Session Overview
| Modules | Solid Solutions |
| Concepts | introduction to phase diagrams, basic definitions of phase, component, and equilibrium, one-component phase diagrams |
| Keywords | stability, pressure, temperature, vapor, liquid, solid, phase, equilibrium, component, triple point, melting, boiling, glass transition temperature, polymorph, sublimation, supercritical |
| Chemical Substances | water (H2O), zirconia (ZrO2), snowflake obsidian, aluminum (Al), silicon (Si), carbon dioxide (CO2), nitrogen (N), bismuth (Bi), sulfur (S), oxygen (O), argon (Ar), "dry ice", carbon (C), mercury (Hg) |
| Applications | failure analysis, cooking food at altitude and in pressure cooker, automobile engine cooling, ice skating, artificial diamonds, coffee decaffeination |
Prerequisites
Before starting this session, you should be familiar with:
- The Bonding and Molecules module, in particular Session 12: Intermolecular Forces
Looking Ahead
This is the first of three sessions on solid solutions and phase diagrams. Proceed to the next session, Session 34.
Learning Objectives
After completing this session, you should be able to:
- Summarize the purpose of a phase diagram.
- Give a detailed interpretation of the phase diagram of water.
- Given a set of material properties data, draw the phase diagram.
- Given a phase diagram, describe some properties of the material, e.g. the relative densities of its solid and liquid forms.
Reading
Archived Lecture Notes #10 (PDF), Part A
| Book Chapters | Topics |
|---|---|
| [Saylor] 11.6, "Critical Temperature and Pressure." | Supercritical fluids; molten salts and ionic liquids |
| [Saylor] 11.7, "Phase Diagrams." | General features of phase diagrams; phase diagrams of water and carbon dioxide |
Lecture Video
> Download from iTunes U (MP4 - 218MB)
> Download from Internet Archive (MP4 - 218MB)
Resources
Lecture Summary
Phase stability is the basis for the solid state of matter. Knowledge of phase stability enables applications like:
- conducting failure analysis -- recognizing phase "signatures" in the material
- cooking at altitude -- adapting to different pressure/temperature relationships
- automobile engine cooling -- exploiting pressure and chemical composition to control the coolant's boiling point (a phase transition temperature)
Prof. Sadoway introduces phase diagrams as "stability maps" and "archives of pressure/temperature relationships."
This lecture defines and gives examples of phase, one phase and two phase systems, equilibrium, component, and triple point. A detailed discussion of the most familiar one phase system, water, is followed by comparisons of the phase diagrams of aluminum and silicon.
Prof. Sadoway does some live demonstrations for the class:
- various objects are immersed in liquid nitrogen, going below their glass transition temperature
- properties of liquid oxygen
- sublimation of solid frozen CO2, aka 'dry ice'
The phase diagram of zirconia illustrates the concept of changing a material's composition to produce desired behaviors at particular temperature/pressure conditions. The phase diagram of carbon illustrates how artificial diamonds are made. Bisumth and sulfur phase diagrams – "phase diagrams from hell" – have many regions. Returning to water, Prof. Sadoway discusses the unusual phases of ice at very high pressures and very low temperatures.
As a final application note, the lecture ends with a quick summary of coffee decaffeination as a process employing sophisticated manipulation of phase transitions.
Homework
More phase diagram homework problems will be provided for the next two sessions.
For Further Study
Culture
Queen. "'Under Pressure' (Live at Wembley)." June 16, 2009. YouTube. Accessed November 18, 2010. http://www.youtube.com/watch?v=SJCTgtDU-74.
Alexander Calder, Mercury Fountain, 1937. Fundació Joan Miró. Barcelona, Spain.
Other OCW and OER Content
| Content | Provider | Level | Notes |
|---|---|---|---|
| 3.012 Fundamentals of Material Science | MIT OpenCourseWare | Undergraduate (second-year) | See Thermodynamics lectures 15-16 on single-component phase diagrams, plus associated recitation and assignment content |