1 0:00:01 --> 00:00:07 From early childhood, we can tell by touch 2 00:00:04 --> 00:00:10 whether an object is hot or whether it is cold. 3 00:00:09 --> 00:00:15 If you want to heat an object, you bring it in contact 4 00:00:12 --> 00:00:18 with a hot object, for instance a flame. 5 00:00:16 --> 00:00:22 If you want to cool an object, 6 00:00:18 --> 00:00:24 you bring it in contact with a cold object. 7 00:00:22 --> 00:00:28 When objects are heated or when they're cooled, then-- 8 00:00:29 --> 00:00:35 and the temperature changes-- 9 00:00:31 --> 00:00:37 then some of their properties change, 10 00:00:33 --> 00:00:39 and those properties are called thermometric properties: 11 00:00:39 --> 00:00:45 ther-mo-metric properties. 12 00:00:46 --> 00:00:52 One very characteristic thermometric property 13 00:00:50 --> 00:00:56 is that most substances when you heat them, they expand, 14 00:00:54 --> 00:01:00 and when you cool them, they shrink. 15 00:00:56 --> 00:01:02 We'll talk more about it later. 16 00:00:59 --> 00:01:05 If you take a gas in a closed volume and you heat it, 17 00:01:02 --> 00:01:08 the pressure goes up. 18 00:01:04 --> 00:01:10 That's a thermometric property. 19 00:01:06 --> 00:01:12 If you take an electric conductor and you heat it, 20 00:01:09 --> 00:01:15 in general the electric resistance will change. 21 00:01:14 --> 00:01:20 If you heat an iron bar, it will expand. 22 00:01:19 --> 00:01:25 And if you place it in contact 23 00:01:20 --> 00:01:26 with another iron bar which is cold, 24 00:01:23 --> 00:01:29 then the one that is hot will shrink 25 00:01:27 --> 00:01:33 and the one that is cold will heat up and will get longer, 26 00:01:31 --> 00:01:37 and this process will go on 27 00:01:33 --> 00:01:39 up to the point that the hot one will not get shorter 28 00:01:37 --> 00:01:43 and that the cold one will not get longer anymore. 29 00:01:41 --> 00:01:47 And that is when the two objects, as we say, 30 00:01:43 --> 00:01:49 are in thermal equilibrium with each other, 31 00:01:46 --> 00:01:52 and that is when the temperature of the two objects are the same. 32 00:01:51 --> 00:01:57 And so you can define a temperature scale 33 00:01:56 --> 00:02:02 by looking at the length of an object. 34 00:02:01 --> 00:02:07 For instance, here is a bar, 35 00:02:03 --> 00:02:09 some material, I clamp it in here, has length L, 36 00:02:09 --> 00:02:15 and I increase the temperature by an amount delta T, 37 00:02:12 --> 00:02:18 and it gets longer by a certain amount delta L. 38 00:02:16 --> 00:02:22 39 00:02:19 --> 00:02:25 I could put the whole thing in melting ice... 40 00:02:26 --> 00:02:32 melting ice... 41 00:02:29 --> 00:02:35 and I could say, "Aha." 42 00:02:31 --> 00:02:37 The length then is L1. 43 00:02:34 --> 00:02:40 Then I could put the whole thing in boiling water 44 00:02:39 --> 00:02:45 and I do that at one atmosphere pressure, and then I say, "Aha." 45 00:02:46 --> 00:02:52 I call that the length L2. 46 00:02:50 --> 00:02:56 And those are my reference points for my temperature scale. 47 00:02:55 --> 00:03:01 Celsius did just that. 48 00:02:58 --> 00:03:04 The idea that he used melting ice, 49 00:03:02 --> 00:03:08 which is now called zero degrees centigrade, 50 00:03:05 --> 00:03:11 and he used boiling point of water, 51 00:03:07 --> 00:03:13 which was his 100 degrees centigrade. 52 00:03:11 --> 00:03:17 He was a Swedish astronomer; 53 00:03:12 --> 00:03:18 in 1742 he introduced this temperature scale. 54 00:03:16 --> 00:03:22 So you could make yourself a plot now 55 00:03:20 --> 00:03:26 of the temperature versus the length of that bar, 56 00:03:25 --> 00:03:31 and you could say, okay, 100 degrees centigrade... 57 00:03:31 --> 00:03:37 if the length of the bar... L2, 58 00:03:36 --> 00:03:42 zero degrees centigrade if the length of the bar is L1. 59 00:03:44 --> 00:03:50 And now you can draw a straight line-- 60 00:03:46 --> 00:03:52 you can always draw a straight line through two points, 61 00:03:48 --> 00:03:54 you have one point here, you have one point there-- 62 00:03:52 --> 00:03:58 and you can define temperature now by saying, 63 00:03:59 --> 00:04:05 if my bar has this length, L of T, 64 00:04:04 --> 00:04:10 then this will be the temperature. 65 00:04:09 --> 00:04:15 So you can introduce a linear scale in this fashion, 66 00:04:12 --> 00:04:18 and the thing, in principle, could act like a thermometer. 67 00:04:17 --> 00:04:23 I'll show you a demonstration of this shortly. 68 00:04:22 --> 00:04:28 Centi in Greek means "one hundredth," 69 00:04:26 --> 00:04:32 and therefore we also call this scale often "centigrade." 70 00:04:32 --> 00:04:38 One degree centigrade is often called... 71 00:04:34 --> 00:04:40 one degree Celsius is often called one centigrade, 72 00:04:37 --> 00:04:43 for the reason that it divides 73 00:04:38 --> 00:04:44 the scale from zero to one hundred in equal portions. 74 00:04:44 --> 00:04:50 So we call them degrees centigrade, degrees Celsius. 75 00:04:48 --> 00:04:54 Fahrenheit, a German scientist, 76 00:04:52 --> 00:04:58 invented the mercury thermometer. 77 00:04:56 --> 00:05:02 We'll talk about the mercury thermometer a little later. 78 00:04:59 --> 00:05:05 In 1714 he introduced a new scale. 79 00:05:04 --> 00:05:10 He lived in Holland at the time, he lived there most of the time, 80 00:05:08 --> 00:05:14 and he used as his reference point body temperature, 81 00:05:10 --> 00:05:16 which he called 100 degrees Fahrenheit, 82 00:05:13 --> 00:05:19 and he used a mixture of salt and ice at zero degrees. 83 00:05:18 --> 00:05:24 Now, neither one of these two are very reproducible. 84 00:05:20 --> 00:05:26 If you pick one person, 85 00:05:22 --> 00:05:28 the temperature today may be a little higher than tomorrow. 86 00:05:24 --> 00:05:30 A person may have fever. 87 00:05:26 --> 00:05:32 In fact, the one that he picked 88 00:05:27 --> 00:05:33 probably did have a little bit of fever. 89 00:05:29 --> 00:05:35 And so the Fahrenheit scale, in that sense, 90 00:05:31 --> 00:05:37 is not very reproducible, and it has been redefined now 91 00:05:36 --> 00:05:42 in such a way that zero degrees centigrade 92 00:05:40 --> 00:05:46 is 32 degrees Fahrenheit, 93 00:05:43 --> 00:05:49 and 100 degrees centigrade is 212 degrees Fahrenheit. 94 00:05:51 --> 00:05:57 And so if you convert-- if you want to convert 95 00:05:53 --> 00:05:59 from Fahrenheit to centigrade or the other way around-- 96 00:05:56 --> 00:06:02 then the temperature in Fahrenheit 97 00:06:01 --> 00:06:07 is 9/5 times the temperature in Celsius plus 32. 98 00:06:07 --> 00:06:13 99 00:06:10 --> 00:06:16 If you take room temperature, 100 00:06:13 --> 00:06:19 the temperature is 20 degrees centigrade, 101 00:06:17 --> 00:06:23 what I was growing up with-- 102 00:06:19 --> 00:06:25 in Europe, everyone uses centigrade there-- 103 00:06:21 --> 00:06:27 then you can see that in terms of Fahrenheit, 104 00:06:25 --> 00:06:31 that becomes 68 degrees Fahrenheit. 