1 00:00:01,390 --> 00:00:06,170 PROFESSOR: OK, degenerate perturbation theory. 2 00:00:06,170 --> 00:00:11,420 OK, we've done nicely our non-degenerate case. 3 00:00:11,420 --> 00:00:19,450 So we'll get degenerate done in a very clear way, I think. 4 00:00:32,060 --> 00:00:34,170 One more blackboard. 5 00:00:34,170 --> 00:00:37,950 So the first thing I want to say about degenerate 6 00:00:37,950 --> 00:00:42,060 perturbation theories, when it fails and why it fails 7 00:00:42,060 --> 00:00:43,350 and what goes wrong. 8 00:00:43,350 --> 00:00:49,170 So degenerate perturbation theory. 9 00:01:04,480 --> 00:01:09,580 Trivial example to begin with, why not, h of lambda, 10 00:01:09,580 --> 00:01:15,880 again, is equal to h0 plus lambda delta h. 11 00:01:15,880 --> 00:01:22,300 And for h0, we'll take original Hamiltonian with energies 1 12 00:01:22,300 --> 00:01:28,755 and 1, and for delta h, I'll take 13 00:01:28,755 --> 00:01:34,340 an off-diagonal Hamiltonian, a Pauli matrix, 14 00:01:34,340 --> 00:01:36,305 and that's our delta h. 15 00:01:42,750 --> 00:01:51,270 And then we say OK, blindly, not worry about this degeneracy, 16 00:01:51,270 --> 00:01:54,810 and use the formulas that we have for non-degenerate states. 17 00:01:54,810 --> 00:01:58,410 And we would say well, for the first state 18 00:01:58,410 --> 00:02:00,330 and the second state what do we have? 19 00:02:04,420 --> 00:02:13,110 E, I'll call them 1 and 2, not 0 and 1. 20 00:02:13,110 --> 00:02:19,310 So let's call them 1 of lambda will 21 00:02:19,310 --> 00:02:27,080 be equal to the first value, 1, plus, if the formula is right, 22 00:02:27,080 --> 00:02:32,540 delta h times lambda, 1, 1. 23 00:02:32,540 --> 00:02:38,250 The matrix element of the perturbation in the 1, 1 state. 24 00:02:38,250 --> 00:02:42,020 Similarly, E2, the other eigenvalue, 25 00:02:42,020 --> 00:02:49,070 should be 1, there's the second eigenvalue, plus lambda, 26 00:02:49,070 --> 00:02:51,260 delta h 2, 2. 27 00:02:54,530 --> 00:02:58,080 That's what the formula would say. 28 00:02:58,080 --> 00:03:02,430 But this is completely incorrect. 29 00:03:02,430 --> 00:03:02,940 Why? 30 00:03:02,940 --> 00:03:12,150 Because delta h 1, 1 is the 1, 1 element of delta h, and it's 0. 31 00:03:12,150 --> 00:03:18,720 And the 2, 2 element of delta h is also 0, 32 00:03:18,720 --> 00:03:22,770 and therefore this says 1 and 1, that the eigenvalues haven't 33 00:03:22,770 --> 00:03:25,260 changed. 34 00:03:25,260 --> 00:03:31,650 On the other hand, we know that the matrix, the total matrix, 35 00:03:31,650 --> 00:03:39,660 which is 1 lambda, lambda 1 has eigenvectors, 36 00:03:39,660 --> 00:03:44,670 1 over square root of 2, 1, 1, and 1 over square root of 2, 37 00:03:44,670 --> 00:03:49,600 1 minus 1, with eigenvalues-- 38 00:03:49,600 --> 00:03:54,730 this is our eigenvectors and eigenvalues-- 39 00:03:54,730 --> 00:03:57,955 1 plus lambda and 1 minus lambda. 40 00:04:02,370 --> 00:04:05,660 So the eigenvalues of the matrix are 1 plus lambda 41 00:04:05,660 --> 00:04:07,050 and 1 minus lambda. 42 00:04:07,050 --> 00:04:11,880 And this formula, to first order in lambda, gave us nothing. 43 00:04:11,880 --> 00:04:16,430 It failed badly. 44 00:04:16,430 --> 00:04:17,184 It's a disaster. 45 00:04:20,630 --> 00:04:25,920 So you can say, well, what happened? 46 00:04:25,920 --> 00:04:32,120 And maybe a clue is on the fact of the eigenvectors. 47 00:04:37,500 --> 00:04:44,450 These are the eigenvectors of the total matrix. 48 00:04:44,450 --> 00:04:47,140 These are in fact, also the eigenvectors 49 00:04:47,140 --> 00:04:48,180 of the perturbation. 