example, the value for a neutron, I believe, 836 00:59:08,690 --> 00:59:12,390 is minus 2.78 or something like that. 837 00:59:12,390 --> 00:59:14,770 It's a strange number. 838 00:59:14,770 --> 00:59:19,070 Another thing that is sort of interesting that is also true 839 00:59:19,070 --> 00:59:22,390 is that this mass is the mass of a particle. 840 00:59:22,390 --> 00:59:25,250 So if you're talking about the magnetic moment 841 00:59:25,250 --> 00:59:28,530 of the proton or the neutron, it's 842 00:59:28,530 --> 00:59:31,740 suppressed with respect to the one of the electron. 843 00:59:31,740 --> 00:59:34,580 The electron one is much bigger because, actually, the mass 844 00:59:34,580 --> 00:59:36,440 shows up here. 845 00:59:36,440 --> 00:59:40,860 So for a neutron or a proton, the magnetic moment 846 00:59:40,860 --> 00:59:44,210 is much, much smaller. 847 00:59:44,210 --> 00:59:48,560 So, in fact, for an electron then, you 848 00:59:48,560 --> 00:59:49,870 would have the following. 849 00:59:49,870 --> 01:00:01,720 Mu is equal to minus g, which is 2, mu B S bar over h. 850 01:00:01,720 --> 01:00:04,280 And actually, we put the minus sign 851 01:00:04,280 --> 01:00:07,820 because the electron has negative charge. 852 01:00:07,820 --> 01:00:12,270 So the magnetic moment actually points opposite. 853 01:00:12,270 --> 01:00:16,120 If you rotate this way, the angular momentum is always up. 854 01:00:16,120 --> 01:00:18,770 But if you rotate this way and you're negative, 855 01:00:18,770 --> 01:00:21,740 it's as if the current goes in the other direction. 856 01:00:21,740 --> 01:00:25,871 So this is due to the fact that the electron is negatively 857 01:00:25,871 --> 01:00:26,370 charged. 858 01:00:26,370 --> 01:00:28,870 And that's the final expression. 859 01:00:31,740 --> 01:00:38,765 So OK, so that's the general story with magnetic moments. 860 01:00:42,390 --> 01:00:45,360 So the next thing is, how do magnetic moments 861 01:00:45,360 --> 01:00:49,530 react when you have magnetic fields? 862 01:00:49,530 --> 01:00:54,710 So that is something that you can calculate, 863 01:00:54,710 --> 01:00:57,790 or you can decide if you have a picture. 864 01:00:57,790 --> 01:01:03,650 For example, if you have a loop of charge like this, 865 01:01:03,650 --> 01:01:10,050 and you have magnetic field lines that go like this, 866 01:01:10,050 --> 01:01:11,795 they diverge a bit. 867 01:01:15,830 --> 01:01:18,220 Let me see you use your right-hand rule 868 01:01:18,220 --> 01:01:20,950 and tell me whether that loop of current 869 01:01:20,950 --> 01:01:22,925 will feel a force up or down. 870 01:01:26,936 --> 01:01:31,090 I'll give you 30 seconds, and I take a vote. 871 01:01:31,090 --> 01:01:32,880 Let's see how we're doing with that. 872 01:01:39,547 --> 01:01:43,280 And I'll prepare these blackboards in the meantime. 873 01:01:59,420 --> 01:02:00,310 All right. 874 01:02:00,310 --> 01:02:03,060 Who votes up? 875 01:02:03,060 --> 01:02:03,560 Nobody. 876 01:02:03,560 --> 01:02:05,503 Who votes down? 877 01:02:05,503 --> 01:02:06,405 Yeah, [INAUDIBLE]. 878 01:02:06,405 --> 01:02:08,640 Down, exactly. 879 01:02:08,640 --> 01:02:10,150 How do you see down? 880 01:02:10,150 --> 01:02:14,250 Well, one way to see this, look at the cross-section. 881 01:02:14,250 --> 01:02:18,980 You would have this wire here like that. 882 01:02:18,980 --> 01:02:22,870 The current is coming in on this side and going out this way. 883 01:02:22,870 --> 01:02:26,470 Here you have the field lines that go through those two 884 01:02:26,470 --> 01:02:33,570 edges, and the magnetic field is like that. 885 01:02:33,570 --> 01:02:38,550 And the force goes like I cross B. So I goes in, B goes out. 886 01:02:38,550 --> 01:02:42,720 The force must be like that, a little bit of force. 