1 00:00:00,917 --> 00:00:01,500 PROFESSOR: OK. 2 00:00:01,500 --> 00:00:14,020 Let me then say a little more about that extra term. 3 00:00:14,020 --> 00:00:18,020 Let's rewrite it in a slightly different way 4 00:00:18,020 --> 00:00:22,180 so that we get the feeling of what 5 00:00:22,180 --> 00:00:24,120 it has to do with Hamiltonians. 6 00:00:26,960 --> 00:00:30,720 So this is a coupling term. 7 00:00:30,720 --> 00:00:39,060 So we try to understand, what is that coupling psi k, psi n dot? 8 00:00:39,060 --> 00:00:40,720 How could we write it? 9 00:00:40,720 --> 00:00:47,200 So what is psi k. 10 00:00:47,200 --> 00:00:48,705 Psi n dot? 11 00:01:00,240 --> 00:01:04,379 To figure this out, we have no option, probably, 12 00:01:04,379 --> 00:01:09,330 except looking at the Schrodinger equation-- 13 00:01:09,330 --> 00:01:11,040 not really the Schrodinger equation-- 14 00:01:11,040 --> 00:01:17,830 the time-instantaneous state conditions-- 15 00:01:17,830 --> 00:01:23,030 En of t, psi n of t. 16 00:01:23,030 --> 00:01:26,810 So you look at this instantaneous state condition 17 00:01:26,810 --> 00:01:30,390 for n and say, OK, I'm going to differentiate, 18 00:01:30,390 --> 00:01:34,080 and then I'm going to make the overlap. 19 00:01:34,080 --> 00:01:37,110 What else could you do? 20 00:01:37,110 --> 00:01:40,860 This is the equation that tells you 21 00:01:40,860 --> 00:01:44,220 how the instantaneous energy eigenstate is 22 00:01:44,220 --> 00:01:45,940 supposed to change in time. 23 00:01:45,940 --> 00:01:49,920 So it must have the information of how to compute this, 24 00:01:49,920 --> 00:01:53,100 or how to rewrite it in terms of other things 25 00:01:53,100 --> 00:01:54,090 that are interesting. 26 00:01:54,090 --> 00:01:57,900 So let's differentiate with respect to time. 27 00:01:57,900 --> 00:02:03,550 Differentiate-- respect to time. 28 00:02:03,550 --> 00:02:06,280 And we use dots, as well. 29 00:02:06,280 --> 00:02:19,750 So let's write this as H dot times psi n plus H psi n dot 30 00:02:19,750 --> 00:02:30,895 is equal to En dot, psi n plus En, psi n dot. 31 00:02:33,730 --> 00:02:35,460 And then we do what-- 32 00:02:38,310 --> 00:02:43,330 we want psi k here from the left. 33 00:02:43,330 --> 00:03:01,430 So we'll have a psi k, H dot, psi n plus-- 34 00:03:01,430 --> 00:03:05,390 Now you're going to put the psi k here. 35 00:03:05,390 --> 00:03:08,450 The H will act on the left. 36 00:03:08,450 --> 00:03:19,410 So we will have an Ek psi k, psi n dot. 37 00:03:19,410 --> 00:03:22,280 That's all that is left from this term. 38 00:03:22,280 --> 00:03:27,600 The psi k came from the left and was acted by the H 39 00:03:27,600 --> 00:03:29,640 to give you an Ek times this. 40 00:03:33,720 --> 00:03:42,720 On this state, I have the psi k already hitting the psi n. 41 00:03:42,720 --> 00:03:46,920 Now, we are interested in this term 42 00:03:46,920 --> 00:03:49,110 when k is different from n. 43 00:03:52,250 --> 00:03:59,900 These are the couplings to other states in the analysis 44 00:03:59,900 --> 00:04:02,420 of the adiabatic approximation. 45 00:04:02,420 --> 00:04:05,930 So let's take k different from n. 46 00:04:05,930 --> 00:04:10,490 In which case, this term will give 0. 47 00:04:10,490 --> 00:04:14,630 Because k is different from n and the state just hits it. 48 00:04:14,630 --> 00:04:21,622 And here we have, finally, En times psi k, psi n dot. 49 00:04:25,070 --> 00:04:26,070 So good. 50 00:04:26,070 --> 00:04:33,650 I think we can solve for this state in terms 51 00:04:33,650 --> 00:04:39,760 of a matrix element of the time derivative of the Hamiltonian. 