50 00:04:53,230 --> 00:04:56,440 On the other hand, when we said OK, this 51 00:04:56,440 --> 00:05:00,880 is the first state, the first eigenvector, 52 00:05:00,880 --> 00:05:04,840 we thought of it as 1, 0 on the Hamiltonian, 53 00:05:04,840 --> 00:05:07,840 on that eigenvector gave you the energy 1. 54 00:05:07,840 --> 00:05:13,660 The second energy corresponds to the eigenvector 0, 1. 55 00:05:13,660 --> 00:05:16,240 That's what we usually use for our matrices. 56 00:05:18,800 --> 00:05:22,450 So here is the strange thing that seems to have happened. 57 00:05:22,450 --> 00:05:25,510 For the original Hamiltonian, [INAUDIBLE] 58 00:05:25,510 --> 00:05:28,690 we had this eigenvector and this eigenvector, 59 00:05:28,690 --> 00:05:32,170 and then suddenly you turn on the perturbation 60 00:05:32,170 --> 00:05:36,370 and lambda can be 10 to the minus 1,000, 61 00:05:36,370 --> 00:05:42,280 and already the eigenvectors jump and become this one. 62 00:05:42,280 --> 00:05:44,860 They go from this one to that one. 63 00:05:44,860 --> 00:05:48,870 You just add a perturbation that you even cannot measure, 64 00:05:48,870 --> 00:05:51,859 and the eigenvectors change. 65 00:05:51,859 --> 00:05:52,400 That's crazy. 66 00:05:55,850 --> 00:06:02,570 The explanation is this thing that we usually, 67 00:06:02,570 --> 00:06:08,180 sometimes forget to say in a mathematically precise way. 68 00:06:08,180 --> 00:06:15,050 These are not the eigenvectors of the original matrix. 69 00:06:15,050 --> 00:06:18,050 Since the original matrix is degenerate, 70 00:06:18,050 --> 00:06:22,220 this is one possible choice of eigenvectors. 71 00:06:22,220 --> 00:06:26,610 Any linear combination of them is an eigenvector. 72 00:06:26,610 --> 00:06:30,720 So this space of eigenvectors of this matrix 73 00:06:30,720 --> 00:06:34,100 is the span of these things. 74 00:06:34,100 --> 00:06:36,590 So there was no reason to say, oh, these 75 00:06:36,590 --> 00:06:41,510 were the eigenvectors before, and now they've changed. 76 00:06:41,510 --> 00:06:42,680 They're this. 77 00:06:42,680 --> 00:06:43,670 No. 78 00:06:43,670 --> 00:06:47,280 Before, you don't know what are the eigenvectors. 79 00:06:47,280 --> 00:06:48,330 They're ambiguous. 80 00:06:48,330 --> 00:06:52,070 There's no way to decide who they are. 81 00:06:52,070 --> 00:06:54,590 This, this, or any linear combination. 82 00:06:54,590 --> 00:06:57,380 Remember, when you have a degenerate eigenstate, 83 00:06:57,380 --> 00:07:00,980 any superposition of them is a degenerate eigenstate. 84 00:07:00,980 --> 00:07:05,896 So the explanation is that, in some sense, 85 00:07:05,896 --> 00:07:11,570 these eigenvectors of the perturbed Hamiltonian 86 00:07:11,570 --> 00:07:15,740 is one of the possible choices of a basis of eigenvectors 87 00:07:15,740 --> 00:07:19,730 for the original space, and what the perturbation 88 00:07:19,730 --> 00:07:23,000 does is break the degeneracy. 89 00:07:23,000 --> 00:07:27,410 All those equivalent eigenvectors suddenly 90 00:07:27,410 --> 00:07:29,110 are not all equivalent. 91 00:07:29,110 --> 00:07:30,680 There are some preferred ones. 92 00:07:34,420 --> 00:07:38,690 So the fact is that the formulas are not working right, 93 00:07:38,690 --> 00:07:43,530 and we have to do this again. 94 00:07:43,530 --> 00:07:45,210 So here is what we're going to do. 95 00:07:45,210 --> 00:07:52,100 We're going to set this up for a systematic analysis 96 00:07:52,100 --> 00:07:55,280 to get this right. 97 00:07:55,280 --> 00:07:57,230 So systematic analysis. 