1 00:00:00,500 --> 00:00:02,370 PROFESSOR: Today, we're going to continue 2 00:00:02,370 --> 00:00:04,500 with the adiabatic subject. 3 00:00:04,500 --> 00:00:09,930 And our main topic is going to be Berry's Phase. 4 00:00:09,930 --> 00:00:12,960 It's interesting part of the phase 5 00:00:12,960 --> 00:00:15,060 that goes in adiabatic process. 6 00:00:15,060 --> 00:00:18,150 And we want to understand what it is 7 00:00:18,150 --> 00:00:21,550 and why people care about it. 8 00:00:21,550 --> 00:00:25,140 And then, we'll turn to another subject 9 00:00:25,140 --> 00:00:29,620 in which the adiabatic approximation is of interest. 10 00:00:29,620 --> 00:00:31,920 And it's a subject of molecules. 11 00:00:31,920 --> 00:00:35,250 So I don't think I'll manage to get through all of that today, 12 00:00:35,250 --> 00:00:37,690 but will we'll make an effort. 13 00:00:37,690 --> 00:00:44,560 So let me remind you of what we had so far. 14 00:00:44,560 --> 00:00:48,150 So we imagine we have a Hamiltonian that 15 00:00:48,150 --> 00:00:52,590 depends on time and maybe had no dependents 16 00:00:52,590 --> 00:00:55,450 before time equals 0 turns on. 17 00:00:55,450 --> 00:01:02,160 And it has no further variation after some time t. 18 00:01:02,160 --> 00:01:06,760 So the Hamiltonian changes like that. 19 00:01:06,760 --> 00:01:13,040 And the adiabatic theorem states that if you 20 00:01:13,040 --> 00:01:17,630 have a state at time equals 0, which 21 00:01:17,630 --> 00:01:25,760 is a particular instantaneous eigenstate, that 22 00:01:25,760 --> 00:01:28,610 is the instantaneous eigenstate, then 23 00:01:28,610 --> 00:01:33,200 that's the full wave function at time equals 0 and it coincides. 24 00:01:33,200 --> 00:01:38,840 Then, at time at any time in this process, if it's slow, 25 00:01:38,840 --> 00:01:42,770 the process, the state of the system, 26 00:01:42,770 --> 00:01:48,110 the full wave function, psi of t, 27 00:01:48,110 --> 00:01:55,440 will tend to remain in that instantaneous eigenstate. 28 00:01:55,440 --> 00:01:57,970 And the way it's stated precisely 29 00:01:57,970 --> 00:02:01,480 is that psi of t minus-- 30 00:02:01,480 --> 00:02:04,040 I'll write it like this-- 31 00:02:04,040 --> 00:02:15,170 psi prime n of t, the norm of this state 32 00:02:15,170 --> 00:02:25,860 is of order 1/T for any t in between 0 and T. 33 00:02:25,860 --> 00:02:31,310 So I'm trying to state the adiabatic theorem in a way that 34 00:02:31,310 --> 00:02:33,200 is mathematically precise. 35 00:02:33,200 --> 00:02:37,280 And let me remind you the norm of a wave function 36 00:02:37,280 --> 00:02:41,180 is you integrate the wave function square 37 00:02:41,180 --> 00:02:43,010 and take the square root. 38 00:02:43,010 --> 00:02:46,130 It's sort of the usual definition 39 00:02:46,130 --> 00:02:52,430 of the norm of a vector is the inner product of the vector 40 00:02:52,430 --> 00:02:54,480 with itself square root. 41 00:02:54,480 --> 00:02:57,390 So that's the norm for wave function. 42 00:02:57,390 --> 00:03:03,560 And here, what this means is that with some suitable choice 43 00:03:03,560 --> 00:03:08,510 of phase, the instantaneous eigenstate 44 00:03:08,510 --> 00:03:11,600 is very close to the true state. 45 00:03:11,600 --> 00:03:18,320 And the error is a Fourier 1/T. So if the process is slow, 46 00:03:18,320 --> 00:03:22,010 it means that the change occurs over long t, 47 00:03:22,010 --> 00:03:23,870 this is a small number. 48 00:03:23,870 --> 00:03:29,370 And there is some instantaneous eigenstate 49 00:03:29,370 --> 00:03:31,470 with some peculiar phase-- 50 00:03:31,470 --> 00:03:33,240 that's why I put the prime-- 51 00:03:33,240 --> 00:03:36,720 for which this difference is very small. 