1 00:00:00,521 --> 00:00:01,020 OK. 2 00:00:01,020 --> 00:00:06,580 So that's our introduction to the subject. 3 00:00:06,580 --> 00:00:08,820 Now, we have to get going. 4 00:00:08,820 --> 00:00:16,860 We have to explore how to set up this scattering problem. 5 00:00:16,860 --> 00:00:21,990 So equations that we need to solve. 6 00:00:21,990 --> 00:00:23,640 Well, what are the equations? 7 00:00:23,640 --> 00:00:26,910 We will have a Hamiltonian, which 8 00:00:26,910 --> 00:00:34,280 is p squared over 2m plus a potential v of r. 9 00:00:37,200 --> 00:00:41,040 Need not be yet a central potential. 10 00:00:41,040 --> 00:00:44,850 As usual, we will think of a wave function that 11 00:00:44,850 --> 00:00:50,060 depends on r and t that will be written 12 00:00:50,060 --> 00:00:58,410 as a psi that depends on r times e to the minus iet over h bar. 13 00:00:58,410 --> 00:01:01,500 An energy eigenstate. 14 00:01:01,500 --> 00:01:04,980 And then the equation that you have to solve, 15 00:01:04,980 --> 00:01:13,570 the time independent the Schrodinger equation, becomes 16 00:01:13,570 --> 00:01:21,730 minus h squared over 2m Laplacian 17 00:01:21,730 --> 00:01:34,730 plus v of r acting on psi of r is equal to e psi of r. 18 00:01:34,730 --> 00:01:39,260 So these are the equations that you have seen already 19 00:01:39,260 --> 00:01:42,020 endlessly in quantum mechanics. 20 00:01:42,020 --> 00:01:46,220 These are equations we write to get warmed up, 21 00:01:46,220 --> 00:01:50,910 and we just repeat for ourselves that we 22 00:01:50,910 --> 00:01:53,310 have a Hamiltonian in the picture where 23 00:01:53,310 --> 00:01:57,630 the particles are scattering off of a central potential. 24 00:01:57,630 --> 00:02:00,300 Not a central potential, in fact, 25 00:02:00,300 --> 00:02:03,240 just often of a potential. 26 00:02:03,240 --> 00:02:05,520 Work with energy eigenstates, and these 27 00:02:05,520 --> 00:02:08,910 are going to be the equation for the energy eigenstates. 28 00:02:08,910 --> 00:02:13,140 Now, let's write the first picture of the scattering 29 00:02:13,140 --> 00:02:17,550 process as some sort of target here 30 00:02:17,550 --> 00:02:24,810 or potential and particles that come in 31 00:02:24,810 --> 00:02:28,690 and scatter off of this potential. 32 00:02:28,690 --> 00:02:34,350 So we're looking for energy eigenstates. 33 00:02:34,350 --> 00:02:41,400 And we will try to identify our energy eigenstates, 34 00:02:41,400 --> 00:02:44,760 and what we're going to assume is that this potential 35 00:02:44,760 --> 00:02:48,895 is finite range as well. 36 00:02:48,895 --> 00:02:49,395 Range. 37 00:02:53,540 --> 00:02:56,150 Finite range we can deal with potentials 38 00:02:56,150 --> 00:02:59,450 that fall off relatively fast. 39 00:02:59,450 --> 00:03:03,640 Already, the coolant potential doesn't fall off that fast, 40 00:03:03,640 --> 00:03:06,070 but potentials that fall faster and the cooler potentials 41 00:03:06,070 --> 00:03:08,840 are potentials that are just localized, 42 00:03:08,840 --> 00:03:14,430 which is pretty common if you have an atom 43 00:03:14,430 --> 00:03:16,730 and you scatter things off of it. 44 00:03:16,730 --> 00:03:20,810 If it's a neutral atom, the potential due to the atom 45 00:03:20,810 --> 00:03:24,770 is zero outside the atom, but as soon as you go inside the atom 46 00:03:24,770 --> 00:03:29,270 you start to experience all the electrical forces that 47 00:03:29,270 --> 00:03:32,060 are due to the nucleus and the electrons. 