98 00:08:02,920 --> 00:08:11,310 So again, we say h0 is known and it will have an E of, say, 99 00:08:11,310 --> 00:08:23,220 1, 0, an E 2, 0, like that, until you encounter an E n, 0 100 00:08:23,220 --> 00:08:28,680 that happens to be equal to the next one, E, n plus 1, 0, 101 00:08:28,680 --> 00:08:30,750 and happens to be equal to the next one, 102 00:08:30,750 --> 00:08:34,650 all the way to an E n plus capital 103 00:08:34,650 --> 00:08:40,950 N minus 1, 0, which is then smaller 104 00:08:40,950 --> 00:08:49,320 than the next one, which is E n plus N and then again. 105 00:08:49,320 --> 00:08:54,090 So I'm saying in funny ways the fact 106 00:08:54,090 --> 00:08:59,550 that, yes, you had some states and suddenly you 107 00:08:59,550 --> 00:09:09,700 hit a collection of N energy eigenvalues that are identical. 108 00:09:09,700 --> 00:09:13,500 They're all equal to En0. 109 00:09:13,500 --> 00:09:23,990 All n states have energy en0. 110 00:09:23,990 --> 00:09:28,940 So it is as if you have this matrix h0 111 00:09:28,940 --> 00:09:30,690 and there are all kinds of numbers. 112 00:09:30,690 --> 00:09:35,240 And then there's a whole block where all the entries of size 113 00:09:35,240 --> 00:09:39,900 n by n where all the entries are the same. 114 00:09:39,900 --> 00:09:48,540 So n, n plus 1, n plus 2, up to N minus 1 is n entries, 115 00:09:48,540 --> 00:09:50,685 and they all have the same energy. 116 00:09:53,790 --> 00:09:58,140 And the corresponding eigenstates 117 00:09:58,140 --> 00:10:01,260 are going to be called n-- 118 00:10:01,260 --> 00:10:04,420 we're going to use the label n for all of them, 119 00:10:04,420 --> 00:10:07,800 even though the energies are all the same. 120 00:10:07,800 --> 00:10:10,330 So there's just an E n energy. 121 00:10:10,330 --> 00:10:13,440 So we have N state, so there will 122 00:10:13,440 --> 00:10:24,460 be an n1, an n2, up to an nN. 123 00:10:28,620 --> 00:10:39,210 All those states are going to form an orthonormal basis 124 00:10:39,210 --> 00:10:43,080 for a space that we're going to call vn. 125 00:10:45,870 --> 00:10:52,110 So the space spanned by this state, we're going to go vn, 126 00:10:52,110 --> 00:10:55,620 with the n reminding you it has to do with the n 127 00:10:55,620 --> 00:11:04,890 states, states with energy described by the label n. 128 00:11:04,890 --> 00:11:08,580 So this is the degenerate subspace. 129 00:11:08,580 --> 00:11:14,760 This is the space of all those states that have energy En0. 130 00:11:14,760 --> 00:11:16,905 So I'll state that here. 131 00:11:20,970 --> 00:11:25,380 So it's quite important to get our notation right here. 132 00:11:27,890 --> 00:11:30,200 Otherwise we don't understand what's going on. 133 00:11:30,200 --> 00:11:42,290 So h0, n0k, they all have energy En0, n0k. 134 00:11:45,440 --> 00:11:54,940 And this is for k equals 1 up to N. Now OK, 135 00:11:54,940 --> 00:11:58,159 this is your degenerate subspace. 136 00:11:58,159 --> 00:11:59,200 These are all the states. 137 00:11:59,200 --> 00:12:03,270 And we now want to know what happens to this space, 138 00:12:03,270 --> 00:12:07,780 to all these states, when the energy turns on. 139 00:12:07,780 --> 00:12:11,890 This is not just a theoretical construct. 140 00:12:11,890 --> 00:12:16,120 When you start asking what happens to the first excited 141 00:12:16,120 --> 00:12:18,640 states in the hydrogen atom, you already 142 00:12:18,640 --> 00:12:24,710 have four states there, l equals 1, l equals 0 states, 143 00:12:24,710 --> 00:12:26,880 n equals 2. 144 00:12:26,880 --> 00:12:30,510 And you have degenerate states and immediately you're 145 00:12:30,510 --> 00:12:34,360 stuck in this situation. 146 00:12:34,360 --> 00:12:46,240 So I will also use the notation that the total space, 147 00:12:46,240 --> 00:12:56,920 a curly h, is the sum of vn plus a v hat. 148 00:12:56,920 --> 00:12:59,420 This is called the direct sum. 149 00:12:59,420 --> 00:13:03,380 At this point it just doesn't matter too much. 150 00:13:03,380 --> 00:13:08,940 These are linearly independent subspaces, vn and v hat, 151 00:13:08,940 --> 00:13:14,320 and basically you think as v hat as all the other states. 