105 00:06:29 --> 00:06:35 9/5 times 20 gives you 36, and then you add 32. 106 00:06:34 --> 00:06:40 107 00:06:37 --> 00:06:43 Minus 40 degrees centigrade 108 00:06:41 --> 00:06:47 is the same as minus 40 degrees Fahrenheit. 109 00:06:45 --> 00:06:51 Check that. 110 00:06:46 --> 00:06:52 That's where the two scales cross over. 111 00:06:49 --> 00:06:55 So almost the entire world uses the Celsius scale; 112 00:06:53 --> 00:06:59 it's part of our metric system. 113 00:06:55 --> 00:07:01 United States is one of the very, very few countries 114 00:06:58 --> 00:07:04 who still, in a rather stubborn way, uses degrees Fahrenheit. 115 00:07:02 --> 00:07:08 And it is really a pain in the neck, degrees Fahrenheit-- 116 00:07:05 --> 00:07:11 at least for me. 117 00:07:06 --> 00:07:12 I have very little feeling for it. 118 00:07:07 --> 00:07:13 I just happen to know that room temperature is 68, 119 00:07:10 --> 00:07:16 because that's the way I set my thermostat at my home, 120 00:07:13 --> 00:07:19 but that's about all. 121 00:07:14 --> 00:07:20 I can't think in terms of degrees Fahrenheit. 122 00:07:17 --> 00:07:23 There is no limit to high temperature, 123 00:07:20 --> 00:07:26 but there is a limit to the low temperatures. 124 00:07:22 --> 00:07:28 There is an absolute zero. 125 00:07:25 --> 00:07:31 This absolute zero below which you cannot go 126 00:07:28 --> 00:07:34 is about minus 273 degrees Celsius... 127 00:07:35 --> 00:07:41 128 00:07:38 --> 00:07:44 And if you take a system 129 00:07:40 --> 00:07:46 that cannot transfer energy to any other system 130 00:07:42 --> 00:07:48 that it is in thermal contact with, 131 00:07:45 --> 00:07:51 then it is at that lowest possible temperature. 132 00:07:48 --> 00:07:54 This is the way we define it. 133 00:07:50 --> 00:07:56 It's about minus 460 degrees Fahrenheit. 134 00:07:54 --> 00:08:00 And so we now have a third scale, 135 00:07:55 --> 00:08:01 which was introduced by Lord Kelvin, was a British scientist. 136 00:08:01 --> 00:08:07 He did a lot of research on heat, 137 00:08:03 --> 00:08:09 and he introduced the absolute scale 138 00:08:05 --> 00:08:11 whereby he uses the lowest possible temperature 139 00:08:09 --> 00:08:15 as zero degrees Kelvin. 140 00:08:12 --> 00:08:18 But the increments in terms of increase of one degree, 141 00:08:15 --> 00:08:21 he uses the same as the Celsius scale. 142 00:08:17 --> 00:08:23 So an increase of two or three degrees Kelvin is the same 143 00:08:20 --> 00:08:26 as an increase of two or three degrees centigrade. 144 00:08:23 --> 00:08:29 So if we now compare the three scales-- 145 00:08:26 --> 00:08:32 Celsius, Fahrenheit and Kelvin-- 146 00:08:31 --> 00:08:37 then 20 degrees centigrade would be 68 Fahrenheit, 147 00:08:36 --> 00:08:42 and that would be 273.15 plus 20. 148 00:08:41 --> 00:08:47 Let's round it off and make it 293, 149 00:08:45 --> 00:08:51 and if we take zero Kelvin, then we would have minus 273.15, 150 00:08:52 --> 00:08:58 but let's leave that off for now, 151 00:08:54 --> 00:09:00 and it is approximately minus 460. 152 00:08:57 --> 00:09:03 We will almost always work with degrees Kelvin in physics 153 00:09:02 --> 00:09:08 and we'll discuss that in more detail Friday. 154 00:09:04 --> 00:09:10 155 00:09:08 --> 00:09:14 Most substances expand when you heat them, 156 00:09:13 --> 00:09:19 and if we start with an object which has length L 157 00:09:20 --> 00:09:26 and I heat it up delta T degrees, 158 00:09:25 --> 00:09:31 it gets longer by an amount delta L. 159 00:09:29 --> 00:09:35 And that delta L can be expressed in a very simple way. 160 00:09:35 --> 00:09:41 It is alpha times L times delta T, 161 00:09:40 --> 00:09:46 and alpha is called the linear expansion coefficient. 162 00:09:47 --> 00:09:53 And the units are one over degrees centigrade, 163 00:09:52 --> 00:09:58 or one over degree Kelvin, which is the same, 164 00:09:55 --> 00:10:01 because it's the increments that matter. 165 00:09:58 --> 00:10:04 166 00:10:03 --> 00:10:09 The various values for alpha differ a great deal. 167 00:10:09 --> 00:10:15 Give you some values for alpha. 168 00:10:11 --> 00:10:17 I'll give you copper, I'll give you brass, I'll give you Pyrex, 169 00:10:17 --> 00:10:23 I'll give you Invar and I'll give you steel, 170 00:10:22 --> 00:10:28 and they are in units 171 00:10:24 --> 00:10:30 of ten to the minus six per degree centigrade, 172 00:10:28 --> 00:10:34 and we will use some of them today. 173 00:10:31 --> 00:10:37 Brass is about 19. 174 00:10:35 --> 00:10:41 Copper is 17. 175 00:10:38 --> 00:10:44 Pyrex 3.3; Invar 0.9; and steel is roughly 12, 176 00:10:44 --> 00:10:50 but there are many different kinds of steel. 177 00:10:47 --> 00:10:53 Invar was a great invention. 178 00:10:50 --> 00:10:56 Notice it has a very low expansion coefficient. 179 00:10:53 --> 00:10:59 It was very important in the 19th century, even today, 180 00:10:58 --> 00:11:04 to make instruments very precise, like clocks. 181 00:11:01 --> 00:11:07 Clocks are affected by the expansion of the gears. 182 00:11:04 --> 00:11:10 And so the invention of Invar, 183 00:11:06 --> 00:11:12 which is a mixture of 64% iron and 36% nickel, 184 00:11:12 --> 00:11:18 was invented by a physicist Guillaume in 1898, 185 00:11:17 --> 00:11:23 and for this discovery, 186 00:11:19 --> 00:11:25 he received the Nobel Prize in 1920. 187 00:11:22 --> 00:11:28 It tells you something how important it was to get an alloy 188 00:11:26 --> 00:11:32 that has a very low expansion coefficient. 189 00:11:30 --> 00:11:36 If we use these numbers, 190 00:11:32 --> 00:11:38 let us look at the expansion of, for instance, a railroad. 191 00:11:36 --> 00:11:42 We take a railroad, and we take a piece, a stretch of rail 192 00:11:40 --> 00:11:46 which is, say, a thousand meters. 193 00:11:44 --> 00:11:50 We take steel, iron-- 194 00:11:46 --> 00:11:52 so this is the expansion coefficient, roughly-- 195 00:11:49 --> 00:11:55 and we compare a cold day, not extremely cold, 196 00:11:53 --> 00:11:59 but a cold day with a hot summer day. 197 00:11:55 --> 00:12:01 A cold winter day, minus 15 degrees centigrade, 198 00:11:59 --> 00:12:05 and a hot summer day, plus 35 degrees centigrade. 199 00:12:03 --> 00:12:09 So delta T would be about 50 degrees centigrade. 200 00:12:09 --> 00:12:15 So what is delta L? 201 00:12:12 --> 00:12:18 Well, that would be 12 times ten to the minus six 202 00:12:19 --> 00:12:25 times ten to the third, times 50, 203 00:12:23 --> 00:12:29 and that is about 0.6 meters, which is about 60 centimeters. 