48 00:03:32,060 --> 00:03:37,210 So a finite range potential, and we're 49 00:03:37,210 --> 00:03:40,260 going to think of solutions that-- 50 00:03:40,260 --> 00:03:44,940 OK, away from the finite range our plane waves, 51 00:03:44,940 --> 00:03:47,980 solutions of constant energy specified 52 00:03:47,980 --> 00:03:53,960 with perhaps some momentum, so we will think of e as h 53 00:03:53,960 --> 00:03:57,460 squared k squared over 2m. 54 00:04:01,410 --> 00:04:06,600 This is a way of thinking of the energy of a given energy 55 00:04:06,600 --> 00:04:07,500 eigenstate. 56 00:04:07,500 --> 00:04:11,830 So it's another label for the energy. 57 00:04:11,830 --> 00:04:13,920 This one, it looks like I've done something 58 00:04:13,920 --> 00:04:19,769 but I haven't done much except to begin an intuition process 59 00:04:19,769 --> 00:04:22,230 in your head in which somehow these 60 00:04:22,230 --> 00:04:27,240 are going to be related to energy eigenstates that 61 00:04:27,240 --> 00:04:34,440 have some momentum as they propagate all over space. 62 00:04:34,440 --> 00:04:38,540 So if I write that, I could just simply put 63 00:04:38,540 --> 00:04:41,900 this on the left hand side and get an equation 64 00:04:41,900 --> 00:04:45,200 that is kind of nicer. 65 00:04:45,200 --> 00:04:52,040 Minus h squared over 2m Laplacian 66 00:04:52,040 --> 00:05:04,080 squared plus k squared plus v of r psi of r equals zero. 67 00:05:13,490 --> 00:05:25,770 OK, it's not really a matter scattering 68 00:05:25,770 --> 00:05:30,090 of solving this equation at this moment. 69 00:05:30,090 --> 00:05:34,740 There is infinitely many solutions of this equation, 70 00:05:34,740 --> 00:05:38,250 and most of them may not be relevant for us. 71 00:05:38,250 --> 00:05:41,640 We're not trying to find every solution of this equation. 72 00:05:41,640 --> 00:05:43,740 We're trying to find solutions that 73 00:05:43,740 --> 00:05:46,200 have something to do with physics, 74 00:05:46,200 --> 00:05:49,710 and you've done that when you had 75 00:05:49,710 --> 00:05:51,760 potentials in one dimension. 76 00:05:51,760 --> 00:05:55,680 And that intuition is going to prove invaluable. 77 00:05:55,680 --> 00:05:58,440 So when you have a potential in one dimension, you didn't say, 78 00:05:58,440 --> 00:06:01,170 OK I'm going to find all the energy eigenstates. 79 00:06:01,170 --> 00:06:04,440 You said, let's search for things 80 00:06:04,440 --> 00:06:09,150 that are reasonable and physically motivated, 81 00:06:09,150 --> 00:06:13,380 so you put in a wave that was moving in 82 00:06:13,380 --> 00:06:17,550 and you said, OK, this wave is a solution 83 00:06:17,550 --> 00:06:21,630 until it reaches this point where it just stops being 84 00:06:21,630 --> 00:06:23,850 a solution and you need more. 85 00:06:23,850 --> 00:06:31,710 If you put in this wave, you will generate a reflected wave 86 00:06:31,710 --> 00:06:34,900 and a transmitted wave. 87 00:06:34,900 --> 00:06:38,770 Those two waves are going to be generated, 88 00:06:38,770 --> 00:06:42,410 and then you write an ansatz for this wave, 89 00:06:42,410 --> 00:06:48,750 some coefficient a e to the ikx, b e to the minus ikx, c 90 00:06:48,750 --> 00:06:51,690 e to the other, and then you solve your equation. 