1 00:00:00,680 --> 00:00:03,770 PROFESSOR: With this, we can phase the construction 2 00:00:03,770 --> 00:00:05,990 of the operators that are going to help 3 00:00:05,990 --> 00:00:09,400 us build totally symmetric states and totally 4 00:00:09,400 --> 00:00:13,820 anti-symmetric states, and understand 5 00:00:13,820 --> 00:00:18,230 why we solve the problem of degeneracy, exchange 6 00:00:18,230 --> 00:00:19,010 degeneracy. 7 00:00:19,010 --> 00:00:26,870 So let us look into that. 8 00:00:35,350 --> 00:00:44,560 So this is called complete symmetrizers 9 00:00:44,560 --> 00:00:54,010 and anti-symmetrizers, complete symmetrizers 10 00:00:54,010 --> 00:00:57,157 and anti-symmetrizers. 11 00:01:10,320 --> 00:01:14,740 Permutation operators don't commute. 12 00:01:14,740 --> 00:01:19,320 So there's no hope ever of simultaneously diagonalizing 13 00:01:19,320 --> 00:01:19,950 them. 14 00:01:19,950 --> 00:01:22,680 There's some of them are not even Hermitian. 15 00:01:22,680 --> 00:01:28,470 So even worse, you cannot find that, oh, 16 00:01:28,470 --> 00:01:30,840 I'm going to get a complete basis of states, 17 00:01:30,840 --> 00:01:35,110 simultaneously diagonalizing, some permutation operators are 18 00:01:35,110 --> 00:01:36,330 Hermitian. 19 00:01:36,330 --> 00:01:38,490 The majority are a unitary. 20 00:01:38,490 --> 00:01:43,080 The transposition operators are the Hermitian ones. 21 00:01:43,080 --> 00:01:45,480 Those you could try to diagonalize. 22 00:01:45,480 --> 00:01:48,780 But if you have the whole permutation group, 23 00:01:48,780 --> 00:01:51,570 you cannot diagonalize it. 24 00:01:51,570 --> 00:01:55,200 It's just too many things that don't commute. 25 00:01:55,200 --> 00:01:58,470 But while you cannot diagonalize these things, 26 00:01:58,470 --> 00:02:06,530 you can find special states that are eigenstates of all 27 00:02:06,530 --> 00:02:08,850 of the elements of a permutation group. 28 00:02:08,850 --> 00:02:12,140 So you remember, when you say-- this is a very important point. 29 00:02:12,140 --> 00:02:16,220 Whenever you say you cannot simultaneously diagonalize two 30 00:02:16,220 --> 00:02:20,750 operators, it means that you cannot find a basis of states 31 00:02:20,750 --> 00:02:25,060 that are simultaneous eigenstates. 32 00:02:25,060 --> 00:02:28,640 But it may happen that you have one state that 33 00:02:28,640 --> 00:02:31,060 is an eigenstate of all these other things that 34 00:02:31,060 --> 00:02:33,680 don't commute. 35 00:02:33,680 --> 00:02:36,990 It is possible to have operators that 36 00:02:36,990 --> 00:02:40,810 don't commute and have one state that's 37 00:02:40,810 --> 00:02:42,830 an eigenstate of all of them. 38 00:02:42,830 --> 00:02:46,940 You cannot have a basis that is an eigenstate of all of them, 39 00:02:46,940 --> 00:02:48,680 because they don't commute. 40 00:02:48,680 --> 00:02:50,870 But one state is possible. 41 00:02:50,870 --> 00:02:53,315 So we can find special states. 42 00:02:55,880 --> 00:03:11,950 Special states that are eigenstates of all permutation 43 00:03:11,950 --> 00:03:12,642 operators. 44 00:03:15,560 --> 00:03:25,362 So let's assume we have n particles, each living on v, 45 00:03:25,362 --> 00:03:33,750 in v, so that the n particles live on v tensor n. 46 00:03:33,750 --> 00:03:37,320 People write it like that, v tensor n, 47 00:03:37,320 --> 00:03:43,800 which is supposed to mean v tensor v with v 48 00:03:43,800 --> 00:03:45,255 appearing n times. 