52 00:03:36,720 --> 00:03:40,480 And we calculated this phase, and we 53 00:03:40,480 --> 00:03:47,190 found the state, psi of t is roughly equal 54 00:03:47,190 --> 00:03:56,640 to e to theta n of t, e to the I gamma n of t, psi n of t. 55 00:03:59,350 --> 00:04:03,310 And in this statement, this is what I would 56 00:04:03,310 --> 00:04:08,310 call the psi n prime of t. 57 00:04:08,310 --> 00:04:11,950 And that's why the real state is just approximately 58 00:04:11,950 --> 00:04:14,590 equal to that one. 59 00:04:14,590 --> 00:04:24,550 And we have these phases in which theta of t is minus 1 60 00:04:24,550 --> 00:04:33,250 over h bar integral from 0 to t E n of t prime dt prime. 61 00:04:33,250 --> 00:04:35,800 That is kind of a familiar phase. 62 00:04:35,800 --> 00:04:41,440 If you had a normal energy eigenstate, time independent 1, 63 00:04:41,440 --> 00:04:44,170 this would be 1 to the-- 64 00:04:44,170 --> 00:04:49,570 well, would be minus e times t over h bar with an I 65 00:04:49,570 --> 00:04:51,370 would be the familiar phase that you 66 00:04:51,370 --> 00:04:53,620 put to an energy eigenstate. 67 00:04:53,620 --> 00:04:58,830 Then it comes the gamma n of t, which 68 00:04:58,830 --> 00:05:07,330 is an integral from 0 to t of some new n of t prime dt prime. 69 00:05:07,330 --> 00:05:19,848 And this new n of t is I psi n of t psi n dot of t. 70 00:05:23,264 --> 00:05:25,830 I think I have it right. 71 00:05:25,830 --> 00:05:30,270 So the second part of the phase is the integral 72 00:05:30,270 --> 00:05:33,570 of this new function. 73 00:05:33,570 --> 00:05:39,240 And this new function is real, because this part 74 00:05:39,240 --> 00:05:44,910 we showed before is imaginary, where with an I, this is real. 75 00:05:44,910 --> 00:05:48,420 And this second part, this gamma n, 76 00:05:48,420 --> 00:05:51,390 is called the geometric phase. 77 00:05:51,390 --> 00:05:56,080 This is the phase that has to do with Berry's phase. 78 00:05:56,080 --> 00:06:00,120 And it's a phase that we want to understand. 79 00:06:00,120 --> 00:06:03,120 And it's geometrical because of one reason 80 00:06:03,120 --> 00:06:04,950 that we're going to show that makes 81 00:06:04,950 --> 00:06:12,600 it quite surprising and quite different from the phase theta. 82 00:06:12,600 --> 00:06:17,620 The phase theta is a little like a clock, 83 00:06:17,620 --> 00:06:20,230 because it runs with time. 84 00:06:20,230 --> 00:06:22,690 The more time you wait on an energy 85 00:06:22,690 --> 00:06:25,975 eigenstate, the more this phase changes. 86 00:06:28,500 --> 00:06:34,590 What will happen with this geometric phase 87 00:06:34,590 --> 00:06:40,580 is that somehow properly viewed is 88 00:06:40,580 --> 00:06:48,030 independent of the time it takes the adiabatic process to occur. 89 00:06:48,030 --> 00:06:52,460 So whether it takes us small time or a long time 90 00:06:52,460 --> 00:06:55,430 to produce this change of the system, 91 00:06:55,430 --> 00:07:00,410 the geometric phase will be essentially the same. 92 00:07:00,410 --> 00:07:04,140 That's very, very unusual. 93 00:07:04,140 --> 00:07:06,530 So that's the main thing we want to understand 94 00:07:06,530 --> 00:07:10,700 about this geometric phase, that it depends only 95 00:07:10,700 --> 00:07:15,960 on the evolution of the state in that configuration space-- 96 00:07:15,960 --> 00:07:19,430 we'll make that clear, what it means-- 97 00:07:19,430 --> 00:07:25,340 and not the time it takes this evolution to occur. 98 00:07:25,340 --> 00:07:29,460 It's a little more subtle, this phase, than the other phase. 99 00:07:29,460 --> 00:07:34,920 So I want to introduce this idea of a configuration space. 