91 00:06:51,690 --> 00:07:00,690 So we need to do the same thing with this kind of equation 92 00:07:00,690 --> 00:07:02,280 and this kind of potential. 93 00:07:02,280 --> 00:07:06,540 We have to set up some sort of situation 94 00:07:06,540 --> 00:07:10,920 where we have the physics intuition of a wave that 95 00:07:10,920 --> 00:07:16,620 is coming in and then whatever the system will do to that wave 96 00:07:16,620 --> 00:07:19,365 to upgrade it into a full solution. 97 00:07:22,220 --> 00:07:27,880 So that's what we want to do here in analogy to that thing. 98 00:07:27,880 --> 00:07:30,070 This could be called the incoming wave, 99 00:07:30,070 --> 00:07:33,100 and this whole thing the reflected and the transmitted 100 00:07:33,100 --> 00:07:36,100 could be called the scattered wave, the thing that 101 00:07:36,100 --> 00:07:40,430 gets produced by the scattering process. 102 00:07:40,430 --> 00:07:48,100 So if you had that there is lots of solutions of that equation, 103 00:07:48,100 --> 00:07:55,720 if v was identical to zero, if you had no potential, 104 00:07:55,720 --> 00:07:59,680 you could have lots of solutions, 105 00:07:59,680 --> 00:08:03,880 because in fact if the potential is not zero, 106 00:08:03,880 --> 00:08:08,950 plane waves are always solutions without any potential. 107 00:08:08,950 --> 00:08:11,860 Particles that move as plane waves so if equal 108 00:08:11,860 --> 00:08:25,010 zero, plane waves of the form psi equal e to the ikx 109 00:08:25,010 --> 00:08:39,779 are solutions with k equal the square root of k dot k. 110 00:08:45,420 --> 00:08:48,358 Or with k squared equals k dot k. 111 00:08:56,010 --> 00:08:58,855 Plane waves are always solutions of this equation. 112 00:09:01,840 --> 00:09:08,440 So if plane waves are solutions of this equation for v 113 00:09:08,440 --> 00:09:12,960 equal to zero, this is the same thing 114 00:09:12,960 --> 00:09:18,990 as saying here that ae to the ikx 115 00:09:18,990 --> 00:09:22,650 is a solution of this equation as long as you 116 00:09:22,650 --> 00:09:24,060 don't hit the potential. 117 00:09:27,130 --> 00:09:30,310 So here, we're going to do something quite similar. 118 00:09:30,310 --> 00:09:35,070 We're going to say that we're going to put in an incident 119 00:09:35,070 --> 00:09:48,320 wave function, and I will instead of writing psi, 120 00:09:48,320 --> 00:09:51,760 I will call it 5x. 121 00:09:51,760 --> 00:09:57,895 The incident wave function 5x is going to be just e to the ikz. 122 00:10:04,390 --> 00:10:05,620 So it's a wave function. 123 00:10:05,620 --> 00:10:09,500 I call it phi to distinguish it from psi. 124 00:10:09,500 --> 00:10:13,180 Psi in general is a full solution 125 00:10:13,180 --> 00:10:16,550 of the Schrodinger equation. 126 00:10:16,550 --> 00:10:19,450 That's our understanding of psi. 127 00:10:19,450 --> 00:10:24,020 So phi, it reminds you that well, it's some wave function. 128 00:10:24,020 --> 00:10:25,740 I'm not sure it's a solution. 129 00:10:25,740 --> 00:10:29,710 In fact, it probably is not the solution as soon 130 00:10:29,710 --> 00:10:34,540 as you have the potential different from zero. 131 00:10:34,540 --> 00:10:38,110 So is this common, we forget that ksv equals zero, 132 00:10:38,110 --> 00:10:43,450 and now we put an incident wave function which is of this form. 133 00:10:43,450 --> 00:10:48,790 This solves the equation as long as you're away 134 00:10:48,790 --> 00:10:50,710 from the potential. 