1 00:00:01,030 --> 00:00:04,250 PROFESSOR: So let's attempt to solve something. 2 00:00:04,250 --> 00:00:09,550 And that first step is going to be nice and simple and very 3 00:00:09,550 --> 00:00:11,020 illuminating, as well. 4 00:00:15,720 --> 00:00:19,790 So we're going to do a three step procedure. 5 00:00:19,790 --> 00:00:22,856 Three step procedure. 6 00:00:22,856 --> 00:00:25,520 Three step procedure. 7 00:00:30,480 --> 00:00:34,710 And basically, we're going to use 8 00:00:34,710 --> 00:00:38,220 this equation, the ordered lambda equation, 9 00:00:38,220 --> 00:00:41,340 to find the energy corrections. 10 00:00:41,340 --> 00:00:49,260 One, ordered lambda equation for energy corrections. 11 00:00:53,130 --> 00:01:03,600 Two, ordered lambda equation to find the component of n1k 12 00:01:03,600 --> 00:01:05,820 in v hat. 13 00:01:05,820 --> 00:01:09,280 And three, we're going to look at the ordered lambda 2 14 00:01:09,280 --> 00:01:13,260 equation to find the component of that same state 15 00:01:13,260 --> 00:01:14,670 in the degenerate subspace. 16 00:01:19,060 --> 00:01:20,730 So let's do the first step. 17 00:01:28,860 --> 00:01:36,200 And for that, we're going to overlap that equation, 18 00:01:36,200 --> 00:01:37,885 this ordered lambda equation. 19 00:01:40,690 --> 00:01:49,740 So for step one, we're going to hit the equation with n0l 20 00:01:49,740 --> 00:01:50,580 from the left. 21 00:01:54,220 --> 00:01:54,790 OK. 22 00:01:54,790 --> 00:01:56,850 n0l from the left. 23 00:01:56,850 --> 00:01:57,910 Here it comes. 24 00:01:57,910 --> 00:01:58,560 Boom. 25 00:01:58,560 --> 00:02:00,700 It's here. 26 00:02:00,700 --> 00:02:03,450 What happens now? 27 00:02:03,450 --> 00:02:07,570 Well, h0 on that state, n0l, that 28 00:02:07,570 --> 00:02:09,770 is part of the degenerate subspace. 29 00:02:09,770 --> 00:02:14,870 So it has energy n0 with respect to the original unperturbed 30 00:02:14,870 --> 00:02:15,980 Hamiltonian. 31 00:02:15,980 --> 00:02:20,450 So you get n0 minus n0, it's 0. 32 00:02:20,450 --> 00:02:23,090 So the left hand side vanishes. 33 00:02:23,090 --> 00:02:28,250 Kills left hand side. 34 00:02:28,250 --> 00:02:31,090 So we just look at the right hand side. 35 00:02:31,090 --> 00:02:48,260 And we got n0l Enk1 minus delta H n0k equals 0. 36 00:02:48,260 --> 00:02:50,330 That was the right hand side. 37 00:02:50,330 --> 00:02:51,710 So far, so good. 38 00:02:51,710 --> 00:02:54,350 Nice and simple. 39 00:02:54,350 --> 00:02:58,220 From here, what do we get? 40 00:02:58,220 --> 00:03:02,180 Let's write it just by moving one term to the left and one 41 00:03:02,180 --> 00:03:05,050 term to the right. 42 00:03:05,050 --> 00:03:14,780 n0k Enk1 delta lk. 43 00:03:18,590 --> 00:03:28,010 And this should be true for all k and l in 1 up to n. 44 00:03:28,010 --> 00:03:31,460 Because those equations are for all k 45 00:03:31,460 --> 00:03:35,510 and we could have hit with all l. 46 00:03:35,510 --> 00:03:38,385 And now this is an amazingly nice equation. 47 00:03:41,190 --> 00:03:45,450 It tells you a nice story. 48 00:03:45,450 --> 00:03:47,740 What is this story? 