1 00:00:00,060 --> 00:00:01,780 The following content is provided 2 00:00:01,780 --> 00:00:04,019 under a Creative Commons license. 3 00:00:04,019 --> 00:00:06,880 Your support will help MIT OpenCourseWare continue 4 00:00:06,880 --> 00:00:10,740 to offer high quality educational resources for free. 5 00:00:10,740 --> 00:00:13,350 To make a donation or view additional materials 6 00:00:13,350 --> 00:00:17,258 from hundreds of MIT courses, visit MIT OpenCourseWare 7 00:00:17,258 --> 00:00:17,883 at ocw.mit.edu. 8 00:00:20,519 --> 00:00:21,935 PROFESSOR: We're going to continue 9 00:00:21,935 --> 00:00:26,520 our discussion of correlation functions, and in particular, 10 00:00:26,520 --> 00:00:28,980 g2 of 0. 11 00:00:28,980 --> 00:00:35,780 If you think I'm focusing a lot on one quantity, g2 of 0, 12 00:00:35,780 --> 00:00:37,290 that's correct. 13 00:00:37,290 --> 00:00:39,230 But I have to tell you, I have been 14 00:00:39,230 --> 00:00:42,400 involved in so many discussions with people 15 00:00:42,400 --> 00:00:46,670 who looked at g2 of 0 with both Einstein condensates 16 00:00:46,670 --> 00:00:49,890 when Bose-Einstein condensates in [INAUDIBLE] were discovered 17 00:00:49,890 --> 00:00:53,680 here at MIT by [INAUDIBLE] and collaborators. 18 00:00:53,680 --> 00:01:00,230 There was some mystery about, in essence, the g2 of 0 function. 19 00:01:00,230 --> 00:01:04,250 So a lot of physics actually goes into it. 20 00:01:04,250 --> 00:01:06,610 And I've learned a lot from my own research 21 00:01:06,610 --> 00:01:08,030 and through discussions. 22 00:01:08,030 --> 00:01:11,830 And in this unit, I want to summarize it. 23 00:01:11,830 --> 00:01:16,240 So the confusion sometimes comes because people 24 00:01:16,240 --> 00:01:18,920 use classical pictures, quantum pictures, 25 00:01:18,920 --> 00:01:21,010 and they may not see the relation. 26 00:01:21,010 --> 00:01:23,435 So let's continue the discussion. 27 00:01:29,990 --> 00:01:35,300 I want to go through four different views 28 00:01:35,300 --> 00:01:37,550 of the same physics that you will 29 00:01:37,550 --> 00:01:40,120 recognize that they're interrelated. 30 00:01:40,120 --> 00:01:41,910 The first one, just to repeat that, 31 00:01:41,910 --> 00:01:45,460 is if you have light which is Gaussian intensity 32 00:01:45,460 --> 00:01:48,690 fluctuations, light from random sources. 33 00:01:48,690 --> 00:01:51,330 I think if you would look at the twinkle of starlight, 34 00:01:51,330 --> 00:01:55,120 if you look at the light from a light bulb, 35 00:01:55,120 --> 00:01:56,970 because of the central limit theorem, 36 00:01:56,970 --> 00:02:00,240 you will find that the intensity that the electric field 37 00:02:00,240 --> 00:02:02,575 has a Gaussian distribution, and the intensity 38 00:02:02,575 --> 00:02:04,870 in exponential distribution. 39 00:02:04,870 --> 00:02:12,540 And if you then ask, what is g2 of 0, you'll find it's 2. 40 00:02:12,540 --> 00:02:15,480 Because for an exponential distribution, 41 00:02:15,480 --> 00:02:17,240 the average of the intensity squared 42 00:02:17,240 --> 00:02:20,660 is two times the intensity, the average of the-- what 43 00:02:20,660 --> 00:02:21,160 did I say. 44 00:02:21,160 --> 00:02:23,470 This average of the squared intensity 45 00:02:23,470 --> 00:02:28,695 is two times the average of the intensity squared. 46 00:02:33,470 --> 00:02:36,560 Before I forget it, one student asked me after class, 47 00:02:36,560 --> 00:02:41,170 I'm discussing g2 of 0, but what about g2 of tau? 48 00:02:41,170 --> 00:02:44,260 Well, my understanding is that almost all of the physics 49 00:02:44,260 --> 00:02:46,045 is in g2 of 0. 50 00:02:46,045 --> 00:02:51,640 And there is a simple number, 1 or 2, in those special cases. 51 00:02:51,640 --> 00:02:55,340 What happens is, if you have completely independent sources, 52 00:02:55,340 --> 00:02:57,600 if you completely independent statistics, 53 00:02:57,600 --> 00:03:02,335 then the probability of finding a second particle, 54 00:03:02,335 --> 00:03:04,700 a second photon, is independent of the first. 55 00:03:04,700 --> 00:03:08,670 So it means g2 of tau would be unity. 56 00:03:08,670 --> 00:03:11,730 This is the case for an uncoordinated system. 57 00:03:11,730 --> 00:03:17,210 But if you have g2 of 0 which is higher, this means correlation. 58 00:03:17,210 --> 00:03:19,100 This means some form of coherence. 59 00:03:19,100 --> 00:03:22,520 And usually, the correlated value simply 60 00:03:22,520 --> 00:03:26,840 decays to the uncorrelated value with a characteristic coherence 61 00:03:26,840 --> 00:03:27,730 time. 62 00:03:27,730 --> 00:03:29,830 And this characteristic coherence time 63 00:03:29,830 --> 00:03:32,880 can be inhomogeneous, technical. 64 00:03:32,880 --> 00:03:37,400 It can be limited by the Fourier transform of a light pulse, 65 00:03:37,400 --> 00:03:39,610 the monochromaticity, the bend which 66 00:03:39,610 --> 00:03:41,990 delta omega is 1 over tau. 67 00:03:41,990 --> 00:03:45,450 So it has all of the usual suspects 68 00:03:45,450 --> 00:03:48,580 for what limits the coherence time. 69 00:03:48,580 --> 00:03:51,230 So therefore in general, we're not 70 00:03:51,230 --> 00:03:54,740 learning something fundamental in looking at g2 of tau. 71 00:03:54,740 --> 00:03:58,400 We're just learning the usual spiel about correlation times 72 00:03:58,400 --> 00:03:59,260 and coherence times. 73 00:04:06,580 --> 00:04:12,560 The second angle I gave you with the brief interference 74 00:04:12,560 --> 00:04:15,720 is something which is deeply insightful. 75 00:04:15,720 --> 00:04:17,430 It shows you the following. 76 00:04:17,430 --> 00:04:22,029 If you have a plane wave, the intensity is constant. 77 00:04:22,029 --> 00:04:25,640 If you have two plane waves which interfere, 78 00:04:25,640 --> 00:04:28,540 you create density fluctuations, because the interference 79 00:04:28,540 --> 00:04:31,660 pattern can be constructive and can be destructive. 80 00:04:31,660 --> 00:04:34,630 So therefore, if the intensity fluctuates, 81 00:04:34,630 --> 00:04:41,360 then i square average is no longer i average square. 82 00:04:41,360 --> 00:04:45,060 And what happens is because of the nature of interference, 83 00:04:45,060 --> 00:04:53,240 because the average of cosine square kx is-- well, 84 00:04:53,240 --> 00:04:55,570 there are factors of 1/2 and 2 which just come out 85 00:04:55,570 --> 00:04:57,580 of cosine and sine square function. 86 00:04:57,580 --> 00:05:01,150 You get exactly g2 of 2. 87 00:05:01,150 --> 00:05:03,780 But that should already tell you something, 88 00:05:03,780 --> 00:05:08,860 which will be important for both quantum particles, and light, 89 00:05:08,860 --> 00:05:10,600 and the classic limit. 90 00:05:10,600 --> 00:05:16,230 The moment if you have light or particles in one single mode, 91 00:05:16,230 --> 00:05:18,410 you can't have any form of interference. 92 00:05:18,410 --> 00:05:20,150 Only two modes can interfere. 93 00:05:20,150 --> 00:05:23,940 And you will always get a g2 function of 1. 94 00:05:23,940 --> 00:05:26,490 But we'll come to that in a second. 95 00:05:26,490 --> 00:05:29,328 Any questions at that point? 96 00:05:29,328 --> 00:05:29,828 Yes. 97 00:05:29,828 --> 00:05:32,369 AUDIENCE: I thought that when we talked about the g2 function 98 00:05:32,369 --> 00:05:36,946 several weeks ago, you said that if we had a single mode 99 00:05:36,946 --> 00:05:39,850 thermal light, it would have the g2 function of 2. 100 00:05:45,520 --> 00:05:48,000 And that's therefore, all we were 101 00:05:48,000 --> 00:05:51,370 using for lasers when we used them in experiments 102 00:05:51,370 --> 00:05:53,700 is the fact that it's single mode, not the coherence 103 00:05:53,700 --> 00:05:54,885 in the g2 function. 104 00:06:00,110 --> 00:06:04,090 PROFESSOR: You have a good-- that's a good point, Cory. 105 00:06:04,090 --> 00:06:07,400 Let's just try to connect the two pictures. 106 00:06:20,750 --> 00:06:22,430 Slowly, slowly. 107 00:06:22,430 --> 00:06:24,660 What did we discuss? 108 00:06:24,660 --> 00:06:27,110 This question is great for me to repeat something. 109 00:06:27,110 --> 00:06:30,070 When we looked at black body radiation, 110 00:06:30,070 --> 00:06:32,050 I wrote down the partition function. 111 00:06:32,050 --> 00:06:35,650 And I said I'm only considering a single mode. 112 00:06:35,650 --> 00:06:43,670 And then, we have of course in thermal equilibrium 113 00:06:43,670 --> 00:06:46,680 a Boltzmann type, or Bose-Einstein type, 114 00:06:46,680 --> 00:06:50,890 distribution of finding certain numbers, 115 00:06:50,890 --> 00:06:55,800 number of photons populating the single mode. 116 00:06:55,800 --> 00:07:00,915 And that resulted in a g2 function of 2. 117 00:07:11,792 --> 00:07:13,958 AUDIENCE: It's not really single mode though, right? 118 00:07:13,958 --> 00:07:16,025 Because you're summing over many frequencies. 119 00:07:16,025 --> 00:07:17,650 PROFESSOR: No, it was single frequency. 120 00:07:24,710 --> 00:07:26,190 I have to think about it. 121 00:07:26,190 --> 00:07:28,090 That's a really good question. 122 00:07:28,090 --> 00:07:32,562 Right now, I would quickly say, in thermal equilibrium-- 123 00:07:32,562 --> 00:07:34,895 I'll give you partial answer, and when I think about it, 124 00:07:34,895 --> 00:07:38,960 I'll give you full answer on Friday 125 00:07:38,960 --> 00:07:41,430 at the beginning of the next class-- 126 00:07:41,430 --> 00:07:43,080 I think would be calculated where 127 00:07:43,080 --> 00:07:46,150 the thermal fluctuations in the intensity. 128 00:07:46,150 --> 00:07:48,515 And the intensity fluctuations, and those intensity 129 00:07:48,515 --> 00:07:49,056 fluctuations. 130 00:07:53,960 --> 00:07:57,585 Those intensity fluctuations result in a g2 function of 2. 131 00:07:57,585 --> 00:07:58,210 That's correct. 132 00:08:01,500 --> 00:08:04,780 Maybe what I want you to say here 133 00:08:04,780 --> 00:08:09,470 is, if you have two modes which have all maybe 134 00:08:09,470 --> 00:08:11,720 single occupation or constant occupation, 135 00:08:11,720 --> 00:08:15,340 and they interfere, then they create a spatial interference 136 00:08:15,340 --> 00:08:18,930 pattern if the phase between the two modes is random, 137 00:08:18,930 --> 00:08:22,340 which gives rise to additional fluctuation. 138 00:08:22,340 --> 00:08:27,890 So most likely, the two fluctuations are independent. 139 00:08:27,890 --> 00:08:30,470 One is the fluctuations because of the interference 140 00:08:30,470 --> 00:08:32,630 of two modes. 141 00:08:32,630 --> 00:08:37,000 But when I say the single mode has a g2 function of 1, 142 00:08:37,000 --> 00:08:40,565 I meant actually a single mode with constant amplitude. 143 00:08:43,260 --> 00:08:45,964 I'll double check and give you a more complete answer on Friday. 144 00:08:45,964 --> 00:08:46,630 Other questions? 