1 00:00:00,527 --> 00:00:01,110 PROFESSOR: OK. 2 00:00:01,110 --> 00:00:03,620 So what is our Schrodinger equation? 3 00:00:03,620 --> 00:00:07,180 Therefore, our Schrodinger equation 4 00:00:07,180 --> 00:00:16,096 is ih bar d psi dt is equal to 1 over 2 m. 5 00:00:16,096 --> 00:00:18,460 H bar over i grad-- 6 00:00:18,460 --> 00:00:30,070 that's p-- minus q over c a squared plus q phi on psi. 7 00:00:34,820 --> 00:00:38,970 We're going to motivate that next time. 8 00:00:38,970 --> 00:00:43,790 But let's look at it for a little while, at least. 9 00:00:43,790 --> 00:00:47,540 There's several things we've done here. 10 00:00:47,540 --> 00:00:54,716 We've replaced p by p minus q over c a. 11 00:01:04,269 --> 00:01:06,160 So this is a replacement. 12 00:01:06,160 --> 00:01:08,020 P has been replaced by that. 13 00:01:08,020 --> 00:01:10,420 We used to have p squared over 2m. 14 00:01:10,420 --> 00:01:13,010 Now we have this quantity. 15 00:01:13,010 --> 00:01:16,580 Well, we'll see why that is the right thing to do, 16 00:01:16,580 --> 00:01:23,270 but you could ask yourself, is this p still 17 00:01:23,270 --> 00:01:29,930 intuitively equal to mv or not? 18 00:01:29,930 --> 00:01:31,020 And the answer is no. 19 00:01:31,020 --> 00:01:33,800 That's not really mv. 20 00:01:33,800 --> 00:01:36,240 We will see that from Heisenberg's equation 21 00:01:36,240 --> 00:01:40,380 of motion, but intuitively, when you have here-- 22 00:01:40,380 --> 00:01:43,200 this is the energy of a particle-- 23 00:01:43,200 --> 00:01:45,750 kinetic energy and potential energy-- 24 00:01:45,750 --> 00:01:47,390 the kinetic energy-- 25 00:01:47,390 --> 00:01:57,590 1 over 2m times m squared v squared. 26 00:01:57,590 --> 00:01:58,700 That's p squared. 27 00:01:58,700 --> 00:02:04,640 So 1 over 2m m squared v squared is 1/2 mv squared. 28 00:02:04,640 --> 00:02:06,050 That's the kinetic energy. 29 00:02:06,050 --> 00:02:08,220 And that should come from here. 30 00:02:08,220 --> 00:02:09,979 So what we will see is that, if you 31 00:02:09,979 --> 00:02:13,910 want to speak about the velocity operator, 32 00:02:13,910 --> 00:02:19,090 this whole thing is the velocity operator. 33 00:02:19,090 --> 00:02:23,350 We don't speak, really, of velocity operators in quantum 34 00:02:23,350 --> 00:02:26,660 mechanics before we put electromagnetic fields, 35 00:02:26,660 --> 00:02:31,420 but here, it will be natural to call this m times the velocity 36 00:02:31,420 --> 00:02:35,660 operator in the sense of Heisenberg equations of motion. 37 00:02:35,660 --> 00:02:38,850 This operator is Heisenberg equation of motion-- 38 00:02:38,850 --> 00:02:43,930 is going to look like the Lorenz force equation. 39 00:02:43,930 --> 00:02:48,130 So it will be reasonable to think of this like that. 40 00:02:48,130 --> 00:02:54,220 This operator is nicer than the operator p, as we will see, 41 00:02:54,220 --> 00:02:55,135 for many reasons. 42 00:02:58,020 --> 00:03:04,690 So we've emphasized gauging variance so that, perhaps, 43 00:03:04,690 --> 00:03:06,910 the most important thing we could say, now, 44 00:03:06,910 --> 00:03:09,610 to end up this lecture is, what is 45 00:03:09,610 --> 00:03:13,835 the statement of gauge invariance for this Schrodinger 46 00:03:13,835 --> 00:03:14,335 equation? 47 00:03:18,660 --> 00:03:23,010 So gauge invariance means that the physics 48 00:03:23,010 --> 00:03:27,570 that you obtain with one set of potentials 49 00:03:27,570 --> 00:03:30,510 should be the same as the physics you 50 00:03:30,510 --> 00:03:34,590 obtain with a gauge-equivalent set of potentials. 51 00:03:41,410 --> 00:03:45,780 So I will say this way-- 52 00:03:45,780 --> 00:03:52,020 suppose you solve the Schrodinger equation 53 00:03:52,020 --> 00:04:00,130 with h bar over i grad minus q over c, 54 00:04:00,130 --> 00:04:05,160 with the new potentials-- 55 00:04:05,160 --> 00:04:20,010 plus q-- or you solve the Schrodinger equation 56 00:04:20,010 --> 00:04:21,638 with the old potentials? 57 00:04:33,490 --> 00:04:35,310 So you have here the two Schrodinger 58 00:04:35,310 --> 00:04:38,430 equations-- one with the new potentials, one 59 00:04:38,430 --> 00:04:39,990 with the old potentials. 60 00:04:44,620 --> 00:04:48,530 They should be the same physical solution. 61 00:04:48,530 --> 00:04:54,610 This is not going to be too obvious how to do, however. 62 00:04:54,610 --> 00:04:59,220 How do I guarantee they are the same physical solution? 