204 00:12:30 --> 00:12:36 So what are you going to do with that now? 205 00:12:32 --> 00:12:38 How is that solved? 206 00:12:33 --> 00:12:39 If the rail wants to get longer and can't get longer, 207 00:12:36 --> 00:12:42 it will start to bulge either in this way, or sideways, 208 00:12:39 --> 00:12:45 whichever is the easiest. 209 00:12:41 --> 00:12:47 But the way this is solved is actually quite simple. 210 00:12:45 --> 00:12:51 When you look at rails, there are openings between them. 211 00:12:51 --> 00:12:57 They're very distinct. 212 00:12:53 --> 00:12:59 They're about five centimeters. 213 00:12:54 --> 00:13:00 If you walk along the rail, you can see the openings. 214 00:12:58 --> 00:13:04 And if you make these openings, say, five centimeters, 215 00:13:03 --> 00:13:09 then you would need 12 of them in thousand meters, 216 00:13:07 --> 00:13:13 so every 80 meters you would need a gap. 217 00:13:10 --> 00:13:16 And you can hear these gaps when the train goes over these gaps. 218 00:13:13 --> 00:13:19 It's a very typical sound. 219 00:13:15 --> 00:13:21 Because imagine when the wheel goes over it, 220 00:13:18 --> 00:13:24 you hear a certain click. 221 00:13:20 --> 00:13:26 You can see them and you can hear them, 222 00:13:22 --> 00:13:28 and that's the way they correct 223 00:13:25 --> 00:13:31 for this expansion and contraction. 224 00:13:28 --> 00:13:34 Bridges can be many kilometers long, 225 00:13:30 --> 00:13:36 and they have, of course, the same problem of expansion, 226 00:13:33 --> 00:13:39 and the way that that is dealt with, also very clever, 227 00:13:37 --> 00:13:43 is as follows. 228 00:13:40 --> 00:13:46 This is a picture that I copied actually from your book. 229 00:13:43 --> 00:13:49 It's called an expansion joint, 230 00:13:45 --> 00:13:51 and there are many of them in bridges, 231 00:13:48 --> 00:13:54 and so what it allows the bridge is to do this-- 232 00:13:51 --> 00:13:57 to breathe, so to speak, adjust to the temperature. 233 00:13:55 --> 00:14:01 There is a bizarre picture whereby the claim is made 234 00:14:00 --> 00:14:06 that this railroad became so warped 235 00:14:03 --> 00:14:09 because of an extremely hot day. 236 00:14:07 --> 00:14:13 I trust it, although it's hard to believe 237 00:14:10 --> 00:14:16 that it could be so bad. 238 00:14:11 --> 00:14:17 It must have been extraordinarily hot. 239 00:14:13 --> 00:14:19 As I mentioned, if a rail cannot expand, then all it can do 240 00:14:17 --> 00:14:23 is either bulge in this way or this way, 241 00:14:20 --> 00:14:26 whichever way is easiest for it, 242 00:14:22 --> 00:14:28 and apparently here, the easiest way is to go sideways, 243 00:14:25 --> 00:14:31 so you see a remarkable destruction, actually, 244 00:14:28 --> 00:14:34 due to an unexpected high temperature. 245 00:14:31 --> 00:14:37 246 00:14:39 --> 00:14:45 I have here a brass bar which is about 36 centimeters long, 247 00:14:47 --> 00:14:53 and I'm going to heat that brass bar. 248 00:14:52 --> 00:14:58 You'll see it there, too. 249 00:14:54 --> 00:15:00 The brass bar is right here, 250 00:14:59 --> 00:15:05 and we have a way of showing you the extension, 251 00:15:02 --> 00:15:08 even though it is extremely small-- 252 00:15:05 --> 00:15:11 only a fraction of a millimeter. 253 00:15:07 --> 00:15:13 We can show that to you very easily. 254 00:15:09 --> 00:15:15 The way we do that is we have some kind of an amplifier. 255 00:15:14 --> 00:15:20 If this is the rod, and I would put here a hand, 256 00:15:21 --> 00:15:27 and pivot that hand here, 257 00:15:26 --> 00:15:32 then it's easy to see that if you push against it here, 258 00:15:30 --> 00:15:36 that this hand will go like this. 259 00:15:34 --> 00:15:40 So very little extension here 260 00:15:35 --> 00:15:41 will give you a large extension there. 261 00:15:38 --> 00:15:44 We do it twice, so we have two levels. 262 00:15:41 --> 00:15:47 And that is this arm. 263 00:15:43 --> 00:15:49 I have here a set screw, 264 00:15:44 --> 00:15:50 and I can make... I can move the bar in this direction. 265 00:15:47 --> 00:15:53 I'm not making it longer, but I can move it, 266 00:15:49 --> 00:15:55 and you will see what effect it has. 267 00:15:51 --> 00:15:57 If I move the bar one way, it goes up. 268 00:15:53 --> 00:15:59 Move the bar back, it goes down. 269 00:15:56 --> 00:16:02 You can think of this as a thermometer. 270 00:15:58 --> 00:16:04 It will be 70 degrees, as it is now, 271 00:16:00 --> 00:16:06 and if I heat it up, then it will get longer 272 00:16:03 --> 00:16:09 and you will see this end go up. 273 00:16:06 --> 00:16:12 We could try that. 274 00:16:08 --> 00:16:14 (blowtorch hissing ) 275 00:16:11 --> 00:16:17 276 00:16:21 --> 00:16:27 There it goes. 277 00:16:24 --> 00:16:30 Doesn't take very much. 278 00:16:27 --> 00:16:33 So we have brass. 279 00:16:30 --> 00:16:36 And L is 36 centimeters. 280 00:16:33 --> 00:16:39 Delta L would be about one millimeter 281 00:16:37 --> 00:16:43 for a temperature increase of only 150 degrees centigrade, 282 00:16:41 --> 00:16:47 which of course is trivial for us with that blowtorch. 283 00:16:45 --> 00:16:51 It's still hot. 284 00:16:48 --> 00:16:54 I could cool it. 285 00:16:51 --> 00:16:57 I could force it to cool it, 286 00:16:52 --> 00:16:58 and then I could even go below this point. 287 00:16:55 --> 00:17:01 This was our 70 degrees, remember? 288 00:16:57 --> 00:17:03 It was the room temperature. 289 00:16:59 --> 00:17:05 I can cool it with some liquid 290 00:17:01 --> 00:17:07 and see whether I can get it down quickly, 291 00:17:03 --> 00:17:09 and even past this point, which would indicate 292 00:17:06 --> 00:17:12 that it is shorter than it was when the lecture started. 293 00:17:10 --> 00:17:16 294 00:17:13 --> 00:17:19 (air whooshing ) 295 00:17:18 --> 00:17:24 296 00:17:23 --> 00:17:29 You see, it's now shorter. 297 00:17:25 --> 00:17:31 Now, what you're looking at 298 00:17:26 --> 00:17:32 is only something like maybe a millimeter 299 00:17:28 --> 00:17:34 or even a little less. 300 00:17:30 --> 00:17:36 But we amplify it 301 00:17:32 --> 00:17:38 and we show that in a quite convincing way, then. 302 00:17:37 --> 00:17:43 A very important implication-- 303 00:17:40 --> 00:17:46 an application of the expansion of metals-- 304 00:17:44 --> 00:17:50 is what we call bimetals. 305 00:17:47 --> 00:17:53 They're all around you. 306 00:17:51 --> 00:17:57 A bimetal is the following. 307 00:17:54 --> 00:18:00 Say I have a strip here, length L, of Invar. 308 00:18:04 --> 00:18:10 And I have another strip here which is attached to it 309 00:18:09 --> 00:18:15 so that they cannot slip relative to each other, 310 00:18:12 --> 00:18:18 and let this be copper. 311 00:18:16 --> 00:18:22 And suppose I make, just as a working example, 312 00:18:20 --> 00:18:26 I make the thickness of each one of them two millimeters. 