145 00:08:50,770 --> 00:08:51,270 OK. 146 00:08:58,100 --> 00:09:07,255 The third view is classical versus quantum statistics. 147 00:09:24,610 --> 00:09:28,200 And I think this really shows that we need at least 148 00:09:28,200 --> 00:09:31,515 some quantumness to find correlations. 149 00:09:35,850 --> 00:09:39,070 Let's assume we have n particles. 150 00:09:39,070 --> 00:09:42,105 And we have N possible states. 151 00:09:49,180 --> 00:09:57,060 And if it's a classical system, let's 152 00:09:57,060 --> 00:10:04,270 assume we want to find one particle in a certain state. 153 00:10:04,270 --> 00:10:07,220 We have a big box and want to-- we have a big box, 154 00:10:07,220 --> 00:10:08,990 have a small sub-volume, and say what 155 00:10:08,990 --> 00:10:11,440 is the probability of finding one particle here? 156 00:10:15,550 --> 00:10:21,960 So this probability to find one particle 157 00:10:21,960 --> 00:10:31,190 is P1 is small n over big N. The probability to find 158 00:10:31,190 --> 00:10:31,900 two particles. 159 00:10:34,550 --> 00:10:41,770 If you have non-interacting classical particles, 160 00:10:41,770 --> 00:10:43,670 well, it's simply P1 squared. 161 00:10:46,880 --> 00:10:49,000 Independent classical particles, they 162 00:10:49,000 --> 00:10:50,560 don't care what they are doing. 163 00:10:50,560 --> 00:10:52,810 You grab into a sub-volume, which 164 00:10:52,810 --> 00:10:54,220 is maybe phase space cell. 165 00:10:54,220 --> 00:10:55,770 And therefore, your quantum state, 166 00:10:55,770 --> 00:10:58,360 you have probability P of finding one. 167 00:10:58,360 --> 00:11:01,820 But since each particle moves around independently, 168 00:11:01,820 --> 00:11:06,180 the probability to find two particles is just P squared. 169 00:11:06,180 --> 00:11:08,566 It's a little bit like if you toss two coins, one 170 00:11:08,566 --> 00:11:10,190 with your left and one with your right, 171 00:11:10,190 --> 00:11:11,690 and you ask what is the probability 172 00:11:11,690 --> 00:11:15,285 to find a head or tail, and you simply 173 00:11:15,285 --> 00:11:16,410 multiply the probabilities. 174 00:11:18,940 --> 00:11:24,880 But now, following reasonings which Bose and Einstein 175 00:11:24,880 --> 00:11:31,180 introduced, you want to use counting statistics, which 176 00:11:31,180 --> 00:11:33,860 takes into account the indistinguishability 177 00:11:33,860 --> 00:11:34,595 of particles. 178 00:11:39,870 --> 00:11:45,490 So if we go from the classical distribution 179 00:11:45,490 --> 00:11:53,360 to the distribution of indistinguishable particles, 180 00:11:53,360 --> 00:12:08,190 then the classical probability P 1 is reduced by n factorial, 181 00:12:08,190 --> 00:12:19,040 because we are not-- let me put it this way. 182 00:12:19,040 --> 00:12:20,805 The number-- I don't want to go through 183 00:12:20,805 --> 00:12:23,040 a mathematical argument. 184 00:12:23,040 --> 00:12:33,240 If you grab one particle, it can be the probability 185 00:12:33,240 --> 00:12:38,880 to find one particle is represented 186 00:12:38,880 --> 00:12:42,090 by a microconfiguration classically. 187 00:12:42,090 --> 00:12:45,630 And each configuration when you permute particles 188 00:12:45,630 --> 00:12:47,500 counts as independent. 189 00:12:47,500 --> 00:12:50,180 But if you have quantum indistinguishability, 190 00:12:50,180 --> 00:12:53,750 you're not counting permutations as 191 00:12:53,750 --> 00:12:55,580 an independent configuration. 192 00:12:55,580 --> 00:12:58,325 And therefore, you have a reduction by n factorial. 193 00:13:02,280 --> 00:13:05,960 If you look at the probability of finding two particles, 194 00:13:05,960 --> 00:13:09,300 the reduction is-- this is just the counting statistics 195 00:13:09,300 --> 00:13:12,100 n factorial by 2. 196 00:13:12,100 --> 00:13:20,500 So therefore, you will find that classically, that quantum 197 00:13:20,500 --> 00:13:33,240 mechanically for bosons, is two times. 198 00:13:46,990 --> 00:13:50,930 The probability to find two bosons in one quantum state 199 00:13:50,930 --> 00:13:56,260 is two times the probability squared to find one boson. 200 00:13:56,260 --> 00:13:57,845 So this is just counting statistics. 201 00:14:03,990 --> 00:14:09,870 This can be applied to conditions 202 00:14:09,870 --> 00:14:12,350 in a Bose-Einstein in a Bose gas. 203 00:14:23,000 --> 00:14:27,730 When you have inelastic collisions, spin relaxation, 204 00:14:27,730 --> 00:14:34,620 dipolar collisions, two body collisions, 205 00:14:34,620 --> 00:14:37,560 two-body collisions have a rate gamma 2, 206 00:14:37,560 --> 00:14:41,280 which is proportional to the probability of finding 207 00:14:41,280 --> 00:14:45,297 two particles at the same time at the same location. 208 00:14:45,297 --> 00:14:46,755 And that brings in the g2 function. 209 00:14:49,300 --> 00:14:58,350 Whereas three-body collisions, gamma 3, 210 00:14:58,350 --> 00:15:01,300 reflects the third order correlation 211 00:15:01,300 --> 00:15:06,890 function g3, which is defined in an analogous way. 212 00:15:06,890 --> 00:15:18,730 So if you now compare at the same density 213 00:15:18,730 --> 00:15:25,060 the two-body rate coefficient, like the same density 214 00:15:25,060 --> 00:15:29,340 means we are looking at the rate of two-body collisions. 215 00:15:29,340 --> 00:15:35,630 And we compare between two-body collision 216 00:15:35,630 --> 00:15:38,500 in a thermal cloud, which is a g2 factor of two, 217 00:15:38,500 --> 00:15:41,780 a thermal cloud of bosons. 218 00:15:41,780 --> 00:15:43,660 Whereas a Bose-Einstein condensate 219 00:15:43,660 --> 00:15:47,330 is a constant occupation of particles in one mode 220 00:15:47,330 --> 00:15:51,670 and has therefore a g2 factor of 1, exactly as [INAUDIBLE] 221 00:15:51,670 --> 00:15:53,500 of the Bose-Einstein condensate is 222 00:15:53,500 --> 00:15:56,960 for particles for meta waves, but the laser is for light. 223 00:15:59,560 --> 00:16:03,040 Whereas, if you look at three-body collisions, 224 00:16:03,040 --> 00:16:05,730 those who do experiments with Bose-Einstein condensates 225 00:16:05,730 --> 00:16:07,930 will know that usually the lifetime 226 00:16:07,930 --> 00:16:09,589 of Bose-Einstein condensates is limited 227 00:16:09,589 --> 00:16:10,630 by three-body collisions. 228 00:16:13,670 --> 00:16:18,290 Well, I didn't derive it, but actually 229 00:16:18,290 --> 00:16:20,880 yes, we have the Gaussian statistics for randomness. 230 00:16:20,880 --> 00:16:26,380 For Gaussian statistics, the n-body collision function 231 00:16:26,380 --> 00:16:29,580 has a factor of n factorial. 232 00:16:29,580 --> 00:16:31,700 So therefore, three-body collisions 233 00:16:31,700 --> 00:16:36,300 scale with 3 factorial, and two-body collisions with 2 234 00:16:36,300 --> 00:16:37,930 factorial. 235 00:16:37,930 --> 00:16:40,090 So in other words, you have a thermal cloud, 236 00:16:40,090 --> 00:16:43,180 you have a Bose-Einstein condensate at the same density. 237 00:16:43,180 --> 00:16:45,470 But what matters for two-body collision 238 00:16:45,470 --> 00:16:47,790 is not the average density. 239 00:16:47,790 --> 00:16:50,240 It is the average of n square. 240 00:16:50,240 --> 00:16:52,750 And the fluctuations in the thermal cloud 241 00:16:52,750 --> 00:16:56,110 because of the g2 function are two times enhanced 242 00:16:56,110 --> 00:16:59,290 compared to Bose-Einstein condensate. 243 00:16:59,290 --> 00:17:02,130 And therefore, you find that at the same density, 244 00:17:02,130 --> 00:17:03,047 you have more loss. 245 00:17:03,047 --> 00:17:05,380 You have a higher rate of two and three-body collisions. 246 00:17:22,690 --> 00:17:30,280 Some of this was not-- became better understood 247 00:17:30,280 --> 00:17:42,530 soon after Bose-Einstein condensates were realized. 248 00:17:42,530 --> 00:17:45,950 The Boulder group studied three-body collisions. 249 00:17:45,950 --> 00:17:54,350 And for two-body collisions, myself 250 00:17:54,350 --> 00:17:57,210 in the post-doc clarified the situation 251 00:17:57,210 --> 00:18:01,960 that even the mean field energy, which everybody had measured 252 00:18:01,960 --> 00:18:06,490 before, requires two particles to interact with short range 253 00:18:06,490 --> 00:18:09,930 interaction is therefore proportional to g2. 254 00:18:09,930 --> 00:18:12,320 And therefore, when people had determined the mean field 255 00:18:12,320 --> 00:18:14,870 energy of a condensate without really knowing 256 00:18:14,870 --> 00:18:16,752 they had already determined the g2 function 257 00:18:16,752 --> 00:18:17,960 of Bose-Einstein condensates. 258 00:18:31,040 --> 00:18:34,880 OK, so this is pretty much the counting statistic 259 00:18:34,880 --> 00:18:38,220 which you do in undergraduate class 260 00:18:38,220 --> 00:18:42,520 when you derive the three different statistics-- 261 00:18:42,520 --> 00:18:45,150 Boltzmann statistics, Bose-Einstein statistics, Fermi 262 00:18:45,150 --> 00:18:46,410 statistics. 263 00:18:46,410 --> 00:18:54,000 And it gives you the result of that is also for bosons, 264 00:18:54,000 --> 00:18:55,750 you have the factor of 2. 265 00:18:55,750 --> 00:18:57,830 For fermions, of course, you get 0. 266 00:18:57,830 --> 00:19:02,630 The average between bosons 2 and fermions 0 is 1. 267 00:19:02,630 --> 00:19:06,330 And this is the classical statistics. 268 00:19:06,330 --> 00:19:06,935 Any questions? 269 00:19:20,960 --> 00:19:25,370 Then let me finish this discussion 270 00:19:25,370 --> 00:19:30,625 with a quantum mechanical description. 271 00:19:39,010 --> 00:19:47,430 If you describe the detection or collision of two 272 00:19:47,430 --> 00:19:54,985 particles in two modes. 273 00:19:58,260 --> 00:19:59,960 So you have mode. 274 00:19:59,960 --> 00:20:04,390 A mode operator, annihilation operator a1 you and a2. 275 00:20:04,390 --> 00:20:06,920 But if you are asking what happens 276 00:20:06,920 --> 00:20:10,580 if I measure two particles, you annihilate two particles 277 00:20:10,580 --> 00:20:13,300 with an operator a1 and a2. 278 00:20:13,300 --> 00:20:16,130 But then, because of the indistinguishability 279 00:20:16,130 --> 00:20:22,350 of particles, you have to consider 280 00:20:22,350 --> 00:20:27,600 an exchange term, which is a2a1. 281 00:20:27,600 --> 00:20:29,440 So whenever you detect two particles 282 00:20:29,440 --> 00:20:31,520 in two different modes, your signal 283 00:20:31,520 --> 00:20:36,370 is proportional to something related to a1a2 plus a2a1. 284 00:20:39,120 --> 00:20:50,050 This extra exchange term gives you an extra factor of 2 285 00:20:50,050 --> 00:20:55,140 for bosons, which is exactly what appears 286 00:20:55,140 --> 00:20:58,760 in the g2 function. 287 00:20:58,760 --> 00:21:06,960 And, of course, if you have an exchange term for fermions, 288 00:21:06,960 --> 00:21:09,930 you get 0. 289 00:21:09,930 --> 00:21:13,640 And this, of course, leads to the antibunching, 290 00:21:13,640 --> 00:21:19,610 or the g2 value of 0 for fermions. 