152 00:13:14,320 --> 00:13:17,470 Yes, there were these degenerate subspace 153 00:13:17,470 --> 00:13:23,110 and all the other states of our v hat. 154 00:13:23,110 --> 00:13:32,140 So v hat is the span of all other states. 155 00:13:32,140 --> 00:13:37,790 And we'll call them p0, or what letter? 156 00:13:37,790 --> 00:13:44,620 Yeah, p0, with p equals some numbers. 157 00:13:44,620 --> 00:13:47,050 So this is a good notation. 158 00:13:47,050 --> 00:13:49,510 It allows you to distinguish. 159 00:13:49,510 --> 00:13:54,040 The degenerate states use 2 labels. 160 00:13:54,040 --> 00:13:56,560 Maybe you only needed 1 label, but you 161 00:13:56,560 --> 00:13:58,660 will get confused with the notation 162 00:13:58,660 --> 00:14:00,350 if you just use 1 label. 163 00:14:00,350 --> 00:14:03,130 So if that's the case, degenerate state, 164 00:14:03,130 --> 00:14:05,560 but by putting the n here you now 165 00:14:05,560 --> 00:14:07,870 know that you're talking about degenerate states. 166 00:14:07,870 --> 00:14:09,520 When you have a single label you're 167 00:14:09,520 --> 00:14:14,110 talking about the other states in the space. 168 00:14:14,110 --> 00:14:19,390 So it's very good when your notation 169 00:14:19,390 --> 00:14:22,000 makes it easy to think and recognize 170 00:14:22,000 --> 00:14:24,890 the equations that you have. 171 00:14:24,890 --> 00:14:30,400 And v hat in this, are orthogonal spaces. 172 00:14:30,400 --> 00:14:34,900 v hat is perpendicular to vn. 173 00:14:34,900 --> 00:14:39,700 The inner product of any state outside of degenerate space, 174 00:14:39,700 --> 00:14:42,090 with a state in the general space, is 0. 175 00:14:46,130 --> 00:14:46,630 OK. 176 00:14:51,030 --> 00:14:51,750 Very good. 177 00:14:51,750 --> 00:14:56,350 So let's now do the important thing. 178 00:15:00,380 --> 00:15:02,560 I can do it here, I think. 179 00:15:02,560 --> 00:15:04,690 I'll do it here. 180 00:15:04,690 --> 00:15:06,360 So what do we want to do? 181 00:15:06,360 --> 00:15:08,310 What is the question here? 182 00:15:08,310 --> 00:15:10,660 The question is the following. 183 00:15:10,660 --> 00:15:14,370 We have a state n0k. 184 00:15:14,370 --> 00:15:19,350 We have N of those states, and we 185 00:15:19,350 --> 00:15:23,250 want to figure out what they become as you 186 00:15:23,250 --> 00:15:25,200 turn on the perturbation. 187 00:15:25,200 --> 00:15:30,030 So using the old notation, we'll say they become this. 188 00:15:30,030 --> 00:15:32,340 And what is that going to be? 189 00:15:32,340 --> 00:15:37,650 It is going to be n0k, the original state, what 190 00:15:37,650 --> 00:15:42,270 it was, plus order lambda, the first correction, 191 00:15:42,270 --> 00:15:51,010 so n1 for this k state, plus dot dot dot. 192 00:15:51,010 --> 00:15:55,210 For the energies, we have En0. 193 00:15:55,210 --> 00:15:58,780 That was the energy of every state 194 00:15:58,780 --> 00:16:00,340 in the degenerate subspace. 195 00:16:00,340 --> 00:16:05,230 Now it's going to become En lambda. 196 00:16:11,740 --> 00:16:16,590 But if I say En lambda I'm already making a mistake, 197 00:16:16,590 --> 00:16:20,860 because I'm looking at the fixed k. 198 00:16:20,860 --> 00:16:25,240 And a fixed k means we chose one of these states, 199 00:16:25,240 --> 00:16:29,800 and any single one of the states, the energy 200 00:16:29,800 --> 00:16:31,720 can grow in a different way. 201 00:16:31,720 --> 00:16:40,140 So I should call this Enk, because we're 202 00:16:40,140 --> 00:16:46,210 talking about this state, will be equal to En0-- 203 00:16:46,210 --> 00:16:51,130 yes, they all have the same first zeroth order energy. 