313 00:18:27 --> 00:18:33 314 00:18:30 --> 00:18:36 And I'm going to heat it. 315 00:18:33 --> 00:18:39 I'm going to heat it, increase in temperature delta T. 316 00:18:37 --> 00:18:43 I'm not interested really in knowing how long the copper gets 317 00:18:41 --> 00:18:47 and how long the Invar gets, 318 00:18:43 --> 00:18:49 but I'm very interested 319 00:18:44 --> 00:18:50 in knowing the difference in the length between the two. 320 00:18:48 --> 00:18:54 Because what's going to happen 321 00:18:49 --> 00:18:55 when one gets longer than the other, 322 00:18:51 --> 00:18:57 something got to give. 323 00:18:53 --> 00:18:59 What do you think will happen? 324 00:18:54 --> 00:19:00 And they're stuck together, 325 00:18:55 --> 00:19:01 they can't slip relative to each other. 326 00:18:57 --> 00:19:03 What will they do? 327 00:19:01 --> 00:19:07 They will bend. 328 00:19:03 --> 00:19:09 And since the Invar is not going to expand very much, 329 00:19:06 --> 00:19:12 but the copper will, 330 00:19:07 --> 00:19:13 if you heat it up, it will go like this. 331 00:19:12 --> 00:19:18 And we'll see that there are many applications of that. 332 00:19:16 --> 00:19:22 So what I'm interested in is really the delta L of the copper 333 00:19:20 --> 00:19:26 minus the delta L of the Invar. 334 00:19:24 --> 00:19:30 That's what I'm after. 335 00:19:26 --> 00:19:32 And that is the alpha of copper minus alpha of Invar 336 00:19:31 --> 00:19:37 times L times delta T. 337 00:19:36 --> 00:19:42 So it is the difference that matters. 338 00:19:38 --> 00:19:44 So the difference is 17 minus one, 339 00:19:41 --> 00:19:47 so that is 16 times ten to the minus six times L times delta T. 340 00:19:50 --> 00:19:56 And if I take a length of ten centimeters 341 00:19:58 --> 00:20:04 and I increase the temperature by 100 degrees centigrade, 342 00:20:02 --> 00:20:08 then this difference, which you can easily calculate, 343 00:20:06 --> 00:20:12 is .16 millimeters-- 0.16 millimeter. 344 00:20:13 --> 00:20:19 Very little. 345 00:20:15 --> 00:20:21 And yet, this one will curve substantially. 346 00:20:22 --> 00:20:28 For those of you who are mathematically oriented, 347 00:20:26 --> 00:20:32 I would advise you to make an attempt to calculate that. 348 00:20:29 --> 00:20:35 So you have, you assume that it is a perfect circle-- 349 00:20:33 --> 00:20:39 that's a reasonable approximation-- 350 00:20:35 --> 00:20:41 and so you have an outer circle 351 00:20:37 --> 00:20:43 which is longer by .16 millimeters than the inner one, 352 00:20:42 --> 00:20:48 and you try to solve and find what that D is. 353 00:20:45 --> 00:20:51 And I went through that exercise, 354 00:20:47 --> 00:20:53 and you want to do that, too, perhaps, 355 00:20:49 --> 00:20:55 and I found that it's four millimeters 356 00:20:51 --> 00:20:57 for these dimensions. 357 00:20:52 --> 00:20:58 Four millimeters-- that's substantial. 358 00:20:56 --> 00:21:02 So this thing is being used for thermostats. 359 00:20:59 --> 00:21:05 Um... you break and make a contact in a heating system, 360 00:21:05 --> 00:21:11 which could, for instance, be as follows. 361 00:21:09 --> 00:21:15 Here would be your bimetal, very schematically. 362 00:21:13 --> 00:21:19 You plug it in the wall here, your 110 volts. 363 00:21:17 --> 00:21:23 Here is your heater. 364 00:21:19 --> 00:21:25 365 00:21:23 --> 00:21:29 And you let it sit like that, 366 00:21:25 --> 00:21:31 and when it's cold, this is down. 367 00:21:29 --> 00:21:35 It's not curled, and the heater works. 368 00:21:32 --> 00:21:38 And when the room temperature goes up, this starts to curl, 369 00:21:36 --> 00:21:42 it breaks, and that's a thermostat. 370 00:21:39 --> 00:21:45 That is the basic idea behind a thermostat. 371 00:21:41 --> 00:21:47 And you have them in your cars, you have them at home. 372 00:21:43 --> 00:21:49 Your central heating system, air conditioner 373 00:21:47 --> 00:21:53 and your heaters-- they're all over the place. 374 00:21:51 --> 00:21:57 They're also being used for safety devices. 375 00:21:54 --> 00:22:00 If you have a gas hot water heater, in the pilot light, 376 00:21:58 --> 00:22:04 in the flame of the pilot light, is a bimetal. 377 00:22:03 --> 00:22:09 And when that bimetal is hot, your gas valve is open. 378 00:22:07 --> 00:22:13 But when that bimetal gets cold, it shuts off the gas valve, 379 00:22:10 --> 00:22:16 which is a safety device. 380 00:22:12 --> 00:22:18 In fact, in Europe, 381 00:22:13 --> 00:22:19 all gas stoves are protected that way by law. 382 00:22:17 --> 00:22:23 Strangely enough, not in the United States, 383 00:22:19 --> 00:22:25 which is very surprising. 384 00:22:21 --> 00:22:27 If I open my gas valves at home of my stove, 385 00:22:24 --> 00:22:30 the gas will just come out, just like that. 386 00:22:28 --> 00:22:34 There's no prevention of that happening. 387 00:22:30 --> 00:22:36 In Europe, that's not possible. 388 00:22:32 --> 00:22:38 There is always a pilot light somewhere with a bimetal 389 00:22:35 --> 00:22:41 that senses that there is a flame nearby to ignite the gas. 390 00:22:39 --> 00:22:45 And if that flame is out, the gas valve will be closed. 391 00:22:42 --> 00:22:48 So bimetals can also be used very effectively 392 00:22:45 --> 00:22:51 for safety devices. 393 00:22:48 --> 00:22:54 I have here a bimetal. 394 00:22:51 --> 00:22:57 One side I believe, we believe, is aluminum, 395 00:22:54 --> 00:23:00 and the other side we believe is iron. 396 00:22:58 --> 00:23:04 And when I heat that, you will see that it starts to bend. 397 00:23:03 --> 00:23:09 398 00:23:07 --> 00:23:13 (blowtorch hissing ) 399 00:23:10 --> 00:23:16 Here we go. 400 00:23:11 --> 00:23:17 401 00:23:47 --> 00:23:53 I think you get the idea. 402 00:23:49 --> 00:23:55 You could use that as a thermometer-- 403 00:23:51 --> 00:23:57 very crude one, 404 00:23:52 --> 00:23:58 but this is the idea of the thermometer, of course. 405 00:23:56 --> 00:24:02 406 00:24:00 --> 00:24:06 Mark Bessette, who is the person 407 00:24:04 --> 00:24:10 who is preparing always these demonstrations 408 00:24:06 --> 00:24:12 in a fabulous way, 409 00:24:08 --> 00:24:14 told me he had at home a coffee maker. 410 00:24:12 --> 00:24:18 And the coffee maker is designed in such a way 411 00:24:15 --> 00:24:21 that there is a bimetal at the bottom of the water reservoir. 412 00:24:18 --> 00:24:24 You heat up the water reservoir, 413 00:24:21 --> 00:24:27 and when the water heats to a certain temperature, 414 00:24:23 --> 00:24:29 the bimetal opens and the water comes out 415 00:24:25 --> 00:24:31 and it goes through the coffee. 416 00:24:27 --> 00:24:33 I'd like to show that to you-- it's really cute. 417 00:24:29 --> 00:24:35 418 00:24:36 --> 00:24:42 Here is that coffee machine. 