100 00:07:34,920 --> 00:07:39,040 So basically, we have that-- 101 00:07:39,040 --> 00:07:42,250 let me forget about time dependence for one second 102 00:07:42,250 --> 00:07:48,330 and think of the Hamiltonian as a function 103 00:07:48,330 --> 00:07:52,500 of a set of coordinates, or parameters. 104 00:07:52,500 --> 00:07:58,650 So the Rs are some coordinates. 105 00:07:58,650 --> 00:08:05,340 R1, R2, maybe up to R capital N are some coordinates 106 00:08:05,340 --> 00:08:09,450 inside some vector space RN. 107 00:08:12,370 --> 00:08:13,900 So its N components. 108 00:08:13,900 --> 00:08:15,260 And what does that mean? 109 00:08:15,260 --> 00:08:17,620 It means maybe that your Hamiltonian 110 00:08:17,620 --> 00:08:21,180 has capital N parameters. 111 00:08:21,180 --> 00:08:23,180 And those are these things. 112 00:08:23,180 --> 00:08:26,260 So you buy this Hamiltonian. 113 00:08:26,260 --> 00:08:27,880 It comes with some parameters. 114 00:08:27,880 --> 00:08:28,750 You buy another one. 115 00:08:28,750 --> 00:08:31,030 It comes with another set of parameters. 116 00:08:31,030 --> 00:08:32,799 Those parameters can be changed. 117 00:08:32,799 --> 00:08:36,370 Or you construct them in the lab, your Hamiltonians 118 00:08:36,370 --> 00:08:38,020 with different parameters. 119 00:08:38,020 --> 00:08:40,870 Those are the parameters of the Hamiltonian. 120 00:08:51,840 --> 00:08:54,690 And suppose you have learned to solve 121 00:08:54,690 --> 00:08:58,740 this Hamiltonian for all values of the parameters. 122 00:08:58,740 --> 00:09:03,270 That is whatever the Rs are you know how 123 00:09:03,270 --> 00:09:06,030 to find the energy eigenstates. 124 00:09:06,030 --> 00:09:11,820 So H of R times-- 125 00:09:11,820 --> 00:09:24,390 there are some eigenstates, psi n of R with energies En of R, 126 00:09:24,390 --> 00:09:33,500 psi n of R. And n maybe is 1, 2, 3. 127 00:09:33,500 --> 00:09:41,310 And these are orthonormal states, 128 00:09:41,310 --> 00:09:43,615 those energy eigenstates. 129 00:09:46,250 --> 00:09:49,160 So this equation says that you have 130 00:09:49,160 --> 00:09:52,880 been able to solve this Hamiltonian whatever 131 00:09:52,880 --> 00:09:55,130 the values of the parameters are. 132 00:09:55,130 --> 00:09:58,140 And you have found all the states of the system, 133 00:09:58,140 --> 00:10:00,950 n equal 1, 2 3, 4, 5, 6. 134 00:10:00,950 --> 00:10:03,980 All of them are in now. 135 00:10:03,980 --> 00:10:08,180 So this is a general situation. 136 00:10:08,180 --> 00:10:12,180 And now, we imagine that for some reason, 137 00:10:12,180 --> 00:10:17,940 these parameters start to begin to depend on time. 138 00:10:17,940 --> 00:10:22,230 So they become time dependent parameters-- 139 00:10:26,330 --> 00:10:33,030 can become time dependent. 140 00:10:33,030 --> 00:10:36,650 So that you now have R of t vector. 141 00:10:36,650 --> 00:10:42,650 These are 1 of t up to our Rn of t. 142 00:10:48,040 --> 00:10:50,155 So how do we represent this? 143 00:10:58,350 --> 00:11:03,750 Well, this is a Cartesian space of parameters. 144 00:11:03,750 --> 00:11:06,540 This is not our normal space. 145 00:11:06,540 --> 00:11:10,110 This is a space where one axis could be the magnetic field. 146 00:11:10,110 --> 00:11:12,690 Another axis could be the electric field. 147 00:11:12,690 --> 00:11:16,980 Another axis could be the spring constant. 148 00:11:16,980 --> 00:11:20,880 Those are abstract axis of configuration space. 149 00:11:20,880 --> 00:11:29,190 Or this could be R1, R2, the axis, R3. 150 00:11:29,190 --> 00:11:32,200 And those are your axes. 151 00:11:32,200 --> 00:11:39,770 And now, how do you represent in this configuration space 152 00:11:39,770 --> 00:11:43,200 the evolution of the system? 