135 00:10:50,710 --> 00:11:00,460 This is true, it's a solution of the Schrodinger equation 136 00:11:00,460 --> 00:11:07,610 away from v of r. 137 00:11:07,610 --> 00:11:11,960 Away from v of r means wherever v of r is equal zero, 138 00:11:11,960 --> 00:11:14,900 you have a solution. 139 00:11:14,900 --> 00:11:19,460 Nevertheless, so if we call the range of the potential-- 140 00:11:19,460 --> 00:11:22,340 let's call the range of the potential finite range a-- 141 00:11:25,320 --> 00:11:29,430 that is to take that if there is an origin here 142 00:11:29,430 --> 00:11:34,530 up to a radius a, there is some potential and beyond the radius 143 00:11:34,530 --> 00:11:37,930 a the potential vanishes. 144 00:11:37,930 --> 00:11:42,550 So this definitely works. 145 00:11:42,550 --> 00:11:54,960 It's all ks away from vr or as long as r is greater than a 146 00:11:54,960 --> 00:11:57,540 for whatever value of z you take. 147 00:11:57,540 --> 00:12:05,650 This is fine, so here is our wave, 148 00:12:05,650 --> 00:12:09,380 and now this is just the incident wave. 149 00:12:09,380 --> 00:12:12,560 This is not going to be the whole solution. 150 00:12:12,560 --> 00:12:15,860 Just like in the one dimensional case, there must be more. 151 00:12:15,860 --> 00:12:17,630 So what is there more? 152 00:12:17,630 --> 00:12:21,670 And our challenge to begin with this problem 153 00:12:21,670 --> 00:12:26,700 is to set up what else could there be. 154 00:12:26,700 --> 00:12:32,390 So looking at it, you'd say, all right. 155 00:12:32,390 --> 00:12:34,700 So the thing comes in. 156 00:12:34,700 --> 00:12:37,380 If there is scattering, particles 157 00:12:37,380 --> 00:12:41,130 are sometimes going to go off in various directions. 158 00:12:41,130 --> 00:12:46,760 So the outgoing wave, here there were outgoing waves 159 00:12:46,760 --> 00:12:48,890 reflected and transmitted. 160 00:12:48,890 --> 00:12:53,000 The outgoing wave in the three dimensional scattering problem 161 00:12:53,000 --> 00:12:58,910 should be some sort of spherical wave moving away from r 162 00:12:58,910 --> 00:13:02,420 equals zero, which is the origin. 163 00:13:02,420 --> 00:13:05,540 That should be the other wave that I would write. 164 00:13:05,540 --> 00:13:10,260 So my ansatz should be that there 165 00:13:10,260 --> 00:13:16,510 is some sort of spherical wave that is moving away. 166 00:13:16,510 --> 00:13:29,750 So to complete this with a spherical outgoing wave. 167 00:13:33,590 --> 00:13:40,910 So while here this is a plane wave moving 168 00:13:40,910 --> 00:13:43,880 in the direction of the vector k, 169 00:13:43,880 --> 00:13:50,420 if I want to write the spherical wave, I would write e to the i 170 00:13:50,420 --> 00:13:51,050 just kr. 171 00:13:54,490 --> 00:13:59,230 E to the ikr is spherically symmetric, 172 00:13:59,230 --> 00:14:02,270 and it propagates radiantly out. 173 00:14:02,270 --> 00:14:04,660 If you remember as usual that you 174 00:14:04,660 --> 00:14:12,220 have e to the minus iet over h bar, so you have kr minus et, 175 00:14:12,220 --> 00:14:16,720 that is a wave that propagates radially out. 176 00:14:16,720 --> 00:14:24,150 So maybe this is kind of the scattered wave. 177 00:14:24,150 --> 00:14:29,190 This e to the ikr moving out everywhere 178 00:14:29,190 --> 00:14:30,735 would be your scattered wave. 179 00:14:35,390 --> 00:14:39,830 If that is the scattered wave, remember 180 00:14:39,830 --> 00:14:44,250 the scattered wave should solve the Schrodinger equation. 