63 00:04:59,220 --> 00:05:03,550 I'll have to go on a limb and try something. 64 00:05:03,550 --> 00:05:04,330 Look. 65 00:05:04,330 --> 00:05:06,310 Here are the gauge transformation. 66 00:05:06,310 --> 00:05:08,590 That's what a prime is. 67 00:05:08,590 --> 00:05:10,495 That's what phi prime is. 68 00:05:14,600 --> 00:05:20,880 Should the same psi be a solution of both? 69 00:05:20,880 --> 00:05:24,450 Should this equation imply this equation, 70 00:05:24,450 --> 00:05:28,830 so that the same psi works when you change the gauge 71 00:05:28,830 --> 00:05:30,930 potentials? 72 00:05:30,930 --> 00:05:32,380 That would not work. 73 00:05:32,380 --> 00:05:34,390 That is asking too much. 74 00:05:37,570 --> 00:05:43,460 Certainly, the same psi worked would be simple looking, 75 00:05:43,460 --> 00:05:51,210 but that's not what you really have to demand. 76 00:05:51,210 --> 00:05:54,020 It's not going to be able to occur here. 77 00:05:54,020 --> 00:05:58,310 What you're going to need is to change psi as well. 78 00:05:58,310 --> 00:06:01,850 The gauge transformation is going to affect the wave 79 00:06:01,850 --> 00:06:03,740 function, too. 80 00:06:03,740 --> 00:06:08,330 Not only the electromagnetic fields get gauge transform-- 81 00:06:08,330 --> 00:06:11,630 the wave function must be gauge transform. 82 00:06:11,630 --> 00:06:13,290 And you would say, OK. 83 00:06:13,290 --> 00:06:16,880 That sounds a little dangerous because if you change the wave 84 00:06:16,880 --> 00:06:19,610 function, you're going to change the physics. 85 00:06:19,610 --> 00:06:20,940 Could happen. 86 00:06:20,940 --> 00:06:22,880 But the change in the wave function 87 00:06:22,880 --> 00:06:25,380 is going to be subtle enough-- 88 00:06:25,380 --> 00:06:28,850 is going to be just by a phase. 89 00:06:28,850 --> 00:06:30,950 That can still change the physics. 90 00:06:30,950 --> 00:06:33,860 If you have a complex phase, you can change the physics. 91 00:06:33,860 --> 00:06:37,730 But will be simple enough that we 92 00:06:37,730 --> 00:06:40,290 will check that the physics is not changed. 93 00:06:40,290 --> 00:06:44,270 So the claim of gauge invariance is a statement 94 00:06:44,270 --> 00:06:50,390 that this equation implies this, or this implies that, 95 00:06:50,390 --> 00:06:57,140 if psi prime also transforms. 96 00:06:57,140 --> 00:07:00,380 And the formula is-- at psi prime-- 97 00:07:00,380 --> 00:07:09,095 should be equal to e to the i q over hc lambda times psi. 98 00:07:16,690 --> 00:07:22,090 So that's the key to it. 99 00:07:22,090 --> 00:07:24,910 When you transform the potentials-- 100 00:07:24,910 --> 00:07:28,390 when you change a to a prime and phi to phi prime-- 101 00:07:28,390 --> 00:07:30,720 you should change psi to psi prime. 102 00:07:30,720 --> 00:07:31,220 What? 103 00:07:31,220 --> 00:07:32,080 With what? 104 00:07:32,080 --> 00:07:35,500 Using the same lambda that you needed 105 00:07:35,500 --> 00:07:41,170 to change the potentials, you do a phase rotation. 106 00:07:41,170 --> 00:07:43,030 And it's not a constant phase. 107 00:07:43,030 --> 00:07:45,460 This depends on x and t. 108 00:07:45,460 --> 00:07:47,680 So it's a substantial change. 109 00:07:47,680 --> 00:07:51,610 So you now have the technical problem of first checking 110 00:07:51,610 --> 00:07:54,040 that this is true. 111 00:07:54,040 --> 00:07:57,580 This is the statement of gauge invariance of the Schrodinger 112 00:07:57,580 --> 00:07:58,450 equation. 113 00:07:58,450 --> 00:08:01,780 There is a way to transform the wave function 114 00:08:01,780 --> 00:08:05,320 so that the new Schrodinger equation 115 00:08:05,320 --> 00:08:08,350 solution is obtained from the old Schrodinger equation 116 00:08:08,350 --> 00:08:08,990 solution. 117 00:08:08,990 --> 00:08:12,580 And then we will have to check that the physics is the same. 118 00:08:12,580 --> 00:08:15,100 If you wanted to compute the expectation 119 00:08:15,100 --> 00:08:20,420 value of x, on this wave function, 120 00:08:20,420 --> 00:08:21,980 this phase factor would cancel. 121 00:08:21,980 --> 00:08:24,320 So it would give you the same. 122 00:08:24,320 --> 00:08:26,550 If you want to compute some other expectation values, 123 00:08:26,550 --> 00:08:27,840 it's a little funny. 124 00:08:27,840 --> 00:08:32,180 So there will be operators that are nice for wave functions 125 00:08:32,180 --> 00:08:34,760 or [INAUDIBLE] gauge invariant operators. 126 00:08:34,760 --> 00:08:39,630 And it will be a nice story that we will develop next time.