153 00:11:43,200 --> 00:11:46,790 What is the evolution of the system in this configuration 154 00:11:46,790 --> 00:11:47,290 space? 155 00:11:50,960 --> 00:11:51,760 How does it look? 156 00:11:51,760 --> 00:11:53,240 Is it a point? 157 00:11:53,240 --> 00:11:54,020 A line? 158 00:11:54,020 --> 00:11:55,603 A surface? 159 00:11:55,603 --> 00:11:56,790 What is it? 160 00:12:02,646 --> 00:12:03,622 Sorry? 161 00:12:03,622 --> 00:12:05,100 STUDENT: A path. 162 00:12:05,100 --> 00:12:06,180 PROFESSOR: It's a path. 163 00:12:06,180 --> 00:12:07,190 It's a line. 164 00:12:07,190 --> 00:12:10,130 Indeed, you look at your clock. 165 00:12:10,130 --> 00:12:13,410 And at time equals 0, well, it takes some values. 166 00:12:13,410 --> 00:12:17,490 And you're fine, OK, here it at time equals 0. 167 00:12:17,490 --> 00:12:20,760 At time equal 1, the values change. 168 00:12:20,760 --> 00:12:23,130 There's one parameter, which is time. 169 00:12:23,130 --> 00:12:26,760 So this traces a path. 170 00:12:26,760 --> 00:12:31,860 As time goes by, the core in this changing in time and this 171 00:12:31,860 --> 00:12:37,090 is a line parameterized by time-- 172 00:12:37,090 --> 00:12:51,060 so a path gamma parameterized by time. 173 00:12:51,060 --> 00:12:56,250 And that represents the evolution of your system. 174 00:12:56,250 --> 00:13:02,370 At time equals 0, this point could be R at t equals 0. 175 00:13:02,370 --> 00:13:09,210 And maybe this point is R a t equal T final. 176 00:13:09,210 --> 00:13:12,510 And this system is going like that. 177 00:13:12,510 --> 00:13:17,130 You should imagine the system as traveling in that configuration 178 00:13:17,130 --> 00:13:18,330 space. 179 00:13:18,330 --> 00:13:19,510 That's what it does. 180 00:13:19,510 --> 00:13:22,780 That's why we put the configuration space. 181 00:13:22,780 --> 00:13:26,040 And we now have a set-- 182 00:13:26,040 --> 00:13:29,190 not the set-- a time dependent Hamiltonian, 183 00:13:29,190 --> 00:13:35,640 because while H was a function of R from the beginning, now 184 00:13:35,640 --> 00:13:37,750 R is a function of time. 185 00:13:37,750 --> 00:13:41,400 So this is your new Hamiltonian. 186 00:13:41,400 --> 00:13:45,010 And this is time dependent-- 187 00:13:45,010 --> 00:13:46,920 dependent Hamiltonian. 188 00:13:51,450 --> 00:13:54,450 But now, the interesting thing is 189 00:13:54,450 --> 00:13:59,610 that the work you did before in finding the energy 190 00:13:59,610 --> 00:14:05,820 eigenstates for any position in this configuration space 191 00:14:05,820 --> 00:14:10,920 is giving you the instantaneous energy eigenstates, 192 00:14:10,920 --> 00:14:19,740 because if this equation here holds for any value of R, 193 00:14:19,740 --> 00:14:24,090 it certainly holds for the values of R corresponding 194 00:14:24,090 --> 00:14:25,870 to some particular time. 195 00:14:28,830 --> 00:14:43,770 So psi n of R of t is equal to En of R of t psi n of R of t. 196 00:14:43,770 --> 00:14:47,780 So it's an interesting interplay in which 197 00:14:47,780 --> 00:14:52,890 the act that you know your energy eigenstates everywhere 198 00:14:52,890 --> 00:14:55,980 in your configuration space allows 199 00:14:55,980 --> 00:15:01,980 you to find the time evolved states, 200 00:15:01,980 --> 00:15:07,800 the time dependent energy eigenstates, the instantaneous 201 00:15:07,800 --> 00:15:12,060 energy eigenstates are found here. 202 00:15:12,060 --> 00:15:17,780 So what we want to do now is evaluate in this language 203 00:15:17,780 --> 00:15:22,830 the geometric phase, this phase. 204 00:15:22,830 --> 00:15:25,380 I want to understand what this phase is 205 00:15:25,380 --> 00:15:28,130 in this geometric language.