291 00:21:23,610 --> 00:21:36,450 However, and this is obvious, if you have a single mode, 292 00:21:36,450 --> 00:21:42,470 then the only operator to detect two particles is a1 times a1. 293 00:21:42,470 --> 00:21:44,910 And this has no exchange term. 294 00:21:51,120 --> 00:21:55,560 And this is the situation of the laser 295 00:21:55,560 --> 00:21:58,440 and the Bose-Einstein condensate. 296 00:21:58,440 --> 00:22:02,870 And that means they have a g2 function of 1. 297 00:22:07,290 --> 00:22:09,250 So Cory, this is another argument 298 00:22:09,250 --> 00:22:14,310 why single mode occupation has a g2 function of 1. 299 00:22:14,310 --> 00:22:17,600 But I have to reconcile it with your question. 300 00:22:17,600 --> 00:22:19,540 Right now, I think there may be difference 301 00:22:19,540 --> 00:22:23,420 between a canonical ensemble and grand canonical ensemble. 302 00:22:23,420 --> 00:22:31,730 In a canonical ensemble, we have [INAUDIBLE] 303 00:22:31,730 --> 00:22:33,370 the total particle number is fixed. 304 00:22:33,370 --> 00:22:35,230 But in a grand canonical it fluctuates. 305 00:22:35,230 --> 00:22:37,380 And maybe this leads to additional fluctuations 306 00:22:37,380 --> 00:22:41,850 for the case of a single mode chaotic light. 307 00:22:41,850 --> 00:22:44,710 But I will have to think about it, your question. 308 00:22:44,710 --> 00:22:47,860 But here is the same argument why 309 00:22:47,860 --> 00:22:50,132 if you occupy only a single mode-- if you look, 310 00:22:50,132 --> 00:22:51,965 for instance, at a Bose-Einstein condensate, 311 00:22:51,965 --> 00:22:55,940 you do not have the second exchange term. 312 00:22:55,940 --> 00:22:58,604 And the missing exchange term just 313 00:22:58,604 --> 00:23:00,520 propagates through the equations and gives you 314 00:23:00,520 --> 00:23:03,840 the g2 factor, the g2 function of 1. 315 00:23:11,930 --> 00:23:14,510 OK so let me sort of wrap it up. 316 00:23:14,510 --> 00:23:17,920 I've given you different angles at the g2 function. 317 00:23:17,920 --> 00:23:22,180 Some are simply classical intensity distribution. 318 00:23:22,180 --> 00:23:26,460 Some is simply interference. 319 00:23:26,460 --> 00:23:31,030 Another aspect is Poissonian counting statistics. 320 00:23:31,030 --> 00:23:33,120 My understanding and my interpretation 321 00:23:33,120 --> 00:23:37,200 is they look as different as they can possibly look, 322 00:23:37,200 --> 00:23:40,300 but they reflect the same physics. 323 00:23:40,300 --> 00:23:45,540 Because interference of to light only happens because light 324 00:23:45,540 --> 00:23:46,535 consists of photons. 325 00:23:46,535 --> 00:23:48,210 And photons are bosons. 326 00:23:48,210 --> 00:23:50,330 So the classical interference and 327 00:23:50,330 --> 00:23:57,350 the quantum mechanical counting of bosons 328 00:23:57,350 --> 00:24:03,190 lead not for random reasons, but lead for profound reasons 329 00:24:03,190 --> 00:24:05,100 to the same result. 330 00:24:05,100 --> 00:24:08,850 And chaotic light, which seems to be determined 331 00:24:08,850 --> 00:24:11,480 by just random fluctuation, well, 332 00:24:11,480 --> 00:24:15,690 the random fluctuations if you have single mode 333 00:24:15,690 --> 00:24:18,250 light, a thermal distribution of single mode photons, 334 00:24:18,250 --> 00:24:19,980 comes from random phases. 335 00:24:19,980 --> 00:24:22,917 And these random phases lead to random interference. 336 00:24:22,917 --> 00:24:24,375 And so we are back to interference. 337 00:24:28,630 --> 00:24:41,830 Finally, let me give you my view on the measurements of g2. 338 00:24:46,190 --> 00:24:47,830 When you look through the literature, 339 00:24:47,830 --> 00:24:51,170 you find the famous Henry [INAUDIBLE] experiment. 340 00:24:51,170 --> 00:24:53,960 In one of your homework assignments, 341 00:24:53,960 --> 00:24:58,030 you looked at a seminal experiment 342 00:24:58,030 --> 00:25:01,700 where people dropped atoms out of cold atom clouds 343 00:25:01,700 --> 00:25:04,470 and measured the g2 function for cold atoms. 344 00:25:08,250 --> 00:25:11,330 Sometimes it's confusing when you directly 345 00:25:11,330 --> 00:25:12,530 compare the two experiments. 346 00:25:15,740 --> 00:25:20,460 But let me try to give you a common description, 347 00:25:20,460 --> 00:25:28,160 or the common denominator, between all these experiments. 348 00:25:28,160 --> 00:25:40,000 You can say that all experiments to measure the two particle 349 00:25:40,000 --> 00:25:43,610 correlation function is about comparing 350 00:25:43,610 --> 00:25:47,910 the probability of finding two particles with a probability 351 00:25:47,910 --> 00:25:49,170 of finding one particle. 352 00:25:52,100 --> 00:25:58,290 And well, you restrict your measurement, your detection 353 00:25:58,290 --> 00:26:06,020 of particles, to either one quantum 354 00:26:06,020 --> 00:26:20,950 state, one mode of the electromagnetic field, one 355 00:26:20,950 --> 00:26:26,420 coherence length, or coherence volume, of light. 356 00:26:26,420 --> 00:26:30,760 Or if you use the semi-classical argument for the description 357 00:26:30,760 --> 00:26:36,660 of particles, you take one phase space cell. 358 00:26:36,660 --> 00:26:40,125 This is one phase space cell, one mode, one coherence volume, 359 00:26:40,125 --> 00:26:49,400 one quantum state, is sort of the different definitions 360 00:26:49,400 --> 00:26:52,740 of what a quantum state is, or what a wave packet 361 00:26:52,740 --> 00:26:56,610 is with Heisenberg limited uncertainty. 362 00:26:56,610 --> 00:27:01,820 You cannot define a particle in phase space to within better 363 00:27:01,820 --> 00:27:05,660 than the phase space volume of a quantum state, 364 00:27:05,660 --> 00:27:09,686 which is h square. 365 00:27:09,686 --> 00:27:10,310 Or is it h bar? 366 00:27:10,310 --> 00:27:14,430 I don't think there is a bar-- h square. 367 00:27:14,430 --> 00:27:17,020 And so this is how you can relate wave packets 368 00:27:17,020 --> 00:27:19,480 to quantum states to phase space volume. 369 00:27:19,480 --> 00:27:24,800 It's pretty much mathematically I could say in different basis 370 00:27:24,800 --> 00:27:29,810 sets, in different basis sets, it is one quantum state. 371 00:27:29,810 --> 00:27:31,230 But you can use wave packets. 372 00:27:31,230 --> 00:27:33,550 You can use time dependent description. 373 00:27:33,550 --> 00:27:36,770 But what I said here-- one quantum state, 374 00:27:36,770 --> 00:27:38,960 one mode, one coherence volume-- this 375 00:27:38,960 --> 00:27:42,420 is as well as you can define a particle or photon 376 00:27:42,420 --> 00:27:47,220 to be by fundamental reasons by Heisenberg's uncertainty 377 00:27:47,220 --> 00:27:48,372 relation. 378 00:27:48,372 --> 00:27:50,714 AUDIENCE: What do you mean by one coherence volume? 379 00:27:50,714 --> 00:27:51,380 PROFESSOR: What? 380 00:27:51,380 --> 00:27:54,100 AUDIENCE: What do we mean by one coherence volume? 381 00:27:54,100 --> 00:27:56,930 PROFESSOR: Well, if you have a laser beam which propagates, 382 00:27:56,930 --> 00:28:01,770 and it is TEM00, you would say the transverse coherence volume 383 00:28:01,770 --> 00:28:04,020 is the size of the laser beam but then 384 00:28:04,020 --> 00:28:05,870 the longitudinal coherence volume 385 00:28:05,870 --> 00:28:09,150 is given by the coherence length. 386 00:28:09,150 --> 00:28:11,880 Just envision you have a laser beam here. 387 00:28:11,880 --> 00:28:17,730 And the coherence volume where all of the photons are coherent 388 00:28:17,730 --> 00:28:22,790 is the area of the laser beam times the coherence length. 389 00:28:22,790 --> 00:28:26,930 And whenever you find a photon in this kind of volume, 390 00:28:26,930 --> 00:28:30,860 then it is in a Heisenberg Uncertainty 391 00:28:30,860 --> 00:28:33,830 limited or Fourier-limited state. 392 00:28:33,830 --> 00:28:37,600 It is in, if it's a wave packet and pulse laser, 393 00:28:37,600 --> 00:28:40,650 it's in a time dependent quantum state. 394 00:28:40,650 --> 00:28:42,236 But it is as coherent. 395 00:28:42,236 --> 00:28:43,110 It is fully coherent. 396 00:28:45,990 --> 00:28:48,270 So you have to figure out for your system what 397 00:28:48,270 --> 00:28:59,050 is this minimum-- what is the coherence volume, what defines 398 00:28:59,050 --> 00:29:03,890 the fundamental phase space cell of your system? 399 00:29:03,890 --> 00:29:06,710 And now you do the following. 400 00:29:06,710 --> 00:29:09,210 You are asking, what is the probability 401 00:29:09,210 --> 00:29:10,950 to find two particles? 402 00:29:10,950 --> 00:29:15,110 And what is the probability to find one particle? 403 00:29:15,110 --> 00:29:29,090 So if p is the probability to find one particle, 404 00:29:29,090 --> 00:29:36,260 then you have three options. 405 00:29:36,260 --> 00:29:43,765 p square, 2 p square or 0 to find two particles. 406 00:29:49,200 --> 00:29:52,960 One is the classical case of distinguishable particle. 407 00:29:52,960 --> 00:29:56,200 This is the case of bosons, bosonic atoms or photons. 408 00:29:56,200 --> 00:29:59,970 Collins Therefore includes the Hanbury Brown-Twiss experiment. 409 00:29:59,970 --> 00:30:01,050 And 0 is fermions. 410 00:30:06,450 --> 00:30:13,460 And the question is now different experiments, 411 00:30:13,460 --> 00:30:17,090 how do you define, with spatial resolution 412 00:30:17,090 --> 00:30:20,560 or temporal resolution, the coherence volume? 413 00:30:20,560 --> 00:30:23,740 And that can involve transverse coordination, 414 00:30:23,740 --> 00:30:25,860 temporal resolution, and whatever 415 00:30:25,860 --> 00:30:34,690 you can use to define the phase space 416 00:30:34,690 --> 00:30:38,500 cell or the coherence links, the coherence volume of a laser 417 00:30:38,500 --> 00:30:39,050 beam. 418 00:30:39,050 --> 00:30:43,070 Let me give you one example, which I think illustrates it. 419 00:30:43,070 --> 00:30:46,260 And this is the example of an atom cloud. 420 00:30:46,260 --> 00:30:52,530 If you have an atom cloud, all the particles 421 00:30:52,530 --> 00:30:55,950 which are in a volume of a thermal de Broglie wavelengths 422 00:30:55,950 --> 00:30:56,510 are coherent. 423 00:31:04,970 --> 00:31:07,830 The momentum uncertainty of particles in a thermal cloud 424 00:31:07,830 --> 00:31:11,590 is 1 over the thermal-- is the thermal momentum. 425 00:31:11,590 --> 00:31:14,810 And according to Heisenberg, the position uncertainty 426 00:31:14,810 --> 00:31:16,770 related with this momentum spread 427 00:31:16,770 --> 00:31:19,160 is just the thermal de Broglie wavelengths. 428 00:31:19,160 --> 00:31:23,470 So you can say that all the atoms in a cubic de Broglie 429 00:31:23,470 --> 00:31:27,460 wavelengths are coherent. 430 00:31:27,460 --> 00:31:33,130 All the atoms are in one semi-classical quantum state. 