204 00:16:51,130 --> 00:17:07,520 But then Enk1 plus lambda squared Enk2 and so on. 205 00:17:07,520 --> 00:17:16,730 So this is the fate of the kth state. 206 00:17:22,900 --> 00:17:28,569 And the degeneracy will be broken to first order 207 00:17:28,569 --> 00:17:34,450 if these Enk's become different numbers, because if they become 208 00:17:34,450 --> 00:17:37,120 different numbers in lambda they're going 209 00:17:37,120 --> 00:17:39,410 to start splitting the states. 210 00:17:39,410 --> 00:17:43,810 Remember this picture we had last time of several states 211 00:17:43,810 --> 00:17:45,100 at one point? 212 00:17:45,100 --> 00:17:48,610 If the order lambda corrections are different, 213 00:17:48,610 --> 00:17:50,560 the states split. 214 00:17:50,560 --> 00:17:53,620 The degeneracy is resolved. 215 00:17:53,620 --> 00:17:56,680 And we can calculate things more easily. 216 00:17:56,680 --> 00:18:01,620 If it's not resolved to first order, it's harder. 217 00:18:01,620 --> 00:18:04,210 It will be all of next lecture to figure out 218 00:18:04,210 --> 00:18:06,910 what happens in that case. 219 00:18:06,910 --> 00:18:10,300 We discussed last time that the n1 correction 220 00:18:10,300 --> 00:18:14,980 didn't have any component along the n0 vector. 221 00:18:14,980 --> 00:18:18,550 We could always arrange that to happen. 222 00:18:18,550 --> 00:18:23,420 Here, we can arrange something similar to happen. 223 00:18:23,420 --> 00:18:29,780 So we will still assume, and we can 224 00:18:29,780 --> 00:18:36,350 check that's always possible, that vnp, 225 00:18:36,350 --> 00:18:50,060 the corrections to the state k at order p for p equals 1, 2, 226 00:18:50,060 --> 00:18:54,960 3, because it's not 0, are orthogonal to n0k. 227 00:18:59,800 --> 00:19:05,830 So this state doesn't have any component along n0k, 228 00:19:05,830 --> 00:19:07,960 and this state doesn't have any component 229 00:19:07,960 --> 00:19:10,010 along the original one. 230 00:19:10,010 --> 00:19:13,300 It's always possible to do that, just like we did it 231 00:19:13,300 --> 00:19:15,580 in the non-degenerate case. 232 00:19:18,220 --> 00:19:22,950 Moreover, this is something I want you to notice. 233 00:19:22,950 --> 00:19:27,450 We're saying that the state n1 doesn't 234 00:19:27,450 --> 00:19:31,860 have any component along the state n0 for a given k, 235 00:19:31,860 --> 00:19:38,280 but the state n1 can have components along n0 236 00:19:38,280 --> 00:19:41,910 for a different k. 237 00:19:41,910 --> 00:19:46,980 So while they've nth order or a pth order correction 238 00:19:46,980 --> 00:19:49,410 doesn't have component along this, 239 00:19:49,410 --> 00:19:54,240 it can have component for an l here, 240 00:19:54,240 --> 00:19:56,430 where l is different from k. 241 00:19:56,430 --> 00:20:16,040 So it means that npk still can have a component in vn. 242 00:20:16,040 --> 00:20:19,020 Remember, vn is this whole thing. 243 00:20:19,020 --> 00:20:22,850 So if you're doing the kth one, well, n1k 244 00:20:22,850 --> 00:20:24,770 doesn't have a component along that one, 245 00:20:24,770 --> 00:20:28,320 but it may have a component along all the others. 246 00:20:28,320 --> 00:20:32,120 So it may still have a component, that correction, 247 00:20:32,120 --> 00:20:33,110 in vn. 248 00:20:33,110 --> 00:20:35,990 In fact, that's what will make the problem a little hard 249 00:20:35,990 --> 00:20:46,040 to do, but it's a good thing to try to figure out this thing. 250 00:20:46,040 --> 00:20:50,560 So what is the equation we want to solve? 