887 01:02:42,720 --> 01:02:46,700 In this one, I cross B would be like that, 888 01:02:46,700 --> 01:02:48,160 a little bit of force. 889 01:02:48,160 --> 01:02:49,070 Yep. 890 01:02:49,070 --> 01:02:52,105 Has a component down because the field lines are diverging. 891 01:02:56,080 --> 01:02:59,920 So what is the force really given by? 892 01:02:59,920 --> 01:03:05,540 The force is given by the gradient 893 01:03:05,540 --> 01:03:14,490 of mu dot B. This is derived in E&M. I will not derive it here. 894 01:03:14,490 --> 01:03:17,490 This is not really the point of this course. 895 01:03:17,490 --> 01:03:21,310 But you can see that it's consistent. 896 01:03:21,310 --> 01:03:26,080 This is saying that the force goes in the direction that 897 01:03:26,080 --> 01:03:29,810 makes mu dot B grow the fastest. 898 01:03:29,810 --> 01:03:34,830 Now mu, in this case, is up. 899 01:03:34,830 --> 01:03:40,170 So mu dot B is positive, because mu and the magnetic field 900 01:03:40,170 --> 01:03:41,550 go in the same direction. 901 01:03:41,550 --> 01:03:43,610 So mu dot b is positive. 902 01:03:43,610 --> 01:03:47,720 So the force will be towards the direction-- that's 903 01:03:47,720 --> 01:03:51,220 what the gradient is-- that this becomes bigger. 904 01:03:51,220 --> 01:03:55,210 So it becomes bigger here, because as the field lines come 905 01:03:55,210 --> 01:03:58,570 together, that means stronger magnetic field. 906 01:03:58,570 --> 01:04:03,550 And therefore, mu dot B would be larger, so it's pointing down. 907 01:04:03,550 --> 01:04:07,790 If you have a magnetic field that is roughly 908 01:04:07,790 --> 01:04:11,010 in the z direction, there will be a simplification, 909 01:04:11,010 --> 01:04:13,020 as we will see very soon. 910 01:04:13,020 --> 01:04:16,480 So what did Stern and Gerlach do? 911 01:04:16,480 --> 01:04:21,110 Well, they were working with silver atoms. 912 01:04:21,110 --> 01:04:25,410 And silver atoms have 47 electrons, 913 01:04:25,410 --> 01:04:30,070 out of which 46 fill up the levels and equal 1, 914 01:04:30,070 --> 01:04:33,620 2, 3, and 4. 915 01:04:33,620 --> 01:04:41,010 Just one lone electron, a 5s electron, the 47th electron, 916 01:04:41,010 --> 01:04:45,810 it's a lonely electron that is out in a spherical shell, 917 01:04:45,810 --> 01:04:49,760 we know now with zero orbital angular momentum. 918 01:04:49,760 --> 01:04:52,130 It's an S state. 919 01:04:52,130 --> 01:04:58,110 And therefore, throwing silver atoms through your apparatus 920 01:04:58,110 --> 01:05:03,320 was pretty much the same thing as throwing electrons, 921 01:05:03,320 --> 01:05:05,810 because all these other electrons 922 01:05:05,810 --> 01:05:08,440 are tied up with each other. 923 01:05:08,440 --> 01:05:11,970 We know now one has spin up, one spin down. 924 01:05:11,970 --> 01:05:15,710 Nothing contributes, no angular momentum as a whole. 925 01:05:15,710 --> 01:05:19,090 And then you have this last electron unpaired. 926 01:05:19,090 --> 01:05:21,060 It has a spin. 927 01:05:21,060 --> 01:05:23,066 So it's like throwing spins. 928 01:05:26,130 --> 01:05:32,820 So moreover, throwing spins, as far as we're concerned, 929 01:05:32,820 --> 01:05:34,510 Stern and Gerlach wouldn't care. 930 01:05:34,510 --> 01:05:39,370 Because of these relations, it's throwing in dipole moments. 931 01:05:39,370 --> 01:05:42,910 And they would care about that because magnetic fields 932 01:05:42,910 --> 01:05:46,740 push dipole moments up or down. 933 01:05:46,740 --> 01:05:52,690 Therefore, what is the apparatus these people had? 934 01:05:52,690 --> 01:06:01,760 It was sort of like this, with an oven, 935 01:06:01,760 --> 01:06:04,580 and you produce some silver atoms 936 01:06:04,580 --> 01:06:10,450 that come out as a gas, a collimating slit. 937 01:06:14,490 --> 01:06:19,490 Then you put axes here-- we put axes just 938 01:06:19,490 --> 01:06:22,060 to know the components we're talking about. 