431 00:31:33,130 --> 00:31:38,460 So therefore, this is sort of atoms in one single mode. 432 00:31:38,460 --> 00:31:42,470 So the Hanbury Brown-Twiss experiment with atoms, 433 00:31:42,470 --> 00:31:44,750 or the measurement of the g2 function, 434 00:31:44,750 --> 00:31:46,720 could be defined as follows. 435 00:31:46,720 --> 00:31:48,160 You have an atom cloud. 436 00:31:48,160 --> 00:31:51,010 And if you had an electron microscope 437 00:31:51,010 --> 00:31:55,470 or some high resolution device, you grab into your cloud 438 00:31:55,470 --> 00:31:57,890 and ask, what is the probability for one particle. 439 00:31:57,890 --> 00:31:59,910 What is the probability for two particles? 440 00:31:59,910 --> 00:32:05,730 And you will find that p2 is 2 times p1 squared. 441 00:32:05,730 --> 00:32:09,250 If your volume is too big, you lose the factor of 2, 442 00:32:09,250 --> 00:32:11,455 because you average over uncorrelated volumes. 443 00:32:14,720 --> 00:32:20,410 Now, in your homework, you were looking at the question, 444 00:32:20,410 --> 00:32:23,060 how can I really grab into a cloud 445 00:32:23,060 --> 00:32:25,752 and just pick out atoms out of one phase space 446 00:32:25,752 --> 00:32:28,970 cell of effective size, lambda de Broglie cubed? 447 00:32:32,340 --> 00:32:49,080 And the way how it was done is that you take an atom cloud 448 00:32:49,080 --> 00:32:55,220 and you drop it and expand it. 449 00:32:55,220 --> 00:32:59,260 When the cloud expands, there is a mapping from momentum space 450 00:32:59,260 --> 00:33:02,200 into position space. 451 00:33:02,200 --> 00:33:21,120 Then you use some form of pinhole, 452 00:33:21,120 --> 00:33:23,695 which provides transverse coordination. 453 00:33:28,910 --> 00:33:44,745 You use a detection laser, which gives you temporal resolution. 454 00:33:49,940 --> 00:33:52,160 And well, this was part of your homework, 455 00:33:52,160 --> 00:33:57,110 but I just wanted to give you the bird's view on it. 456 00:33:57,110 --> 00:34:00,160 By controlling the transverse correlation 457 00:34:00,160 --> 00:34:03,850 and the temporal resolution of the detection, 458 00:34:03,850 --> 00:34:08,580 you create a situation that what you count only atoms which 459 00:34:08,580 --> 00:34:12,940 originated from one phase space cell in your cloud. 460 00:34:12,940 --> 00:34:15,010 So in other words, let's say experiment 461 00:34:15,010 --> 00:34:16,949 where without electron microscope, 462 00:34:16,949 --> 00:34:20,110 without submicron spatial resolution, 463 00:34:20,110 --> 00:34:23,080 you can literally grab into a cloud, 464 00:34:23,080 --> 00:34:26,170 capture a volume of the thermal de Broglie wavelengths, 465 00:34:26,170 --> 00:34:28,420 open your hand, and figure out how 466 00:34:28,420 --> 00:34:30,510 is the probability for two particles related 467 00:34:30,510 --> 00:34:32,604 to the probability of finding one particle. 468 00:34:36,690 --> 00:34:37,565 Any questions? 469 00:34:47,699 --> 00:34:48,199 All right. 470 00:35:17,560 --> 00:35:18,370 OK, good. 471 00:35:18,370 --> 00:35:28,740 So it's time for new chapter. 472 00:35:49,870 --> 00:35:52,320 So in this chapter, we want to look 473 00:35:52,320 --> 00:35:55,370 at interactions between light and atoms 474 00:35:55,370 --> 00:35:57,710 using Feynman diagrams. 475 00:35:57,710 --> 00:36:03,180 And I know this part of the course is a little bit formal. 476 00:36:03,180 --> 00:36:09,110 We are using exact solutions for the time evolution 477 00:36:09,110 --> 00:36:11,330 operator in quantum physics. 478 00:36:11,330 --> 00:36:17,470 But I'm not doing it to teach you sophisticated formalism. 479 00:36:17,470 --> 00:36:20,450 Well, it's interesting to learn it anyway. 480 00:36:20,450 --> 00:36:26,310 But it is this picture of really writing down 481 00:36:26,310 --> 00:36:32,730 the exact solution of the time evolution operator, which 482 00:36:32,730 --> 00:36:38,140 helped me to understand much better what virtual states are, 483 00:36:38,140 --> 00:36:41,060 what certain virtual photons are. 484 00:36:41,060 --> 00:36:43,870 So there are things we talk about it all the time. 485 00:36:43,870 --> 00:36:46,730 And the question is, how do you define a virtual state? 486 00:36:46,730 --> 00:36:49,690 What is the virtual emission of a photon? 487 00:36:49,690 --> 00:36:53,420 And the only way how I can really explain it to you 488 00:36:53,420 --> 00:36:56,090 is by showing you the equation and say look, 489 00:36:56,090 --> 00:37:01,020 the virtual photon is just a term in this equation. 490 00:37:01,020 --> 00:37:04,530 So that's the goal of this chapter. 491 00:37:04,530 --> 00:37:08,300 I don't want to overemphasize the mathematical rigor, 492 00:37:08,300 --> 00:37:10,210 but I want to really show you what 493 00:37:10,210 --> 00:37:13,070 it means to have virtual photons and what 494 00:37:13,070 --> 00:37:16,160 exactly virtual states are. 495 00:37:16,160 --> 00:37:35,460 So let me first motivate that by reminding you of two diagrams. 496 00:37:35,460 --> 00:37:37,650 In physics, we always like to draw something-- 497 00:37:37,650 --> 00:37:39,450 a few lines, a few doodles. 498 00:37:39,450 --> 00:37:44,880 And when we have a two level system, 499 00:37:44,880 --> 00:37:49,690 we have the two processes which are emission and absorption. 500 00:37:58,170 --> 00:38:07,010 Well, so this is easy as long as the light is in resonance. 501 00:38:07,010 --> 00:38:16,170 But if the light is not in resonance, 502 00:38:16,170 --> 00:38:25,390 we may ask what about this process? 503 00:38:29,500 --> 00:38:34,840 And since somehow the weekly line of the photon ends here, 504 00:38:34,840 --> 00:38:37,700 I may even put in a dashed line and say, 505 00:38:37,700 --> 00:38:39,610 this is a virtual state. 506 00:38:39,610 --> 00:38:43,030 What does it mean? 507 00:38:43,030 --> 00:38:48,020 Or we can even ask, is it possible-- 508 00:38:48,020 --> 00:38:51,720 I'm just playing with straight lines which are quantum state 509 00:38:51,720 --> 00:38:55,110 and wiggly lines-- is it possible 510 00:38:55,110 --> 00:38:56,470 that this process happens. 511 00:38:59,000 --> 00:39:03,690 That would actually mean that an atom in the ground state, 512 00:39:03,690 --> 00:39:06,720 just out of the blue, emits a photon. 513 00:39:06,720 --> 00:39:08,230 Can that happen? 514 00:39:08,230 --> 00:39:10,060 And I can again draw a dashed line 515 00:39:10,060 --> 00:39:11,590 and say, here's a virtual state. 516 00:39:14,190 --> 00:39:19,070 Or, we can say we start in the excited state. 517 00:39:19,070 --> 00:39:24,560 The atom is in the excited state. 518 00:39:24,560 --> 00:39:27,730 But can the atom-- its a two level system, 519 00:39:27,730 --> 00:39:31,100 so we don't include higher states-- but can a two level 520 00:39:31,100 --> 00:39:39,130 atom in the excited state absorb another photon? 521 00:39:42,770 --> 00:39:53,540 So let me just change the color of these photons 522 00:39:53,540 --> 00:40:09,656 to red, because I want to-- and this would remain black. 523 00:40:14,540 --> 00:40:17,211 All right. 524 00:40:17,211 --> 00:40:17,710 Good. 525 00:40:17,710 --> 00:40:19,630 So question is, are those processes possible? 526 00:40:24,690 --> 00:40:25,660 Yes or no? 527 00:40:25,660 --> 00:40:26,540 AUDIENCE: Yes. 528 00:40:26,540 --> 00:40:28,710 PROFESSOR: Yes, they are. 529 00:40:28,710 --> 00:40:34,550 And they have experimental, observable consequences. 530 00:40:34,550 --> 00:40:38,380 However, they look funny because something 531 00:40:38,380 --> 00:40:41,580 seems to be strange with energy conservation. 532 00:40:41,580 --> 00:40:45,360 And what we will see is that in the end, 533 00:40:45,360 --> 00:40:48,050 at the end of the day, that means 534 00:40:48,050 --> 00:40:55,220 if you let the system evolve for a long time, after a long time, 535 00:40:55,220 --> 00:40:59,655 energy has to be conserved. 536 00:41:02,760 --> 00:41:15,930 And therefore, we will always need a second photon 537 00:41:15,930 --> 00:41:17,205 to conserve energy. 538 00:41:22,640 --> 00:41:25,690 So those weirder processes, where 539 00:41:25,690 --> 00:41:27,760 photons are emitted by ground states out 540 00:41:27,760 --> 00:41:32,620 of the blue or excited states absorb other photons 541 00:41:32,620 --> 00:41:38,692 without-- also, there is no higher lying state. 542 00:41:38,692 --> 00:41:40,025 That looks a little bit strange. 543 00:41:42,630 --> 00:41:45,250 So what you will see is-- and I want 544 00:41:45,250 --> 00:41:47,410 to show you that mathematically-- 545 00:41:47,410 --> 00:41:53,790 if an atom emits a photon out of the ground state, 546 00:41:53,790 --> 00:41:56,050 you would say, where does the energy come from. 547 00:41:56,050 --> 00:42:03,510 But quantum mechanic allows us to violate energy conservation 548 00:42:03,510 --> 00:42:07,840 by an amount delta e for a time which is h bar over delta e. 549 00:42:07,840 --> 00:42:11,290 So for short movement, energy can be violated. 550 00:42:11,290 --> 00:42:13,015 But then, you need the second photon 551 00:42:13,015 --> 00:42:15,330 to reconcile energy conservation. 552 00:42:15,330 --> 00:42:18,242 You can violate energy only for short times. 553 00:42:18,242 --> 00:42:19,950 And if you would say, what does it really 554 00:42:19,950 --> 00:42:22,910 mean to violate energy conservation for short times? 555 00:42:22,910 --> 00:42:25,180 Well, I want to show you the equation, 556 00:42:25,180 --> 00:42:26,940 which exactly explains what it means. 557 00:42:36,700 --> 00:42:39,150 Next question, just to see. 558 00:42:39,150 --> 00:42:42,490 If you have an excited state, and you just 559 00:42:42,490 --> 00:42:46,580 say it's possible to absorb another atom, 560 00:42:46,580 --> 00:42:51,000 you are in the excited state, and you absorb another photon. 561 00:42:51,000 --> 00:42:53,470 And at least you said, yes this is possible. 562 00:42:53,470 --> 00:42:56,080 My question is, when you are in the excited state 563 00:42:56,080 --> 00:42:59,980 and absorb a photon, in which quantum state is the atom 564 00:42:59,980 --> 00:43:02,926 after absorbing a photon? 565 00:43:02,926 --> 00:43:04,012 AUDIENCE: Ground state. 566 00:43:04,012 --> 00:43:04,762 PROFESSOR: Pardon? 567 00:43:04,762 --> 00:43:05,720 AUDIENCE: Ground state. 568 00:43:05,720 --> 00:43:08,460 PROFESSOR: In the ground state. 569 00:43:08,460 --> 00:43:09,090 Yes. 570 00:43:09,090 --> 00:43:10,710 There is no other state. 571 00:43:10,710 --> 00:43:13,610 And the operator-- and I want to show you 572 00:43:13,610 --> 00:43:16,930 that-- when photons are exchanged, 573 00:43:16,930 --> 00:43:19,904 always transforms the ground to the excited state, 574 00:43:19,904 --> 00:43:21,320 because a dipole operator connects 575 00:43:21,320 --> 00:43:23,140 the ground to the excited state. 576 00:43:23,140 --> 00:43:27,660 So therefore-- but we'll see that all in the time evolution 577 00:43:27,660 --> 00:43:32,600 operator in the formal solution that this dash line is actually 578 00:43:32,600 --> 00:43:34,500 the ground state. 