181 00:14:44,250 --> 00:14:46,280 In fact, the sum of these two should 182 00:14:46,280 --> 00:14:48,450 solve the scattering equation. 183 00:14:48,450 --> 00:14:50,390 On the other hand, we've seen that this 184 00:14:50,390 --> 00:14:55,370 solves it as long as you're away from the potential, 185 00:14:55,370 --> 00:14:58,100 and therefore this should also solve it 186 00:14:58,100 --> 00:15:00,290 if you're away from the potential. 187 00:15:03,450 --> 00:15:07,340 So I ask you, do you think this solves the Schrodinger equation 188 00:15:07,340 --> 00:15:09,170 when you're away from the potential? 189 00:15:14,140 --> 00:15:17,840 Would e to the ikr solve the equation? 190 00:15:17,840 --> 00:15:21,240 Well for that, you would need that if you're away 191 00:15:21,240 --> 00:15:26,250 from the potential, do you have Laplacian of e 192 00:15:26,250 --> 00:15:30,680 to the ikr roughly equals zero? 193 00:15:34,540 --> 00:15:35,190 Is that true? 194 00:15:44,550 --> 00:15:46,850 Would it solve it. 195 00:15:46,850 --> 00:15:47,520 No. 196 00:15:47,520 --> 00:15:48,630 It doesn't solve it. 197 00:15:48,630 --> 00:15:52,620 Doesn't even come close to solving it. 198 00:15:52,620 --> 00:15:57,990 It's pretty bad, but the reason it's bad is physically clear. 199 00:15:57,990 --> 00:16:04,890 This wave as it expands out must become weaker and weaker 200 00:16:04,890 --> 00:16:09,720 so that the probability flux remains constant. 201 00:16:09,720 --> 00:16:11,910 You know, you don't want an accumulation 202 00:16:11,910 --> 00:16:16,110 of probability between a shell at one kilometer and a shell 203 00:16:16,110 --> 00:16:17,230 at two kilometers. 204 00:16:17,230 --> 00:16:22,190 So whatever flux is going out from the shell in one kilometer 205 00:16:22,190 --> 00:16:24,930 should be going out of the bigger shell. 206 00:16:24,930 --> 00:16:29,280 So therefore, it should fall off with r. 207 00:16:29,280 --> 00:16:30,300 Oh, I'm sorry. 208 00:16:30,300 --> 00:16:34,320 I didn't write this well. 209 00:16:34,320 --> 00:16:39,090 So if you are going to have this to be 210 00:16:39,090 --> 00:16:43,320 a solution of the Schrodinger equation outside of vr 211 00:16:43,320 --> 00:16:49,250 equals zero, you should have Laplacian k squared 212 00:16:49,250 --> 00:16:51,570 of this thing equal to zero. 213 00:16:51,570 --> 00:16:55,210 So if this is equal to zero and the potential is equal to zero, 214 00:16:55,210 --> 00:16:57,480 the whole thing is equal to zero. 215 00:16:57,480 --> 00:17:00,030 So we need this to hold. 216 00:17:00,030 --> 00:17:03,880 But even this one, of course, is not true. 217 00:17:03,880 --> 00:17:06,010 It is just absolutely not true. 218 00:17:06,010 --> 00:17:09,599 The one that works is the following. 219 00:17:12,690 --> 00:17:23,329 Laplacian plus k squared of e to the ikr over r 220 00:17:23,329 --> 00:17:28,830 is equal to zero for r different from zero. 221 00:17:28,830 --> 00:17:32,750 This is a computation I think you guys have 222 00:17:32,750 --> 00:17:35,390 done before when you were studying 223 00:17:35,390 --> 00:17:37,880 the Hermiticity of p squared. 224 00:17:37,880 --> 00:17:40,310 You ended up doing this kind of things. 