419 00:24:38 --> 00:24:44 It's not working anymore, it's a very old one, 420 00:24:40 --> 00:24:46 but I want to show you at least that bimetal. 421 00:24:45 --> 00:24:51 This is that bimetal strip. 422 00:24:47 --> 00:24:53 Water goes in here, you heat it, 423 00:24:49 --> 00:24:55 and when it's hot enough, the bimetal lifts up 424 00:24:54 --> 00:25:00 and you can see there is a hole there. 425 00:24:55 --> 00:25:01 This is the hole. 426 00:24:57 --> 00:25:03 And the water comes out, and when the bimetal is closed, 427 00:24:59 --> 00:25:05 then it closes off that hole. 428 00:25:02 --> 00:25:08 So it's an amazing, simple idea. 429 00:25:04 --> 00:25:10 The criterion for letting the water go through the coffee 430 00:25:07 --> 00:25:13 is simply when the water reaches 431 00:25:09 --> 00:25:15 that temperature close to boiling 432 00:25:11 --> 00:25:17 and you have your bimetal control it. 433 00:25:15 --> 00:25:21 So bimetals in many ways control matters. 434 00:25:19 --> 00:25:25 Thermostats, in this case they act like... like a valve. 435 00:25:24 --> 00:25:30 Bimetals can be used as thermometers. 436 00:25:30 --> 00:25:36 In fact, the one that you see right here 437 00:25:35 --> 00:25:41 is driven exclusively by a bimetal. 438 00:25:40 --> 00:25:46 If you look in the back of this thermometer-- 439 00:25:42 --> 00:25:48 and I will show that to you shortly 440 00:25:44 --> 00:25:50 because I broke one open for you-- 441 00:25:47 --> 00:25:53 then it looks like this. 442 00:25:50 --> 00:25:56 There's a coil. 443 00:25:53 --> 00:25:59 This end of the coil is attached to the plastic casing. 444 00:25:58 --> 00:26:04 And here is the red hand. 445 00:26:02 --> 00:26:08 It's a pivot here-- the red hand. 446 00:26:07 --> 00:26:13 But this is fixed, this cannot move. 447 00:26:10 --> 00:26:16 I heat it up. 448 00:26:11 --> 00:26:17 What will happen when I heat it up? 449 00:26:13 --> 00:26:19 This is already a bimetal, it's already curved. 450 00:26:15 --> 00:26:21 But when I heat it up, it will tighten even more, 451 00:26:17 --> 00:26:23 it will curl up even more. 452 00:26:19 --> 00:26:25 And when this one curls up even more, 453 00:26:21 --> 00:26:27 it will go into this direction. 454 00:26:23 --> 00:26:29 So this is when the temperature increases. 455 00:26:26 --> 00:26:32 And when it, of course, gets colder, it will uncurl, 456 00:26:29 --> 00:26:35 and so here is cold. 457 00:26:32 --> 00:26:38 And that's what the whole thermometer is based upon. 458 00:26:35 --> 00:26:41 And in the back is this coil. 459 00:26:39 --> 00:26:45 And so I broke one open for you 460 00:26:41 --> 00:26:47 in order to make you see that coil. 461 00:26:43 --> 00:26:49 462 00:26:48 --> 00:26:54 Now, I have that here. 463 00:26:49 --> 00:26:55 464 00:26:54 --> 00:27:00 This is the part that is in the back, 465 00:26:57 --> 00:27:03 and this is that bimetal-- the bimetal coil. 466 00:26:59 --> 00:27:05 This is the bottom part, this is the top, 467 00:27:02 --> 00:27:08 and this is just the hand that is attached to it. 468 00:27:05 --> 00:27:11 And then it goes into this case. 469 00:27:09 --> 00:27:15 Let's make sure that the pivot goes in there-- yeah. 470 00:27:16 --> 00:27:22 If I increase the temperature, try to see that. 471 00:27:20 --> 00:27:26 You see the coil tightens up. 472 00:27:23 --> 00:27:29 See, the coil gets tighter. 473 00:27:25 --> 00:27:31 And when I make the temperature go down artificially now 474 00:27:28 --> 00:27:34 by uncurling the coil, it goes in this direction. 475 00:27:33 --> 00:27:39 Now, what we can do is we can actually heat it up. 476 00:27:38 --> 00:27:44 We have to set the temperature at whatever we think it is now. 477 00:27:41 --> 00:27:47 It's about 70 degrees in the room. 478 00:27:43 --> 00:27:49 Is that what it is? 479 00:27:46 --> 00:27:52 Well, that's close enough. 480 00:27:48 --> 00:27:54 This is Fahrenheit-- oh, what a terrible scale. 481 00:27:50 --> 00:27:56 Yeah, by the way, you also see some civilized scale there. 482 00:27:52 --> 00:27:58 You see centigrade in addition to the Fahrenheit. 483 00:27:58 --> 00:28:04 So it's close enough, it's a little bit over 70, 484 00:28:01 --> 00:28:07 and I can now make sure that this is stuck to it, 485 00:28:06 --> 00:28:12 to the case. 486 00:28:08 --> 00:28:14 I can heat it. 487 00:28:09 --> 00:28:15 (motor purring ) 488 00:28:13 --> 00:28:19 489 00:28:20 --> 00:28:26 The bimetal tightens up more. 490 00:28:26 --> 00:28:32 So when I heat it, the bimetal tightens up more, 491 00:28:29 --> 00:28:35 and when I blow air over it, I can actually make it cool 492 00:28:31 --> 00:28:37 a little faster than it will otherwise. 493 00:28:36 --> 00:28:42 (blowing ) 494 00:28:45 --> 00:28:51 So as simple as that. 495 00:28:47 --> 00:28:53 Very simple device with... 496 00:28:50 --> 00:28:56 the bimetals have many, many applications. 497 00:28:54 --> 00:29:00 498 00:29:04 --> 00:29:10 Your thermostats in your dormitories 499 00:29:10 --> 00:29:16 of your heating systems, 500 00:29:12 --> 00:29:18 and also perhaps of the air-conditioning systems, 501 00:29:15 --> 00:29:21 almost all have a coil like this in there. 502 00:29:17 --> 00:29:23 It was an extremely ingenious device. 503 00:29:21 --> 00:29:27 It has a coil, and at the end of the coil is a little glass tube, 504 00:29:26 --> 00:29:32 only one centimeter large, and there is mercury inside. 505 00:29:30 --> 00:29:36 So the coil is like this. 506 00:29:32 --> 00:29:38 507 00:29:35 --> 00:29:41 Bimetal. 508 00:29:37 --> 00:29:43 And at the end here is a glass container 509 00:29:42 --> 00:29:48 and there is some mercury, 510 00:29:43 --> 00:29:49 and the mercury is here on this side, 511 00:29:46 --> 00:29:52 because notice the way I have tilted it a little. 512 00:29:49 --> 00:29:55 The mercury rolls to the left. 513 00:29:52 --> 00:29:58 And there are here two wires, electric wires, 514 00:29:55 --> 00:30:01 one here and one here, which go to the heating system. 515 00:29:59 --> 00:30:05 And so when the mercury is here, which has a good conductivity, 516 00:30:02 --> 00:30:08 the heater is on. 517 00:30:06 --> 00:30:12 Now, the room gets warmer and warmer and warmer 518 00:30:08 --> 00:30:14 and the bimetal will tighten up, will curl even more. 519 00:30:12 --> 00:30:18 And so there comes a time 520 00:30:13 --> 00:30:19 that this glass thing will go like this 521 00:30:17 --> 00:30:23 and the mercury rolls out. 522 00:30:19 --> 00:30:25 And when the mercury rolls out-- here is the mercury-- 523 00:30:24 --> 00:30:30 these contacts here are open, and the heater will stop. 524 00:30:28 --> 00:30:34 And that's in almost every room. 525 00:30:31 --> 00:30:37 Very ingenious device. 