579 00:43:34,500 --> 00:43:36,650 And while it's not obvious, what is this dash line? 580 00:43:36,650 --> 00:43:37,580 AUDIENCE: The excited state. 581 00:43:37,580 --> 00:43:39,038 PROFESSOR: It is the excited state. 582 00:43:39,038 --> 00:43:42,050 The atom in the ground state emits a photon. 583 00:43:42,050 --> 00:43:44,730 Therefore, the atomic system has now lower energy, 584 00:43:44,730 --> 00:43:46,960 because a photon has been emitted. 585 00:43:46,960 --> 00:43:50,480 But the character of this state is now the excited state. 586 00:43:53,320 --> 00:43:58,810 So we will later see that this means that in a perturbation 587 00:43:58,810 --> 00:44:01,280 analysis, we are violating energy. 588 00:44:01,280 --> 00:44:04,390 We are violating energy, because the real excited 589 00:44:04,390 --> 00:44:11,460 state is omega photon plus omega atom, the resonant energy 590 00:44:11,460 --> 00:44:12,190 for the atom. 591 00:44:12,190 --> 00:44:17,200 The real excited state is omega photon plus omega atom higher. 592 00:44:17,200 --> 00:44:21,560 So you will actually find that in a perturbation analysis, 593 00:44:21,560 --> 00:44:25,590 this term has an energy denominator, which 594 00:44:25,590 --> 00:44:31,490 is of resonant by exactly this separation. 595 00:44:31,490 --> 00:44:34,720 And this term, because the real count state is here, 596 00:44:34,720 --> 00:44:37,550 the virtual state here which is the count state is here, 597 00:44:37,550 --> 00:44:42,210 has actually the same energy denominator as that state. 598 00:44:42,210 --> 00:44:43,790 And for this state, of course, this 599 00:44:43,790 --> 00:44:46,060 is something you've seen of resonant light scattering. 600 00:44:46,060 --> 00:44:47,842 The energy [? denominator ?] is there. 601 00:44:52,470 --> 00:45:04,050 So, OK. 602 00:45:04,050 --> 00:45:12,800 So I'll explain to you that we involve virtual states. 603 00:45:12,800 --> 00:45:18,920 So when we have virtual states, we 604 00:45:18,920 --> 00:45:26,370 want to clarify what is their energy. 605 00:45:26,370 --> 00:45:28,890 But we discussed that already in the discussion. 606 00:45:28,890 --> 00:45:33,560 And what is the wave function, ground or excited state. 607 00:45:38,950 --> 00:45:39,450 Yes. 608 00:45:51,000 --> 00:45:54,700 So just to repeat it, when we draw those diagrams, 609 00:45:54,700 --> 00:46:02,150 those diagrams show the energy of the atom, 610 00:46:02,150 --> 00:46:09,080 but taking into account the energy of the photon. 611 00:46:09,080 --> 00:46:14,790 In other words, if you have a ground state, 612 00:46:14,790 --> 00:46:18,820 and we absorb a photon, the photon has disappeared, 613 00:46:18,820 --> 00:46:21,070 and the energy of the atom is now 614 00:46:21,070 --> 00:46:22,820 the ground state and the photon energy. 615 00:46:22,820 --> 00:46:24,780 And this is a dashed line. 616 00:46:24,780 --> 00:46:29,360 Similarly, when an atom emits a photon in the ground state, 617 00:46:29,360 --> 00:46:31,020 the photon is emitted. 618 00:46:31,020 --> 00:46:35,400 Therefore, the atomic energy is lower than the ground state 619 00:46:35,400 --> 00:46:36,980 by the photon energy. 620 00:46:36,980 --> 00:46:39,490 And we draw the dashed line here. 621 00:46:39,490 --> 00:46:43,070 This is what we mean when we say that is 622 00:46:43,070 --> 00:46:45,009 the energy of the virtual state. 623 00:46:45,009 --> 00:46:46,800 And this is what we draw in those diagrams. 624 00:46:50,170 --> 00:46:53,660 By the way, yesterday we had the CUA seminar. 625 00:46:53,660 --> 00:46:59,880 And the speaker was actually talking about trapping atoms 626 00:46:59,880 --> 00:47:01,750 with quantum fluctuations. 627 00:47:01,750 --> 00:47:06,380 And he conceded explicitly Casimir forces, 628 00:47:06,380 --> 00:47:08,000 forces of the vacuum. 629 00:47:08,000 --> 00:47:10,780 And diagrammatically, forces of the vacuum 630 00:47:10,780 --> 00:47:14,880 come, because the ground state atom emits a virtual photon 631 00:47:14,880 --> 00:47:17,000 and reabsorbs. 632 00:47:17,000 --> 00:47:19,810 This is actually, I will mention it later, 633 00:47:19,810 --> 00:47:21,270 the same diagram is actually also 634 00:47:21,270 --> 00:47:23,060 the diagram which leads to the Lamb shift. 635 00:47:23,060 --> 00:47:26,810 These are all sort of when you have atoms in the lowest state, 636 00:47:26,810 --> 00:47:29,450 and they interact with the electromagnetic field. 637 00:47:29,450 --> 00:47:31,740 Well, if they interact with the vacuum, 638 00:47:31,740 --> 00:47:33,140 they cannot absorb photon. 639 00:47:33,140 --> 00:47:38,350 All we can do is emit a photon, and this leads to this diagram. 640 00:47:38,350 --> 00:47:40,780 But just to tell you that you have to be careful, 641 00:47:40,780 --> 00:47:45,020 yesterday's speakers actually used this process. 642 00:47:45,020 --> 00:47:46,240 But he drew this diagram. 643 00:47:46,240 --> 00:47:48,930 He drew it in the opposite way, which 644 00:47:48,930 --> 00:47:51,650 I think confused some people in the audience. 645 00:47:51,650 --> 00:47:54,430 The correct way is to draw it like this. 646 00:47:54,430 --> 00:47:59,440 The virtual state for vacuum fluctuations 647 00:47:59,440 --> 00:48:01,880 for the Lamb shift for the Casimir force 648 00:48:01,880 --> 00:48:03,970 is below the current state. 649 00:48:07,360 --> 00:48:17,610 OK, so we have-- let me just redraw those three diagrams. 650 00:48:17,610 --> 00:48:27,840 I want to now introduce the time evolution. 651 00:48:27,840 --> 00:48:31,165 So I want to use those. 652 00:48:38,380 --> 00:48:40,235 Seems I'm running out of space. 653 00:48:50,280 --> 00:48:57,000 So we want to introduce the time axis 654 00:48:57,000 --> 00:49:04,830 for-- so we had this diagram. 655 00:49:04,830 --> 00:49:08,480 We had this diagram. 656 00:49:08,480 --> 00:49:21,100 And we had-- this is a virtual state. 657 00:49:21,100 --> 00:49:22,290 OK. 658 00:49:22,290 --> 00:49:32,090 So those three diagrams correspond 659 00:49:32,090 --> 00:49:33,340 to the following situation. 660 00:49:37,690 --> 00:49:42,860 If time evolves from the bottom to the top, 661 00:49:42,860 --> 00:49:46,010 we can now draw the first process 662 00:49:46,010 --> 00:49:48,300 when atom in the ground state first 663 00:49:48,300 --> 00:49:49,790 absorbs and then emits a photon. 664 00:50:01,750 --> 00:50:08,250 And let's label the second photon in the purple color. 665 00:50:08,250 --> 00:50:12,260 So an atom starts out in the ground state. 666 00:50:12,260 --> 00:50:14,980 Then it reaches the time where it 667 00:50:14,980 --> 00:50:17,860 interacts the electromagnetic field. 668 00:50:17,860 --> 00:50:21,320 There is a photon which propagates 669 00:50:21,320 --> 00:50:27,060 from earlier times to this time, t equals t prime. 670 00:50:27,060 --> 00:50:30,940 At the time t prime, the photon disappears. 671 00:50:30,940 --> 00:50:36,440 And the atom, which was in the ground state, 672 00:50:36,440 --> 00:50:38,980 goes to the excited state. 673 00:50:38,980 --> 00:50:42,690 It may propagate in the excited state for a while. 674 00:50:42,690 --> 00:50:48,470 And then it emits the photon and is back into the ground state. 675 00:50:48,470 --> 00:50:52,730 So this is the temporal diagram for this process. 676 00:50:52,730 --> 00:50:59,640 For the next situation, we also start 677 00:50:59,640 --> 00:51:03,540 with an atom in the ground state. 678 00:51:03,540 --> 00:51:06,980 But now we have the situation that a photon 679 00:51:06,980 --> 00:51:09,980 is emitted by the ground state. 680 00:51:12,600 --> 00:51:17,220 As a result, the atom switches to the excited state. 681 00:51:17,220 --> 00:51:23,780 Strong violation of energy, but possible for short times. 682 00:51:23,780 --> 00:51:31,780 Then there is a real photon, which is now absorbed, 683 00:51:31,780 --> 00:51:35,030 absorbed by an atom in the excited state. 684 00:51:35,030 --> 00:51:39,520 And that takes us back down to the ground state. 685 00:51:39,520 --> 00:51:43,560 And finally, in the third scenario, 686 00:51:43,560 --> 00:51:45,850 we have an atom in the excited state. 687 00:51:49,080 --> 00:51:52,650 There is a real photon which is absorbed 688 00:51:52,650 --> 00:51:56,290 that switches the atom into the ground state. 689 00:51:56,290 --> 00:52:03,210 And then the atom in the ground state emits a photon. 690 00:52:03,210 --> 00:52:06,440 And as a result, it is back in the excited state. 691 00:52:17,390 --> 00:52:32,160 So let me just make a note that when a ground state 692 00:52:32,160 --> 00:52:47,290 atom absorbs a photon, this is the co-rotating term 693 00:52:47,290 --> 00:52:53,390 in the quantum description, which a lot of you have seen. 694 00:52:53,390 --> 00:53:01,460 The opposite process of emitting a virtual photon-- I 695 00:53:01,460 --> 00:53:05,060 shouldn't say virtual photon. 696 00:53:05,060 --> 00:53:05,940 It's a photon. 697 00:53:05,940 --> 00:53:09,050 What makes it virtual we will see later 698 00:53:09,050 --> 00:53:12,010 when we have the more accurate mathematical formulation. 699 00:53:12,010 --> 00:53:14,660 So this is a counter-rotating term. 700 00:53:22,160 --> 00:53:34,890 And we have used the rule that every photon, which 701 00:53:34,890 --> 00:53:40,250 with a real or virtual-- every photon which is interchanged 702 00:53:40,250 --> 00:53:42,950 with the atom absorbs or emitted-- 703 00:53:42,950 --> 00:53:48,910 changes the atomic state from ground to excited. 704 00:53:48,910 --> 00:53:52,660 So an atom goes from the ground to the excited state 705 00:53:52,660 --> 00:53:55,810 either by photon absorption or by photon emission. 706 00:53:55,810 --> 00:53:56,800 Both is possible. 707 00:54:00,440 --> 00:54:04,130 So whenever photon appears or disappears, 708 00:54:04,130 --> 00:54:07,000 it changes-- let's say we start in the ground state. 709 00:54:07,000 --> 00:54:09,030 We go to the excited state. 710 00:54:09,030 --> 00:54:15,060 And this is possible by photon absorption-- 711 00:54:15,060 --> 00:54:18,485 this is a co-rotating term-- or emission. 712 00:54:23,170 --> 00:54:27,490 What I've just said reflects that when 713 00:54:27,490 --> 00:54:32,910 we derived the dipole approximation, 714 00:54:32,910 --> 00:54:40,330 that the essential term of the dipole operator is of diagonal. 715 00:54:40,330 --> 00:54:42,110 The dipole operator is an operator 716 00:54:42,110 --> 00:54:44,770 between calm and excited state. 717 00:54:44,770 --> 00:54:51,180 Therefore, it has those two matrix elements. 718 00:54:51,180 --> 00:54:56,700 Whereas electric field operator is the equation 719 00:54:56,700 --> 00:55:00,550 and annihilation operator a and a dagger. 720 00:55:00,550 --> 00:55:05,410 Or which is very elegant if I use for the two level 721 00:55:05,410 --> 00:55:08,160 system a spin one half description. 