939 01:06:22,060 --> 01:06:39,850 And then there's magnets, some sort of magnet like this, 940 01:06:39,850 --> 01:06:41,780 and the screen over there. 941 01:06:45,320 --> 01:06:49,285 So basically, this form of this magnet 942 01:06:49,285 --> 01:06:53,330 that I've tried to draw there, although it's not so easy, if I 943 01:06:53,330 --> 01:06:56,945 would take a cross-section it would look like this. 944 01:07:01,740 --> 01:07:03,866 So the magnetic field has a gradient. 945 01:07:06,430 --> 01:07:09,330 The lines bend a bit, so there's a gradient 946 01:07:09,330 --> 01:07:10,445 of the magnetic field. 947 01:07:10,445 --> 01:07:16,870 And it's mostly in the z direction, so z direction 948 01:07:16,870 --> 01:07:18,280 being pointed out here. 949 01:07:18,280 --> 01:07:19,590 So there's the magnetic field. 950 01:07:19,590 --> 01:07:21,800 The beam then comes here. 951 01:07:21,800 --> 01:07:24,045 And the question is, what do you get on this screen? 952 01:07:27,570 --> 01:07:33,278 Now, I have it a little too low. 953 01:07:33,278 --> 01:07:37,110 The beam comes there and goes through there. 954 01:07:37,110 --> 01:07:41,840 So the analysis that we would have to do 955 01:07:41,840 --> 01:07:47,100 is basically an analysis of the forces. 956 01:07:47,100 --> 01:07:52,020 And relatively, we don't care too much. 957 01:07:52,020 --> 01:07:55,870 The fact is that there's basically, 958 01:07:55,870 --> 01:07:59,190 because the magnetic field is mostly in the z direction 959 01:07:59,190 --> 01:08:01,570 and varies in z direction, there will 960 01:08:01,570 --> 01:08:04,940 be a force basically in the z direction. 961 01:08:04,940 --> 01:08:05,790 Why is that? 962 01:08:05,790 --> 01:08:07,720 Because you take this, and you say, 963 01:08:07,720 --> 01:08:15,870 well, that's roughly mu z Bz, because it's mostly 964 01:08:15,870 --> 01:08:18,120 a magnetic field in the z direction. 965 01:08:18,120 --> 01:08:24,670 And mu is a constant, so it's basically gradient of Bz. 966 01:08:24,670 --> 01:08:26,029 Now, that's a vector. 967 01:08:26,029 --> 01:08:30,160 But we're saying also most of the gradient of Bz 968 01:08:30,160 --> 01:08:37,109 is in the z direction, so it's basically dBz dz. 969 01:08:45,569 --> 01:08:47,830 Now, there is some bending of the lines, 970 01:08:47,830 --> 01:08:50,750 so there's a little bit of gradient in other directions. 971 01:08:50,750 --> 01:08:54,220 But people have gone through the analysis, 972 01:08:54,220 --> 01:08:57,790 and they don't matter for any calculation that you do. 973 01:08:57,790 --> 01:09:00,830 They actually average out. 974 01:09:00,830 --> 01:09:04,850 So roughly, this gradient is in the z direction. 975 01:09:04,850 --> 01:09:09,040 I'm sorry, the gradient is supposed to be a vector. 976 01:09:09,040 --> 01:09:11,600 So you get a force in the z direction. 977 01:09:11,600 --> 01:09:16,350 And therefore, the thing that people expected 978 01:09:16,350 --> 01:09:17,870 was the following. 979 01:09:17,870 --> 01:09:24,200 You know, here comes one atom, and it has its magnetic moment. 980 01:09:24,200 --> 01:09:28,420 Well, they've all been boiling in this oven for a while. 981 01:09:28,420 --> 01:09:29,740 They're very disordered. 982 01:09:29,740 --> 01:09:33,055 Some have a z component of magnetic-- the magnetic moment 983 01:09:33,055 --> 01:09:37,029 is pointing like that, so they have some component, some down. 984 01:09:37,029 --> 01:09:37,880 Some are here. 985 01:09:37,880 --> 01:09:39,569 They have no component. 