526 00:30:33 --> 00:30:39 527 00:30:36 --> 00:30:42 Now I want to move from linear expansion coefficients 528 00:30:41 --> 00:30:47 to cubic expansion coefficients. 529 00:30:44 --> 00:30:50 I will leave these numbers there, 530 00:30:45 --> 00:30:51 because I will need them later on. 531 00:30:50 --> 00:30:56 But now I take a block of some material 532 00:30:53 --> 00:30:59 and want to discuss the volume increase-- not just the length, 533 00:30:57 --> 00:31:03 but the volume increase. 534 00:31:01 --> 00:31:07 So here I have a solid material. 535 00:31:07 --> 00:31:13 Let's make it simple, all sides L. 536 00:31:10 --> 00:31:16 And I increase it by an amount of temperature delta T. 537 00:31:15 --> 00:31:21 Well, the old volume is L cubed, 538 00:31:20 --> 00:31:26 and then I'm going to increase the temperature by delta T, 539 00:31:22 --> 00:31:28 so all these sides will get longer by amount delta L, 540 00:31:26 --> 00:31:32 and so the new volume will be L plus delta L to the power 3. 541 00:31:33 --> 00:31:39 542 00:31:37 --> 00:31:43 This can also be written as L to the third times one 543 00:31:43 --> 00:31:49 plus delta L over L to the power 3. 544 00:31:48 --> 00:31:54 Same thing, right? 545 00:31:51 --> 00:31:57 Now, perhaps you remember, or at least you should remember, 546 00:31:55 --> 00:32:01 that one plus x to the power n, 547 00:32:00 --> 00:32:06 in case that x is much, much smaller than one, 548 00:32:03 --> 00:32:09 is approximately one plus nx. 549 00:32:06 --> 00:32:12 We've used that before when we discussed the Doppler shift-- 550 00:32:09 --> 00:32:15 light from receding stars. 551 00:32:13 --> 00:32:19 This is called the binomial series, binomial expansion. 552 00:32:17 --> 00:32:23 It's really the first order terms of the Taylor expansion. 553 00:32:21 --> 00:32:27 If you, as an example, if you take x equals 0.05 554 00:32:27 --> 00:32:33 and you calculate the exact value with your calculator, 555 00:32:32 --> 00:32:38 you would find 1.158. 556 00:32:35 --> 00:32:41 If you do it this way, you will find 1.15, which is very close. 557 00:32:41 --> 00:32:47 Approximation is better than one percent. 558 00:32:44 --> 00:32:50 So I will use the same approximation here, 559 00:32:47 --> 00:32:53 and so we're going to get L to the third 560 00:32:51 --> 00:32:57 times one plus three delta L divided by L. 561 00:32:59 --> 00:33:05 So that is L to the third plus three delta L, L squared. 562 00:33:10 --> 00:33:16 So the difference in terms of delta V, 563 00:33:15 --> 00:33:21 the old volume was this. 564 00:33:17 --> 00:33:23 And this volume is V plus delta V, 565 00:33:21 --> 00:33:27 so delta V is the difference between the two, 566 00:33:27 --> 00:33:33 is three delta L, L squared. 567 00:33:31 --> 00:33:37 But I know that delta L equals alpha times L times delta T. 568 00:33:38 --> 00:33:44 And so I can substitute that in here, and so I find that delta V 569 00:33:43 --> 00:33:49 equals three alpha times L squared times L-- 570 00:33:49 --> 00:33:55 that is L cubed-- times delta T. 571 00:33:52 --> 00:33:58 But L cubed was the old volume, 572 00:33:55 --> 00:34:01 and so I now find that delta V equals three alpha 573 00:34:00 --> 00:34:06 times the old volume times delta T, 574 00:34:03 --> 00:34:09 and this one is often called beta. 575 00:34:06 --> 00:34:12 Beta is the cubical expansion coefficient, 576 00:34:09 --> 00:34:15 as opposed to the linear one. 577 00:34:12 --> 00:34:18 So you will say, well, big deal. 578 00:34:13 --> 00:34:19 I mean, why are you talking about beta? 579 00:34:15 --> 00:34:21 Because if we have the values for alpha, all we have to do 580 00:34:18 --> 00:34:24 if we go to a volume, to make that beta three alpha, 581 00:34:22 --> 00:34:28 and we are in business. 582 00:34:24 --> 00:34:30 Well, when you have liquids, in general, 583 00:34:27 --> 00:34:33 you don't find in the tables values for alpha. 584 00:34:30 --> 00:34:36 So when you deal with liquids, for instance, mercury, 585 00:34:34 --> 00:34:40 which is the one that I want to use today, 586 00:34:38 --> 00:34:44 then you find that the cubic expansion coefficient 587 00:34:42 --> 00:34:48 is 18 times ten to the minus five per degree centigrade. 588 00:34:49 --> 00:34:55 If I compare that with Pyrex, 589 00:34:54 --> 00:35:00 you have to take three times this value, 590 00:34:56 --> 00:35:02 so that's very roughly ten to the minus five 591 00:35:02 --> 00:35:08 per degree centigrade. 592 00:35:05 --> 00:35:11 And so now you begin to smell the idea 593 00:35:08 --> 00:35:14 of a mercury thermometer. 594 00:35:11 --> 00:35:17 595 00:35:14 --> 00:35:20 I put some mercury in Pyrex glass, 596 00:35:18 --> 00:35:24 and the Pyrex glass is not going to expand very much, 597 00:35:21 --> 00:35:27 but the mercury will. 598 00:35:25 --> 00:35:31 And then the mercury, which is in an enclosed environment, 599 00:35:29 --> 00:35:35 will have to expand, and it expands into my thermometer 600 00:35:34 --> 00:35:40 and that's the way that we read the temperature. 601 00:35:37 --> 00:35:43 602 00:35:41 --> 00:35:47 So here is a glass tube which is very, very narrow. 603 00:35:47 --> 00:35:53 All this is closed here. 604 00:35:49 --> 00:35:55 And let's say the radius here is only 0.1 millimeter. 605 00:35:56 --> 00:36:02 And here is a reservoir, mercury, just a working example, 606 00:36:03 --> 00:36:09 and suppose we take one cubic centimeter-- 607 00:36:07 --> 00:36:13 just simple numbers. 608 00:36:08 --> 00:36:14 Just want to show you the basic idea behind the thermometer. 609 00:36:13 --> 00:36:19 I'm going to increase the temperature of this mercury, 610 00:36:16 --> 00:36:22 say by ten degrees, 611 00:36:19 --> 00:36:25 so delta T, ten degrees centigrade. 612 00:36:24 --> 00:36:30 So by how much will this volume expand? 613 00:36:27 --> 00:36:33 Well, delta V equals beta 18 times ten to the minus fifths 614 00:36:37 --> 00:36:43 times the volume, which is one cubic centimeter-- 615 00:36:39 --> 00:36:45 let me just put the volume in there; 616 00:36:41 --> 00:36:47 you may want to do it in cubic meters-- I leave it up to you-- 617 00:36:44 --> 00:36:50 times the delta T. 618 00:36:47 --> 00:36:53 And you will find 619 00:36:48 --> 00:36:54 that the expansion in terms of cubic centimeters 620 00:36:52 --> 00:36:58 is 0.0018 cubic centimeters. 621 00:36:58 --> 00:37:04 See, if you leave V in cubic centimeters, which you can do, 622 00:37:01 --> 00:37:07 then you get your answer also in cubic centimeters, of course. 623 00:37:04 --> 00:37:10 You do not always work... have to work mks. 624 00:37:09 --> 00:37:15 So this is an extraordinarily small increase 625 00:37:11 --> 00:37:17 in terms of its volume. 