251 00:20:50,560 --> 00:20:57,250 The usual equation, h of lambda on nk lambda 252 00:20:57,250 --> 00:21:05,860 is equal to Enk of lambda nk of lambda. 253 00:21:05,860 --> 00:21:08,830 So we produce the general state that's 254 00:21:08,830 --> 00:21:11,380 its energy for the full Hamiltonian. 255 00:21:17,360 --> 00:21:19,350 That's our Schrodinger equation. 256 00:21:19,350 --> 00:21:20,920 So what do we have to do? 257 00:21:20,920 --> 00:21:25,640 We have to do exactly what we did before, 258 00:21:25,640 --> 00:21:29,930 plug in that series, separate the terms with various lambdas, 259 00:21:29,930 --> 00:21:33,150 and see what we get. 260 00:21:33,150 --> 00:21:34,580 So here is what we get. 261 00:21:34,580 --> 00:21:48,830 To order lambda to the 0, you get h0 minus En0 on n0k 262 00:21:48,830 --> 00:21:49,750 equals 0. 263 00:21:53,670 --> 00:21:59,340 And that equation, as it was the case for the non-degenerate 264 00:21:59,340 --> 00:22:01,770 case-- 265 00:22:01,770 --> 00:22:04,620 sorry for the redundancy-- 266 00:22:04,620 --> 00:22:06,420 it's trivially satisfied. 267 00:22:06,420 --> 00:22:10,560 We've stated that those are the energies in the top equation 268 00:22:10,560 --> 00:22:11,490 on that blackboard. 269 00:22:11,490 --> 00:22:13,980 So this equation we don't need to worry about. 270 00:22:13,980 --> 00:22:17,150 That's not too difficult. 271 00:22:17,150 --> 00:22:31,180 Lambda 1, h0 minus En0 and 1k will 272 00:22:31,180 --> 00:22:40,495 be equal to Enk1 minus delta h n0k. 273 00:22:50,180 --> 00:22:51,910 Last equation. 274 00:22:51,910 --> 00:22:58,980 I'm starting to get lazy to write them out, but we must. 275 00:23:02,190 --> 00:23:25,790 n2k is equal to minus delta h and 1k plus Enk2 and 0k. 276 00:23:29,040 --> 00:23:38,100 OK and these equations are equations for k fixed, 277 00:23:38,100 --> 00:23:42,600 but every term in the equation has the same k, 278 00:23:42,600 --> 00:23:46,560 but k then can run from 1 up to n. 279 00:23:46,560 --> 00:23:52,675 So three equations times n times, there we go. 280 00:23:55,520 --> 00:23:58,115 OK, these are our equations this time. 281 00:24:01,570 --> 00:24:03,060 And we need to understand them. 282 00:24:05,620 --> 00:24:08,430 In fact, we need to solve them. 283 00:24:08,430 --> 00:24:13,920 What we've gained experience with the non-degenerate case 284 00:24:13,920 --> 00:24:16,020 is going to come very useful here, 285 00:24:16,020 --> 00:24:19,440 although some things are not going to be exactly the same. 286 00:24:19,440 --> 00:24:25,310 We're going to try to find the energy corrections here, 287 00:24:25,310 --> 00:24:29,780 but calculating the state n1 is going to be a little harder. 288 00:24:29,780 --> 00:24:31,250 We won't finish today-- 289 00:24:31,250 --> 00:24:33,350 we won't have much time left-- 290 00:24:33,350 --> 00:24:37,900 but what's going to happen is that you 291 00:24:37,900 --> 00:24:47,400 can calculate the state n1, the part in the space v hat. 292 00:24:47,400 --> 00:24:50,550 But the part in the degenerate subspace, 293 00:24:50,550 --> 00:24:54,500 where I said that npk still can have a component 294 00:24:54,500 --> 00:24:57,870 in the degenerate subspace, cannot be calculated from this 295 00:24:57,870 --> 00:24:59,460 equation. 296 00:24:59,460 --> 00:25:03,570 So even when we're finished doing this first equation, 297 00:25:03,570 --> 00:25:05,160 you're going to find this equation, 298 00:25:05,160 --> 00:25:09,720 you still have not calculated all of the states n1. 299 00:25:09,720 --> 00:25:13,080 You're going to have to go through the second equation 300 00:25:13,080 --> 00:25:16,380 to find the missing part of the state n1. 301 00:25:16,380 --> 00:25:20,720 So it's going to be pretty interesting.