986 01:09:39,569 --> 01:09:44,260 It's all Boltzmann distributed all over the directions. 987 01:09:44,260 --> 01:09:49,870 Therefore, you're going to get a smudge like this. 988 01:09:49,870 --> 01:09:53,240 Some ones are going to be deflected a lot because they 989 01:09:53,240 --> 01:09:57,030 have lots of z component of angular 990 01:09:57,030 --> 01:10:00,240 momentum or z magnetic moment. 991 01:10:00,240 --> 01:10:04,720 Others are going to be deflected little. 992 01:10:04,720 --> 01:10:07,590 So this was the classical expectation. 993 01:10:07,590 --> 01:10:11,080 And the shock was that you got, actually, 994 01:10:11,080 --> 01:10:16,010 one peak here, an empty space, and another peak there. 995 01:10:16,010 --> 01:10:17,950 That was called space quantization. 996 01:10:22,720 --> 01:10:26,790 Stern and Gerlach worked with a magnetic field 997 01:10:26,790 --> 01:10:35,190 that was of about 0.1 tesla, a tenth of a tesla. 998 01:10:35,190 --> 01:10:38,600 And in their experiment, the space quantization, 999 01:10:38,600 --> 01:10:42,680 this difference, was 1/5 of a millimeter. 1000 01:10:45,740 --> 01:10:51,110 So not that big, but it was a clear thing. 1001 01:10:51,110 --> 01:10:53,700 It was there. 1002 01:10:53,700 --> 01:11:00,350 So everybody was confused. 1003 01:11:00,350 --> 01:11:04,340 They thought it was the orbital spin, angular momentum that 1004 01:11:04,340 --> 01:11:06,600 somehow had been measured. 1005 01:11:06,600 --> 01:11:08,880 At the end of the day, that was wrong. 1006 01:11:08,880 --> 01:11:10,370 It couldn't have been that. 1007 01:11:10,370 --> 01:11:13,400 People understood the Bohr atom, realized, no, there's 1008 01:11:13,400 --> 01:11:15,220 no angular momentum there. 1009 01:11:15,220 --> 01:11:17,810 The idea of the spin came back, and you 1010 01:11:17,810 --> 01:11:20,820 would have to do a calculation to determine 1011 01:11:20,820 --> 01:11:23,030 what is the value of the spin. 1012 01:11:23,030 --> 01:11:28,960 So the exact factor took a while to get it right. 1013 01:11:28,960 --> 01:11:36,660 But with the idea that mu z is equal to minus 2 Bohr magenton 1014 01:11:36,660 --> 01:11:39,250 Sz over h bar, which we wrote before. 1015 01:11:42,330 --> 01:11:46,900 Well, mu z, if you know the strength 1016 01:11:46,900 --> 01:11:51,350 of your magnetic field, you can calculate the deflections. 1017 01:11:51,350 --> 01:11:53,030 You know what mu B is. 1018 01:11:53,030 --> 01:11:57,040 So therefore, you get the value for Sz over h. 1019 01:11:57,040 --> 01:12:00,540 And experiments suggested that Sz over h 1020 01:12:00,540 --> 01:12:04,165 was either plus or minus 1/2. 1021 01:12:08,000 --> 01:12:15,280 And this kind of particle, it has Sz over h bar equal plus 1022 01:12:15,280 --> 01:12:20,970 or minus 1/2, is called the spin-1/2 particle. 1023 01:12:20,970 --> 01:12:26,400 So again, from this equation, this can be measured. 1024 01:12:29,930 --> 01:12:34,725 And you then use this, and you get this value. 1025 01:12:39,800 --> 01:12:43,160 So the experiment is a little confusing. 1026 01:12:43,160 --> 01:12:44,760 Why did this happen? 1027 01:12:44,760 --> 01:12:48,020 And how do we think of it quantum mechanically? 1028 01:12:48,020 --> 01:12:53,340 Now 804 sort of began with these kind of things. 