626 00:37:13 --> 00:37:19 However, the Pyrex is not expanding at all. 627 00:37:17 --> 00:37:23 You can just forget that for now. 628 00:37:19 --> 00:37:25 If you want to calculate how much it is, it's fine, 629 00:37:21 --> 00:37:27 but it is 18 times less, 630 00:37:24 --> 00:37:30 so the fact that the vessel gets a little larger 631 00:37:26 --> 00:37:32 of course is important, 632 00:37:27 --> 00:37:33 but I will just ignore that for now. 633 00:37:30 --> 00:37:36 And so I will just assume 634 00:37:31 --> 00:37:37 that all this mercury will be driven up here. 635 00:37:35 --> 00:37:41 And so if the mercury, then, changes its height 636 00:37:39 --> 00:37:45 by an amount delta h, 637 00:37:41 --> 00:37:47 and if this is a tube with a radius .1 millimeters, 638 00:37:45 --> 00:37:51 then this amount of mercury 639 00:37:48 --> 00:37:54 must be the same as pi r squared times delta h, 640 00:37:53 --> 00:37:59 which is the volume of the new column-- 641 00:37:56 --> 00:38:02 the increase in the column. 642 00:37:59 --> 00:38:05 And so you take your .1 millimeters and you'll find 643 00:38:04 --> 00:38:10 that delta h for this example that I chose is 5.7 centimeters. 644 00:38:15 --> 00:38:21 That's huge. 645 00:38:17 --> 00:38:23 That's very easy to see. 646 00:38:18 --> 00:38:24 For ten degrees increase in temperature, 647 00:38:22 --> 00:38:28 it's 5.7 centimeters. 648 00:38:24 --> 00:38:30 So for one degree centigrade, you would get six millimeters. 649 00:38:28 --> 00:38:34 It's very easy to see, 650 00:38:29 --> 00:38:35 and so that's the idea behind a mercury thermometer. 651 00:38:37 --> 00:38:43 I have a mercury thermometer here, 652 00:38:40 --> 00:38:46 but they're very hard to read. 653 00:38:44 --> 00:38:50 But I have one here. 654 00:38:46 --> 00:38:52 It's a medical one. 655 00:38:49 --> 00:38:55 It says "oral," 656 00:38:50 --> 00:38:56 not to be confused. 657 00:38:53 --> 00:38:59 And I can stick it in my mouth and measure my temperature 658 00:38:57 --> 00:39:03 using this scale. 659 00:38:59 --> 00:39:05 It's easier for me to show you 660 00:39:01 --> 00:39:07 the one that I have in my office, 661 00:39:04 --> 00:39:10 which also works on liquid. 662 00:39:09 --> 00:39:15 (mumbling ): This one. 663 00:39:10 --> 00:39:16 664 00:39:15 --> 00:39:21 So this one, you see the red liquid? 665 00:39:22 --> 00:39:28 Let me be sure that we have the right light setting. 666 00:39:27 --> 00:39:33 This should go off. 667 00:39:29 --> 00:39:35 Okay. 668 00:39:30 --> 00:39:36 So you see the red liquid. 669 00:39:32 --> 00:39:38 There it is. 670 00:39:35 --> 00:39:41 And also notice that it is degrees Fahrenheit, 671 00:39:39 --> 00:39:45 which is unfortunate. 672 00:39:41 --> 00:39:47 But it's helping. 673 00:39:43 --> 00:39:49 When the temperature is here, 674 00:39:44 --> 00:39:50 at least you know that you're going to get ice. 675 00:39:46 --> 00:39:52 (a few chuckles ) 676 00:39:50 --> 00:39:56 Well, that's somewhere near 32... 32 Fahrenheit. 677 00:39:53 --> 00:39:59 That must be here. 678 00:39:55 --> 00:40:01 Snow. 679 00:39:56 --> 00:40:02 And this makes you feel good-- sun. 680 00:40:00 --> 00:40:06 Yeah. 681 00:40:01 --> 00:40:07 You know, just in case you don't remember. 682 00:40:03 --> 00:40:09 I could heat it up. 683 00:40:05 --> 00:40:11 (blow-dryer humming ) 684 00:40:09 --> 00:40:15 685 00:40:31 --> 00:40:37 You always should be careful when you heat it up 686 00:40:34 --> 00:40:40 that you don't go too far, 687 00:40:35 --> 00:40:41 because the top of the thermometer is closed. 688 00:40:38 --> 00:40:44 In the case of a mercury thermometer, 689 00:40:39 --> 00:40:45 there is vacuum in here, and so if you-- 690 00:40:42 --> 00:40:48 when I was a kid, I loved to do this-- 691 00:40:44 --> 00:40:50 to take the medical thermometer of my parents 692 00:40:46 --> 00:40:52 and heat it up with a hair dryer 693 00:40:48 --> 00:40:54 and then it would just burst through it, 694 00:40:50 --> 00:40:56 it would just break the glass, 695 00:40:51 --> 00:40:57 because the expansion is huge, the force, 696 00:40:53 --> 00:40:59 and it would just pop off. 697 00:40:54 --> 00:41:00 And then I'd put it back and say nothing. 698 00:40:57 --> 00:41:03 And that can happen with this, too. 699 00:40:59 --> 00:41:05 So it doesn't have an opening. 700 00:41:01 --> 00:41:07 It is not open, it's a closed thing, 701 00:41:03 --> 00:41:09 so you've got to be quite careful. 702 00:41:09 --> 00:41:15 There is a technique which is called "shrink fitting," 703 00:41:14 --> 00:41:20 and shrink fitting is the following. 704 00:41:18 --> 00:41:24 705 00:41:19 --> 00:41:25 You have a piece of metal-- 706 00:41:21 --> 00:41:27 let's take just a solid cylinder as a working example-- 707 00:41:26 --> 00:41:32 and you have a ring. 708 00:41:28 --> 00:41:34 The ring could be itself a cylinder. 709 00:41:31 --> 00:41:37 Well, this one, this opening is smaller than this-- 710 00:41:38 --> 00:41:44 just a little smaller-- purposely made that way. 711 00:41:41 --> 00:41:47 Just a little smaller. 712 00:41:42 --> 00:41:48 You heat this one. 713 00:41:44 --> 00:41:50 Expands. 714 00:41:46 --> 00:41:52 And you put it over here, it will fit. 715 00:41:49 --> 00:41:55 And then you let it sit. 716 00:41:50 --> 00:41:56 It cools, and it tightens itself up. 717 00:41:52 --> 00:41:58 That's called shrink fitting, a technique which is often used. 718 00:41:57 --> 00:42:03 I have something to show you here 719 00:41:59 --> 00:42:05 which is the opposite of shrink fitting. 720 00:42:02 --> 00:42:08 I have a ring-- I'll show you shortly on the screen there-- 721 00:42:08 --> 00:42:14 and that's made of brass, 722 00:42:11 --> 00:42:17 and I have a ball which goes through there. 723 00:42:17 --> 00:42:23 Just barely, but it goes through there. 724 00:42:20 --> 00:42:26 And then I will heat up this ball, 725 00:42:22 --> 00:42:28 and then it won't go through there, 726 00:42:24 --> 00:42:30 so it's the reverse, but at least you get the idea. 727 00:42:27 --> 00:42:33 And then if you wait and it cools, 728 00:42:30 --> 00:42:36 when you bring them in contact with each other, 729 00:42:32 --> 00:42:38 this one will cool and this one will get warmer. 730 00:42:35 --> 00:42:41 So you catch two birds with one stone. 731 00:42:38 --> 00:42:44 This one will shrink, 732 00:42:39 --> 00:42:45 and at the same time, this one will become a little larger, 733 00:42:42 --> 00:42:48 and so then clearly it will fall through, 734 00:42:46 --> 00:42:52 and that's the idea. 735 00:42:48 --> 00:42:54 And let's try that. 736 00:42:51 --> 00:42:57 Get the best lighting that we can under the circumstances, 737 00:42:56 --> 00:43:02 and we'll change to... is that it? 738 00:43:02 --> 00:43:08 Yeah, this is the ring. 739 00:43:05 --> 00:43:11 And here is that brass ball. 740 00:43:08 --> 00:43:14 It goes through there quite easily. 