52 00:04:45,730 --> 00:04:46,925 So what do we have? 53 00:04:52,390 --> 00:05:04,280 We have that psi k, psi n dot is equal to 1 54 00:05:04,280 --> 00:05:20,030 over En minus Ek times psi k, H dot, psi n, which is-- 55 00:05:20,030 --> 00:05:25,910 we can use the notation H dot kn. 56 00:05:25,910 --> 00:05:32,780 The kn matrix element of H dot is not 57 00:05:32,780 --> 00:05:39,140 equal to the time derivative of the kn matrix element of H. 58 00:05:39,140 --> 00:05:42,680 You calculate the H dot. 59 00:05:42,680 --> 00:05:44,720 And you put the kn if you wish. 60 00:05:47,420 --> 00:05:52,460 It really is this thing-- the matrix element of H 61 00:05:52,460 --> 00:05:58,770 dot kn over En minus Ek. 62 00:06:01,350 --> 00:06:03,900 The nice thing of this representation 63 00:06:03,900 --> 00:06:06,450 is that it now begins to give you 64 00:06:06,450 --> 00:06:13,080 a feeling of why we care even about slow changes. 65 00:06:13,080 --> 00:06:16,710 We have, in this coupling term-- 66 00:06:20,290 --> 00:06:24,990 this is the coupling term that will take you away 67 00:06:24,990 --> 00:06:28,200 from an instantaneous energy eigenstate. 68 00:06:28,200 --> 00:06:32,980 This is the term that can ruin your adiabatic approximation. 69 00:06:32,980 --> 00:06:36,600 And that term, now, you understand 70 00:06:36,600 --> 00:06:42,210 that it has to do with the rate of change of the Hamiltonian, 71 00:06:42,210 --> 00:06:47,910 which, after all, is the thing that drives the physics. 72 00:06:47,910 --> 00:06:50,070 You could say that term must be small, 73 00:06:50,070 --> 00:06:54,780 because the instantaneous energy eigenstates must be slow. 74 00:06:54,780 --> 00:06:56,610 And that's true. 75 00:06:56,610 --> 00:07:03,120 But this equation makes it clear that you 76 00:07:03,120 --> 00:07:09,540 have here a matrix element or some information about the time 77 00:07:09,540 --> 00:07:11,430 rate of change of your Hamiltonian. 78 00:07:11,430 --> 00:07:15,480 And if that is slow, then this term is small. 79 00:07:15,480 --> 00:07:19,320 And presumably, a small term in a differential equation 80 00:07:19,320 --> 00:07:21,600 has little effect. 81 00:07:21,600 --> 00:07:29,220 So probably, it's a good idea to just represent 82 00:07:29,220 --> 00:07:31,700 a particular case of a Hamiltonian 83 00:07:31,700 --> 00:07:35,020 to just complete this discussion. 84 00:07:35,020 --> 00:07:38,930 So imagine you have a Hamiltonian that-- 85 00:07:38,930 --> 00:07:42,320 it's of this kind, varies a bit. 86 00:07:42,320 --> 00:07:46,190 Maybe it doesn't vary for time equal less than 0. 87 00:07:46,190 --> 00:07:51,930 It varies for a while, and then it stops varying. 88 00:07:51,930 --> 00:07:57,920 And let's call the time capital T-- the time for the variation. 89 00:08:00,870 --> 00:08:03,665 This is the typical thing that people do 90 00:08:03,665 --> 00:08:05,600 in the adiabatic approximation. 91 00:08:05,600 --> 00:08:10,100 So that is the language of things-- 92 00:08:10,100 --> 00:08:17,010 nothing, variation during a time T, nothing after all. 93 00:08:17,010 --> 00:08:21,230 So what is the goal, the result here? 94 00:08:21,230 --> 00:08:23,780 What is the real statement at the end 95 00:08:23,780 --> 00:08:27,950 of the day is that the errors that 96 00:08:27,950 --> 00:08:30,500 appear in the adiabatic approximation 97 00:08:30,500 --> 00:08:35,490 are all proportional to 1 over t. 98 00:08:35,490 --> 00:08:38,400 So that is a mathematical statement. 99 00:08:38,400 --> 00:08:43,299 The 1 over this capital T controls all the errors. 100 00:08:43,299 --> 00:08:46,230 So if the change happens very slowly, 101 00:08:46,230 --> 00:08:51,180 the errors go to 0, like 1 over t. 102 00:08:51,180 --> 00:08:53,430 And we can see the beginning of that, 103 00:08:53,430 --> 00:08:58,100 because I could make a model of this Hamiltonian 104 00:08:58,100 --> 00:09:00,020 that is a little different. 105 00:09:00,020 --> 00:09:05,230 It just may be a line growing here, for example. 106 00:09:05,230 --> 00:09:09,180 So this is a Hamiltonian H of t that 107 00:09:09,180 --> 00:09:18,040 begins as H0 plus t over capital T times V. 108 00:09:18,040 --> 00:09:23,950 That is for t between 0 and capital T, 109 00:09:23,950 --> 00:09:35,580 and then H0 plus V for t greater than that capital T. 110 00:09:35,580 --> 00:09:37,920 So here is H0. 