49 00:03:50,850 --> 00:03:57,950 So here is a claim that we're going 50 00:03:57,950 --> 00:04:03,440 to postulate the existence of symmetric states. 51 00:04:03,440 --> 00:04:06,050 Those are the states that eventually will see 52 00:04:06,050 --> 00:04:09,550 are the ones physics ones. 53 00:04:09,550 --> 00:04:27,160 So postulate that there are the existence of symmetric states, 54 00:04:27,160 --> 00:04:33,000 psi s, n v tensor n. 55 00:04:33,000 --> 00:04:36,680 In the whole big space, there's symmetric states. 56 00:04:36,680 --> 00:04:41,070 And what is the characteristic of a symmetric state? 57 00:04:41,070 --> 00:04:45,290 The p alpha, any permutation. 58 00:04:45,290 --> 00:04:49,040 Remember, alpha means all these set of indices on psi 59 00:04:49,040 --> 00:04:56,170 s is equal to psi s for all alpha. 60 00:04:59,440 --> 00:05:03,080 So the state is invariant. 61 00:05:03,080 --> 00:05:07,720 So we want to see that there is such a thing, states that 62 00:05:07,720 --> 00:05:11,950 are invariant, under all the permutation operators 63 00:05:11,950 --> 00:05:13,510 that we've constructed. 64 00:05:18,020 --> 00:05:23,540 This state would be eigenstates of all the permutation 65 00:05:23,540 --> 00:05:27,860 operators with eigenvalue equals to 1. 66 00:05:30,430 --> 00:05:33,550 So it's a simultaneous eigenvector 67 00:05:33,550 --> 00:05:37,620 of all these operators. 68 00:05:37,620 --> 00:05:40,730 But since the permutation operators don't commute, 69 00:05:40,730 --> 00:05:43,830 you cannot expect the basis. 70 00:05:43,830 --> 00:05:47,040 So if there are symmetric states, 71 00:05:47,040 --> 00:05:51,780 they cannot form a basis in the full Hilbert space. 72 00:05:51,780 --> 00:05:54,480 There must be some smaller space. 73 00:05:54,480 --> 00:05:59,070 So we should be able to reach them by a projector 74 00:05:59,070 --> 00:06:02,310 into a subspace of symmetric states. 75 00:06:05,850 --> 00:06:14,245 How about defining now postulate anti-symmetric states. 76 00:06:21,640 --> 00:06:33,895 Psi A. P alpha on psi A should then be equal to-- 77 00:06:37,490 --> 00:06:39,770 what should I put? 78 00:06:39,770 --> 00:06:49,810 Negative psi A. 79 00:06:49,810 --> 00:06:53,640 Well, yeah, that's the first thing we would put, 80 00:06:53,640 --> 00:06:59,050 but that's pretty problematic actually. 81 00:06:59,050 --> 00:07:02,620 So even when you postulate things, 82 00:07:02,620 --> 00:07:06,880 you know, postulate means, OK, we think they exist, 83 00:07:06,880 --> 00:07:09,460 then we'll try to build them. 84 00:07:09,460 --> 00:07:11,650 Here, we're trying to postulate that there 85 00:07:11,650 --> 00:07:14,300 are states that do this. 86 00:07:14,300 --> 00:07:16,510 There's a little bit of problems with this. 87 00:07:16,510 --> 00:07:19,450 First obvious problem, you say, oh well, this 88 00:07:19,450 --> 00:07:21,820 is a mathematical technicality. 89 00:07:21,820 --> 00:07:27,850 The identity element is supposed to be a permutation p 1, 2, 3. 90 00:07:27,850 --> 00:07:31,090 And the identity element is not going to change this one. 91 00:07:33,660 --> 00:07:36,420 So that's not good. 92 00:07:36,420 --> 00:07:41,220 So suppose you have one transposition, and changes 93 00:07:41,220 --> 00:07:47,430 the state, a transposition should produce a minus sign, 94 00:07:47,430 --> 00:07:48,680 because it's anti-symmetric. 95 00:07:48,680 --> 00:07:51,530 But suppose you have now two transpositions. 96 00:07:51,530 --> 00:07:54,950 You act on them with two transpositions. 