722 00:55:08,160 --> 00:55:11,030 And I use sigma plus and sigma minus, 723 00:55:11,030 --> 00:55:12,890 raising and lowering operator. 724 00:55:12,890 --> 00:55:15,980 Sigma plus takes the ground state to the excited state. 725 00:55:15,980 --> 00:55:19,090 Sigma minus takes the exciting state to the ground state. 726 00:55:19,090 --> 00:55:23,230 Then in the fundamental atom light interaction, 727 00:55:23,230 --> 00:55:25,770 we have those four terms. 728 00:55:25,770 --> 00:55:30,030 And now you see that sigma plus takes the atom 729 00:55:30,030 --> 00:55:33,720 from the calm to the excited state. 730 00:55:33,720 --> 00:55:37,850 But sigma plus appears both with photon absorption 731 00:55:37,850 --> 00:55:39,640 and with photon emission. 732 00:55:39,640 --> 00:55:41,866 So therefore, the atom can-- this 733 00:55:41,866 --> 00:55:43,490 is what the quantum mechanical operator 734 00:55:43,490 --> 00:55:46,430 tells us-- go from the ground to the excited state 735 00:55:46,430 --> 00:55:51,170 either by photon absorption or by photon emission. 736 00:55:54,992 --> 00:55:55,575 Any questions? 737 00:56:00,840 --> 00:56:01,834 Yes. 738 00:56:01,834 --> 00:56:04,567 AUDIENCE: So if we were to look beyond the dipole 739 00:56:04,567 --> 00:56:09,289 approximation, would we see transitions 740 00:56:09,289 --> 00:56:11,277 that leave the [INAUDIBLE] state? 741 00:56:20,230 --> 00:56:22,700 PROFESSOR: Yes or no. 742 00:56:22,700 --> 00:56:25,270 What we need here is a bilinear interaction, 743 00:56:25,270 --> 00:56:28,920 which has an raising and lowering operator for the atom. 744 00:56:28,920 --> 00:56:31,100 And here it has a raising and lowering atom 745 00:56:31,100 --> 00:56:33,490 operator for the photon number. 746 00:56:33,490 --> 00:56:37,930 And it has the co-rotating term where you raise here 747 00:56:37,930 --> 00:56:39,350 and you lower there. 748 00:56:39,350 --> 00:56:41,040 You lower here and you raise there. 749 00:56:41,040 --> 00:56:45,110 But it has also terms where you raise the atomic excitation, 750 00:56:45,110 --> 00:56:47,470 and you raise the photon number by one, 751 00:56:47,470 --> 00:56:49,480 which of course violates energy. 752 00:56:49,480 --> 00:56:52,870 But the message I want to give you is this 753 00:56:52,870 --> 00:56:54,250 is possible for short times. 754 00:56:54,250 --> 00:56:58,190 And this is exactly what the quantum mechanical equations 755 00:56:58,190 --> 00:57:00,460 tell us. 756 00:57:00,460 --> 00:57:02,540 So the short answer to your question 757 00:57:02,540 --> 00:57:05,090 is, as long as we describe the system 758 00:57:05,090 --> 00:57:09,100 by the dipole interaction, or what we have even beyond-- 759 00:57:09,100 --> 00:57:10,900 I'm not using a perturbation argument. 760 00:57:10,900 --> 00:57:13,570 I'm writing down the operator. 761 00:57:13,570 --> 00:57:16,470 And this operator can now effect the system 762 00:57:16,470 --> 00:57:18,700 to all possible orders. 763 00:57:18,700 --> 00:57:22,060 So even the non-perturbative strong coupling limit 764 00:57:22,060 --> 00:57:25,850 will always have products of atomic raising operators, 765 00:57:25,850 --> 00:57:28,660 lowering operators with photon raising and lowering operators. 766 00:57:32,790 --> 00:57:36,590 The little bit longer answer is, some of what I'm telling you 767 00:57:36,590 --> 00:57:39,090 may be gauge dependence. 768 00:57:39,090 --> 00:57:46,810 If you work in the-- if you use, not the dipole description, 769 00:57:46,810 --> 00:57:50,450 but you use the p dot a Hamiltonian, 770 00:57:50,450 --> 00:57:53,850 this Hamiltonian has a e square term. 771 00:57:53,850 --> 00:58:00,570 The e square term allows the atoms 772 00:58:00,570 --> 00:58:04,420 to exchange two photons at the same time. 773 00:58:04,420 --> 00:58:08,640 So in other words, in the a square interaction, 774 00:58:08,640 --> 00:58:16,140 we may have a vertex point in time 775 00:58:16,140 --> 00:58:19,280 where the atom interact with the photon field 776 00:58:19,280 --> 00:58:23,060 where two photons are exchanged. 777 00:58:23,060 --> 00:58:26,100 And then the rules are different. 778 00:58:26,100 --> 00:58:28,770 So in that sense-- but this is quite often 779 00:58:28,770 --> 00:58:30,950 when we give a quantum mechanical pictures, which 780 00:58:30,950 --> 00:58:34,590 has terms, which nicely shows the time evolution. 781 00:58:34,590 --> 00:58:36,670 And you think wow, yeah, this is what happens. 782 00:58:36,670 --> 00:58:38,640 One photon at a time, the atom goes 783 00:58:38,640 --> 00:58:40,370 ground, excited, excited, ground state. 784 00:58:40,370 --> 00:58:41,590 And you have your picture. 785 00:58:41,590 --> 00:58:44,920 And it is fully consistent with the exact quantum 786 00:58:44,920 --> 00:58:46,420 mechanical result. 787 00:58:46,420 --> 00:58:48,822 You may be able to get the same result out 788 00:58:48,822 --> 00:58:49,780 of a different picture. 789 00:58:53,830 --> 00:58:57,202 That point will actually occur again 790 00:58:57,202 --> 00:58:58,660 when we talk, for instance, when we 791 00:58:58,660 --> 00:59:09,390 talk about density operators. 792 00:59:09,390 --> 00:59:12,960 A density operator is an average of our quantum states. 793 00:59:12,960 --> 00:59:15,640 But you can get the same density operator 794 00:59:15,640 --> 00:59:19,860 by averaging quantum states in different basis sets. 795 00:59:19,860 --> 00:59:25,910 So if you get one picture out of one specific basis set, 796 00:59:25,910 --> 00:59:27,642 it gives you the correct intuition, 797 00:59:27,642 --> 00:59:29,350 it's a correct description, but it is not 798 00:59:29,350 --> 00:59:32,168 the only possible description. 799 00:59:32,168 --> 00:59:33,102 [? Collin ?]. 800 00:59:33,102 --> 00:59:35,390 AUDIENCE: Maybe the thing, I don't know. 801 00:59:35,390 --> 00:59:36,890 AUDIENCE: I think what you're trying 802 00:59:36,890 --> 00:59:40,490 to get at is that picture works as long as you can limit 803 00:59:40,490 --> 00:59:42,716 yourself to a two level system. 804 00:59:42,716 --> 00:59:44,810 Because that's correct on a whole. 805 00:59:44,810 --> 00:59:47,010 Or is it like strong coupling? 806 00:59:47,010 --> 00:59:50,535 But as long as you can identify the two level system, 807 00:59:50,535 --> 00:59:55,525 or I think the dipole versus particle approximations 808 00:59:55,525 --> 00:59:59,517 [INAUDIBLE] an atom may have transition probabilities 809 00:59:59,517 --> 01:00:03,010 to others, like from an [INAUDIBLE] state. 810 01:00:03,010 --> 01:00:04,507 But-- 811 01:00:04,507 --> 01:00:06,503 AUDIENCE: Actually, I was just wondering 812 01:00:06,503 --> 01:00:09,247 if it was possible to have it like a transition matrix 813 01:00:09,247 --> 01:00:12,531 element to [INAUDIBLE] coupling the ground state to the ground 814 01:00:12,531 --> 01:00:13,030 state. 815 01:00:13,030 --> 01:00:13,770 PROFESSOR: Yes. 816 01:00:13,770 --> 01:00:16,920 The e square operator does that, because 817 01:00:16,920 --> 01:00:21,206 in the other gauge, which is pa, pa. 818 01:00:21,206 --> 01:00:25,450 p is in dipole operator. p is the momentum operator 819 01:00:25,450 --> 01:00:26,550 for the atoms. 820 01:00:26,550 --> 01:00:29,776 And the p operator will switch the atom from ground 821 01:00:29,776 --> 01:00:31,010 to excited state. 822 01:00:31,010 --> 01:00:34,820 a, the vector potential, involves a and a daggers. 823 01:00:34,820 --> 01:00:38,730 So the p dot a term does pretty much the same 824 01:00:38,730 --> 01:00:41,100 as the d dot e term, because it's 825 01:00:41,100 --> 01:00:43,790 a bilinear product of an operator which 826 01:00:43,790 --> 01:00:47,150 has an effect on the atoms and has an effect on the photons. 827 01:00:47,150 --> 01:00:50,990 And it means you always switch the quantum state in your atom 828 01:00:50,990 --> 01:00:53,430 and create or annihilate the photon. 829 01:00:53,430 --> 01:00:56,380 But the a squared term-- it's just a square, 830 01:00:56,380 --> 01:00:58,350 it doesn't have a p in front of it-- 831 01:00:58,350 --> 01:01:06,820 will allow an atom in without changing the state to create 832 01:01:06,820 --> 01:01:08,320 two photons, emit two photons. 833 01:01:08,320 --> 01:01:10,030 And then there's probably a cross term 834 01:01:10,030 --> 01:01:12,700 which means to absorb and emit a photon. 835 01:01:12,700 --> 01:01:17,547 You will actually, in one of your next homework assignments, 836 01:01:17,547 --> 01:01:19,380 you will actually look at the a square term. 837 01:01:19,380 --> 01:01:21,650 And I think it's a very educational problem. 838 01:01:21,650 --> 01:01:23,375 So you really see that you have two 839 01:01:23,375 --> 01:01:28,040 very different descriptions, but the results fully agree. 840 01:01:28,040 --> 01:01:30,860 But this is already an expert discussion. 841 01:01:30,860 --> 01:01:34,660 Why don't we for now just hang onto the dipole approximation. 842 01:01:34,660 --> 01:01:37,070 We have d dot e, and we just learn 843 01:01:37,070 --> 01:01:39,790 what is inside the dipole approximation, 844 01:01:39,790 --> 01:01:43,400 and what is an exact quantum mechanical description using 845 01:01:43,400 --> 01:01:45,670 the dipole approximation. 846 01:01:45,670 --> 01:01:49,650 But and then we can come back to the discussion, 847 01:01:49,650 --> 01:01:52,730 is everything we describe really real. 848 01:01:52,730 --> 01:01:54,750 And while the answer is, what is real 849 01:01:54,750 --> 01:01:57,350 in quantum physics is the final result, 850 01:01:57,350 --> 01:01:59,570 the intermediate results, you have 851 01:01:59,570 --> 01:02:03,380 to say that this is only one possibility 852 01:02:03,380 --> 01:02:04,725 to go to the final result. 853 01:02:08,290 --> 01:02:23,765 OK, so we want to-- let me just put in one more page. 854 01:02:39,740 --> 01:02:44,820 So what we want to do now is we want to do a calculation. 855 01:02:44,820 --> 01:02:47,080 It's a perturbative calculation, but we 856 01:02:47,080 --> 01:02:48,200 can take it to all orders. 857 01:02:48,200 --> 01:02:51,480 So therefore it's exact and general. 858 01:02:51,480 --> 01:02:58,720 We want to do a perturbative calculation of transition 859 01:02:58,720 --> 01:02:59,220 amplitudes. 860 01:03:07,660 --> 01:03:17,020 And what I am following here the discussion in atom photon 861 01:03:17,020 --> 01:03:23,290 interaction on those pages. 862 01:03:23,290 --> 01:03:26,140 And the idea is the following. 863 01:03:26,140 --> 01:03:29,670 We have the Hamiltonian for the atom. 864 01:03:29,670 --> 01:03:31,790 And then we have a Hamiltonian which 865 01:03:31,790 --> 01:03:35,320 describes the transverse field. 866 01:03:44,380 --> 01:03:48,000 And the interaction of the transverse field 867 01:03:48,000 --> 01:03:50,690 with the atoms. 