1 00:00:01,220 --> 00:00:04,840 PROFESSOR: OK, so that's our equation. 2 00:00:04,840 --> 00:00:09,400 Three terms-- first term, spontaneous emission, 3 00:00:09,400 --> 00:00:14,290 second term, stimulated emission proportional to Nb, 4 00:00:14,290 --> 00:00:18,430 third term increases Nb's absorption. 5 00:00:18,430 --> 00:00:21,130 Our strategy now is, so what do you do with this? 6 00:00:21,130 --> 00:00:24,540 This looks like a good equation, but what are we to do? 7 00:00:24,540 --> 00:00:26,950 We haven't used three, really. 8 00:00:26,950 --> 00:00:31,720 So we can solve for U. And this time, the equation 9 00:00:31,720 --> 00:00:34,150 won't want to make U equal 0. 10 00:00:34,150 --> 00:00:36,190 It will give us something. 11 00:00:36,190 --> 00:00:40,780 And then we can compare with a thermal equilibrium relation 12 00:00:40,780 --> 00:00:42,760 to get something. 13 00:00:42,760 --> 00:00:46,000 So that's our goal. 14 00:00:46,000 --> 00:00:49,270 So how do we solve for U? 15 00:00:49,270 --> 00:00:52,780 Let's divide by Nb. 16 00:00:56,510 --> 00:01:02,030 So divide by Nb. 17 00:01:02,030 --> 00:01:08,970 So a 0 here, pass this to that side, and divide by Nb. 18 00:01:08,970 --> 00:01:13,815 So you get A on the left-hand side equals-- 19 00:01:16,860 --> 00:01:18,740 let's see, should I put the-- 20 00:01:18,740 --> 00:01:24,770 well, minus Bba Nb. 21 00:01:24,770 --> 00:01:28,200 Actually, I'll do it like this-- 22 00:01:28,200 --> 00:01:29,610 the second term first. 23 00:01:29,610 --> 00:01:41,700 Bab Na over Nb times U-- 24 00:01:41,700 --> 00:01:47,430 so I'll put it here, a U of omega Ba-- 25 00:01:47,430 --> 00:01:49,620 minus Bba. 26 00:01:54,080 --> 00:01:58,380 OK, so I moved the first term to the left-hand side, grouped 27 00:01:58,380 --> 00:02:02,580 the U. Why did I group the U? 28 00:02:02,580 --> 00:02:05,610 Because I said, let's find what U 29 00:02:05,610 --> 00:02:10,080 is, and try to compare with other things that we have. 30 00:02:10,080 --> 00:02:20,080 So now we can solve for the U. U of omega ba 31 00:02:20,080 --> 00:02:24,490 is equal to A divided by this quantity. 32 00:02:24,490 --> 00:02:30,220 So it's A divided by a big thing. 33 00:02:30,220 --> 00:02:32,590 Let me factor out the Bab. 34 00:02:36,730 --> 00:02:50,860 So now we have here Na over Nb minus Bba over Bab, 35 00:02:50,860 --> 00:03:03,670 or A over Bab 1 over Na over Nb is there, 36 00:03:03,670 --> 00:03:09,550 is e to the beta h bar omega ba-- 37 00:03:12,530 --> 00:03:16,910 It's a minus sign with respect to number 2-- 38 00:03:16,910 --> 00:03:21,185 minus Bba over Bab. 39 00:03:26,050 --> 00:03:28,540 OK, this is great. 40 00:03:28,540 --> 00:03:30,015 We're in very good shape. 41 00:03:34,446 --> 00:03:40,200 In fact, we're here. 42 00:03:40,200 --> 00:03:44,700 Let's compare with our thermal radiation. 43 00:03:44,700 --> 00:03:46,920 So here is what we got. 44 00:03:46,920 --> 00:03:51,150 And we have to compare with fact number 45 00:03:51,150 --> 00:03:55,200 three, which is the thermal radiation formula, which 46 00:03:55,200 --> 00:04:11,870 is h bar over pi squared C cubed omega cubed 1 over e 47 00:04:11,870 --> 00:04:15,530 to the beta h omega. 48 00:04:15,530 --> 00:04:20,240 And I'm comparing with the thermal radiation, 49 00:04:20,240 --> 00:04:22,520 U of omega ab. 50 00:04:22,520 --> 00:04:28,550 I canceled the D omegas, because this is U without the D omegas. 51 00:04:28,550 --> 00:04:33,830 So omega ba minus 1. 52 00:04:33,830 --> 00:04:38,370 All right. 53 00:04:38,370 --> 00:04:41,730 It's perfectly nice and ready. 54 00:04:41,730 --> 00:04:45,120 We need to compare this formula with this one. 55 00:04:45,120 --> 00:04:48,670 They have to be equal. 56 00:04:48,670 --> 00:04:53,560 Well, this factor, must be equal to this factor, given 57 00:04:53,560 --> 00:04:57,580 that here you have e to the beta h bar omega ba. 58 00:04:57,580 --> 00:04:59,350 These are constants. 59 00:04:59,350 --> 00:05:04,450 And the first thing that you discover is Bba equal Bab. 60 00:05:04,450 --> 00:05:06,880 And so yes, very nice. 61 00:05:06,880 --> 00:05:09,520 This is what we learn in perturbation theory. 62 00:05:09,520 --> 00:05:14,170 These two processes have identical rates. 63 00:05:14,170 --> 00:05:19,780 So the first statement that this equality requires 64 00:05:19,780 --> 00:05:30,100 is that Bab is equal to Bba. 65 00:05:30,100 --> 00:05:34,210 So there's just one B coefficient, 66 00:05:34,210 --> 00:05:37,810 just like there's one A coefficient. 