225 00:17:40,310 --> 00:17:45,860 This Laplacian produces a delta function at r equals zero, 226 00:17:45,860 --> 00:17:49,620 but r equals zero is not the place we're interested in. 227 00:17:49,620 --> 00:17:53,780 We're trying to find how the waves look away 228 00:17:53,780 --> 00:17:57,420 from the scattering center. 229 00:17:57,420 --> 00:18:02,240 So we need this to hold away from r 230 00:18:02,240 --> 00:18:06,860 equals zero, in fact, bigger for r bigger than a. 231 00:18:06,860 --> 00:18:11,630 One way of checking this kind of thing 232 00:18:11,630 --> 00:18:18,200 is to remember that the Laplacian of a function of r 233 00:18:18,200 --> 00:18:27,290 is in fact one over r d second dr squared r times f. 234 00:18:27,290 --> 00:18:32,330 That's a neat formula for the Laplacian of a function that 235 00:18:32,330 --> 00:18:33,620 just depends on r. 236 00:18:33,620 --> 00:18:36,960 If it depends on theta and phi, it's more complicated. 237 00:18:36,960 --> 00:18:40,730 But with this function, it becomes a one line calculation 238 00:18:40,730 --> 00:18:44,450 to do this, and the r here is just fantastic, 239 00:18:44,450 --> 00:18:48,830 because by the time you multiply by r this function is 240 00:18:48,830 --> 00:18:49,930 just exponential. 241 00:18:49,930 --> 00:18:55,820 You take two derivatives, you get minus k squared, 242 00:18:55,820 --> 00:18:58,940 and then the r gets canceled as well 243 00:18:58,940 --> 00:19:02,490 and everything works beautifully here. 244 00:19:02,490 --> 00:19:09,770 And so this equation holds OK. 245 00:19:09,770 --> 00:19:15,890 And then we do have a possible scattered wave. 246 00:19:15,890 --> 00:19:18,410 So we're almost there. 247 00:19:18,410 --> 00:19:29,550 We can write the scattering wave size scattering 248 00:19:29,550 --> 00:19:45,470 of x could be e to the ikr over r and then leave it at that. 249 00:19:45,470 --> 00:19:48,120 But this would not be general enough. 250 00:19:48,120 --> 00:19:53,470 There is no reason why this wave would not 251 00:19:53,470 --> 00:19:56,270 depend also on theta and phi. 252 00:19:59,560 --> 00:20:03,130 Here is the z direction, and there's 253 00:20:03,130 --> 00:20:07,450 points with angle theta, and if you rotate it with some angle 254 00:20:07,450 --> 00:20:13,930 phi here, and therefore this function could as well 255 00:20:13,930 --> 00:20:16,420 depend on theta and phi. 256 00:20:16,420 --> 00:20:24,590 So we'll include that factor f of theta and phi. 257 00:20:31,550 --> 00:20:34,000 Now you would say, look, you have 258 00:20:34,000 --> 00:20:37,090 a nice solution of the Schrodinger equation 259 00:20:37,090 --> 00:20:45,110 already here, and what should you be doing? 260 00:20:45,110 --> 00:20:48,020 Why do you add this factor? 261 00:20:48,020 --> 00:20:52,100 With this factor, it may not be anymore a solution 262 00:20:52,100 --> 00:20:53,537 of the Schrodinger equation. 263 00:20:53,537 --> 00:20:55,745 The Schrodinger equation is going to have a Laplacian 264 00:20:55,745 --> 00:20:59,040 and it's going to be more complicated. 265 00:20:59,040 --> 00:21:03,140 Well, this is true and we will see that better soon, 266 00:21:03,140 --> 00:21:07,040 but this will remain an approximate solution 267 00:21:07,040 --> 00:21:14,690 for r much bigger than a is the leading term of the solution, 268 00:21:14,690 --> 00:21:19,385 leaving term of the solution. 