97 00:07:54,950 --> 00:07:56,540 One will change its sign. 98 00:07:56,540 --> 00:07:58,830 The other will change its sign. 99 00:07:58,830 --> 00:08:02,060 Now the total double transposition 100 00:08:02,060 --> 00:08:04,070 is a permutation operator. 101 00:08:04,070 --> 00:08:07,040 Shouldn't change the sign of the state. 102 00:08:07,040 --> 00:08:12,690 So in fact, this is untenable. 103 00:08:12,690 --> 00:08:15,870 We're not even-- so even if we postulate something, 104 00:08:15,870 --> 00:08:19,750 we'd have to postulate something that makes some sense. 105 00:08:19,750 --> 00:08:22,140 And so far, it doesn't make sense. 106 00:08:22,140 --> 00:08:24,360 So what can we use? 107 00:08:24,360 --> 00:08:27,870 We can use the fact that there's some even permutations 108 00:08:27,870 --> 00:08:29,920 and some odd permutations. 109 00:08:29,920 --> 00:08:33,210 So we'll put the sign factor here, 110 00:08:33,210 --> 00:08:38,280 psi A. This is the only way to solve this problem 111 00:08:38,280 --> 00:08:42,919 is to put the sign factor epsilon sub alpha associated 112 00:08:42,919 --> 00:08:44,220 to the permutation. 113 00:08:44,220 --> 00:08:46,680 Sometimes it's going to be a minus. 114 00:08:46,680 --> 00:08:49,050 Sometimes it's going to be a plus. 115 00:08:49,050 --> 00:08:52,680 For example, for the identity operator, it should be a plus. 116 00:08:52,680 --> 00:08:55,320 For a transposition, it should be a minus. 117 00:08:55,320 --> 00:08:58,740 So what is this epsilon alpha? 118 00:08:58,740 --> 00:09:05,880 Epsilon alpha is equal to 1 if p alpha 119 00:09:05,880 --> 00:09:14,490 is an even [? transpose ?] even or minus 1 if p alpha is odd. 120 00:09:18,740 --> 00:09:21,740 So an odd permutation is one that 121 00:09:21,740 --> 00:09:24,150 has an odd number of transpositions. 122 00:09:24,150 --> 00:09:25,295 So that makes sense. 123 00:09:29,190 --> 00:09:34,550 This is a way to do this consistently. 124 00:09:34,550 --> 00:09:36,260 If you have a single transposition, 125 00:09:36,260 --> 00:09:39,410 and we'll put the minus, but if you have two transposition, 126 00:09:39,410 --> 00:09:42,350 it will put a plus, as it should. 127 00:09:42,350 --> 00:09:48,710 And the identity element is an even permutation. 128 00:09:48,710 --> 00:09:51,870 Therefore, it works as well. 129 00:09:51,870 --> 00:09:54,740 So this is a nice thing. 130 00:09:54,740 --> 00:09:56,990 This is the only way you can define 131 00:09:56,990 --> 00:10:02,430 this anti-symmetric states, even before we construct them. 132 00:10:02,430 --> 00:10:11,030 So here are the names, and we'll stop and build them next time. 133 00:10:13,760 --> 00:10:23,270 So the symmetric state, symmetric states 134 00:10:23,270 --> 00:10:43,540 form a subspace of VN called sym N V. Symmetric 135 00:10:43,540 --> 00:10:51,790 in N states of V. The anti-symmetric states 136 00:10:51,790 --> 00:11:07,070 form a subspace of VN called anti N of V. 137 00:11:07,070 --> 00:11:14,450 And our task for next time is to construct the projectors that 138 00:11:14,450 --> 00:11:18,200 bring you down to those spaces, analyze 139 00:11:18,200 --> 00:11:20,300 what are the properties of these spaces, 140 00:11:20,300 --> 00:11:25,340 and show that it solves the problem of exchange degeneracy, 141 00:11:25,340 --> 00:11:29,180 and that requires an extra postulate in quantum 142 00:11:29,180 --> 00:11:34,570 mechanics, a postulate for identical particles.