1029 01:12:53,340 --> 01:12:56,680 And you know by now that what's happening 1030 01:12:56,680 --> 01:13:01,090 is the following, that somehow, mathematically, every state is 1031 01:13:01,090 --> 01:13:04,000 a superposition of a spin up and a spin down. 1032 01:13:04,000 --> 01:13:06,410 So every particle that goes there 1033 01:13:06,410 --> 01:13:10,230 has half of its brain in the spin up and half of its brain 1034 01:13:10,230 --> 01:13:11,630 in the spin down. 1035 01:13:11,630 --> 01:13:14,170 And then as it goes through the magnetic field, 1036 01:13:14,170 --> 01:13:17,990 this thing splits, but each particle is in both beams 1037 01:13:17,990 --> 01:13:19,880 still. 1038 01:13:19,880 --> 01:13:22,140 And they just have this dual existence 1039 01:13:22,140 --> 01:13:25,130 until there's a screen and there's detectors. 1040 01:13:25,130 --> 01:13:27,460 So they have to decide what happens, and then 1041 01:13:27,460 --> 01:13:33,260 either collapses in the top beam or lower beam. 1042 01:13:33,260 --> 01:13:35,630 Nothing happens until you put the screen. 1043 01:13:35,630 --> 01:13:38,790 That's what we think now is the interpretation 1044 01:13:38,790 --> 01:13:39,980 of this experiment. 1045 01:13:39,980 --> 01:13:43,720 But let's use the last few minutes 1046 01:13:43,720 --> 01:13:50,440 to just write this in terms of boxes and get the right ideas. 1047 01:13:50,440 --> 01:13:57,590 So instead of drawing all that stuff, 1048 01:13:57,590 --> 01:14:01,620 we'll draw a little box called a z hat 1049 01:14:01,620 --> 01:14:04,690 box, a Stern-Gerlach apparatus. 1050 01:14:04,690 --> 01:14:10,350 In comes a beam, out would come two beams, 1051 01:14:10,350 --> 01:14:17,150 Sz equal h bar over 2 and Sz equal minus h bar over 2. 1052 01:14:17,150 --> 01:14:19,980 And the convention is that the plus goes up 1053 01:14:19,980 --> 01:14:21,840 and the minus goes down, which I think 1054 01:14:21,840 --> 01:14:24,555 is probably consistent with that drawing. 1055 01:14:27,470 --> 01:14:29,980 And that's the Stern-Gerlach apparatus. 1056 01:14:29,980 --> 01:14:34,150 It measures Sz, and it splits the beam. 1057 01:14:34,150 --> 01:14:36,510 Each particle goes into both beams 1058 01:14:36,510 --> 01:14:38,520 until there's a device that measures 1059 01:14:38,520 --> 01:14:41,270 and decides where you go. 1060 01:14:41,270 --> 01:14:44,440 So you can do the following arrangements. 1061 01:14:44,440 --> 01:14:50,590 So here's arrangement number 1, a Stern-Gerlach device with z. 1062 01:14:50,590 --> 01:14:54,000 Then you block the lower one and let 1063 01:14:54,000 --> 01:15:03,650 the top one go as Sz equal h bar over 2. 1064 01:15:03,650 --> 01:15:08,710 And then you put another Stern-Gerlach machine, z hat, 1065 01:15:08,710 --> 01:15:12,220 that has two outputs. 1066 01:15:12,220 --> 01:15:15,270 And then you ask, what's going to happen? 1067 01:15:15,270 --> 01:15:19,680 And the experiment can be done and, actually, there's 1068 01:15:19,680 --> 01:15:23,720 nothing here coming out, and all the particles come out here 1069 01:15:23,720 --> 01:15:26,250 with Sz equal h bar over 2. 1070 01:15:30,230 --> 01:15:34,280 What are we going to learn from this? 1071 01:15:34,280 --> 01:15:36,710 In our picture of quantum mechanics, 1072 01:15:36,710 --> 01:15:39,450 we're going to think of this as there 1073 01:15:39,450 --> 01:15:43,700 are states of the electron that have-- 1074 01:15:43,700 --> 01:15:46,610 and I will write them with respect 1075 01:15:46,610 --> 01:15:51,950 to z-- they have plus h bar over 2 1076 01:15:51,950 --> 01:15:58,060 and states that have minus h bar over 2. 1077 01:15:58,060 --> 01:16:03,590 And what we will think is that these are really old basis 1078 01:16:03,590 --> 01:16:09,080 states, that any other state, even one that points along x, 1079 01:16:09,080 --> 01:16:11,950 is a superposition of those two. 1080 01:16:11,950 --> 01:16:15,030 This is a very incredible physical assumption. 