868 01:03:50,690 --> 01:03:55,920 What we want to use is we want to use the interaction 869 01:03:55,920 --> 01:04:02,980 picture, which is often the nicest picture 870 01:04:02,980 --> 01:04:08,380 to describe the effect of the interaction between two 871 01:04:08,380 --> 01:04:10,570 systems. 872 01:04:10,570 --> 01:04:17,750 In the interaction picture, you are transforming 873 01:04:17,750 --> 01:04:22,480 from you Schrodinger type e function 874 01:04:22,480 --> 01:04:27,390 to wave function psi tilde. 875 01:04:27,390 --> 01:04:32,580 And those wave function psi tilde include already 876 01:04:32,580 --> 01:04:35,860 the dynamics of the Hamiltonian H naught. 877 01:04:43,620 --> 01:04:50,760 So that means that all operators in the normal Schrodinger 878 01:04:50,760 --> 01:04:56,270 picture become now operators in the interaction picture 879 01:04:56,270 --> 01:04:59,430 by canonical transformation, which 880 01:04:59,430 --> 01:05:05,195 involves the dynamics due to the unperturbed Hamiltonian. 881 01:05:10,850 --> 01:05:14,490 And so that's just a reminder what 882 01:05:14,490 --> 01:05:16,610 the interaction picture is. 883 01:05:16,610 --> 01:05:20,800 And we are now interested what happens in the interaction 884 01:05:20,800 --> 01:05:26,780 picture to an initial wave function psi of ti. 885 01:05:26,780 --> 01:05:29,860 This wave function already includes the time evolution 886 01:05:29,860 --> 01:05:31,610 due to H naught. 887 01:05:31,610 --> 01:05:35,240 So the only change now comes because we have interactions 888 01:05:35,240 --> 01:05:37,220 with the electromagnetic field. 889 01:05:37,220 --> 01:05:39,950 So this allows us now to focus only 890 01:05:39,950 --> 01:05:42,419 on the relevant interactions, the interactions we 891 01:05:42,419 --> 01:05:43,210 want to understand. 892 01:05:51,190 --> 01:05:55,950 And the formalism which is used in atom photon interaction 893 01:05:55,950 --> 01:05:58,530 focuses on the time evolution operator, 894 01:05:58,530 --> 01:06:01,960 which I'm sure all of you have seen. 895 01:06:01,960 --> 01:06:07,330 So the time evolution of our system, 896 01:06:07,330 --> 01:06:09,510 how the wave function involves from the initial 897 01:06:09,510 --> 01:06:14,990 to the final time, is described by the time evolution operator. 898 01:06:17,930 --> 01:06:20,370 I will come back to the wave function later, 899 01:06:20,370 --> 01:06:26,020 but in order to derive the time evolution of the wave function, 900 01:06:26,020 --> 01:06:31,360 it's at least convenient to focus first 901 01:06:31,360 --> 01:06:33,120 on the time evolution operator. 902 01:06:33,120 --> 01:06:34,700 So in other words, I want to show 903 01:06:34,700 --> 01:06:37,850 you a formal solution for the time evolution operator. 904 01:06:37,850 --> 01:06:40,800 And once we know the time evolution operator, 905 01:06:40,800 --> 01:06:42,370 we apply it to the wave function. 906 01:06:42,370 --> 01:06:44,619 And then we are talking again about the wave function. 907 01:06:52,350 --> 01:06:58,140 OK, since the derivation involves many equations 908 01:06:58,140 --> 01:07:02,050 and they are all printed in the full beauty in atom photon 909 01:07:02,050 --> 01:07:08,970 interaction, I decided to use pre-written slides here. 910 01:07:08,970 --> 01:07:12,530 Also, most of it is fairly elementary. 911 01:07:12,530 --> 01:07:17,360 The equations are complicated, but the concepts behind them 912 01:07:17,360 --> 01:07:19,540 are very, very simple. 913 01:07:19,540 --> 01:07:20,920 It's actually the beauty of using 914 01:07:20,920 --> 01:07:22,490 a kind of a time evolution operator. 915 01:07:22,490 --> 01:07:24,690 It's a little bit mathematically formal, 916 01:07:24,690 --> 01:07:28,990 but it allows us to express what is really 917 01:07:28,990 --> 01:07:32,160 going on in the solution in very, very simple terms. 918 01:07:41,730 --> 01:07:44,460 So the goal is to do a perturbative expansion 919 01:07:44,460 --> 01:07:47,300 for the time evolution operator. 920 01:07:47,300 --> 01:07:51,890 If we have no interaction potential v, the interaction 921 01:07:51,890 --> 01:07:54,630 picture, nothing happens in the interaction picture, 922 01:07:54,630 --> 01:07:56,380 and therefore, the time evolution operator 923 01:07:56,380 --> 01:07:57,910 is a unity matrix. 924 01:07:57,910 --> 01:08:02,840 But if you have a coupling term v, there is time evolution. 925 01:08:02,840 --> 01:08:05,130 And the time evolution can be treated 926 01:08:05,130 --> 01:08:09,110 in lowest or in higher orders in the perturbation. 927 01:08:09,110 --> 01:08:12,495 And we want to use now perturbation expansion, where 928 01:08:12,495 --> 01:08:14,640 we have correction terms, which is 929 01:08:14,640 --> 01:08:17,149 the first order, second order, and nth order 930 01:08:17,149 --> 01:08:20,689 correction for time evolution operator. 931 01:08:20,689 --> 01:08:22,790 So what we simply want to do is we 932 01:08:22,790 --> 01:08:25,580 want to do an iterative solution. 933 01:08:25,580 --> 01:08:28,130 We want to find an iterative solution for the time evolution 934 01:08:28,130 --> 01:08:28,630 operator. 935 01:08:31,700 --> 01:08:34,240 The next two lines is just a reminder. 936 01:08:37,080 --> 01:08:40,510 What is the differential equation for the time evolution 937 01:08:40,510 --> 01:08:42,446 operator? 938 01:08:42,446 --> 01:08:45,029 Well, we are really just talking about Schrodinger's equation. 939 01:08:45,029 --> 01:08:47,350 Schrodinger's equation for the wave function 940 01:08:47,350 --> 01:08:49,850 turns into differential equation for the time evolution 941 01:08:49,850 --> 01:08:50,979 operator. 942 01:08:50,979 --> 01:08:53,630 Schrodinger's equation in the interaction picture 943 01:08:53,630 --> 01:08:56,970 says that the time derivative of the wave 944 01:08:56,970 --> 01:08:59,310 function in the interaction picture 945 01:08:59,310 --> 01:09:00,819 has nothing to do H naught. 946 01:09:00,819 --> 01:09:02,689 H naught has already been absorbed 947 01:09:02,689 --> 01:09:04,710 in the definition of the wave function. 948 01:09:04,710 --> 01:09:06,939 So the time evolution in the interaction picture 949 01:09:06,939 --> 01:09:10,890 only comes from the interaction term. 950 01:09:10,890 --> 01:09:20,810 And now, if you write the wave function at time tf 951 01:09:20,810 --> 01:09:24,420 as the time evolved wave function from the initial time 952 01:09:24,420 --> 01:09:29,600 to the final time, then you take the derivative here. 953 01:09:29,600 --> 01:09:33,220 You actually take a derivative of the time evolution operator. 954 01:09:33,220 --> 01:09:38,130 And therefore, in one step, from Schrodinger's equation, 955 01:09:38,130 --> 01:09:41,609 you find a differential equation for the time evolution 956 01:09:41,609 --> 01:09:43,710 operator. 957 01:09:43,710 --> 01:09:47,010 In other words, this is now the operator equation 958 01:09:47,010 --> 01:09:48,880 for the time evolution operator. 959 01:09:48,880 --> 01:09:53,640 And it's nothing else than a 100% rewrite of the Schrodinger 960 01:09:53,640 --> 01:09:54,140 equation. 961 01:10:02,180 --> 01:10:04,900 Interrupt me if you have questions. 962 01:10:04,900 --> 01:10:08,580 This part should be-- we'll go through that 963 01:10:08,580 --> 01:10:10,400 for solely pedagogical reasons. 964 01:10:10,400 --> 01:10:13,920 And that means you should really understand it. 965 01:10:13,920 --> 01:10:22,250 So this equation can now be formally solved 966 01:10:22,250 --> 01:10:23,740 in the following way. 967 01:10:23,740 --> 01:10:27,310 Take this expression for the time evolution operator 968 01:10:27,310 --> 01:10:31,790 and insert it in this equation, and you find an identity. 969 01:10:31,790 --> 01:10:33,720 Of course, you haven't really solved it, 970 01:10:33,720 --> 01:10:37,610 because you have the time evolution operator expressed 971 01:10:37,610 --> 01:10:39,830 by the time evolution operator. 972 01:10:39,830 --> 01:10:42,150 This looks like a circular conclusion, 973 01:10:42,150 --> 01:10:43,960 which is just nonsense. 974 01:10:43,960 --> 01:10:46,300 But if you inspect it more closely, 975 01:10:46,300 --> 01:10:50,570 you observe that the time evolution operator here 976 01:10:50,570 --> 01:10:54,260 is expressed by the time evolution operator multiplied 977 01:10:54,260 --> 01:10:59,370 with v. And if you now think in an iterative solution 978 01:10:59,370 --> 01:11:01,590 that we want to express. 979 01:11:01,590 --> 01:11:04,110 We want to expand the time evolution operator 980 01:11:04,110 --> 01:11:09,320 in the different orders in the interaction parameter v. Then 981 01:11:09,320 --> 01:11:15,250 you find actually that if you are only 982 01:11:15,250 --> 01:11:19,210 interested in the first order of the interaction operator, 983 01:11:19,210 --> 01:11:21,220 you can use the [INAUDIBLE] order here, 984 01:11:21,220 --> 01:11:23,620 because you get one more power of v. 985 01:11:23,620 --> 01:11:25,330 So that's how you get the first order. 986 01:11:25,330 --> 01:11:28,610 If you want to know the second order of the time evolution 987 01:11:28,610 --> 01:11:30,720 operator, you can plug-in the first order 988 01:11:30,720 --> 01:11:32,150 on the right hand side. 989 01:11:32,150 --> 01:11:36,410 So therefore, you get an iterative solution. 990 01:11:36,410 --> 01:11:38,710 The first order solution is one. 991 01:11:38,710 --> 01:11:41,120 The [INAUDIBLE] order solution is the unity operator. 992 01:11:41,120 --> 01:11:45,120 The first order solution is by just putting the unity operator 993 01:11:45,120 --> 01:11:45,890 here. 994 01:11:45,890 --> 01:11:49,220 The second order solution is by taking the first order 995 01:11:49,220 --> 01:11:51,480 solution, plugging it in in here. 996 01:11:51,480 --> 01:11:53,980 And then you get two integrals over the operator 997 01:11:53,980 --> 01:12:00,100 v. So in that sense, we have formally 998 01:12:00,100 --> 01:12:09,000 solved the time evolution of the system in all orders. 999 01:12:09,000 --> 01:12:10,524 So this is what we get out of it. 1000 01:12:18,120 --> 01:12:20,660 Yes, the equations are getting longer. 1001 01:12:20,660 --> 01:12:23,520 But the structure is fairly obvious. 1002 01:12:23,520 --> 01:12:30,970 So you saw that the-- let me just flashback. 1003 01:12:30,970 --> 01:12:34,130 The first order term had a temporal integral 1004 01:12:34,130 --> 01:12:38,650 over v. The second order term has two temporal integrals 1005 01:12:38,650 --> 01:12:45,130 over v. And there's a time order in between tau 1 and tau 2. 1006 01:12:45,130 --> 01:12:52,370 And the nth order term now involves n temporal integrals 1007 01:12:52,370 --> 01:12:54,987 where the times are ordered in such a way. 1008 01:13:03,610 --> 01:13:07,940 Now we want to go back to the Schrodinger equation. 1009 01:13:07,940 --> 01:13:12,410 So we want to use this already fairly complicated expression 1010 01:13:12,410 --> 01:13:18,540 for the time evolution operator and apply it 1011 01:13:18,540 --> 01:13:20,860 to the initial wave function. 