269 00:21:30,850 --> 00:21:36,660 So if you have a leading term of a solution here, 270 00:21:36,660 --> 00:21:38,810 this is all you want. 271 00:21:38,810 --> 00:21:44,270 You are working at r much bigger than a, and your whole wave 272 00:21:44,270 --> 00:21:46,880 and finally be written. 273 00:21:46,880 --> 00:21:53,100 So your full wave psi, or your full energy eigenstates psi 274 00:21:53,100 --> 00:21:57,380 of rt, is going to be equal, approximately 275 00:21:57,380 --> 00:22:00,740 equal to e to the ik-- 276 00:22:00,740 --> 00:22:03,260 well, I'll write it this way. 277 00:22:03,260 --> 00:22:09,680 Phi of r, that incident wave we wrote-- 278 00:22:09,680 --> 00:22:12,020 I wrote if x there, I'm sorry. 279 00:22:12,020 --> 00:22:17,940 Plus psi scattering of-- 280 00:22:17,940 --> 00:22:22,320 I should decide x or r. 281 00:22:22,320 --> 00:22:26,550 Let's call this r. 282 00:22:26,550 --> 00:22:27,870 And I should call this r. 283 00:22:33,826 --> 00:22:37,930 Psi of r plus psi scattering of r, 284 00:22:37,930 --> 00:22:47,460 and it's therefore equal to e to the ikz plus f of theta phi e 285 00:22:47,460 --> 00:22:56,160 to the ikr over r, and this is only valid for r much bigger 286 00:22:56,160 --> 00:22:57,690 than a. 287 00:22:57,690 --> 00:22:59,520 Far away. 288 00:22:59,520 --> 00:23:05,430 This had an analog in our problem in one dimension. 289 00:23:05,430 --> 00:23:12,860 In one dimension, you set up a wave and you put here the wave 290 00:23:12,860 --> 00:23:17,430 and there is a reflected wave, and there's a transmitted wave, 291 00:23:17,430 --> 00:23:21,180 and in setting the problem, say this is valid far to the left, 292 00:23:21,180 --> 00:23:25,530 far to the left meaning at least to the left of the barrier, 293 00:23:25,530 --> 00:23:28,110 this is valid to the right. 294 00:23:28,110 --> 00:23:33,300 And these were exact solutions in this region here. 295 00:23:33,300 --> 00:23:37,470 You can't do that well, but you can do reasonably well, 296 00:23:37,470 --> 00:23:44,850 you can write solutions that are leading term accurate 297 00:23:44,850 --> 00:23:48,370 as long as you are far away. 298 00:23:48,370 --> 00:23:54,630 So this is the first step in this whole process in which we 299 00:23:54,630 --> 00:23:59,830 are setting up the wave functions that 300 00:23:59,830 --> 00:24:01,840 is the most important equation. 301 00:24:01,840 --> 00:24:05,810 This is the way we're going to try to find solutions. 302 00:24:09,030 --> 00:24:11,640 Now, when you try to find solutions 303 00:24:11,640 --> 00:24:13,770 at the end of the day, you will have 304 00:24:13,770 --> 00:24:19,050 to work in the region r going to zero. 305 00:24:19,050 --> 00:24:22,410 So sooner or later we'll get there. 306 00:24:22,410 --> 00:24:25,980 But for the time being, we have all the information 307 00:24:25,980 --> 00:24:30,510 about what's going on far away, and from there we 308 00:24:30,510 --> 00:24:33,360 can get most of what we need. 309 00:24:33,360 --> 00:24:38,160 In particular, this f of theta and phi 310 00:24:38,160 --> 00:24:42,510 is the quantity we need to figure out. 311 00:24:42,510 --> 00:24:47,160 This f of theta and phi is called 312 00:24:47,160 --> 00:24:49,770 the scattering amplitude. 313 00:24:49,770 --> 00:24:58,040 F of theta and phi called scattering amplitude.