1081 01:16:15,030 --> 01:16:20,310 It's saying this system is a 2-dimensional complex vector 1082 01:16:20,310 --> 01:16:24,850 space, two vectors, two unit, two basis vectors. 1083 01:16:24,850 --> 01:16:28,860 And from those two, all linear combinations that are infinite 1084 01:16:28,860 --> 01:16:33,860 represent all possible spin configurations. 1085 01:16:33,860 --> 01:16:36,090 And what is this saying? 1086 01:16:36,090 --> 01:16:41,060 Well, as we will translate it into algebra, 1087 01:16:41,060 --> 01:16:45,480 we will say that, look, here is a state plus. 1088 01:16:45,480 --> 01:16:49,380 And when you try to measure, if it had any minus component, 1089 01:16:49,380 --> 01:16:50,740 it had nothing. 1090 01:16:50,740 --> 01:16:55,410 So we will state that as saying that these states are 1091 01:16:55,410 --> 01:16:56,330 orthogonal. 1092 01:16:56,330 --> 01:17:00,590 The minus state and the plus state have zero overlap. 1093 01:17:03,330 --> 01:17:05,950 They are orthogonal basis states. 1094 01:17:05,950 --> 01:17:10,910 And, for example, well, you could also do it this way. 1095 01:17:10,910 --> 01:17:12,800 That would also be 0. 1096 01:17:12,800 --> 01:17:17,540 And you could also say that z plus 1097 01:17:17,540 --> 01:17:23,370 and z plus is 1, because every state that came in 1098 01:17:23,370 --> 01:17:26,040 as a plus came out as a plus. 1099 01:17:26,040 --> 01:17:27,910 They had perfect overlap. 1100 01:17:27,910 --> 01:17:32,130 So these are two orthonormal basis vectors. 1101 01:17:32,130 --> 01:17:34,395 That's what this seems to suggest. 1102 01:17:34,395 --> 01:17:36,940 And it's a little strange, if you think, 1103 01:17:36,940 --> 01:17:41,950 because there's a clash between arrows 1104 01:17:41,950 --> 01:17:45,300 and the notion of orthonormality. 1105 01:17:45,300 --> 01:17:48,110 In 3-dimensional vectors, you think 1106 01:17:48,110 --> 01:17:50,489 of this vector being orthogonal to this. 1107 01:17:50,489 --> 01:17:52,030 But you wouldn't think of this vector 1108 01:17:52,030 --> 01:17:54,280 as being orthogonal to that one. 1109 01:17:54,280 --> 01:18:00,130 And here is the spin is up, and this is the spin down. 1110 01:18:00,130 --> 01:18:01,600 And those two are orthogonal. 1111 01:18:01,600 --> 01:18:03,450 You say, no, they're anti-parallel. 1112 01:18:03,450 --> 01:18:04,780 They're not orthogonal. 1113 01:18:04,780 --> 01:18:06,820 No, they are orthogonal. 1114 01:18:06,820 --> 01:18:12,070 And that's the endlessly confusing thing about spin-1/2. 1115 01:18:12,070 --> 01:18:16,830 So these states, their pictures of the spins are arrows. 1116 01:18:16,830 --> 01:18:20,020 But don't think that those arrows and the dot product 1117 01:18:20,020 --> 01:18:23,370 give you the orthogonality, because this is up and down. 1118 01:18:23,370 --> 01:18:26,280 If you would be doing the dot product of an up and down 1119 01:18:26,280 --> 01:18:28,000 vector, you would not get 0. 1120 01:18:28,000 --> 01:18:29,870 But this is 0. 1121 01:18:29,870 --> 01:18:31,860 Then you do the following experiment. 1122 01:18:36,550 --> 01:18:38,390 So let's do the next one. 1123 01:18:42,820 --> 01:18:47,680 And the next one is, again, the z filter. 1124 01:18:47,680 --> 01:18:50,920 Take this one, block it. 1125 01:18:50,920 --> 01:18:53,025 Then you put an x filter. 1126 01:18:55,610 --> 01:18:58,550 And what actually happens is that you would get states 1127 01:18:58,550 --> 01:19:05,570 with Sx, now, h bar over 2 and Sx equal minus h bar over 2, 1128 01:19:05,570 --> 01:19:07,070 because it's an x filter. 1129 01:19:07,070 --> 01:19:10,490 The magnetic field is a line in the x direction. 1130 01:19:10,490 --> 01:19:16,630 Now, all these things have Sz equal h bar over 2. 