111 00:09:37,920 --> 00:09:44,280 Here's H0 plus V. 112 00:09:44,280 --> 00:09:49,680 So if you have this thing here, you 113 00:09:49,680 --> 00:09:58,290 will have that H dot is equal to V over T-- 114 00:09:58,290 --> 00:10:01,350 capital T. And that's intuitive. 115 00:10:01,350 --> 00:10:05,550 The more time you take to make this finite transition, 116 00:10:05,550 --> 00:10:09,780 the smaller the value of the derivative. 117 00:10:09,780 --> 00:10:17,970 And therefore, an H dot matrix element kn 118 00:10:17,970 --> 00:10:22,830 will be 1 over capital T, the matrix element 119 00:10:22,830 --> 00:10:31,140 kn of the operator V. 120 00:10:31,140 --> 00:10:41,460 This term, this overlap, will be proportional to 1 over T. 121 00:10:41,460 --> 00:10:45,390 And this error term in the differential equation 122 00:10:45,390 --> 00:10:51,700 will be proportional to 1 over capital T. 123 00:10:51,700 --> 00:10:57,790 That takes still some effort to show that when you integrate 124 00:10:57,790 --> 00:11:02,710 the differential equation, the error remains 1 over capital T. 125 00:11:02,710 --> 00:11:04,660 It doesn't get increased. 126 00:11:04,660 --> 00:11:09,160 But that is precisely the statement 127 00:11:09,160 --> 00:11:11,560 of the adiabatic theorem. 128 00:11:11,560 --> 00:11:14,945 The adiabatic theorem says that-- 129 00:11:14,945 --> 00:11:23,000 and I'll quote it, maybe, this way. 130 00:11:39,340 --> 00:11:44,590 If you have the norm of a wave function, 131 00:11:44,590 --> 00:11:50,710 you can define the square root of the overlap of the wave 132 00:11:50,710 --> 00:11:52,670 function. 133 00:11:52,670 --> 00:11:56,620 And the way people precisely state 134 00:11:56,620 --> 00:12:01,350 the adiabatic theorem is that. 135 00:12:01,350 --> 00:12:17,580 The state psi, during a time t minus the psi adiabatic-- 136 00:12:17,580 --> 00:12:22,320 the [? n sets ?] for the adiabatic state of time t. 137 00:12:22,320 --> 00:12:23,870 The true-- the different-- 138 00:12:23,870 --> 00:12:24,430 I'm sorry. 139 00:12:24,430 --> 00:12:27,580 The difference between the true state 140 00:12:27,580 --> 00:12:31,780 psi of t and the adiabatic approximation t, 141 00:12:31,780 --> 00:12:41,020 for t between 0 and T, is less than 142 00:12:41,020 --> 00:12:49,690 or equal than a number of times T. 143 00:12:49,690 --> 00:12:55,090 So the adiabatic approximation that we've written, 144 00:12:55,090 --> 00:12:57,850 the state with all these phases, is 145 00:12:57,850 --> 00:13:02,890 as close to the real Schrodinger equation solution-- 146 00:13:02,890 --> 00:13:07,250 the error is less than 1 over T, where 147 00:13:07,250 --> 00:13:15,140 T is this time in which you have nothing here, nothing there. 148 00:13:15,140 --> 00:13:20,000 And this, in fact, gets even better for larger times. 149 00:13:20,000 --> 00:13:24,050 So after larger times, the error doesn't increase. 150 00:13:24,050 --> 00:13:25,670 So you can keep-- 151 00:13:25,670 --> 00:13:30,950 the change has already happened, and it doesn't matter. 152 00:13:30,950 --> 00:13:36,920 So basically, we've argued intuitively 153 00:13:36,920 --> 00:13:38,930 what the adiabatic approximation should 154 00:13:38,930 --> 00:13:42,830 be by tracking an instantaneous eigenstate. 155 00:13:42,830 --> 00:13:48,570 We've now done it with explicit differential equations. 156 00:13:48,570 --> 00:13:52,460 If you have an explicit problem, you can, after all, 157 00:13:52,460 --> 00:13:56,660 solve this and see what things happen, 158 00:13:56,660 --> 00:14:01,970 and therefore, reach the conclusion that then there are 159 00:14:01,970 --> 00:14:05,310 a good number of conditions. 160 00:14:05,310 --> 00:14:07,800 Many situations, they're slowly varying. 161 00:14:07,800 --> 00:14:10,980 The adiabatic [? n sets ?] will give a good solution 162 00:14:10,980 --> 00:14:14,290 to the Schrodinger equation. 163 00:14:14,290 --> 00:14:17,740 So that completes our first part of the analysis. 164 00:14:17,740 --> 00:14:22,400 Now we're going to turn into a little different story.