741 00:43:13 --> 00:43:19 I'll put it horizontal now. 742 00:43:16 --> 00:43:22 743 00:43:20 --> 00:43:26 And then I will start heating up this ball. 744 00:43:22 --> 00:43:28 (flame whooshing ) 745 00:43:27 --> 00:43:33 Here's the ball. 746 00:43:32 --> 00:43:38 It can't be too close to the ring, 747 00:43:33 --> 00:43:39 because then the ring will also be heated, 748 00:43:37 --> 00:43:43 and then of course if the two have the same temperature, 749 00:43:41 --> 00:43:47 then the ball will still go through. 750 00:43:44 --> 00:43:50 (flame whooshing ) 751 00:43:45 --> 00:43:51 752 00:44:11 --> 00:44:17 Let's see. 753 00:44:14 --> 00:44:20 Now it doesn't want to go through. 754 00:44:16 --> 00:44:22 So we'll leave it like that, and we'll see what happens. 755 00:44:20 --> 00:44:26 So the ring will now expand a little because it gets hotter, 756 00:44:25 --> 00:44:31 and the ball will shrink a little because it gets colder 757 00:44:28 --> 00:44:34 and it shouldn't take too long 758 00:44:30 --> 00:44:36 for the ball to be able to get through. 759 00:44:33 --> 00:44:39 If I heat them both with the torch, 760 00:44:37 --> 00:44:43 then of course they will always be able 761 00:44:39 --> 00:44:45 to go through each other. 762 00:44:45 --> 00:44:51 And there it goes. 763 00:44:49 --> 00:44:55 So if I heat them both... 764 00:44:50 --> 00:44:56 (flame whooshing ) 765 00:44:54 --> 00:45:00 766 00:45:00 --> 00:45:06 ...so they both expand, since it's both brass, 767 00:45:04 --> 00:45:10 there is no differential expansion like with bimetals, 768 00:45:10 --> 00:45:16 then no matter what you do, 769 00:45:14 --> 00:45:20 it will always be able to go through. 770 00:45:18 --> 00:45:24 771 00:45:23 --> 00:45:29 It's only when I... 772 00:45:24 --> 00:45:30 773 00:45:27 --> 00:45:33 ...heat the ball and not the ring 774 00:45:29 --> 00:45:35 that you get the effect that it won't get through. 775 00:45:32 --> 00:45:38 It may actually get through now, still get through. 776 00:45:34 --> 00:45:40 Yeah. 777 00:45:35 --> 00:45:41 778 00:45:39 --> 00:45:45 What I've left out of my discussion with you is water. 779 00:45:44 --> 00:45:50 Why have I not mentioned to you 780 00:45:46 --> 00:45:52 what is the expansion coefficient, 781 00:45:49 --> 00:45:55 the cubical expansion coefficient of water? 782 00:45:51 --> 00:45:57 Water is so important in our lives. 783 00:45:53 --> 00:45:59 Well, there is a reason why I left it out, 784 00:45:55 --> 00:46:01 because there is something very special with water. 785 00:45:59 --> 00:46:05 If you take 20-degree centigrade water and you cool it, 786 00:46:03 --> 00:46:09 it shrinks. 787 00:46:04 --> 00:46:10 Normal behavior. 788 00:46:06 --> 00:46:12 Beta has a positive value. 789 00:46:07 --> 00:46:13 But when you reach four degrees centigrade 790 00:46:10 --> 00:46:16 and you go all the way down to zero, 791 00:46:13 --> 00:46:19 then it doesn't shrink-- it expands. 792 00:46:16 --> 00:46:22 So in that range, 793 00:46:17 --> 00:46:23 from zero degrees centigrade to four degrees centigrade, 794 00:46:20 --> 00:46:26 water has a negative value for beta. 795 00:46:23 --> 00:46:29 When you heat it, it shrinks, 796 00:46:26 --> 00:46:32 and when you cool it, it expands. 797 00:46:28 --> 00:46:34 And that makes water extremely unusual. 798 00:46:32 --> 00:46:38 But it's great for fish, 799 00:46:34 --> 00:46:40 because it means that water of four degrees centigrade 800 00:46:37 --> 00:46:43 has the highest possible density. 801 00:46:40 --> 00:46:46 It's higher density than at 20 degrees, 802 00:46:43 --> 00:46:49 and a higher density than at zero degrees. 803 00:46:46 --> 00:46:52 And so when in the winter the ponds freeze, 804 00:46:50 --> 00:46:56 the highest density water goes to the bottom, 805 00:46:52 --> 00:46:58 and that's why the way... that's the way that fish can survive. 806 00:46:55 --> 00:47:01 Rather than becoming deep-freeze fish right there, they can swim. 807 00:46:59 --> 00:47:05 So most of the pond in the winter, 808 00:47:02 --> 00:47:08 the bottom layers are four degrees centigrade, 809 00:47:05 --> 00:47:11 which is safely from the freezing point. 810 00:47:09 --> 00:47:15 Now, when you melt a solid and it becomes liquid, 811 00:47:13 --> 00:47:19 in almost all cases the liquid expands. 812 00:47:17 --> 00:47:23 Sort of natural. 813 00:47:18 --> 00:47:24 And so the solids sink in the liquids. 814 00:47:21 --> 00:47:27 If you take crystals, they sink in their own liquid. 815 00:47:26 --> 00:47:32 But not water. 816 00:47:27 --> 00:47:33 Water and ice are very anomalous. 817 00:47:30 --> 00:47:36 If you take water at zero degrees and you freeze it 818 00:47:35 --> 00:47:41 and it becomes ice crystals, it expands. 819 00:47:39 --> 00:47:45 And the expansion is enormous, 820 00:47:41 --> 00:47:47 because the density of ice is eight percent lower 821 00:47:45 --> 00:47:51 than the density of water. 822 00:47:47 --> 00:47:53 The density of ice is 0.92 grams per cubic centimeter, 823 00:47:50 --> 00:47:56 and water per definition is one. 824 00:47:52 --> 00:47:58 This is why pipes can burst in the winter when they freeze. 825 00:47:58 --> 00:48:04 The pipes freeze, 826 00:47:59 --> 00:48:05 people have water pipes near the outside walls. 827 00:48:02 --> 00:48:08 They cool, they freeze, the pipes burst, 828 00:48:04 --> 00:48:10 because the ice expands. 829 00:48:06 --> 00:48:12 They're not aware of that, 830 00:48:07 --> 00:48:13 and in the spring when the water melts, when the ice melts, 831 00:48:11 --> 00:48:17 all of a sudden-- they have a flood because the pipe burst. 832 00:48:15 --> 00:48:21 This is why theTitanic sank. 833 00:48:17 --> 00:48:23 Because ice floats on water. 834 00:48:20 --> 00:48:26 Ice has a lower density. 835 00:48:22 --> 00:48:28 Without ice floating, no icebergs. 836 00:48:26 --> 00:48:32 This is why you can skate on ponds, 837 00:48:29 --> 00:48:35 because ice has a lower density than water, 838 00:48:32 --> 00:48:38 so ice floats on water. 839 00:48:35 --> 00:48:41 The best way that I can demonstrate to you 840 00:48:37 --> 00:48:43 that ice floats is to treat myself 841 00:48:40 --> 00:48:46 and give myself a glass of something. 842 00:48:43 --> 00:48:49 Today it will be apple cider. 843 00:48:47 --> 00:48:53 And I have here some ice cubes. 844 00:48:50 --> 00:48:56 And I put some ice cubes in here, and they float. 845 00:48:53 --> 00:48:59 And if you don't believe it, come and take a look. 846 00:48:57 --> 00:49:03 Okay, enjoy your weekend. 847 00:48:59 --> 00:49:05 Oh, no, we still have a lecture on Friday. 848 00:49:01 --> 00:49:07 See you then. 849 00:49:03 --> 00:49:09 850 00:49:06 --> 00:49:12