1131 01:19:16,630 --> 01:19:18,860 And what happens in the experiment 1132 01:19:18,860 --> 01:19:21,860 is that 50% of the particles come out here 1133 01:19:21,860 --> 01:19:23,790 and 50% come out there. 1134 01:19:23,790 --> 01:19:29,280 So a spin state along the x direction 1135 01:19:29,280 --> 01:19:33,340 has some overlap with a spin state along the z direction. 1136 01:19:33,340 --> 01:19:38,190 Normal vectors, a z vector and an x vector, are orthogonal. 1137 01:19:38,190 --> 01:19:40,470 Not here for spins. 1138 01:19:40,470 --> 01:19:44,350 The spin pointing in the z and the spin pointing in the x 1139 01:19:44,350 --> 01:19:46,100 are not orthogonal states. 1140 01:19:46,100 --> 01:19:47,890 They have overlaps. 1141 01:19:47,890 --> 01:19:53,690 So this means that, for example, the x plus state and the z 1142 01:19:53,690 --> 01:19:58,990 plus state have an overlap. 1143 01:19:58,990 --> 01:20:02,840 This is notations that-- we're going to be precise later. 1144 01:20:02,840 --> 01:20:11,170 But the same thing with the x minus state, it has an overlap, 1145 01:20:11,170 --> 01:20:14,140 and somehow they're about the same. 1146 01:20:14,140 --> 01:20:21,920 Finally, the last experiment is this, z hat, block again, 1147 01:20:21,920 --> 01:20:26,640 x hat, but this time block one. 1148 01:20:26,640 --> 01:20:32,040 So here is a state with Sx equals minus h bar over 2. 1149 01:20:32,040 --> 01:20:35,830 Here is a state with Sz equal h bar over 2. 1150 01:20:35,830 --> 01:20:38,400 And now you put the z machine again. 1151 01:20:40,980 --> 01:20:44,160 And what happens? 1152 01:20:44,160 --> 01:20:46,330 Well, there's two options. 1153 01:20:46,330 --> 01:20:48,520 People who were inventing quantum mechanics 1154 01:20:48,520 --> 01:20:50,190 no wonder thought about them. 1155 01:20:50,190 --> 01:20:55,290 Here they could say, look, I filtered this thing, 1156 01:20:55,290 --> 01:21:01,100 and now all these electrons have Sz equal h bar over 2. 1157 01:21:01,100 --> 01:21:06,340 And now all these electrons have Sx equal minus h bar over 2. 1158 01:21:06,340 --> 01:21:08,830 Maybe, actually, all these electrons 1159 01:21:08,830 --> 01:21:13,420 have both Sz equal h over 2 and that 1160 01:21:13,420 --> 01:21:15,090 because I filtered it twice. 1161 01:21:15,090 --> 01:21:16,850 So it maybe satisfies both. 1162 01:21:16,850 --> 01:21:20,530 So if all these electrons would have Sz equals 1163 01:21:20,530 --> 01:21:23,690 h over 2 and this, then you would only 1164 01:21:23,690 --> 01:21:26,080 get something from the top one. 1165 01:21:26,080 --> 01:21:28,350 But no, that's not what happens. 1166 01:21:28,350 --> 01:21:30,330 You get in both. 1167 01:21:30,330 --> 01:21:36,870 So somehow, the memory of these states coming from Sz 1168 01:21:36,870 --> 01:21:39,260 equals h over 2 has been destroyed 1169 01:21:39,260 --> 01:21:41,020 by the time it turned into a state 1170 01:21:41,020 --> 01:21:44,130 with Sx equal minus h over 2. 1171 01:21:44,130 --> 01:21:48,970 And a state cannot have simultaneously this and that. 1172 01:21:48,970 --> 01:21:54,840 That's two properties, because you get 50% here and 50% there. 1173 01:21:54,840 --> 01:21:57,760 So we'll discuss next time a little more 1174 01:21:57,760 --> 01:22:00,500 about these relations and how can the states 1175 01:22:00,500 --> 01:22:04,480 be related, the ones that we use as the basis 1176 01:22:04,480 --> 01:22:07,590 vectors and all the others along x and others 1177 01:22:07,590 --> 01:22:09,790 that we could build some other way. 1178 01:22:09,790 --> 01:22:10,430 All right. 1179 01:22:10,430 --> 01:22:11,340 See you next week. 1180 01:22:11,340 --> 01:22:18,110 There's office hours today, 5:00 to 6:00, Monday, 4:30 to 5:30.