49 00:03:47,740 --> 00:03:51,210 The story is that look at this. 50 00:03:51,210 --> 00:03:57,310 This equation says that if you want this to hold it better 51 00:03:57,310 --> 00:04:05,440 be that delta H is diagonal on the basis that you're using. 52 00:04:05,440 --> 00:04:11,590 Because for k and l running in n by n. 53 00:04:11,590 --> 00:04:22,420 So this says that delta H is diagonal in the chosen 54 00:04:22,420 --> 00:04:27,700 basis of the subspace vn. 55 00:04:27,700 --> 00:04:30,430 Delta H is not diagonal elsewhere. 56 00:04:30,430 --> 00:04:34,210 On the big space, it may not be diagonal. 57 00:04:34,210 --> 00:04:40,360 But on the little degenerate space, it better be diagonal. 58 00:04:40,360 --> 00:04:44,470 So what it says is that, if you want to start your perturbation 59 00:04:44,470 --> 00:04:48,790 theory, you cannot use an arbitrary basis of states. 60 00:04:48,790 --> 00:04:50,530 Maybe you chose it wrong. 61 00:04:50,530 --> 00:04:54,830 You have to start in the degenerate subspace 62 00:04:54,830 --> 00:04:59,910 with a basis that makes the perturbation diagonal. 63 00:04:59,910 --> 00:05:03,360 And that's what our little example had. 64 00:05:03,360 --> 00:05:07,100 It says, even to begin with, you should 65 00:05:07,100 --> 00:05:11,520 have started with the basis that makes the perturbation 66 00:05:11,520 --> 00:05:12,510 diagonal. 67 00:05:12,510 --> 00:05:16,830 In that case, you will find the formulas giving you 68 00:05:16,830 --> 00:05:18,570 the right answers. 69 00:05:18,570 --> 00:05:26,090 And then, once you have the matrix being diagonal, 70 00:05:26,090 --> 00:05:31,580 you can take l equal to k. 71 00:05:31,580 --> 00:05:33,860 And then you'll find on the right hand 72 00:05:33,860 --> 00:05:40,400 sides Enk1 is equal to n. 73 00:05:40,400 --> 00:05:47,210 l is equal to k, so n0k delta H n0k. 74 00:05:50,600 --> 00:05:55,400 So the energy corrections are the diagonal elements 75 00:05:55,400 --> 00:05:56,450 of this matrix. 76 00:05:56,450 --> 00:05:57,900 What you would expect. 77 00:05:57,900 --> 00:06:03,770 So we will write this as delta H. We could put kk, 78 00:06:03,770 --> 00:06:05,710 but to remind you, its degenerate. 79 00:06:05,710 --> 00:06:08,330 You put nk nk. 80 00:06:12,290 --> 00:06:14,630 So we've done the first step and we've 81 00:06:14,630 --> 00:06:18,440 realized that this perturbation is a little funny. 82 00:06:18,440 --> 00:06:22,220 You really have to get started with the right basis. 83 00:06:22,220 --> 00:06:23,930 And what is the right basis? 84 00:06:23,930 --> 00:06:27,460 The basis that makes delta H diagonal. 85 00:06:27,460 --> 00:06:30,740 We'll see that everything is much simpler 86 00:06:30,740 --> 00:06:35,310 if the eigenvalues of this matrix are all different. 87 00:06:35,310 --> 00:06:37,290 So the degeneracy is broken. 88 00:06:37,290 --> 00:06:39,260 Then things are easier. 89 00:06:39,260 --> 00:06:42,250 If the degeneracy is not broken, then the degeneracy 90 00:06:42,250 --> 00:06:44,850 may be broken to order lambda squared, 91 00:06:44,850 --> 00:06:47,690 which is more interesting and it will be something 92 00:06:47,690 --> 00:06:49,500 we'll study next time. 93 00:06:49,500 --> 00:06:51,940 So that's all.