67 00:05:37,810 --> 00:05:47,530 And the second thing that you learn is that A over Bab 68 00:05:47,530 --> 00:05:48,415 is this ratio-- 69 00:05:52,320 --> 00:05:58,845 is h bar omega ba cubed over pi squared C cubed. 70 00:06:04,640 --> 00:06:09,380 So we will be able to calculate the B coefficients, 71 00:06:09,380 --> 00:06:12,770 because they represent the familiar properties 72 00:06:12,770 --> 00:06:15,470 of harmonic perturbations transitions, 73 00:06:15,470 --> 00:06:18,020 and we've done already. 74 00:06:18,020 --> 00:06:21,620 Calculating A is harder, in principle. 75 00:06:21,620 --> 00:06:25,070 The process of spontaneous emission is a harder process. 76 00:06:25,070 --> 00:06:28,710 But this relation says that we don't have to worry about it. 77 00:06:28,710 --> 00:06:34,355 We already, if we know B, these are constants, we know A. 78 00:06:34,355 --> 00:06:38,780 So many times, even in problems in the homework, 79 00:06:38,780 --> 00:06:42,980 you will be asked, what is the spontaneous transition 80 00:06:42,980 --> 00:06:45,170 rate for this decay? 81 00:06:45,170 --> 00:06:46,580 You have an oscillator. 82 00:06:46,580 --> 00:06:48,080 It's in an excited state. 83 00:06:48,080 --> 00:06:51,680 What is the rate of spontaneous transition? 84 00:06:51,680 --> 00:06:53,720 And then you say, OK, this is complicated. 85 00:06:53,720 --> 00:06:57,830 But you calculate the stimulated transition rate, 86 00:06:57,830 --> 00:07:00,230 and then plug in this coefficient. 87 00:07:00,230 --> 00:07:04,480 So it will not be difficult. 88 00:07:04,480 --> 00:07:12,060 Now, spontaneous emission, as we discussed there in the top, 89 00:07:12,060 --> 00:07:14,310 doesn't include the factor having 90 00:07:14,310 --> 00:07:18,750 to do with the density of photons, the U that tells you 91 00:07:18,750 --> 00:07:20,220 how many photons there are. 92 00:07:20,220 --> 00:07:23,730 Because the photons play no deep role 93 00:07:23,730 --> 00:07:26,610 in producing the transition. 94 00:07:26,610 --> 00:07:32,190 But at some level, this transition-- 95 00:07:32,190 --> 00:07:35,820 while it's not stimulated by the photons that are flying 96 00:07:35,820 --> 00:07:37,110 around-- 97 00:07:37,110 --> 00:07:44,600 when you calculate it, in a serious, detailed calculation, 98 00:07:44,600 --> 00:07:47,960 you can think of them as stimulated 99 00:07:47,960 --> 00:07:52,410 by the vacuum fluctuations of the electromagnetic field. 100 00:07:52,410 --> 00:07:56,670 So if you were to quantize the electromagnetic field, 101 00:07:56,670 --> 00:07:59,030 there are vacuum fluctuations. 102 00:07:59,030 --> 00:08:02,750 And those vacuum fluctuations, you could say, 103 00:08:02,750 --> 00:08:09,420 they are stimulating what we call "spontaneous emission." 104 00:08:09,420 --> 00:08:12,570 So at the end of the day, the electromagnetic field 105 00:08:12,570 --> 00:08:14,520 is a quantum field. 106 00:08:14,520 --> 00:08:19,260 And therefore, it has zero point energies, Casimir effects, 107 00:08:19,260 --> 00:08:21,120 vacuum fluctuations. 108 00:08:21,120 --> 00:08:22,870 You can't get away from it. 109 00:08:22,870 --> 00:08:29,400 So in some sense, everything is stimulated emission, 110 00:08:29,400 --> 00:08:32,370 stimulated by a lot of photons or stimulated 111 00:08:32,370 --> 00:08:34,260 by the vacuum fields. 112 00:08:34,260 --> 00:08:38,789 Anyway, we'll still remain with the name 113 00:08:38,789 --> 00:08:44,610 "spontaneous emission," and keep those things very distinct. 114 00:08:44,610 --> 00:08:47,610 These rates have different effects 115 00:08:47,610 --> 00:08:51,520 at different temperatures, as well. 116 00:08:51,520 --> 00:08:57,900 So we'll consider that, for example, 117 00:08:57,900 --> 00:09:05,460 in that at low temperatures, the black body radiation has a very 118 00:09:05,460 --> 00:09:07,360 little number of photons. 119 00:09:07,360 --> 00:09:10,590 So most of the transitions, if they occur, 120 00:09:10,590 --> 00:09:14,130 are happening due to spontaneous transitions. 121 00:09:14,130 --> 00:09:17,020 On the other hand, as you increase the temperature, 122 00:09:17,020 --> 00:09:21,630 the number of photons that are available per unit volume 123 00:09:21,630 --> 00:09:26,320 increases, and stimulated emission takes over. 124 00:09:26,320 --> 00:09:32,870 So these are the different contributions to the rates. 125 00:09:32,870 --> 00:09:35,700 And it gives you a perspective-- at very low temperature, 126 00:09:35,700 --> 00:09:37,590 spontaneous dominates. 127 00:09:37,590 --> 00:09:43,130 At very high temperatures, stimulated emission dominates.