1012 01:13:20,860 --> 01:13:22,880 And we want to calculate matrix elements 1013 01:13:22,880 --> 01:13:26,090 between the initial wave function and some other phi 1014 01:13:26,090 --> 01:13:32,670 f, some other wave function in a given basis. 1015 01:13:32,670 --> 01:13:43,380 So we are also going back. 1016 01:13:43,380 --> 01:13:45,130 I don't want to go through too many steps. 1017 01:13:45,130 --> 01:13:49,270 Here, we're also going back to the original Schrodinger 1018 01:13:49,270 --> 01:13:50,010 picture. 1019 01:13:50,010 --> 01:13:53,150 So I've taken all the tildes off. 1020 01:13:53,150 --> 01:13:56,140 But you know the step form the Schrodinger 1021 01:13:56,140 --> 01:13:58,590 picture to the interaction picture 1022 01:13:58,590 --> 01:14:01,740 was only taking out the Hamiltonian H naught. 1023 01:14:01,740 --> 01:14:07,880 And the Hamiltonian H naught for eigenstates phi i and phi f, 1024 01:14:07,880 --> 01:14:13,260 is simply a time evolution, e to the e ei with a certain time. 1025 01:14:13,260 --> 01:14:17,110 So all what this transformation to the interaction picture 1026 01:14:17,110 --> 01:14:21,080 gave us, it eliminated, at least for a short while, 1027 01:14:21,080 --> 01:14:24,210 all of those phase factors, which are simply 1028 01:14:24,210 --> 01:14:25,715 the evolution of the eigenfunction 1029 01:14:25,715 --> 01:14:26,840 in the Schrodinger picture. 1030 01:14:47,460 --> 01:14:52,100 So let me look at a typical term which we have right now. 1031 01:14:52,100 --> 01:14:54,850 And you can't expect something simpler 1032 01:14:54,850 --> 01:14:57,325 than this, because this is the general solution. 1033 01:14:57,325 --> 01:15:00,200 It's an exact solution to all orders. 1034 01:15:00,200 --> 01:15:02,890 It's a summation over terms to all orders. 1035 01:15:02,890 --> 01:15:06,410 And eventually the summation of an infinite number of diagrams 1036 01:15:06,410 --> 01:15:09,270 is an exact solution. 1037 01:15:09,270 --> 01:15:15,090 So what we've got here is we have an integral over n times. 1038 01:15:15,090 --> 01:15:17,570 And the n times are time ordered. 1039 01:15:17,570 --> 01:15:22,650 This is the formal solution for the time evolution operator. 1040 01:15:22,650 --> 01:15:30,950 And that means that we integrate overall times, 1041 01:15:30,950 --> 01:15:34,420 but what it is under the integral sign 1042 01:15:34,420 --> 01:15:39,290 is a product of the operator v at times 1043 01:15:39,290 --> 01:15:42,510 tau 1, tau 2, tau 3, tau 4. 1044 01:15:45,230 --> 01:15:50,240 Since we got back to the Schrodinger picture, what 1045 01:15:50,240 --> 01:15:55,180 happens is between times tau 1, and tau 2, 1046 01:15:55,180 --> 01:15:59,370 the particle simply evolves with the phase factor 1047 01:15:59,370 --> 01:16:03,530 given by the Hamiltonian H naught. 1048 01:16:03,530 --> 01:16:05,540 So the picture is the following. 1049 01:16:05,540 --> 01:16:11,030 The time evolution operator in the interaction picture 1050 01:16:11,030 --> 01:16:24,760 is a product over the operator v tilde at different times. 1051 01:16:24,760 --> 01:16:28,100 If you simply plug it back into the above equation-- 1052 01:16:28,100 --> 01:16:30,110 and you have to look at it for a little while 1053 01:16:30,110 --> 01:16:32,810 to see that everything works out correctly. 1054 01:16:32,810 --> 01:16:38,785 But what that means is then that if you go to the Schrodinger 1055 01:16:38,785 --> 01:16:42,210 picture and write down the operator in the Schrodinger 1056 01:16:42,210 --> 01:16:44,900 in the basis of unperturbed eigenfunction, 1057 01:16:44,900 --> 01:16:50,900 that you have products of the operator v at times 1058 01:16:50,900 --> 01:16:54,510 t1, tau 2, tau 3, they're time ordered. 1059 01:16:57,590 --> 01:17:00,400 And because we have left the interaction picture, 1060 01:17:00,400 --> 01:17:04,400 you also get the propagation with the phase factors 1061 01:17:04,400 --> 01:17:07,850 given by the eigenenergies of the unperturbed Hamiltonian H 1062 01:17:07,850 --> 01:17:09,620 naught. 1063 01:17:09,620 --> 01:17:12,480 So therefore, you get just an infinite number 1064 01:17:12,480 --> 01:17:16,840 of terms which have all the following structure, 1065 01:17:16,840 --> 01:17:20,830 that the particle propagates in its eigenstate. 1066 01:17:20,830 --> 01:17:24,770 It reaches a vertex where the interaction switches 1067 01:17:24,770 --> 01:17:27,520 the particle from one state to the next. 1068 01:17:27,520 --> 01:17:30,890 Then in the next state, which may now be the excited state, 1069 01:17:30,890 --> 01:17:33,850 we have propagation in the excited state. 1070 01:17:33,850 --> 01:17:37,560 Then the excited state is, again, exchanging a photon, 1071 01:17:37,560 --> 01:17:41,090 has an interaction term, and is switched to-- well, 1072 01:17:41,090 --> 01:17:43,880 for the two level system, it has to go back to the ground state. 1073 01:17:43,880 --> 01:17:47,740 In a more general situation, it goes to another quantum state. 1074 01:17:47,740 --> 01:18:02,160 So therefore, what we have exactly derived 1075 01:18:02,160 --> 01:18:06,640 is that the propagation, or the time evolution, 1076 01:18:06,640 --> 01:18:12,940 of the wave function is nothing else then 1077 01:18:12,940 --> 01:18:14,590 many, many of those factors. 1078 01:18:17,490 --> 01:18:21,060 And each of those factors can be represented 1079 01:18:21,060 --> 01:18:22,460 by a diagram like this. 1080 01:18:33,260 --> 01:18:42,410 So let me just write down what this diagram here 1081 01:18:42,410 --> 01:18:45,010 means mathematically. 1082 01:18:45,010 --> 01:18:51,970 It means that initially, we have a photon of energy epsilon, 1083 01:18:51,970 --> 01:18:56,200 of polarization epsilon, wave factor k, and a certain energy. 1084 01:18:56,200 --> 01:18:59,080 And we have particles in state a. 1085 01:18:59,080 --> 01:19:10,970 That means that we get from the initial time to the time tau 1. 1086 01:19:10,970 --> 01:19:14,650 And tau 1 is the time of the first vertex 1087 01:19:14,650 --> 01:19:20,970 of the first photon exchange, that the wave function evolves. 1088 01:19:23,850 --> 01:19:28,800 And it evolves with an energy of the unperturbed Hamiltonian, 1089 01:19:28,800 --> 01:19:31,450 which is the atomic energy. 1090 01:19:31,450 --> 01:19:33,510 And we have one photon h bar omega. 1091 01:19:36,160 --> 01:19:39,860 At the time tau 1-- and this is when 1092 01:19:39,860 --> 01:19:41,560 the diagram on the left hand side 1093 01:19:41,560 --> 01:19:47,070 has a vertex-- we are now bringing in the interaction 1094 01:19:47,070 --> 01:19:50,880 operator, which acts on the atom. 1095 01:19:50,880 --> 01:19:55,100 It takes the atom from state A to state B. 1096 01:19:55,100 --> 01:19:58,640 And it changes the state of the photon. 1097 01:19:58,640 --> 01:20:01,690 In this case, a photon with a certain wave factor 1098 01:20:01,690 --> 01:20:06,500 and polarization simply disappears. 1099 01:20:06,500 --> 01:20:14,140 So this is now the time tau 1. 1100 01:20:14,140 --> 01:20:18,610 The next Vertex is reached at time tau 2. 1101 01:20:18,610 --> 01:20:23,580 And between the time tau 2 and tau 1, 1102 01:20:23,580 --> 01:20:29,710 the system evolves according to the Hamiltonian H naught. 1103 01:20:29,710 --> 01:20:34,710 And the energy is now, because we have no photon, 1104 01:20:34,710 --> 01:20:41,440 is simply the energy of the atom in state B. 1105 01:20:41,440 --> 01:20:44,910 Then we reach the next vertex. 1106 01:20:44,910 --> 01:20:48,350 We start with a state B and no photon. 1107 01:20:48,350 --> 01:20:52,190 The interaction switches, as now I 1108 01:20:52,190 --> 01:20:54,000 assumed we have more than two levels. 1109 01:20:54,000 --> 01:20:57,620 Two are state C. And we have now a photon, which 1110 01:20:57,620 --> 01:21:02,600 may be different, k prime epsilon prime. 1111 01:21:02,600 --> 01:21:08,410 Since we are now, for this given example, I've selected n 1112 01:21:08,410 --> 01:21:11,290 equals 2, something which is second order 1113 01:21:11,290 --> 01:21:12,790 in the perturbation. 1114 01:21:12,790 --> 01:21:19,600 But that means now that between the time tau 1115 01:21:19,600 --> 01:21:25,790 2 and the final tie-in for the time propagation, that's 1116 01:21:25,790 --> 01:21:27,340 now everything is done. 1117 01:21:27,340 --> 01:21:29,300 Things propagate. 1118 01:21:29,300 --> 01:21:33,380 And the unperturbed Hamiltonian H naught 1119 01:21:33,380 --> 01:21:36,010 gives us now a phase factor, which 1120 01:21:36,010 --> 01:21:40,580 reflects the energy of the atomic state, 1121 01:21:40,580 --> 01:21:44,770 and the energy of the photon in mode k 1122 01:21:44,770 --> 01:21:49,510 prime epsilon prime with energy omega h per omega prime. 1123 01:21:49,510 --> 01:21:53,200 So in other words, I hope you see that at the end of this-- 1124 01:21:53,200 --> 01:21:55,510 I mean, this is why people have Feynman diagrams. 1125 01:21:55,510 --> 01:21:58,630 It's a complicated, involved mathematical formulation 1126 01:21:58,630 --> 01:22:00,270 with multiple integrations. 1127 01:22:00,270 --> 01:22:03,330 But at the end of the day, what we have derived 1128 01:22:03,330 --> 01:22:06,772 is that the most general solutions 1129 01:22:06,772 --> 01:22:13,330 to all orders in the probation is nothing else than a sum 1130 01:22:13,330 --> 01:22:16,610 and integral over diagrams like this. 1131 01:22:16,610 --> 01:22:21,210 So when I depict it here, the second order diagram, of course 1132 01:22:21,210 --> 01:22:25,860 this has an exact mathematical meaning. 1133 01:22:25,860 --> 01:22:28,350 And what we have to do is when we solve 1134 01:22:28,350 --> 01:22:30,540 a quantum mechanical equation, we 1135 01:22:30,540 --> 01:22:33,330 have to now allow those interactions, which 1136 01:22:33,330 --> 01:22:37,910 happen at time tau 1 and tau 2, to happen at arbitrary times. 1137 01:22:37,910 --> 01:22:40,680 So therefore, we have to sum over amplitudes 1138 01:22:40,680 --> 01:22:44,162 by integrating over times tau 1 and tau 2. 1139 01:22:47,050 --> 01:22:49,890 So on Friday-- I have to stop now. 1140 01:22:49,890 --> 01:22:51,980 I think there's a seminar right now. 1141 01:22:51,980 --> 01:22:56,540 On Friday, I will show you that with this description, 1142 01:22:56,540 --> 01:23:00,720 we have actually captured everything I explained to you 1143 01:23:00,720 --> 01:23:04,410 earlier-- those virtual states, the emission 1144 01:23:04,410 --> 01:23:06,890 of virtual or real photons. 1145 01:23:06,890 --> 01:23:08,840 So everything that which was maybe 1146 01:23:08,840 --> 01:23:12,180 qualitative at the beginning of this section 1147 01:23:12,180 --> 01:23:15,340 has now a precise, mathematical meaning. 1148 01:23:15,340 --> 01:23:17,720 But that's what we do on Friday.